Bismarck Sea Research Articles

A new insular species of Gehyra (Squamata: Gekkonidae) from Papua New Guinea closely related to Gehyra oceanica

The wide-ranging gecko Gehyra oceanica occupies numerous islands across much of the Pacific Ocean basin. Previous work has identified six divergent genetic lineages within lizards assigned to this species. During an expedition to islands off of northern New Guinea we collected lizards of this complex on Crown Island that differ from all other known Gehyra in being sexually dimorphic in colour pattern. We find this population to also be genetically divergent to the other lineages previously identified, as we do with another lineage of populations from nearby islands. Given the unique colour pattern of the Crown Island population, combined with its divergent range of precloacal-femoral pores in males and its phylogenetic uniqueness from other members of this complex, we describe this population as a new species, Gehyra corona sp. nov. currently known only from Crown Island, Papua New Guinea. The discovery of this new species and an additional divergent genetic lineage from within the G. oceanica complex highlights the need for further taxonomic revision of that species complex. It seems likely that the new species we identify will prove endemic to Crown Island, but additional islands from around the Bismarck Sea need survey to establish its full range. Given the undisturbed habitat on most of Crown Island and the low human population there, we suggest that this species’ IUCN Red List conservation status be Least Concern. http://zoobank.org/urn:lsid:zoobank.org:pub:299432A3-6AC1-408D-9CCD-ECCB054A78FF

Additional Sarasinosides from the Marine Sponge Melophlus sarasinorum Collected from the Bismarck Sea.

In our continuing efforts to describe the biological and chemical diversity of sponges from Kimbe Bay, Papua New Guinea, the known 30-norlanostane saponin sarasinoside C1 (1) was identified along with six new analogues named sarasinosides C4, C5, C6, C7, C8, and C9 (2-7) from the sponge Melophlus sarasinorum. The structures of the new compounds were elucidated by analysis of 1D and 2D NMR and HRMS data, as well as comparison with literature data. All new compounds are characterized by the same tetraose moiety, β-d-Xylp-(1→6)-β-d-GlcNAcp-(1→2)-[β-d-GalNAcp-(1→4)]-β-d-Xylp, as described previously for sarasinoside C1, but differed in their aglycone moieties. When comparing NMR data of sarasinoside C8 with those of known analogues, a misassignment was identified in the configuration of the C-8/C-9 diol for the previously described sarasinoside R (8), and it has been corrected here using a combination of ROESY analysis and molecular modeling.

Lobophora dispersa (Dictyotaceae: Phaeophyceae), a new record for the coast of Veracruz and insights into Lobophora genetic differentiation in the Gulf of Mexico and the Caribbean Sea

Species of Lobophora (Dictyotales) are distributed throughout the sub-tropical and tropical seas worldwide. Recent analyses have revealed high species diversity in regions previously presumed to host only a single species, such as the Bismarck Sea, Eastern Pacific, Western Atlantic, Mediterranean Sea, and Greater Caribbean. Here, samples from Veracruz and Quintana Roo, Mexico, were collected, and 2 genetic markers (cox3 and psbA) were sequenced. The results confirmed the presence of L. dispersa and L. variegata. Lobophora dispersa is recorded for the first time on the Mexican coast. The distribution of its cox3 haplotypes shows genetic differentiation within the Greater Caribbean and Gulf of Mexico, possibly indicating limited dispersal and isolation by distance. Lobophora variegata exhibits lower genetic variability compared to L. dispersa, but its haplotypes did not show any obvious pattern. Lobophora declerckii, previously reported in the “Anegada de Afuera” reef, Veracruz, was not found, possibly due to its affinity to subtidal depths. Morphologically, L. dispersa and L. variegata align with previous descriptions, although we observed more variation in thallus cell thickness in L. dispersa. However, relying solely on morphological characters is insufficient to confidently identify the species, necessitating further sampling to determine the species diversity in Mexico.

