Rb-Sr Biotite Research Articles

The Holleford structure: Insights into the pre- and post-impact geology of the Frontenac Terrane, Canada

A multi-chronometric investigation has been conducted on the ∼2.0-km-diameter Holleford impact structure of Ontario, Canada. In situ triple quadrupole laser ablation−inductively coupled−mass spectrometry U-Pb and Rb-Sr geochronology, along with (U-Th)/He thermochronology, have been applied to multiple mineral phases from impact melt-bearing breccias and overlying sedimentary units. Impact-induced resetting is absent in all three isotopic systems. While Holleford’s small size resulted in insufficient heating to reset geochronometers during impact, our investigation has defined a more detailed pre- and post-impact geologic setting within the Precambrian basement and overlying Paleozoic lithologies. Target rock age determinations include those associated with the Proterozoic Frontenac Terrane. These are manifest as the Rigolet (1004 ± 5 Ma, U-Pb apatite dating) and Ottawan (1074 ± 12 Ma, Rb-Sr biotite dating) phases of the Grenville Orogeny. Pre-Grenville ages associated with the Penokean (1806 ± 46 Ma, apatite dating) and the Shawinigan (1184 ± 8 Ma, U-Pb titanite dating; 1134 ± 21 Ma, U-Pb zircon dating) orogenies are also retained. A Paleoproterozoic age records Superior Province tectonometamorphism (2421 ± 97 Ma, U-Pb zircon dating). Dated post-impact events include dolomitization associated with Silurian marine transgression (430 ± 14 Ma, U-Pb dolomite dating) and regional K-metasomatism of Mississippian age (346 ± 5 Ma, U-Pb titanite dating). Extremely young (U-Th)/He ages (27−3 Ma) were obtained from planar fractured and recrystallized apatite, which we interpret to be the result of impact-induced diffusion domain reduction. This, combined with low-temperature heating due to burial, significantly limited He retention. Stratigraphic constraints place the Holleford impact event at ca. 458 Ma, close to the Darriwilian−Sandbian boundary of the Ordovician. This age indicates that Holleford may be part of the Late Ordovician group of terrestrial impact craters related to L-chondrite parent breakup.

On the viability of detrital biotite Rb–Sr geochronology

Abstract. Re-examination of International Ocean Discovery Program (IODP) sediment samples collected from the Bay of Bengal via laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) Rb–Sr geochronology demonstrates the viability of the biotite Rb–Sr system for use as a detrital chronometer. The age population defined by the Rb–Sr dates essentially reproduces that previously published for detrital 40Ar/39Ar dates. The effect of unknown/assumed initial 87Sr/86Sr on the calculated population can be ameliorated by filtering for higher 87Rb/86Sr ratios. Such filtering, however, could introduce bias toward more radiogenic populations, especially in younger material that has not had time to accumulate radiogenic product (e.g. limiting the effect of initial 87Sr/86Sr to ∼ <5 % requires filtering of 87Rb/86Sr >500 at 250 Ma and 87Rb/86Sr >50 at 2500 Ma). Finally, Ti-in-biotite temperatures calculated based on element concentration data collected during LA-ICP-MS overlap with those calculated for the same material based on electron probe microanalyzer data, demonstrating the potential for in situ biotite petrochronology based on the Rb–Sr system.

Structural Evolution, Exhumation Rates, and Rheology of the European Crust During Alpine Collision: Constraints From the Rotondo Granite—Gotthard Nappe

AbstractThe rheology of crystalline units controls the large‐scale deformation geometry and dynamics of collisional orogens. Defining a time‐constrained rheological evolution of such units may help unravel the details of collisional dynamics. Here, we integrate field analysis, pseudosection calculations and in situ garnet U–Pb and mica Rb–Sr geochronology to define the structural and rheological evolution of the Rotondo granite (Gotthard nappe, Central Alps). We identify a sequence of four (D1–D4) deformation stages. Pre‐collisional D1 brittle faults developed before Alpine peak metamorphism, which occurred at 34–20 Ma (U–Pb garnet ages) at 590 ± 25°C and 0.9 ± 0.1 GPa. The reactivation of D1 structures controlled the rheological evolution, from D2 reverse mylonitic shearing at amphibolite facies (520 ± 40°C and 0.8 ± 0.1 GPa) at 18–20 Ma (white mica Rb–Sr ages), to strike‐slip, brittle‐ductile shearing at greenschist‐facies D3 (395 ± 25°C and 0.4 ± 0.1 GPa) at 14–15 Ma (white mica and biotite Rb–Sr ages), and then to D4 strike‐slip faulting at shallow conditions. Although highly misoriented for the Alpine collisional stress orientation, D1 brittle structures controlled the localization of D2 ductile mylonites accommodating fast (∼3 mm/yr) exhumation rates due to their weak shear strength (<10 MPa). This structural and rheological evolution is common across External Crystalline Massifs (e.g., Aar, Mont Blanc), suggesting that the European upper crust was extremely weak during Alpine collision, its strength controlled by weak ductile shear zones localized on pre‐collisional deformation structures, that in turn controlled localized exhumation at the scale of the orogen.

