This article presents a comprehensive Computational Fluid Dynamics (CFD) assessment of fast pyrolysis of three different agricultural feedstocks representing three different categories: Red oak (hardwood), Switchgrass (herbaceous biomass), and Picea glauca (softwood). The study aimed to evaluate the performance of each feedstock based on particle density, temperature distribution, and volume fraction distribution. The comparison of the simulation results with experimental data showed an average error factor below 13%. The study discovered that Red oak had the highest bio-oil production yield, followed by Switchgrass, which had a yield 10% lower, and Picea glauca, which had the weakest performance having a yield 20% lower than Red oak. Interestingly, optimal operating conditions for the production of bio-oil across all three feedstocks comprised a temperature of 500 °C and particle size of approximately 400 μm. However, increasing the pyrolysis temperature resulted in an increase in gas yield, whereas increasing particle size led to a rise in char production yield. Furthermore, the findings suggest that herbaceous biomass tends to perform better in fast pyrolysis for bio-oil production compared to softwood. This is attributed to the higher hemicellulose content in herbaceous feedstock which has a significant impact on bio-oil yield compared to cellulose and lignin. Moreover, hardwood and herbaceous samples, which have similar levels of cellulose and hemicellulose, demonstrated superior performance compared to softwood, which has lower hemicellulose content. Nonetheless, herbaceous biomass had about 10% extractable content, which made it perform weaker than hardwood.
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