Mark Lardas, B-25 Mitchell vs. Japanese Destroyer. Battle of the Bismarck Sea 1943 by Robert L. Shoop

Mark Lardas, B-25 Mitchell vs. Japanese Destroyer. Battle of the Bismarck Sea 1943 by Robert L. Shoop

Papua New Guinea Moho inversion based on XGM 2019e gravity field model

The construction of the high-resolution Moho depth model is significant for studying the characteristics of the complex tectonic movement (seafloor spreading, plate subduction phenomena) in Papua New Guinea. We calculate the region’s Moho relief and lithosphere thinning factor using the XGM 2019e gravity field model and nonlinear fast gravity inversion method under the GEMMA Moho depth model’s constraint considering the influence of lithosphere thermal gravity anomaly. The calculation result shows that the Moho depth is between 6—34 km, forming two large depressions in Woodlark Basin (WB) and Solomon Sea Plate (SSP) with deep scattered islands. In addition, the findings suggest that Significant differences exist in the shape and tectonic movement intensity of the North and South oceanic crust at the WB. Nevertheless, the lithosphere extends evenly in Manus Basin (MB). WB collided with the Solomon Islands at a higher angle than the SSP subducted under Bismarck Sea Plate (BSP); strong earthquakes may frequently occur on both sides and in deeper positions at West New Britain Trench in the future.

Obliquity-driven subtropical forcing of the thermocline after 240 ka in the southern sector of the Western Pacific Warm Pool

Changes in vertical geochemical gradients within the Western Pacific Warm Pool (WPWP) are important indicators of the region's upper ocean response to climate changes and to the oceanographic coupling between the thermocline and surface mixed layer. Here, we reconstruct temperature and δ18Osw at International Ocean Discovery Program Site U1486 (1332 m water depth, 2°22′S, 144°36′E) located in the Bismarck Sea in the southern sector of the WPWP. A 670-kyr record of Δδ18O between the surface-dwelling foraminifera Globigerinoides ruber sensu stricto and the thermocline-dwelling foraminifera Pulleniatina obliquiloculata and Globorotalia tumida (when combined with Mg/Ca-based temperature and δ18Osw estimates) suggests long-term thermocline shoaling and a progressively increasing vertical salinity gradient commencing near 240 ka. Through a detailed comparison to other Pacific records, it becomes clear this is not solely a local phenomenon, as we identify widespread cooling of the thermocline in the low-latitude Pacific after ∼240 ka. After examining our temperature reconstructions alongside new δ18Osw and constant flux proxy-derived focusing factor records, we potentially also validate previous models which find obliquity-induced strengthening of low-latitude Pacific currents. We extend this to support periods of increased transport of high-salinity thermocline water masses through the South Pacific low-latitude western boundary current system. These results indicate greater variability in thermocline circulation given amplified obliquity and strengthen previous evidence that variability in the WPWP thermocline is independent from the drivers of WPWP surface variability.

Equatorial Pacific bulk sediment δ15N supports a secular increase in Southern Ocean nitrate utilization after the mid-Pleistocene Transition

In much of the equatorial Pacific, surface nitrate is consistently available due to upwelling of sub-Antarctic Mode Water-derived nitrate from the thermocline. However, in the low-latitude western boundary current (WBC) region, surface nitrate is limited due to reduced upwelling and less nitrate-replete thermocline water masses. In order to explore South Pacific WBC paleoceanography via upper ocean nitrate dynamics, we present a new bulk sediment δ15N record from within this WBC region at International Ocean Discovery Program Site U1486 (2°22′S, 144°36′E) in the Bismarck Sea north of New Guinea. This record spans from 1420 ka to recent – surpassing nearby sediment δ15N reconstructions by over a million years and allowing for direct comparison to low-latitude Pacific sediment core δ15N records of similar length. Core-top and down-core bulk sediment δ15N, TOC/TN and δ13Corg values indicate minimal or no terrestrial influence on the organic fraction at Site U1486, which is consistent with previous studies of modern processes in the region. After comparison, differences in orbital variability and secular trends throughout the Middle and Late Pleistocene suggest that nitrate dynamics along the equator and in the WBCs were relatively disparate. We observe that δ15N at Site U1486 is consistent with patterns of eastern Pacific denitrification, while we suggest increasing δ15N after the mid-Pleistocene Transition (MPT; ∼1250–700 ka) at Sites 806 (0°19′N, 110°30′W) and 849 (0°19′N, 160°E) is linked to increasing Southern Ocean nitrate utilization. Enhanced nitrate utilization is a key indicator of the strengthened biological pump that contributed to a reduction in atmospheric pCO2 during the last glacial. Therefore, a post-MPT increase in nitrate utilization may bolster the role of the Southern Ocean biological pump in driving the deeper and longer glacial periods of the 100-kyr world.