Reassessing the timing of high-strain deformation in the Strangways Metamorphic Complex, Central Australia, by in situ mica Rb–Sr and titanite U–Pb geochronology

Dating the timing of deformation within shear zones is critical to quantifying orogenic processes and developing time-resolved regional tectonic frameworks. Such work requires the integration of detailed microstructural analysis with in situ geochronology to quantify when deformation mechanisms were active at the micro-scale. The Proterozoic, granulite-facies Strangways Metamorphic Complex was exhumed during the Devonian to Carboniferous intracontinental Alice Springs Orogeny. New microstructural observations, quartz c -axis orientation analyses, mica chemistry, Ti-in-biotite thermometry, in situ mica Rb–Sr and titanite U–Pb geochronology outline a detailed history of ductile shearing across the complex. Movement along the north boundary shear zone of Strangways Metamorphic Complex appears to have initiated c. 382 Ma, preceding peak metamorphism in the area during the Alice Springs Orogeny. Widespread reverse-sense ductile shearing occurred within the Strangways Metamorphic Complex between c. 365 and 355 Ma, and correlates with rapid cooling of the region. Late-stage ductile deformation is recorded at c. 335 Ma, likely reflecting the terminal exhumation of the Strangways Metamorphic Complex. Finally, the new in situ muscovite and biotite Rb–Sr data collected herein permit comparison with previous two-point mica Rb–Sr isochrons and 40 Ar– 39 Ar dates from the same specimens. In the rocks analysed, the biotite Rb–Sr system returned dates similar to the previous 40 Ar– 39 Ar white mica dates, perhaps indicating a similar effective closure temperature. Supplementary material: Test results and previous geochronology data from the Alice Springs Orogeny are available in tabular form at https://osf.io/yjp24/?view_only=0bf5bec9f5c94a1aa4fb413320ec24e8

Thermo-tectonic evolution of the Neoarchaean Southern Marginal Zone of the Limpopo granulite Complex (South Africa)

Abstract Combined geophysical, structural geological, metamorphic, geochronological, and stable isotope information is employed to elucidate the Neoarchaean thermo-tectonic evolution of the Southern Marginal Zone (SMZ) within the Limpopo Complex (South Africa) during the Limpopo orogeny (2.72 to 2.62 Ga). The complex evolutionary history of the SMZ was controlled by an allochthonous SMZ granulite nappe that was extruded from a rising granulite diapir through a process of mid-crustal heterogeneous channel flow. This granulite nappe with its embedded structures (steeply plunging reclined folds and steep shear zones) was formed during emplacement of the diapir to mid-crustal level (6 kbar, 20 km depth) from where it was thrust south-westwards along the Hout River shear zone (HRSZ) sole thrust against the Kaapvaal Craton (KVC) at 2.72 to 2.69 Ga. Evidence for the thermo-tectonic interaction of the granulite nappe with the KVC includes (1) thrust complexes (referred to as hot-iron zones) that are developed at the frontal ramp sections of the HRSZ juxtaposed against the granite-greenstone belts of the KVC, and (2) strike-slip shear deformation associated with the lateral ramp section of the HRSZ, which developed against the KVC devoid of greenstone belts. The emplacement of the post-tectonic Matok granitic pluton at ~2.68 Ga into the SMZ signified the end of the thermo-tectonic event that established the regional fold- and shear deformational framework of the granulite facies SMZ. Post-Matok secondary shear zones reflect evidence for HRSZ-linked tectonism that continued intermittently to 2.65 to 2.62 Ga. Low H2O-activity fluids (H2O activity of 0.1 to 0.3) released from devolatilisation of underthrust greenstone material passively infiltrated and interacted with the overlying cooling granulites. This established a retrograde anthophyllite-in isograd at ~6 kbar and ~620°C that subdivides the SMZ into a northern granulite domain and a southern retrograde hydrated granulite domain. Simultaneously, gold-bearing fluids focused into these minor shear zones established shear zone-hosted orogenic gold mineralisation at 2.65 to 2.62 Ga. Emplacement of the post-tectonic Palmietfontein granite at ~2.46 Ga and associated sub-volcanic granitic dykes into both the retrograde hydrated granulite domain and the granulite domain signifies the end of all thermo-tectonic activity in the SMZ. A Palaeoproterozoic thermal overprint at ~2.1 Ga is recorded by Rb-Sr biotite and phlogopite ages derived from various rocks from the SMZ and adjacent KVC. This thermal event is not associated with deformation and did not result in the formation of new mineral assemblages. Integrated data presented and discussed in this paper contradict the interpretation of age and petrological data utilised to support alternative models for the evolution of the SMZ, including a proposed ~2.1 Ga Palaeoproterozoic polymetamorphic amphibolite-grade thermo-tectonic event.

