Granite Research Articles

Formation of the intrusion-hosted orogenic-type gold lodes: Exemplified by the Axile gold deposit in the Chinese Altai

Unlike the gold deposits typically hosted in metamorphosed volcanic-sedimentary sequences, the recently discovered Axile gold deposit (over 13 t Au at 5.35 g/t) is a unique example in the Chinese Altai for evaluating the genesis of intrusion-hosted lode gold deposits in metamorphic terranes. The orebodies in this deposit occur as quartz veins and altered tectonites hosted in the sinistrally sheared quartz diorite and biotite granite zones in the Habahe intrusion. The quartz vein-type ores are composed of quartz-pyrite veins and quartz-polymetallic sulfide veins, in which gold-tellurides also occur. The altered tectonites, spatially associated with the quartz veins, are composed of deformed and altered rocks of quartz diorite and biotite granite. Main alterations include quartz, sericite, calcite, chlorite, albite, pyrite, chalcopyrite, and gold-tellurides. Two types of fluid inclusions are identified in the ores, i.e., (1) carbonic-aqueous (C-type) and (2) aqueous (W-type), with the C-type being dominated. These fluid inclusions yield salinity ranging from 3.6 to 9.0 wt% NaCl equivalent and homogenization temperatures in the range of 249 − 387 ℃, suggesting a typical mesothermal NaCl-CO2-H2O system. The Axile deposit thus corresponds to an orogenic-type gold deposit.The hydrothermal titanites in the auriferous quartz-pyrite veins yield in situ U-Pb ages around 278.4 ± 2.4 Ma (MSWD = 3.1, 2σ), which constrain the gold mineralization timing as Permian. The mineralized quartz diorite and biotite granite yield zircon U-Pb ages of 377.0 ± 1.0 Ma (MSWD = 0.1; 1σ) and 394.0 ± 1.2 Ma (MSWD = 0.4; 1σ), respectively, which show that the ore-hosting intrusions were emplaced in the Devonian, obviously earlier than the gold mineralization. The light δ13CV-PDB values (−15.5 ‰ to −6.7 ‰, average −10.7 ‰) of the CO2 extracted from the fluid inclusions display a significant contribution from the organic carbon in sediments. Given the sedimentary rocks underwent Permian greenschist to amphibolite facies metamorphism in the Chinese Altai, accompanied by the synchronous structural deformation and shearing activities, it could be concluded that the Axile gold deposit is formed by a shear zone-controlled mesothermal system that originated from metamorphic-devolatilization. The Chinese Altai Orogen is an orogenic-type gold metallogenic belt, containing both the intrusion- and metamorphic rock-hosted gold deposits, illustrated by a consistent genetic model.

Geochronological and geochemical constraints on the multistage magmatic processes of the Lianhuashan batholith, South China: Implications for the petrogenesis and polymetallic mineralization

The Lianhuashan batholith, which is a composite pluton located in the middle part of a world-class giant tungsten (W) polymetallic belt of South China, hosts a huge reserve of more than 50000 t of W. Despite this great economic significance, the petrogenesis of each phases of the Lianhuashan batholith, as well as its temporal and genetic relationships to the W polymetallic mineralization, is still unclear. To address these questions, we conducted a comprehensive study for the Lianhuashan batholith, including LA-ICP-MS zircon U-Pb dating, whole-rock geochemical and in-situ mineral trace element analyses. Different from previous studies, four main granitic phases (G1 to G4) were identified. The biotite granite (G1) formed from 168.6 to 165.3 Ma, has the lowest Si content and high Al and Fe contents, and is significantly depleted in Ba, Sr, Ti, P, and Nb whereas enriched in U, Hf, Zr, and Y contents. In contrast, the two-mica granite (G2) and fine-grained muscovite granite (G3), formed from 162.8 to 160.5 Ma, exhibit similar characteristics including enrichment in La, Y, Hf, Th, U, and depletion in Ba, Sr, and P. The porphyritic granite (G4) is the latest magmatic phase and formed at 158.3 Ma. It is characterized by high K, Si, Th, U, Zr, Hf contents but low Al, Fe, Sr, P, and Ti contents. These features support that four main phases of the Lianhuashan batholith belong to S-type granites that experienced significant fractional crystallization, and display reduced and low temperature features. Combined with previously published studies, we suggest that the Lianhuashan batholith formed in an intraplate extensional setting triggered by the high-angle rollback subduction of the paleo-Pacific plate. The three early phases (i.e., G1–G3) are in turn more oxidized and are responsible for the transition from Sn- to W-dominated mineralization. In contrast, the G4 granite, characterized by lower oxygen fugacity, is resposible for Pb-Zn-Ag-U polymetallic mineralization.