‘Walking along with development’: Climate resilient pathways for political resource curses

Adaptation pathways are decision-making processes which sequence actions over time to account for rapid change and future uncertainty. In developing economies pathways practice can guide climate-resilient development (CRD) but is hampered by complex political dynamics, intensified by ‘resource curses’ of abundant natural resources. We tested an adaptation pathways approach for large-scale natural resource development in Papua New Guinea’s Bismarck Sea. We engaged with five contested development proposals for deep sea mining, oil palm and tourism to integrate CRD principles into decision-making. The process involved three steps: mapping decision-making and power, participatory pathways planning, and evaluation and learning. CRD-relevant information was fed into decision-making about the proposals. ‘Political spaces’ were created through participatory planning that levelled power asymmetries, enabled common interests to emerge, democratised knowledge co-production, enhanced networks and coordination, and galvanised collective action to re-design the proposals with CRD considerations. The common political interests formed leverage points for conflict transformation and collaboration. Evaluation revealed the suspension of an oil palm development to allow a landuse plan to be formulated to account for food security, conservation and climate adaptation. The study highlighted three learnings: the importance of analysing politics and power in decision-making and identifying leverage points; the challenges for researchers wishing to create political spaces; and the necessity for capacity-building amongst local knowledge brokers to continue this role. We conclude by assessing the feasibility of mainstreaming this approach into decision-making in resource curses, dubbed by one decision-maker as ‘walking along with development’.

Cetaceans of the Northern Bismarck Sea, Papua New Guinea1

There is little known about cetaceans in the waters of Papua New Guinea (PNG). Here we present findings from the first two sets of cetacean sighting and acoustic surveys conducted within the Admiralty Island group in the northern Bismarck Sea. More than 1,000 cetaceans were sighted during our boat-based surveys–the most common being spinner dolphins (Stenella longirostris), followed by pantropical spotted dolphins (Stenella attenuata), short-finned pilot whales (Globicephala macrorhynchus), and sperm whales (Physeter macrocephalus). The relative group size of spinner dolphins was different between years with group sizes in 2010 being significantly lower (median = 15, range = 2–50) than those recorded in 2013 (median = 50, range = 5–100). The presence of large aggregations of spinner dolphins (including calves) as well as sightings of Vulnerable sperm whales suggest the northern Bismarck Sea as an area of conservation importance for cetaceans. Our surveys also provide useful baseline data for a variety of marine protected area planning processes and management initiatives that are ongoing in PNG.

Seismic reconstruction of seafloor sediment deformation during volcanic debris avalanche emplacement offshore Sakar, Papua New Guinea