On the virtues and pitfalls of combined laser ablation Rb–Sr biotite and U–Pb monazite–zircon geochronology: an example from the isotopically disturbed Cape Woolamai Granite, SE Australia

Abstract Different mineral clocks in granite can provide age information reflecting various aspects of rock formation, including cooling or post-emplacement fluid–rock interaction. However, the dating tool chosen can yield inconclusive age information due to differences in closure temperatures and susceptibility to fluid alteration among chronometers. This has led to an inferred superiority of U–Pb in zircon over U–Pb in monazite or Rb–Sr in mica. Here, we investigate age systematics using Rb–Sr biotite grains, U–Pb in monazite and zircon in a Devonian granite from Australia. Single-grain laser ablation ICP-MS/MS biotite analyses are combined with zircon–monazite U–Pb ages and trace element systematics. Textural and trace element evidence combined with age systematics reveals a Rb–Sr closure age of c. 360–330 Ma relative to a putative 364 Ma emplacement age, suggesting hydrothermal alteration of the granite. Trace element systematics and magnetic susceptibility in biotite grains reflect their partial chemical reset and fluid overprint in the granite. However, similar systematics are also observed for zircon and monazite. Our multiple chronometer dating approach, studied with modern laser-ablation methods, highlights the need for detailed investigation of isotope and trace element systematics in single grains and that individual ages should be used cautiously when dating altered granitoids.

Dating mylonitic overprinting of ancient rocks

Deformation in shear zones is difficult to date because mylonites can preserve partially reset pre-existing isotopic signatures. However, mylonites can be key structural elements in terrane recognition, so an accurate estimation of their age is important. Here we determine the in situ Rb–Sr isotopic composition of mica from major NE-SW trending mylonitic zones in the Archean Akia Terrane of Greenland and complement this information with inverse thermal history modelling. Rb–Sr isochrons indicate a dominant age of radiogenic-Sr accumulation in biotite of around 1750 million years (Ma) ago. Yet, magmatic titanite is unreset yielding a U–Pb age of around 2970 Ma. These constraints require that biotite Rb–Sr directly dates mylonitic fabric generation. The 1750 Ma mylonites, associated with the Proterozoic Nagssugtoqidian Orogeny, overprint Archean crust widely regarded as preserving evidence of early Earth horizontal tectonics.

Episodic alteration within a gold-bearing Archean shear zone revealed by in situ biotite Rb–Sr dating

Many economic gold deposits formed in the Neoarchean under greenschist facies conditions in association with ductile–brittle shear zones that were conduits for sulfur-bearing hydrothermal fluids. Although the large-scale architecture and formation history of Neoarchean structurally controlled gold deposits has been the subject of many studies, the timing, rates, and durations of mineralization-related alteration remain challenging to deconvolve owing to a lack of event-specific geochronometers and the potential multitude of overprinting processes. In an effort to better understand the alteration history along the mineralized Zuleika Shear Zone in the Eastern Goldfields Superterrane of the Yilgarn Craton in Western Australia, we present the results of biotite Rb–Sr from 13 drill core samples (seven with apatite Sr isotopes) from the Kundana gold camp and the Carbine area. The Kundana district is a lode gold deposit that represents an ideal case study area to test the longevity of mineralization-associated alteration systems. We use in situ laser ablation collision cell triple quadrupole mass spectrometry on biotite from a range of characteristic alteration assemblages with well-defined relative growth ages. Biotite Rb–Sr ages constrain the timing of four different alteration stages between ∼2700 and 2550 Ma. The correlation between relative alteration chronology and Rb–Sr age and the lack of any relationship between grain size and age supports an interpretation of Rb–Sr ratios reflecting biotite growth during hydrothermal alteration with subsequent rapid cooling. Initial 87Sr/86Sr ratios of biotite and apatite are similar and indicate compositions that are more radiogenic than chondritic values and generally slightly more radiogenic than modelled Neoarchean Bulk Silicate Earth values, consistent with a mixture of mantle and crustal fluid sources. Ti-in-biotite thermometry yields temperatures between 540 and 615 °C, peaking towards the main gold mineralization phase. Although it is not possible to link individual Rb–Sr ages to specific faulting events, the absolute age dating for the various alteration assemblages indicates a prolonged, multiphase alteration system lasting ∼150 Ma. Long-term permeability networks with episodic short-lived fluid pulses that outlast terrane- or camp-scale deformation may not only apply to Neoarchean lode gold deposits, but to any tectonically driven zone of weakness in the continental crust.