Fracture and fractal characteristics of high-temperature granite under confined space water jet impact

In the application of jet assisted deep drilling technology, the fracture mode and rock fragment characteristics of high-temperature rock in the confined space of jet drilling are not yet clear. We analyzed the fragmentation and debris distribution of high-temperature granite under confined space jet action using 3D reconstruction technology and statistical fractal theory to examine their fragmentation patterns and fractal characteristics. The results show that high-temperature rocks exhibit obvious thermal fracturing characteristics under the impact of confined water jet, and as the rock temperature increases, vertical compression shear cracks connect with radial tensile cracks. The maximum damage area is located near the bottom of the confined hole, and the distribution of cracks is more complex. As the degree of jet confinement decreases, the rock cracking form changes from radial tensile cracking to vertical compression shear cracking. As the rock temperature increases and the confined space size decreases, the total mass and large debris mass percentages of rock debris increase. The particle size distribution of rock debris follows an Rosin-Rammler (R-R) distribution and has obvious fractal characteristics. The fracture and fragmentation of high-temperature rocks under confined water jet impact are mainly caused by the combination of jet impact stress waves and thermal stress. The temperature difference of rocks affects the heat transfer between jet and rock, and the confined space size directly affects the heat transfer efficiency between jet and rock, which is manifested in different numbers of fracture cracks, internal damage area, and rock debris size distribution. These findings can provide a theoretical and parameter optimization basis for jet-assisted deep reservoir drilling applications.

Petrogenesis of U-rich two-mica granite from the Mesozoic Reshui pluton (Nanling Range, South China) with implications for uranium mineralization

Muscovite-bearing granites are the dominant rock type associated with metallic deposits in South China. Some of these granites are rich in U and considered potential sources for subsequent hydrothermal uranium mineralization. Although widely studied, the petrogenesis of muscovite-bearing granites remains obscure. The Reshui pluton contains fine-grained biotite granite and coarse grained two-mica granite (CGTG). CGTG exhibits high U concentrations (5.07–40.15 ppm, average 15.94 ppm) and is typical of U-rich granite in South China. We conducted detailed petrographic, geochemical and biotite mineralogical analyses of the CGTG from the Reshui pluton. Our findings provide new insights into the petrogenesis of U-rich granites in South China and their significance for uranium mineralization. LA-ICP-MS zircon U–Pb dating shows that the CGTG were formed at 167.3 ± 1.7 Ma. Integrated petrological, whole-rock geochemical and biotite geochemical data, the negative and limited variation of the εNd(t) values (from − 10.8 to − 9.6) and a two-stage Paleoproterozoic model age (1.72 to 1.83 Ga), suggest the U-rich S-type CGTG formed by partial melting of Paleoproterozoic clay-rich pelitic rocks and underwent extensive fractional crystallization. The U-rich pelitic magma sources characterized by relatively low oxygen fugacity and temperature, relatively high degree of magmatic differentiation and F content are the main factors controlling U enrichment in the Reshui pluton CGTG. The petrologic and whole-rock geochemical characteristics, together with the biotite chemical compositions and disseminated U-rich accessory minerals including uraninite, indicate that the CGTG in the Reshui pluton has a high uranium mineralization potential and should be given more attention in further explorations.

Generation of Neoproterozoic granites of the Huangling batholith in the northern Yangtze Block, South China: Implications for the evolution of the Precambrian continental crust

Granites may contain critical information about composition and reworking of continental crust and are widely used to investigate continental crust evolution. Extensive Neoproterozoic granites in the northern Yangtze Block are significant to the Neoproterozoic continental evolution of the Yangtze Block. We investigated the petrology, mineralogy, whole-rock geochemistry, and zircon U–Pb–Hf isotopes of the Neoproterozoic Wuduhe biotite granites and Xiabaoping K-feldspar granites of the Huangling batholith in the northern Yangtze Block to determine their source characteristics and geological implications for the northern Yangtze Block. The Wuduhe biotite granites yielded zircon U–Pb ages of ca. 818–815 Ma. They displayed high SiO2 contents (70.19–74.23 wt%) and Na2O/K2O ratios (1.38–3.35) but low MgO (0.37–0.90 wt%) and CaO (1.49–2.97 wt%) contents, representing calc-alkaline Na-rich I-type granites. They exhibited enriched whole-rock εNd(t) (−19.8 to − 18.8) and zircon εHf(t) values (−41.3 to − 24.2), and had low CaO/Na2O (0.34–0.63), Al2O3/TiO2 (46.6–89.7), Rb/Ba (0.02–0.08), and Rb/Sr (0.04–0.12) ratios, as well as low zircon saturation temperatures (739 − 770 °C), indicating derivation from Na-rich metabasalts of the Archean Kongling complex. The Xiabaoping K-feldspar granites had zircon U − Pb crystallization ages of ca. 816–812 Ma. They displayed high SiO2 (70.82–74.80 wt%), K2O (4.41–6.35 wt%), and Al2O3 (13.46–16.31 wt%) contents, suggesting A2-type affinities. They showed enriched zircon εHf(t) (−44.3 to − 18.4) and whole-rock εNd(t) values (−23.4 to − 18.4) and high zircon saturation temperatures (869–912 °C), indicating formation by anhydrous melting of K-rich felsic rocks from the Archean Kongling complex. The geochemical diversity of these granites from the Huangling batholith was primarily controlled by source heterogeneity of the Kongling complex and distinct melting temperatures. We infer that the northern Yangtze Block underwent significant remelting of ancient continental crust in a subduction background during the Neoproterozoic, induced by continuous upwelling of mantle-derived mafic magmas.