Volcanic island sector collapses have produced some of the most voluminous mass movements on Earth and have the potential to trigger devastating tsunamis. In the marine environment, landslide deposits offshore the flanks of volcanic islands often consist of a mixture of volcanic material and incorporated seafloor sediments. The interaction of the initial volcanic failure and the substrate can be highly complex and have an impact on both the total landslide deposit volume and its emplacement velocity, which are important parameters during tsunami generation and need to be correctly assessed in numerical landslide-tsunami simulations. Here, we present a 2D seismic analysis of two previously unknown, overlapping volcanic landslide deposits north-west of the island of Sakar (Papua New Guinea) in the Bismarck Sea. The deposits are separated by a package of well-stratified sediment. Despite both originating from the same source, with the same broad movement direction, and having similar deposit volumes (~15.5–26 km3), the interaction of these landslides with the seafloor is markedly different. High-resolution seismic reflection data show that the lower, older deposit comprises a proximal, chaotic, volcanic debris avalanche component and a distal, frontally confined component of deformed pre-existing well-bedded seafloor sediment. We infer that deformation of the seafloor sediment unit was caused by interaction of the initial volcanic debris avalanche with the substrate. The deformed sediment unit shows various compressional structures, including thrusting and folding, over a downslope distance of more than 20 km, generating >27% of shortening over a 5 km distance at the deposit's toe. The volume of the deformed sediments is almost the same as the driving debris avalanche deposit. In contrast, the upper, younger landslide deposit does not show evidence for substrate incorporation or deformation. Instead, the landslide is a structurally simpler deposit, formed by a debris avalanche that spread freely along the contemporaneous seafloor (i.e., the top boundary of the intervening sediment unit that now separates this younger landslide from the older deposit). Our observations show that the physical characteristics of the substrate on which a landslide is emplaced control the amount of seafloor incorporation, the potential for secondary seafloor failure, and the total landslide runout far more than the nature of the original slide material or other characteristics of the source region. Our results indicate the importance of accounting for substrate interaction when evaluating submarine landslide deposits, which is often only evident from internal imaging rather than surface morphological features. If substrate incorporation or deformation is extensive, then treating landslide deposits as a single entity substantially overestimates the volume of the initial failure, which is much more important for tsunami generation than secondary sediment failure.

Integrative taxonomy reveals a rare and new cusk-eel species of Luciobrotula (Teleostei, Ophidiidae) from the Solomon Sea, West Pacific

With six valid species, Luciobrotula is a small genus of the family Ophidiidae, commonly known as cusk-eels. They are benthopelagic fishes occurring at depths ranging from 115–2300 m in the Atlantic, Indian, and Pacific Oceans. Among them, Luciobrotula bartschi is the only known species in the West Pacific. Three specimens of Luciobrotula were collected from the Philippine Sea, Bismarck Sea, and Solomon Sea in the West Pacific during the AURORA, PAPUA NIUGINI, and MADEEP expeditions under the Tropical Deep-Sea Benthos program, and all of them were initially identified as L. bartschi. Subsequent examination with integrative taxonomy indicates that they belong to two distinct species, with the specimen collected from the Solomon Sea representing a new species, which is described here. In terms of morphology, Luciobrotula polylepis sp. nov. differs from its congeners by having a relatively longer lateral line (end of the lateral line below the 33rd dorsal-fin ray) and fewer vertebrae (abdominal vertebrae 13, total vertebrae 50). In the inferred COI gene tree, the two western Pacific species of Luciobrotula do not form a monophyletic group. The genetic K2P distance between the two species is 13.8% on average at the COI locus.

Deep pacific circulation: New insights on pathways through the Solomon Sea

In the South Pacific Ocean, upper and lower Circumpolar Deep Water (UCDW and LCDW, respectively) occupy the deep layers; however, the presence and fate of these two water masses in the western equatorial Pacific have been mostly based on sparse measurements in both space and time. In this study, unprecedented deep measurements from three cruises conducted in the Solomon Sea region along with the World Ocean Database 2018 are examined to better characterize the properties and pathways of deep water in the Southwest Pacific. At depths encompassing most of UCDW, estimated transports derived from two inverse model solutions indicate interbasin exchanges between the Solomon Sea Basin and the Coral Sea Basin to the south, and the East Caroline Basin to the north. The deep water transport variability found across the Solomon Sea is consistent with observed water mass modifications due, for the most part, to diapycnal mixing. At depths greater than about 2600 m, deep water inflow into the Solomon Sea Basin is limited to the south, emanating from the Coral Sea remote basins via complex trench topography. Spreading of LCDW in the Coral Sea and subsequently into the Solomon Sea is blocked by the Tonga-Kermadec Ridge to the east and bottom topography to the south, however, the densest part of UCDW entering both the Coral and Solomon Seas is likely influenced by LCDW properties, as oxygen is found to increase and silicate decrease with depth in the region. Waters trapped in closed deep basins, in the Bismarck Sea below 1750 m and the northern Solomon Sea below 3500 m show a remarkably constant pattern in oxygen with depth.