Lithological fabric as a proxy for Rb–Sr isotopic complexity

In situ Rb–Sr dating, made possible by recent analytical advancement, is a powerful chronometer that enables the timing of crystal growth or cooling to be determined for fabric forming minerals (e.g. alkali feldspar, muscovite, biotite). In contrast with accessory phase geochronology, Rb–Sr geochronology can be deployed on minerals that constitute a significant component of a wide range of rock types. Here we report laser ablation inductively coupled plasma tandem mass spectrometry (LA-ICP-MS/MS) biotite Rb–Sr ratios in metaigneous and metasedimentary samples from across Western Australia. These biotite samples span a diversity of structural, metamorphic, and temporal states, yet highlight common salient features of this chronometer. Biotite in these samples received its isotopic compositions from completely to partially homogenized Sr reservoirs, as evident from isochronous to more complex distributions of isotopic ratios. The utility of the classic isochron approach is contrasted with biotite model ages for the geologic interpretation of Rb–Sr results for samples with and without constrained initial 87Sr/86Sr ratio. Model ages calculated from individual analyses aid in identifying multiple discrete events that may have only partially equilibrated isotopic systems. Thus, single-analysis model ages can enable the extraction of thermochronological information from complex Rb–Sr data sets, if interpreted under consideration of their geologic context. Textural analysis of thin sections via Fourier component image analysis quantifies the preferred orientation of biotite fabrics. This analysis reveals a correlation between diversity of grain orientation and biotite age complexity. Such a simple texture-to-age relationship highlights a potential pre-analysis screening tool to facilitate sample selection where Rb–Sr isochrons are sought.Results reveal a thermal event at ca. 550–500 Ma in the Lamboo Province, West Kimberley, and multiple contact metamorphic events at ca. 633 Ma and 619–615 Ma that occurred in the Yeneena Basin, Paterson Orogen. Biotite from the Yilgarn Craton yields a strong E-W trend in cooling ages, from 2477 Ma in the central Yilgarn Craton to 580 Ma at the western margin of the craton. These ages support slow cooling and thermo-tectonic quiescence after cratonisation in the central Yilgarn Craton, while the western margin was subject to Neoproterozoic reworking. Placed into a regional geologic context, these results highlight the sensitivity of the in situ Rb–Sr dating method to constrain the timing of geologic events that are not commonly captured by other isotopic systems.

Metamorphic P–T Evolution and In Situ Biotite Rb–Sr Geochronology of Garnet–Staurolite Schist From the Ramba Gneiss Dome in the Northern Himalaya

The North Himalayan gneiss domes provide a window for looking into the deeper crust and record abundant clues of continent collisional orogenesis. This study carried out detailed petrology, in situ LA–ICP–MS biotite Rb–Sr dating, and phase equilibrium modeling on garnet–staurolite–two-mica schist in the Ramba gneiss dome in order to constrain metamorphic P–T evolution and the timing of metamorphism. A clock-wise P–T path, involving an early prograde process that evolves from ∼540°C at ∼4.4 kbar to ∼630°C at ∼6.0 kbar, was constructed for garnet–staurolite–two-mica schist in the Ramba gneiss dome. In situ LA–ICP–MS biotite Rb–Sr analysis yielded two metamorphic ages of 37.17 ± 5.66 and 5.27 ± 3.10 Ma, corresponding to the timing of retrograde cooling and the cooling age of the dome following the thermal resetting by the emplacement of ca. 8 Ma leucogranite pluton in the core of the dome, respectively. The peak metamorphism is inferred to be older than ca. 37 Ma. Based on these results and the data previously published, the garnet–staurolite–two-mica schist recorded the Eocene crustal thickening, following the India–Asia collision and later the exhumation process.

Apatite and biotite thermochronometers help explain an Arctic Caledonide inverted metamorphic gradient