Development and application of a thermo-hydro-mechanical coupling test system for a single rock fracture

A thermo-hydro-mechanical coupling test system was developed to study the physical and mechanical properties of a single rock fracture under the interaction of multi-physics field. The test system mainly contained a loading system, a shear-flow box and sealing system, a high-temperature environment box and a seepage system. The test system can conduct the normal compression and shear-flow coupling test under complex stress paths within 300 °C. Two load cells were set at both ends of the shear direction to solve problem of inaccurate shear force monitoring. The unique shear-flow box was designed to solve the dynamic sealing problem. To verify the reliability of the test system, the seepage tests during heating–cooling process and a shear-flow coupling test for a single granite fracture under various boundary conditions were carried out. The test system provides research equipment for understanding the interaction mechanism of multi-physical field in deep underground engineering.

Lithological and Structural Mapping of Basement Rock Units in the Ikara North-Central Basement Complex, Nigeria

Study’s Excerpt The lithological and structural composition of the Ikara North-Central Basement Complex in Nigeria is investigated. Detailed field and petrographic analyses were carried out to identify the rock types of the area. The geological map of the area is updated. Full Abstract The lithological and structural architecture to unravel the compositions and tectonic evolution of the Nigerian Basement Complex has not been fully documented by geoscientists. As such, this research aimed to investigate the lithological and structural characteristics of the Ikara North-Central Basement Complex. Detailed petrographic and field analysis reveals the prevalence of gneiss and granite lithologies characterized by significant structural features such as fractures, folds, and foliations. These findings offer new understandings of the tectonic evolution of the region. The study area mapped is the Ikara Sheet 103 Federal Survey Topographic Sheet to a scale of 1:100,000. The major lithological units underlying the study area are gneisses and granites. However, these major rock types have varieties, namely migmatitic gneiss, granite gneiss, migmatitic (augen) gneiss, porphyroblastic gneiss, medium to coarse-grained granites, and porphyritic granites. These rock types were intruded by quartzites, pegmatitic dykes, quartz, and aplite veins. Rock samples were observed and studied based on their mineralogical composition, color, and texture. The results of the petrographic analysis showed that the rocks are mainly composed of quartz, plagioclase feldspars, alkali feldspars, mica (biotite and muscovite), hornblende, garnet, and accessory minerals like zircon and magnetite. Geological structures were also observed during the field study, namely fractures (joints and fractures), foliations, lineations, veins, dykes, and various landforms. Photomicrographs from thin section analyses revealed micro-structures like myrmekites, micro-folds, and micro-fractures were also observed. Mineralization such as amethyst and cassiterite were hosted by quartz veins and pegmatites in porphyritic granites, respectively. A litho-structural map was produced, exhibiting the lithological units and regional structures cross-cutting the area of research.

Modeling interactions between hydraulic fracture and pre-existing microcracks in crystalline rocks using hydro-grain-texture model

The heterogeneity of the mineral grains and pre-existing microcracks significantly impacts the cracking behavior of crystalline rocks. However, these characteristics have not been adequately addressed in the existing hydraulic fracturing studies. To bridge this gap, this study introduces a fluid-solid coupling method enhanced by a microcrack simulation component, called Hydro-Grain-Texture Model (HGTM), to investigate the influence of mineral structures and pre-existing microcracks on hydraulic fracturing processes in granite. Compared with existing methods, the HGTM incorporates a “grain growth” algorithm that can more accurately represent the characteristics of mineral grains. This study investigates the base case of intact rock, and four additional cases featuring microcracks oriented in various directions, i.e., horizontal, diagonal, vertical and complex microcracks, under both hydrostatic and non-hydrostatic in-situ stress conditions. The HGTM effectively captures a range of microscopic behaviors during the hydraulic fracturing of granite, including the formation of rock fragments, fracture branches, and dry fractures, among others. Furthermore, by comparing numerical results for breakdown pressure with analytical results, the accuracy of the HGTM in predicting breakdown pressure is substantiated. The findings indicate that mineral structures (grain boundaries) and microcracks contribute to a more intricate pattern of hydraulic fractures propagation. The pre-existing microcracks significantly influence the propagation path of primary hydraulic fractures. Under fluid-driven pressures, these pre-existing microcracks experience shear failure distinct from tensile failure observed in the surrounding rock matrix.