Depth Profiling Investigation of Seawater Using Combined Multi-Optical Spectrometry.

Depth profiling investigation plays an important role in studying the dynamic processes of the ocean. In this paper, a newly developed hyphenated underwater system based on multi-optical spectrometry is introduced and used to measure seawater spectra at different depths with the aid of a remotely operated vehicle (ROV). The hyphenated system consists of two independent compact deep-sea spectral instruments, a deep ocean compact autonomous Raman spectrometer and a compact underwater laser-induced breakdown spectroscopy system for sea applications (LIBSea). The former was used to take both Raman scattering and fluorescence of seawater, and the LIBS signal could be recorded with the LIBSea. The first sea trial of the developed system was taken place in the Bismarck Sea, Papua New Guinea, in June 2015. Over 4000 multi-optical spectra had been captured up to the diving depth about 1800 m at maximum. The depth profiles of some ocean parameters were extracted from the captured joint Raman-fluorescence and LIBS spectra with a depth resolution of 1 m. The concentrations of and the water temperatures were measured using Raman spectra. The fluorescence intensities from both colored dissolved organic matter (CDOM) and chlorophyll were found to be varied in the euphotic zone. With LIBS spectra, the depth profiles of metallic elements were also obtained. The normalized intensity of atomic line Ca(I) extracted from LIBS spectra raised around the depth of 1600 m, similar to the depth profile of CDOM. This phenomenon might be caused by the nonbuoyant hydrothermal plumes. It is worth mentioning that this is the first time Raman and LIBS spectroscopy have been applied simultaneously to the deep-sea in situ investigations.

Cuttability and drillability studies towards predicting performance of mechanical miners excavating in hyperbaric conditions of deep seafloor mining

The research program outlined in this paper starts with the assumption that if there is a significant relationship between drilling and cutting specific energies in atmospheric conditions, there would also be a significant relationship between these variables in hyperbaric conditions. Five “model rock samples” having uniaxial compressive strength varying from 9 to 160 MPa were subjected to full-scale laboratory drilling tests with polycrystalline diamond compact (PDC) drill bits and a core drill, as well as laboratory full- and small-scale linear cutting tests with a conical and chisel cutter in atmospheric conditions. As a result, significant correlations between drilling and cutting specific energies were found for atmospheric conditions of laboratory. PDC drill bits and core drill bit used in laboratory tests were also used in the subsea drilling operations under hyperbaric conditions in Bismarck Sea. The conical cutter used in the laboratory tests are intended to be used on mechanical miners for subsea metal production. Core samples taken from Bismarck undersea mineral deposits were also subjected to physical and mechanical property tests in the deck and separately in the laboratories of Istanbul Technical University; and small-scale linear cutting tests were also applied in the university. Significant correlations were also found between the results of small- and full-scale cutting test. It is concluded that the capabilities of in-situ measurements will permit to detect some physical and mechanical properties of undersea mineral deposits. These properties interpreted with laboratory drilling and cutting tests would serve a basis to predict performance of mechanical miners to be used in hyperbaric conditions.