Biotite generates significant radiogenic Sr and is thus suitable for Rb–Sr dating, which can be achieved directly in thin section via laser ablation and provides a means to directly date growth of this important fabric-forming mineral or its cooling. In contrast, apatite has an extremely low Rb/Sr ratio and hence offers a useful tool to estimate source 87Sr/86Sri. Plagioclase also contains significant Sr and may further assist in understanding the rocks Sr isotopic system. However, the fluid source of growing or recrystallizing apatite, plagioclase, and biotite need not be the same. Compounding the complexity, apatite may gain radiogenic Sr from biotite during recrystallization or dissolution–reprecipitation that accompanies metamorphism. In this contribution, we present a case study from the Kalak Nappe Complex in the Scandinavian Caledonides, Arctic Norway, where a combined geochronology program, critically supported by biotite Rb–Sr dating, helps to resolve the conspicuous inverted metamorphic field gradient found upwards through the nappe stack in this orogen. Apatite U–Pb ages of 417–413 Ma in the upper nappes are interpreted as cooling through the Pb retention zone. Such ages contrast with the suggestion of older, partially reset apatite ages in the lower nappes. Biotite Rb–Sr ages of c. 413 Ma in the upper nappes are similar to U–Pb ages of coexisting apatite but conspicuously different from c. 433 Ma biotite Rb–Sr ages in the lower nappes. Ages of c. 433 Ma are comparable to muscovite 40Ar/39Ar and titanite and monazite U–Pb ages throughout the complex and may directly date mineral growth at peak thermal conditions during the Scandian orogenic event. Apatite 87Sr/86Sr ratios also track the influence of metamorphism and imply more radiogenic signatures relative to relic plagioclase in samples which have greater overprinting in the upper nappes of the complex. Phase equilibrium modelling establishes Palaeozoic peak P–T conditions of 610–750 °C at <12 kbar in the upper nappes, comparable to peak conditions previously established for the lower nappes. Combined thermal modelling of the post-peak Scandian orogenic history based on published 40Ar/39Ar, paired with new Rb–Sr, and U–Pb data, implies a slower cooling pathway in the upper nappes relative to the lower nappes. We reconcile this thermal history with a geodynamic model of obduction of a hot back-arc, as represented by the Silurian Magerøy Nappe, onto the upper nappes of the Kalak Nappe Complex at c. 430 Ma. These results demonstrate that in-situ laser ablation Rb–Sr dating of biotite provides a powerful tool for resolving orogenic tectonothermal histories in orogens flushed with excess argon.

The Kuunga Orogeny in the Eastern Ghats Belt: Evidence from geochronology of biotite, amphibole and rutile, and implications for the assembly of Gondwana

The Eastern Ghats Belt, India, is a high grade polymetamorphic terrane; most of it was metamorphosed under high temperature to ultra-high temperature (UHT) conditions at 1000–900 Ma. This study presents new Rb–Sr biotite, 40Ar–39Ar amphibole and U–Pb rutile ages for 32 samples of HT and UHT lithologies from across the Eastern Ghats, Jaypore and Rengali Provinces. This dataset provides the first comprehensive evidence for a pervasive, region-wide amphibolite facies metamorphism at ca. 500 Ma throughout the Eastern Ghats Belt that overprinted the earlier (U)HT mineral assemblages. The lower-grade Cambrian overprint did not lead to retrogression of the high grade mineral assemblages but is recorded by different geochronometers. Rb–Sr biotite, 40Ar–39Ar amphibole and U–Pb rutile ages from the entire Eastern Ghats Belt cluster around ca. 500 Ma. U-Pb ages for zircon from six of the samples dated by Rb–Sr biotite and/or U–Pb rutile do not record this young event but yield ages that correspond to the earlier high-grade metamorphism. Combined with previously published geochronological information, the new ages show that a medium grade tectonothermal event during the Cambrian affected the whole Eastern Ghats Belt on a regional scale. This last regional metamorphism was essentially fluid-absent, as the parageneses originating from high-grade metamorphism at 1000–900 Ma are still pristine and do not show pervasive retrograde mineral reactions. This Cambrian metamorphic episode is also recorded as a high-T overprint in the high-grade gneisses of Sri Lanka, southern India and Madagascar and is the result of the assembly of Gondwana that led to the collision of Antarctica with India, which formed part of the Kuunga orogeny. The new data provide evidence for the extension of the Kuunga orogeny into eastern India and support it representing a major orogenic event in the assembly of Gondwana.

Polyphase deformation along the South Bohemian Batholith-Moldanubian nappes boundary – The Freyenstein Fault System (Bohemian Massif/Austria)