Cement-Free Geopolymer Paste: An Eco-Friendly Adhesive Agent for Concrete and Masonry Repairs

This study aimed to investigate the feasibility of using geopolymer paste (GP) as an adhesive agent for (i) anchoring steel bars in concrete substrates, (ii) repairing concrete, and (iii) repairing limestone and granite masonry blocks commonly found in historic buildings. In this investigation, seven cement-free GP mixes were developed with different combinations of binder materials (slag, silica fume, and metakaolin). The mechanical properties, adhesive performance, and production cost of the developed GP mixes were compared to those of a commercially epoxy adhesive mortar (EAM). The results obtained from this study indicated that the use of GPs enhanced the bonding between steel bars and concrete substrates, achieving bonding strengths that were 19.7% to 49.2% higher than those of control specimens with steel bars directly installed during casting. In concrete repairs, the GPs were able to restore about 60.6% to 87.9% of the original capacity of the control beams. Furthermore, GPs exhibited a promising performance in repairing limestone and granite masonry blocks, highlighting their potential suitability for masonry structures. The best adhesive performance was observed when a ternary binder material system consisting of 70% slag, 20% metakaolin and 10% silica fume was used. This combination, compared to the investigated EAM, showed comparable adhesive properties at a significantly low cost, indicating the viability of GPs as a cost-effective, eco-friendly adhesive agent.

Geochemistry and Zircon U–Pb Chronology of Jinchanshan Gold-Hosted Granitoids, Inner Mongolia: Implications for Petrogenesis and Geodynamic Evolution

Jinchanshan is a medium-sized, granitoid-hosted gold deposit located in the Kalaqin area of Inner Mongolia. Mineralization predominantly occurs in the contact zone between biotite granites and quartz porphyry rocks, associated with the Jinchanshan minor intrusion, suggesting a genetic link to the granitoid-hosted gold deposit. In this study, the petrography, geochemistry, and LA-ICP-MS zircon U–Pb chronology of these two granitoid samples were studied. The results indicate that the zircon U–Pb age of the biotite granites is 127.9 ± 3.0 Ma, while that of the quartz porphyry is 121.4 ± 1.5 Ma, both dating back to the Early Cretaceous. The average SiO2 content of the granites is 66.64%, and the rocks have high total alkali (K2O + Na2O) content, averaging 9.13%. The average K2O content is 4.39%, with a K2O/Na2O ratio of 0.93. The quartz porphyry rocks are enriched in SiO2 (74.41%–76.85%) and have high Na2O + K2O content (8.67%–9.59%), but are low in MgO (0.03%–0.09%), CaO (0.44%–1.02 %), and TiO2 (0.08%–0.12%). Most samples of the biotite granite and the quartz porphyry rocks exhibit high-K peraluminous and medium-K calc-alkaline characteristics, respectively. Both rock types are enriched in Rb, Th, U, K, Zr, Hf, and Gd and relatively depleted in Ba, Sr, P, Ti, Nb, Ta, and Eu, with a pronounced negative Eu anomaly. The biotite granites show high ∑LREE/∑HREE ratios (6.1–6.9), while the quartz porphyry rocks exhibit lower ratios (2.0–4.2). Both granitoid types have elevated FeOT content and FeOT/(FeOT + MgO) ratios, indicating that the Jinchanshan granitoids are A-type granites. The zircon U–Pb ages, combined with the regional tectonic settings, suggest that these granitoids formed during large-scale metallogenic events in the Early Cretaceous, within the Yanshanian post-orogenic extensional tectonic regime. This is consistent with the lithospheric thinning and extensional processes in Eastern China during this period.

Rubidium (Rb) enrichment processes in a highly evolved granitic system: Insights from the petrology and geochemistry of the Guobaoshan Rb deposit in eastern Tianshan, NW China