Performing \u2018blue degrowth\u2019: critiquing seabed mining in Papua New Guinea through creative practice

Scripted as a sustainable alternative to terrestrial mining, the licence for the world’s first commercial deep-sea mining (DSM) site was issued in Papua New Guinea in 2011 to extract copper and gold from a deposit situated 1600 m below the surface of the Bismarck Sea. Whilst DSM’s proponents locate it as emergent part of a blue economy narrative, its critics point to the ecological and economic uncertainty that characterises the proposed practice. Yet, due its extreme geography, DSM is also profoundly elusive to direct human experience and thus presents a challenge to forms of resistance against an industry extolled as having ‘no human impact’. Against this background, this paper analyses the ways in which ‘blue degrowth’—as a distinct form of counter-narrative—might be ‘performed’, and which imagined (and alternative) geographies are invoked accordingly. To do this it critically reflects upon 2 years of participatory research in the Duke of York Islands focusing on three, community-developed methods of resisting DSM. Practices of counter mapping, sculpture and participatory drama all sought to ‘perform’ the deep-ocean environment imagined as relational whilst simultaneously questioning the very notion of ‘economy’ central to the discourse of ‘blue growth’.

Shark longline fishery of Papua New Guinea: size and species composition and spatial variation of the catches

This study provides the first detailed investigation of the catches of the shark longline fishery in Papua New Guinea. Fisheries observers collected data on shark catches from a total of 318 longline sets between May and June 2014, before its closure in July 2014. In all, 14694 sharks were recorded with a total estimated biomass of 439 tonnes (Mg). Eighteen species of sharks were recorded in the observer data, with the most dominant species being Carcharhinus falciformis, which constituted more than 90% of the total catches by both weight and number of individuals. The level of observer misidentification was low (<10%), which reflected the use of region-specific identification guides by well-trained fisheries observers. The most diverse catches were in the Solomon Sea area, whereas catches in most other areas, particularly the Bismarck Sea areas, were less diverse and more strongly dominated by C. falciformis. Size and sex ratios varied by species, highlighting the importance of obtaining species-level information from the fishery being investigated. Any consideration by fisheries managers to reopen this fishery needs to consider the effect this will have on the species targeted and the livelihoods of coastal fishers who also rely on the same resources.

Origin of Cu in the PACMANUS hydrothermal field from the eastern Manus back-arc basin: evidence from mass balance modeling

Hydrothermal precipitates associated with active vents in the eastern Manus Basin, an actively opening back-arc basin in the Bismarck Sea, Papua New Guinea, are among the most Cu-rich on the modern seafloor. The volcanic rocks associated with this mineralization may be insufficiently enriched in Cu to account for the Cu content of the sulfides by simple leaching. The PACMANUS hydrothermal field lies in the eastern portion of the eastern Manus Basin. Mass balance modeling of the PACMANUS hydrothermal system indicates that simple leaching of a stationary reaction zone (0.144 km3) by hydrothermal fluids cannot yield the Cu found in associated sulfide deposits because unacceptably high leaching, transportation and precipitation efficiencies are required to derive the Cu in sulfides by leaching processes. With 100% leaching, transport and precipitating efficiency, 0.166 km3 of volcanic rocks would need to be leached to account for the Cu budget of hydrothermal sulfide deposits. The key requirement for forming metal-rich magmatic fluids is a large amount of metals available to enter the exsolved vapor phase. Magmas generated in the eastern Manus Basin inherently have high fO2 because of metasomatism of the mantle source by oxidized materials from the subducted slab, leading to copper enrichment in the magma chamber. Moreover, the presence of Cu in gas-rich melt inclusi on bubbles in Pual Ridge andesite is evidence that degassing and partitioning of Cu into the magmatic volatile phase has occurred in the eastern Manus Basin. Numerical mass balance modeling indicates that approximately 0.236 Mt Cu was potentially transferred to the hydrothermal system per cubic kilometer magma. Magmatic degassing seems to play a more significant role than leaching.

Re-description of type material of Xenia Lamarck, 1816 (Octocorallia: Xeniidae).