Abstract This work describes the Freyenstein Fault System, which extends over 45 km in the southeastern part of the Bohemian Massif (Lower Austria). It represents a ductile shear zone overprinted by a brittle fault located at the eastern edge of the South Bohemian Batholith towards the Moldanubian nappes. It affects Weinsberg- and a more “fine-grained” granite, interlayered aplitic granite and pegmatite dikes as well as paragneiss of the Ostrong Nappe System. The ductile shear zone is represented by approximately 500 m thick greenschist-facies mylonite dipping about 60° to the southeast. Shear-sense criteria like clast geometries, SCC`-type shear band fabrics as well as abundant microstructures show top to the south/ southsouthwest normal shearing with a dextral strike-slip component. Mineral assemblages in mylonitized granitoid consist of pre- to syntectonic muscovite- and biotite-porphyroclasts as well as dynamically recrystallized potassium feldspar, plagioclase and quartz. Dynamic recrystallization of potassium feldspar and the stability of biotite indicate upper green-schist-facies metamorphic conditions during the early phase of deformation. Fluid infiltration at lower greenschist-facies conditions led to local sericitization of feldspar and synmylonitic chloritisation of biotite during a later stage of ductile deformation. Finally, a brittle overprint by a north-south trending, subvertical, sinistral strike-slip fault that shows a normal component is observed. Ductile normal shearing along the Freyenstein Shear Zone is interpreted to have occurred between 320 Ma and c. 300 Ma. This time interval is indicated by literature data on the emplacement of the hostrock and cooling below c. 300°C inferred from two Rb-Sr biotite ages measured on undeformed granites close to the shear zone yielding 309.6 ± 3 Ma and 290.9 ± 2.9 Ma, respectively. Brittle sinistral strike-slip faulting at less than 300°C presumably took place not earlier than 300 Ma. Early ductile shearing along the Freyenstein Fault System may be genetically, but not kinematically linked to the Strudengau Shear Zone, as both acted in an extensional regime during late Variscan orogenic collapse. A relation to other major northeast-southwest trending faults of this part of the Bohemian Massif (e.g. the Vitis-Pribyslav Fault System) is indicated for the phase of brittle sinistral movement.

Structural evolution and medium-temperature thermochronology of central Madagascar: implications for Gondwana amalgamation

Madagascar occupied an important place in the amalgamation of Gondwana and preserves a record of several Neoproterozoic events that are linked to orogenesis of the East African Orogen. In this study, we integrate remote sensing, field data and thermochronology to unravel complex deformation in the Ikalamavony and Itremo domains of central Madagascar. The deformation sequence comprises a gneissic foliation (S 1 ), followed by south- to SW-directed, tight to isoclinal, recumbent folding (D 2 ). These are overprinted by north-trending upright folds that formed during an approximately east–west shortening event (D 3 ). Together these produced type 1 and type 2 fold interference patterns throughout the Itremo and Ikalamavony domains. We show that the Itremo and Ikalamavony domains were deformed together in the same orogenic system, which we interpret as the c . 630 Ma collision of Azania with Africa along the Vohibory Suture in southwestern Madagascar. In eastern Madagascar, deformation is syn- to post-550 Ma, and probably formed in response to final closure of the Mozambique Ocean along the Betsimisaraka Suture that amalgamated Madagascar with the Dharwar Craton of India. Apatite U–Pb and novel laser ablation triple quadrupole inductively coupled plasma mass spectrometry (LA-QQQ-ICP-MS) muscovite and biotite Rb–Sr thermochronology indicates that much of central Madagascar cooled through c . 500°C at c . 500 Ma. Supplementary material: A detailed geological map of central Madagascar (Supplementary A), detailed methods and geo- and thermochronology results (Supplementary B), isotopic data for geo- and thermochronology (Supplementary C) and Landsat images and structural interpretation examples (Supplementary D) are available at https://doi.org/10.6084/m9.figshare.c.4840575

Age and geological context of the Barby Formation, a key volcanic unit in the Mesoproterozoic Sinclair Supergroup of southern Namibia

Abstract Volcanic and sedimentary rocks of the Sinclair Supergroup occur in the Konkiep Terrane of Southern Namibia. Three volcanic and sedimentary cycles are recognised. In this work we describe and date volcanic rocks of the Barby Formation, a key unit in the Sinclair area. The coeval Spes Bona Syenite and the Tiras Granite Gneiss are also described and dated. The rock types in the Barby Formation are rhyolites, basaltic trachyandesites, trachybasalts and trachydacites as well as volcanoclastic rocks. The rocks are largely undeformed and partly altered by deuteric and contact metamorphic processes but not regionally metamorphosed. Our samples represent both the calc-alkaline and alkaline trends documented in previous work. U-Pb ion probe and laser ablation inductively coupled plasma (LA-ICP) multicollector mass spectrometer Lu-Hf microbeam analyses were made of zircon and baddeleyite grains from four samples. A felsic tuff sample from the base of the Barby Formation has a 207Pb/206Pb zircon age of 1214 ± 5 Ma (2σ). A rhomb porphyry sample from the top of an 8.5 km-thick stratigraphic section gives a 207Pb/206Pb baddeleyite age of 1217 ± 2 Ma. The Spes Bona Syenite which intrudes the top of the Barby Formation has a 207Pb/206Pb baddeleyite age of 1217 ± 3 Ma and an indistinguishable LA-ICP collision cell mass spectrometer Rb-Sr biotite isochron age of 1238 ± 20 Ma, showing that there was no &amp;gt;350°C regional metamorphic event. Multi-element diagrams for the calc-alkaline samples show a dominant signature of reworked crust which is superimposed on a possible subduction signature. However the alkaline samples contain clear subduction signatures which are not seen in the underlying 1.37 Ga Kumbis rhyolite. The Barby Formation samples and coeval Spes Bona Syenite have Lu-Hf crustal residence ages between 1682 and 1873 Ma, suggesting that both of these units formed from a mixture of juvenile mantle-derived and older crustal material. The Barby Formation is considered to have originated due to a subduction event which took place during the assembly of the Rodinia supercontinent. The duration of the Barby magmatic episode is constrained to a maximum 9 m.y. period between 1219 and 1210 Ma, and during this period the Konkiep Terrane was an active continental margin. The 1204 ± 9 Ma Tiras Granite Gneiss is slightly younger than the Barby Formation and intruded across the Lord Hills Shear Zone, which is the suture between the hardly metamorphosed Konkiep Terrane and the highly metamorphosed Grunau Terrane of the Namaqua-Natal Province. Its intrusion reflects the end of subduction-related volcanism, due to the collision of Namaqua terranes with the Konkiep Terrane.