Highly fractionated granitoids are closely associated with Rb mineralization, yet the mechanisms that control Rb enrichment and details about the enrichment process have not been well constrained. The Guobaoshan Rb deposit in eastern Tianshan, NW China, is one of the largest granite-related Rb deposits; it preserves a series of gradual lithofacies ranging from biotite granite and muscovite granite to Rb-rich amazonite granite and pegmatite, and provides an excellent opportunity to constrain the Rb enrichment processes in granitic systems. The large Guobaoshan Rb deposit hosts 281,000 tons of Rb2O at a grade of 0.12% mainly in its amazonite-bearing granite and amazonite granite lithofacies. In this contribution, we integrate geochronology, bulk-rock geochemistry, and analysis of Nd and zircon Hf isotopes to characterize the evolution of the Guobaoshan granitic pluton and the mechanisms that generated Rb enrichment. The zircon U-Pb age of the biotite granite and columbite U-Pb age of the amazonite granite are 244.8 ± 1.8 Ma (1σ, mean square of weighted deviates [MSWD] = 1.1) and 241.9 ± 2.3 Ma (1σ, MSWD = 1.0), respectively. In situ Rb-Sr analysis of orthoclase, mica, and albite from the amazonite-bearing granite, amazonite granite, and pegmatite yields ages of 249.1 ± 7.3 Ma (2σ, MSWD = 1.6), 245.5 ± 16.8 Ma (2σ, MSWD = 0.63), and 245.8 ± 9.8 Ma (2σ, MSWD = 3.3), respectively. Together, these ages demonstrate that the Guobaoshan granitic pluton formed during the Triassic and underwent a protracted magmatic evolution. The Guobaoshan granitic pluton is characterized by high concentrations of SiO2, alkalis, and Al2O3, and low concentrations of MgO, Fe2O3, CaO, P2O5, and TiO2, with an Al saturation index (A/CNK) of 1.01−1.14. It is enriched in Rb, but depleted in Ba, Sr, P, and Eu, has low total rare earth element (REE) contents (83.1−221 ppm), and is characterized by significantly negative anomalies (Eu/Eu* = 0.01−0.44). The biotite granite is enriched in light rare earth elements (LREEs), whereas the muscovite granite, amazonite-bearing granite, amazonite granite, and pegmatite are depleted in LREEs, and exhibit a marked tetrad effect (TE1.3 = 1.05−1.50). These geochemical characteristics, combined with the non-CHARAC (charge-radius−controlled) ratios of Zr/Hf, Nb/Ta, Y/Ho, and K/Rb, are indicative of melt-fluid interaction during the evolution of the Guobaoshan magma. Given that the biotite granite is the least-evolved rock, its petrological and geochemical characteristics suggest that it is an I-type granite. The slightly variable εHf(t) and consistently negative εNd(t) values indicate that the magma from which the Guobaoshan granitic pluton crystallized was likely sourced from the Mesoproterozoic crust, with limited mantle contributions. The coeval ages and coherent geochemical variations and mineral compositions of these rocks suggest that they formed via fractional crystallization of plagioclase, mica, quartz, and K-feldspar in the same magmatic system. This is supported by fractional crystallization simulations using the rhyolite-MELTS software package. Based on the petrological, mineralogical, and geochemical characteristics of the muscovite granite, amazonite-bearing granite, amazonite granite, and pegmatite, as well as simulations using rhyolite-MELTS, high degrees of fractional crystallization of granitic magma and interaction of this evolving magma with F-rich fluids are suggested to have been the key mechanisms that caused enrichment of Rb, while the melt-fluid interaction was more critical for Rb mineralization.

Water content drives distinct evolution trajectory of Early Cretaceous granitoids in inland and coastal southeast China

Water plays a crucial role in determining the crystallization sequence of magma, which subsequently influences the chemical compositions of magmatic rocks across different tectonic settings. In this study, we compared the evolutionary features of granitic rocks along the coast and inland areas of southeast China, aiming to identify the key factors influencing their evolution. Our work indicates that multiple granitic intrusions formed between 126 and 142 Ma in the coastal region of southeastern China, which is consistent with the formation ages of large-scale granitoids in the inland Gan-Hang Belt. Isotopic characteristics suggest that the granitic rocks in southern Fujian originated from the melting of juvenile crust, while those in northern Fujian and eastern Zhejiang were formed from the partial melting of ancient crustal rocks, incorporating mafic magma evolved from the mantle. Most of the granitoids from the coastal region of southeastern China exhibit low zircon saturation temperatures (680–800 °C) and Zr/Sr ratios (<1), suggesting their origin from a cold, wet magma reservoir. The porphyritic quartz diorite and porphyritic monzogranite represent the residual cumulate rocks of this hydrous magma reservoir, whereas the granitic porphyry and high-silica equigranular alkali feldspar granite evolved from the felsic melts extracted from the same reservoir. In contrast, most of the Early Cretaceous granitoids in the Gan-Hang Belt, located in the inland areas of southeast China, display high zircon saturation temperatures (800–900 °C) and Zr/Sr ratios (>1), indicating their origin from hot, water-poor magma reservoirs. The porphyritic granites in this region represent residual cumulate rocks formed in water-poor magma reservoirs, whereas the high-silica equigranular granites evolved from hot felsic melts extracted from similar magma reservoirs. In the Early Cretaceous, the coastal region of southeastern China was closer to the Late Mesozoic paleo-Pacific subduction zone, where crystal-melt segregation within cold, wet magma reservoirs predominantly influenced magma evolution. Conversely, the granitoids in the Gan-Hang Belt in the inland region, located farther from the Late Mesozoic paleo-Pacific subduction zone, were associated with a rift tectonic setting and formed through crystal-melt segregation within hot, water-poor magma reservoirs. Our study underscores the critical role of water content in magma reservoirs in shaping the chemical composition of granitic rocks through crystal-melt segregation, thereby deepening our understanding of crustal formation processes across diverse tectonic environments.