In this study we examined the original types of 21 of the 56 morphospecies of Xenia currently listed in WoRMS. Unfortunately, our attempts to locate additional type material failed, and we conclude that they have been lost. The type localities of the material examined include the Red Sea, West and Central Indian Ocean, the South Pacific, Indonesia, The Philippines, and the Bismarck Sea, reflecting the extensive biogeographical distribution of this genus throughout the Indo-Pacific Ocean. A neotype was designated from the northern Red Sea for X. umbellata, and sequencing established its position in the phylogenetic tree in relation to other genera of the family Xeniidae. In addition, X. flexibilis n. sp. was described from The Philippines. The findings from the current study led to the synonymizing of X. actuosa with X. sansibariana and of X. plicata with X. blumi. Overall, the study has re-described the types of 17 species considered to be valid based on morphological characters. Validation of the morphological features of original type material along with species-diagnostic genetic characters are required in order to facilitate our ability to correctly employ Latin binomials, both in phylogenetic studies and in any other biological surveys.

Advection without compounding errors through flow map composition

We propose a novel numerical methodology to compute the advective transport and diffusion-reaction of tracer quantities. The tracer advection occurs through flow map composition and is super-accurate, yielding numerical solutions almost devoid of compounding numerical errors, while allowing for direct parallelization in the temporal direction. It is computed by implicitly solving the characteristic evolution through a modified transport partial differential equation and domain decomposition in the temporal direction, followed by composition with the known initial condition. This advection scheme allows a rigorous computation of the spatial and temporal error bounds, yields an accuracy comparable to that of Lagrangian methods, and maintains the advantages of Eulerian schemes. We further show that there exists an optimal value of the composition timestep that yields the minimum total numerical error in the computations, and derive the expression for this value. We develop schemes for the addition of tracer diffusion, reaction, and source terms, and for the implementation of boundary conditions. Finally, the methodology is applied in three flow examples, namely an analytical reversible swirl flow, an idealized flow exiting a strait undergoing sudden expansion, and a realistic ocean flow in the Bismarck sea. New benchmark problems for advection-diffusion-reaction schemes are developed and used to compare and contrast results with those of classic schemes. The results highlight the theoretical properties of the methodology as well as its efficiency, super-accuracy with minimal numerical errors, and applicability in realistic simulations.

Geochemistry of hot-springs at the SuSu Knolls hydrothermal field, Eastern Manus Basin: Advanced argillic alteration and vent fluid acidity

Abstract SuSu Knolls is an area of ongoing magmatic activity and recent volcanism located in the back-arc spreading environment of the Manus Basin in the Bismarck Sea, Papua New Guinea. In 2006, hydrothermal fluids were collected from three areas of submarine hot-spring venting and analyzed for the chemical and isotopic composition of major and trace species. Fluids were characterized by temperatures that varied from 226–325 °C, and formed grey to black smoke as they mixed with bottom seawater. The compositions of seawater derived vent fluids are regulated by the relative contributions of fluid-rock and fluid-sediment interaction, phase separation, and the addition of volatiles from magmatic degassing. In addition to phase separation, leaching of Cl from felsic rocks that compose the lithosphere in back-arc environments may produce Cl concentrations in excess of seawater values. The measured pH25°C of SuSu Knolls smoker fluids varied from 1.5–3.7, a range that includes values substantially more acidic than typically observed in fluids at mid-ocean ridge spreading centers. Late stage addition of magmatic volatiles in the shallow seafloor is directly responsible for the most acidic fluids (pH25°C values below 2). In contrast, the acidity of vent fluids characterized by pH25°C values between 2 and 3 is not the direct result of the direct addition of magmatically-derived acidic species. Instead, the pH of these fluids likely reflects reaction with rocks that were previously altered by highly acidic magmatic fluids to an advanced argillic alteration assemblage containing quartz-illite-pyrophyllite-anhydrite ± alunite in hydrothermal upflow zones. Fluids that do not react with advanced argillic alteration assemblages during upflow have measured pH25°C values between 3 and 4.