Constraints of zircon U-Pb and biotite Rb-Sr ages and P-T conditions on the emplacement and uplifting of the Late Mesozoic Jinan gabbro, eastern North China

The North China Craton underwent exceptional lithospheric thinning. A debate remains as to the mechanism and timing of this thinning partly as a result of the lack of information on the crustal uplift. Mantle-derived mafic rocks can carry key messages of lithospheric thinning and facilitate the determination of the time and mechanism. Gabbroic rocks from the Jinan area in eastern North China were emplaced in the peak period of the thinning and, for this reason, were chosen as the study object. Isotopic ages and P-T conditions of the Jinan gabbro pluton were measured to examine the uplifting and cooling history of the magma. Jinan gabbros were enriched in large ion lithophile elements and large rare earth elements but depleted in high field strength elements without a significant Eu anomaly. Their Sr-Nd-Pb isotopic features suggest that the magma was derived from the partial melting of an enriched lithospheric mantle (EMI). This pluton was emplaced at ~130 Ma, and crystallization temperatures of pyroxene and biotite were 909–1116 °C and 828–952 °C, respectively. The core and rim crystallization pressures of clinopyroxene and plagioclase are ~4.45 kbar and ~2.56–3.91 kbar, respectively. These might record the pressure changes during the uplift process from ~16.5 to 9.5 km. The Rb-Sr isotopic system of biotite was closed at ~121–117 Ma, constrained by the single–grain biotite Rb-Sr ages. This shows that the cooling depth of pluton is ~8.4 ± 2.4 km. Consequently, the pluton was rapidly uplifted from the ~16.5 km to ~8.4 km, at an uplift rate of 0.81 ± 0.24 km/Ma and/or a cooling rate of approximately 50 °C/Ma during 130–120 Ma. This fast uplift was related to the delamination and thinning of the lithosphere that caused activities associated with magmatism and mineralization in eastern North China during the late Mesozoic.

Major fault zones in the Austroalpine units of the Kreuzeck Mountains south of the Tauern Window (Eastern Alps, Austria)

The Kreuzeck Mountains are located between the Tauern Window in the north and the Southalpine unit in the south. They expose an Eoalpine (Cretaceous) nappe stack of Adria derived continental crust. The Koralpe–Wolz Nappe System in the footwall partly experienced Cretaceous eclogite-facies metamorphism, while the Drauzug-Gurktal Nappe System in the hanging wall remained at anchizonal to greenschist-facies conditions in Cretaceous time. From the Late Cretaceous onward the Austroalpine units in the Kreuzeck Mountains were affected by brittle/ductile shearing and brittle deformation. This contribution is based on mapping of the southeastern part of the Kreuzeck Mountains at the 1:10000 scale in combination with structural and petrological investigations and Rb–Sr biotite dating. The new data indicate that the boundary between the Koralpe–Wolz Nappe System and the overlying Drauzug-Gurktal Nappe System consists of three segments. It includes (1) the south dipping Wallner Normal Fault representing a more than 500 m wide shear zone responsible for the Cretaceous exhumation of the eclogite-bearing Polinik Complex to shallow crustal levels (2) the Oligocene to Miocene Ragga-Teuchl Fault and (3) the Groshalsgraben Fault. The latter is mechanically related to the Molltal Fault and shows a dextral offset. The Drauzug-Gurktal Nappe System is from bottom to top composed of the Strieden, the Gaugen and the Goldeck complexes, which are transgressively overlain Permo-Triassic (meta)sediments. It is dissected by the steeply north dipping Lessnigbach Shear Zone with a dominant top to the south reverse sense of shear and the ENE–WSW trending, sub-vertical Blassnig Shear Zone showing sinistral kinematics. Both faults were active in the Late Cretaceous, but might have been initiated in the Late Jurassic.