Comparison of fracture behavior of set concretes based on natural and crushed aggregates

Abstract The studies were carried out to diagnose the effects of coarse aggregate type on the mechanical behavior of plain concretes under incremental loading. During the studies mechanical parameters including compressive strength (fcm) and splitting tensile strength (fctm), as well as fracture parameters involving critical stress intensity factor (K_Ic^S) and critical crack tip opening displacement (CTODc) were evaluated. Crushed aggregates covered: basalt (BA), granite (GT) and limestone (LM) and natural peeble gravel aggregate (GL) were used in the concrete mixtures. The composite made on pebble aggregate acted as a reference concrete, as it were, in the analysis of the test results. For better understanding of the crack initiation and propagation in concretes with different coarse aggregates, a macroscopic failure surfaces examination of the tested beams is also presented. Both of the analyzed fracture mechanics parameters, i.e. 〖 K〗_Ic^S and CTODc increased significantly in the case of concretes which were manufactured based on crushed aggregates. They amounted in comparison to concrete based on gravel aggregate at levels ranging from 20% for concrete with limestone aggregate, to over 30% for concrete with a granite aggregate, and to as much as over 70% for concrete with basalt aggregate. Moreover, a clear correlation in the changes in the obtained results between the main strength parameters and fracture mechanics parameters was observed. The fracture process in each series of concrete was: quasi-plastic in the case of gravel concrete, semi-brittle in the case of limestone concrete, and clearly brittle in the case of the concretes based on granite and basalt aggregate. The results obtained help to explain how the coarse aggregate type affects the strength parameters and fracture toughness at bending.

Effect of Coarse Aggregate Type on the Fracture Toughness of Ordinary Concrete

This research work aims to compare the strength and fracture mechanics properties of plain concretes, obtained from different coarse aggregates. During the study, mechanical parameters including compressive strength (fcm) and splitting tensile strength (fctm), as well as fracture parameters involving critical stress intensity factor (KIcS) and critical crack tip opening displacement (CTODc) were evaluated. The effect of the aggregates used on the brittleness of the concretes was also analyzed. For better understanding of the crack initiation and propagation in concretes with different coarse aggregates, a macroscopic failure surfaces examination of the tested beams is also presented. Crushed aggregates covered were basalt (BA), granite (GT), and limestone (LM), and natural peeble gravel aggregate (GL) were used in the concrete mixtures. Fracture toughness tests were performed on an MTS 810 testing machine. Due to the high strength of the rock material, the rough surface of the aggregate grains, and good bonding in the ITZ area between the aggregate and the paste, the concretes with crushed aggregates exhibited high fracture toughness. Both of the analyzed fracture mechanics parameters, i.e., KIcS and CTODc, increased significantly in the case of concretes which were manufactured with crushed aggregates. They amounted, in comparison to concrete based on gravel aggregate, to levels ranging from 20% for concrete with limestone aggregate to over 30% for concrete with a granite aggregate, and to as much as over 70% for concrete with basalt aggregate. On the other hand, the concrete with gravel aggregate showed the lowest fracture toughness because of the smooth surface of the aggregate grains and poor bonding between the aggregate and the cement paste. However, the fracture process in each series of concrete was quasi-plastic in the case of gravel concrete, semi-brittle in the case of limestone concrete, and clearly brittle in the case of the concretes based on granite and basalt aggregates. The results obtained help to explain how the coarse aggregate type affects the strength parameters and fracture toughness at bending.

Application of Different Image Processing Methods for Measuring Rock Fracture Structures under Various Confining Stresses

Fractures within granite may become channels for fluid flow and have a significant impact on the safety of waste storage. However, internal aperture variation under coupled conditions are usually difficult to grasp, and the inevitable differences between the measured data and the real fracture structure will lead to erroneous permeability predictions. In this study, two different CT (Computed Tomography) image processing methods are adopted to grasp internal fractures. Several CT images are extracted from different positions of a rock sample under different confining stresses. Two critical factors, i.e., aperture and the contact area ratio value within a single granite fracture sample, are investigated. Results show that aperture difference occurs under these two image processing methods. The contact area ratio value under two image processing methods has less than 1% difference without confining stress. However, there is larger than ten times difference when the confining stress increases to 3.0 MPa. Moreover, the edge detection method has the capability to obtain a relatively accurate internal fracture structure when confining pressure is applied to the rock sample. The analysis results provide a better approach to understanding practical rock fracture variations under various conditions.

Damage index correlation in massive granite-porous backfills under hydromechanical triaxial cyclic loading using acoustic emissions and X-ray computed tomography

The characterization accuracy of damage indices in massive and porous composite biomaterials under complex osmotic conditions has long been a challenge in engineering materials science. Establishing correlations between damage indices calculated using different methodologies is crucial to validate and improve defects characterizations. In this study, we investigated the damage index correlation of cylindrical massive granite-porous backfill structural composites under both dry and seepage conditions. A series of triaxial cyclic loading and unloading tests were conducted on specimens under hydromechanical conditions with varying osmotic pressures (0, 1, 3, 5, 7, and 9 MPa) and a confining pressure of 9 MPa involving acoustic emission monitoring and phase-based 3D nondestructive CT scanning. The results revealed the AE energy was lower under osmotic conditions compared to dry conditions. The AE Damage Index (DAE), defined by separating tensile and shear microcracking signals, significantly increased from 0.32 to 0.55 with rising osmotic pressure. 3D mesoscopic fracture visualization provided detailed insights into the fractures in granite and backfill interfaces. The number of small-angle cracks increased with osmotic pressure, and the crack inclination distribution range expanded from 63°- 85° to 49°–80°. The average crack angle showed a significant monotonic decrease with increasing osmotic pressure. An Energy Dissipation Damage Index (DED) was defined, and its correlation with the DAE under dry conditions was modeled using a reciprocal function DED=a/(DAE+bσ3)+c. This novel approach offers insights into the transition points between tensile and shear-dominated failure stages. Furthermore, an exponential function DV=aDAEb(b<0) was used to model the correlation between AE Damage Index and Visual Damage Index (DV) under osmotic conditions. The damage indices derived from different methods can be mathematically correlated, providing a comprehensive evaluation of material damage states. The study found the flow transition between different natural-human medias results in different damage mechanisms, which are all obey the correlation law. These damage mechanisms offered constructive recommendations for engineering applications based on varying ratios of osmotic pressure to confining pressure.

Advanced exploration of rare metal mineralization through integrated remote sensing and geophysical analysis of structurally-controlled hydrothermal alterations

Fusing multi-source (remote sensing and geophysical) data and diverse approaches validation in targeting hydrothermal alteration and structural anomalies enhances the potential for accurately detecting and characterizing mineralization zones. Sentinel 2 data and ASTER were processed for lithological and hydrothermal alteration mapping in the rare metal-rich Umm Naggat area (Egypt). Different image processing techniques were implemented, including false color composites, minimum noise fraction, band rationing, band math, mineral indices, relative absorption band depth, and constrained energy minimization. The rare metal-bearing Umm Naggat younger granite (NYG) pluton was lithologically discriminated and intra-differentiated to mafic-rich biotite granites, mafic-poor alkali feldspar granites, and albitized granites. Extensive hydrothermal alterations, such as albitization, ferrugination, propylitization, argillization, and phyllitization, overprint the NYG pluton. Normalized standard deviation, automatic lineament extractions, and trend analysis highlighted the key structural directions (NW, NNW, NNE, and NE) and distinguished the NYG pluton as a moderate to high structural density zone. The high structural density and intensive alteration zones are spatially associated and more localized within the NYG pluton than the surrounding rocks. Spatial overlay analysis confirmed that the hydrothermal alterations and fluid circulation systems are structurally-controlled. Furthermore, the hydrothermal alteration mapping and structural analysis outcomes were verified by combining fieldwork, slab polishing, petrographic investigations, and mineral chemistry through semi-quantitative scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and quantitative electron probe microanalysis (EPMA) analysis. As a result, the hydrothermal genesis of rare metal-bearing minerals (Nb-rutile, Nb-ilmenite, and columbite) close to or incorporated within alteration minerals (chlorite, muscovite, and hematite) is confirmed from the alteration zones (propylitic, phyllic, and ferruginated). In addition, biotite muscovitization and chloritization significantly contribute to the secondary rare metal enrichment. The current study emphasizes the extensive distribution of secondary rare metal-bearing minerals within the entire NYG pluton (not only limited to the northern albitized granite as depicted by previous studies), which might shed light on these hydrothermally-altered younger granites as a new potential source for Nb and Ta in Egypt.