The LA-ICP-MS U-Pb zircon age of rhyolite from the Dong Trau formation and its geological significances

Zircons separated from an rhyolite sample in the Dong Trau formation, in the southern of Hà Tĩnh province were dated to determine the protolith age for the complex. Sixteen LA-ICP-MS U-Pb zircon analyses give concordant ages concentrated at 256 Ma (weighted mean). These results indicate the protolith age of the rhyolite (primary magma crystallization age). The value of this age are close to the analytical results pf the whole rock by Rb-Sr method and biotite Rb-Sr method. Therefore the crystallization age of the rhyolite from the Đồng Trầu formation corresponded period late Permian to early Triassic.

U-Pb geochronology of grossular-andradite garnet

This study presents a new laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) based U-Pb geochronometric method for dating grossular-andradite (grandite) garnet. Grandite is a primary skarn mineral, therefore dating its growth directly dates hydrothermal activity. As zircon U-Pb geochronometry provides a high-resolution record of magmatic processes, grandite U-Pb dating has the potential to provide a complementary record for hydrothermal systems. This study characterizes four garnets of variable grossular-andradite content and age as potential reference materials for LA-ICPMS U-Pb geochronology: Willsboro Andradite (~1020Ma, Adirondacks, USA), Red and Yellow Mali Grandite (~200Ma, Southern Mali) and Lake Jaco Grossular (~35Ma, Coahuila, Mexico). Isotope dilution-thermal ionization mass spectrometry (ID-TIMS) U-Pb analyses of Willsboro andradite yield a mean 206Pb/238U date of 1022±16Ma. We use Willsboro Andradite as a primary reference material for LA-ICPMS U-Pb characterization of the two other garnets. The non-radiogenic Pb (Pbc) concentration in grandite is variable between specimens. Willsboro Andradite and Mali Grandites contain almost purely radiogenic Pb (Pb*), however Lake Jaco Grossular has a higher Pbc concentration comparatively and yields discordant U/Pb ratios. For specimens with highly variable Pb*/Pbc, linear regression is employed to derive a lower-intercept age. LA-ICPMS U-Pb dates for Yellow Mali Grandite (202±2Ma; 206Pb/238U weighted mean) and Lake Jaco Grossular (35±2Ma; lower intercept) agree with independent ID-TIMS U-Pb (202.0±1.2Ma) and (U-Th)/He dates (35±5Ma) derived for each specimen. The precision of LA-ICPMS U-Pb dates varies between 1–10% (2σ) for the analyzed garnets. Considering the short estimated lifespans of pluton-related hydrothermal systems (tens of thousands to a few million years), Neogene skarns present the best opportunity to test for and resolve separate episodes of garnet growth at these precision levels. As a performance test for the method, we present new U-Pb andradite data from a Late Miocene skarn system on Serifos Island, Greece. This garnet yields a lower-intercept age of 9.15±0.36Ma, in agreement with biotite Rb-Sr and zircon U-Pb dates from the causative pluton.

Rb–Sr and Sm–Nd study of granite–charnockite association in the Pudukkottai region and the link between metamorphism and magmatism in the Madurai Block

Pudukkottai region in the northeastern part of the Madurai Block exposes the garnetiferous pink granite that intruded the biotite gneiss. Charnockite patches are associated with both the rock types. Rb–Sr biotite and Sm–Nd whole-rock isochron ages indicate a regional uplift and cooling at ∼550 Ma. The initial Nd isotope ratios (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}=-20\) to −22) and Nd depleted-mantle model ages (TDM = 2.25 to 2.79 Ga) indicate a common crustal source for the pink-granite and associated charnockite, while the biotite gneiss and the charnockite within it represent an older crustal source (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}= -29\) and TDM = > 3.2 Ga). The Rb–Sr whole-rock data and initial Sr–Nd isotope ratios also help demonstrate the partial but systematic equilibration of Sr isotope and Rb/Sr ratios during metamorphic mineral-reactions resulting in an ‘apparent whole-rock isochron’. The available geochronological results from the Madurai Block indicate four major periods of magmatism and metamorphism: Neoarchaean–Paleoproterozoic, Mesoproterozoic, mid-Neoproterozoic and late-Neoproterozoic. We suggest that the high-grade and ultrahigh-temperature metamorphism was preceded by magmatism which ‘prepared’ the residual crust to sustain the high P–T conditions. There also appears to be cyclicity in the tectono-magmatic events and an evolutionary model for the Madurai Block should account for the cyclicity in the preserved records.