Analysis of microstructure of prefabricated fractured granite under thermal effects based on CT technology

In this study, Computed Tomography (CT) technology was employed to visually analyze the influence of thermal effects on the microstructure of prefabricated fractured granite. The porosity and heterogeneity of the samples were calculated using three-dimensional reconstruction techniques, and two parameters, crack length and orientation, were introduced to quantitatively evaluate the impact of prefabricated fractures on subsequent crack propagation. The results indicated that at 400 °C–500 °C, numerous microcracks were generated within the samples, but they did not interconnect. Above 600 °C, microcracks gradually propagated, forming well-connected crack networks. Due to the uneven thermal stress distribution caused by the prefabricated fractures, samples subjected to temperatures above 600 °C exhibited higher heterogeneity in the vertical direction. While in other directions, the samples gradually tended to homogenize as the temperature rose. Below 500 °C, crack length was significantly affected by the prefabricated fractures, although this influence diminished with increasing distance from the fractures. When the temperature was below 400 °C, microcracks mainly propagated along the direction of the prefabricated fractures. However, when the temperature exceeded 500 °C, microcracks began to initiate and propagate in the opposite direction of the prefabricated fractures, and anti-wing cracks started to emerge.

Petrogenesis of REE-mineralized granitic plutons in central Thailand, Southeast Asian tin belt: New insights from geochemistry and zircon U–Pb geochronology

Granitic rocks including biotite granite and biotite-muscovite granite exposed in the Uthai Thani area, central Thailand are located on the main eastern and central granitic belts of Southeast Asia. The biotite granites are characterized by an equigranular texture, whereas biotite-muscovite granites exhibit a porphyritic texture with K-feldspar megacrysts. Geochemically, biotite granites show metaluminous to weakly peraluminous high-K calc-alkaline affinity, whereas biotite-muscovite granite exhibits strongly peraluminous and shoshonitic. The biotite granites and biotite-muscovite granites have trace element features consistent with formation in subduction and syn-collision settings, respectively. The pressure–temperature conditions of emplacement in biotite and biotite-muscovite granite types are 1.94–2.28 kbar/676 °C–713 °C and 1.39–2.00 kbar/669 °C–698 °C, respectively, indicating solidification in upper crustal paleo-depths. Positive εHf (t) values of zircon in the biotite granites indicate similarity to I-type granite of the Sukhothai Terrane, whereas negative εHf (t) values of zircon in the biotite-muscovite granites compare well with S-type granites form in the Inthanon zone. Zircon U–Pb geochronology indicates that biotite granites might have emplaced during the Late Triassic is related to Paleo-Tethys subduction beneath the Indochina terrane, whereas biotite-muscovite granites might have emplaced during the Late Triassic to Early Jurassic period, probably as a result of collision between the Sibumasu and the Indochina Terranes. In the Uthai Thani area, the high total REE contents and the presence of primary REE minerals in granitic rocks reflect mineralization potential with respect to light REE, together with the magmatism related to Fe-Cu and Sn mineralization along the main granite belts in Thailand.

Multi‐Stage Magmatism During Slab Exhumation Drives the Geochemical Evolution of Continental Crust: Insights From Paleozoic Granitoids in South Altyn, Western China

AbstractThe present continental crust is characterized by a felsic upper crust and a mafic lower crust, resulting from significant geochemical differentiation over geological time. While various processes have been proposed to explain this differentiation, subduction zones remain pivotal regions for understanding the compositional evolution of continental crust. This study focuses on the South Altyn (SA) continental subduction‐collision belt in western China, a unique setting that experienced ultra‐deep (&gt;300 km) continental subduction followed by multi‐stage exhumation. We present a comprehensive study of four granitoid suites from Tatelekebulake (TTLK) area in SA: biotite granite (BG), monzogranite (MG), K‐feldspar granite (KG), and leucogranite (LG). Comprehensive studies on petrology, geochemistry and zircon U‐Pb dating show that these granitoids formed at 494, 451, 414, and 418 Ma, respectively, and originated from protoliths with affinity to the subducted continental crust in SA. Phase equilibrium modeling suggests that BG formed at ∼800°C and 0.6 GPa, while the MG, KG, and LG formed by differentiation crystallization of the BG magma under progressively decreasing temperature and pressure conditions (750°C, 0.5 GPa; 740–700°C, 0.2 GPa; and 700–640°C, 0.1 GPa, respectively). These results, combined with previous studies, allow us to reconstruct the tectonic processes of continental exhumation and subsequent orogenic collapse in SA during the Early Paleozoic. Importantly, our findings reveal that magmatism derived from partial melting of subducted continental crust can promote the geochemical evolution of continental crust toward more felsic compositions, even in the absence of significant crustal growth or mantle‐derived magmatism. This study provides a valuable case for understanding the compositional evolution of continental crust in deep subduction zones and challenges conventional models that rely heavily on arc magmatism for crustal differentiation. Moreover, our results contribute to a broader understanding of crustal evolution processes in collisional orogens worldwide and highlight the importance of recycling and differentiation of subducted continental material in shaping crustal compositions.