Biodegradation In Soil Research Articles

Hydrogenating Polyethylene Terephthalate into Degradable Polyesters

The recycling and upcycling of polyethylene terephthalate (PET), the most widely used polyester plastic globally, has attracted growing attention concerning its disposal as non‐degradable waste in the natural environment. Transforming end‐of‐life PET into (bio)degradable polyester offers a novel approach to managing its waste. In this study, we introduce a simple process capable of converting waste PET into degradable polyester, polyethylene terephthalate‐polyethylene‐1,4‐cyclohexanedicarboxylate (PET‐PECHD), by partly hydrogenating the aromatic rings (x) into aliphatic ones (y). The polyesters with variable x/y compositions ranging from 100/0 to 0/100 can be achieved, and the molecular weight (Mw) can be maintained when x/y > 87/13 due to the nonobvious depolymerization. Pronounced depolymerization would occur with deeper hydrogenation, which generates a blend of PET‐PECHD and polyethylene‐1,4‐cyclohexanedicarboxylate (PECHD) with lower Mw, and finally a single‐type polymer PECHD. The PET‐PECHD demonstrates comparable thermal stability and mechanical strength compared to PET, along with superior extensibility, barrier properties, and (bio)degradability in acidic, alkaline solutions, and moist soil. This research highlights the potential for cost‐effective, large‐scale production of degradable polyester from real‐life plastic waste.

Hydrogenating Polyethylene Terephthalate into Degradable Polyesters.

The recycling and upcycling of polyethylene terephthalate (PET), the most widely used polyester plastic globally, has attracted growing attention concerning its disposal as non-degradable waste in the natural environment. Transforming end-of-life PET into (bio)degradable polyester offers a novel approach to managing its waste. In this study, we introduce a simple process capable of converting waste PET into degradable polyester, polyethylene terephthalate-polyethylene-1,4-cyclohexanedicarboxylate (PET-PECHD), by partly hydrogenating the aromatic rings (x) into aliphatic ones (y). The polyesters with variable x/y compositions ranging from 100/0 to 0/100 can be achieved, and the molecular weight (Mw) can be maintained when x/y > 87/13 due to the nonobvious depolymerization. Pronounced depolymerization would occur with deeper hydrogenation, which generates a blend of PET-PECHD and polyethylene-1,4-cyclohexanedicarboxylate (PECHD) with lower Mw, and finally a single-type polymer PECHD. The PET-PECHD demonstrates comparable thermal stability and mechanical strength compared to PET, along with superior extensibility, barrier properties, and (bio)degradability in acidic, alkaline solutions, and moist soil. This research highlights the potential for cost-effective, large-scale production of degradable polyester from real-life plastic waste.

Hydrogen isotope labeling unravels origin of soil-bound organic contaminant residues in biodegradability testing

Biodegradability testing in soil helps to identify safe synthetic organic chemicals but is still obscured by the formation of soil-bound ‘non-extractable’ residues (NERs). Present-day methodologies using radiocarbon or stable (13C, 15N) isotope labeling cannot easily differentiate soil-bound parent chemicals or transformation products (xenoNERs) from harmless soil-bound biomolecules of microbial degraders (bioNERs). Hypothesizing a minimal retention of hydrogen in biomolecules, we here apply stable hydrogen isotope – deuterium (D) – labeling to unravel the origin of NERs. Soil biodegradation tests with D- and 13C-labeled 2,4-D, glyphosate and sulfamethoxazole reveal consistently lower proportions of applied D than 13C in total NERs and in amino acids, a quantitative biomarker for bioNERs. Soil-bound D thus mostly represents xenoNERs and not bioNERs, enabling an efficient quantification of xenoNERs by just measuring the total bound D. D or tritium (T) labeling could thus improve the value of biodegradability testing results for diverse organic chemicals forming soil-bound residues.

Circular Economy in Action: Transforming Textile Waste into sustainable soil additives - physicochemical properties and biodegradability

In recent years, there has been an increasing interest in soil additives used in environmental ecosystems. Currently, most soil amendments are produced from synthetic materials. Some synthetic amendments break down into microplastics, which persist in the environment and can be ingested by soil organisms, affecting soil health and biodiversity and the chemicals they contain can leach into groundwater. At the same time, the number and availability of biodegradable technologies are limited, and the aspects related to their biodegradation in soil are not sufficiently known. The study developed a sustainable water-saving and vegetation-supporting technology in the form of a biodegradable water-absorbing geocomposite (BioWAG). BioWAGs were produced using biodegradable materials derived from animal and plant waste, such as waste wool, jute, and linen. In a three-year field experiment, their physicochemical properties in the soil were analyzed. These were characterized using a.o. surface weight, scanning electron microscopy (SEM), and FTIR. The results indicate that the degree of biodegradation of materials used in BioWAG depended on the raw material and production technology. Needle-punched nonwovens underwent intensive biodegradation just 6 months after being buried in the soil, while stitched nonwovens retained their mechanical properties even for three growing seasons. In the case of seamed non-woven fabrics, a decrease in selected physical parameters was observed. The addition of wool-based soil additive, a decrease in surface mass was observed by 85% after 6 months, 88% after 18 months and 90% after 30 months. Regardless of the waste materials used, BioWAGs provided plants with continuous access to water and nutrients. The work indicates a sustainable method of managing textile waste and analyzes its properties in the soil, which enables the development of technologies based on natural fibers for applications such as geotextiles, mulches and controlled-release fertilizers. The technology was developed in line with the principles of a circular economy and can improve soil quality, mitigate the effects of climate change and reduce environmental pollution.

A multi-layer antimicrobial cellulose filter with electrostatic adsorption properties prepared by coating cellulose with chitosan and CuO

The health impacts of air pollution such as particulate matter (PM) and bioaerosols have prompted a focus on the utilization of personal protective filters. Traditional filters pose environmental concerns due to their non-biodegradable composition, while cellulose presents a promising alternative for biodegradable air filtration applications. This research involved the development of cellulose filter substrates with a customizable pore structure by adjusting the nanofiber content in cellulose filters and employing a simultaneous freeze-drying method. By integrating chitosan and CuO nanoparticles, the filters gained electrostatic adsorption capabilities, leading to a substantial enhancement in filtration efficiency, as well as imparting moisture resistance and durable antimicrobial properties to the filter. Subsequently, a three-layer cellulose filter integrated with chitosan and CuO (abbreviated as Int-Cs&CuO) was constructed based on the generalized Murray’s law to enable multi-stage PM filtration. The Int-Cs&CuO cellulose filter demonstrated filtration efficiencies of 99.2 % for non-oily PM0.3 and 99.5 % for oily PM0.3, with a low pressure drop of 49.5 Pa. Under humid conditions, the filtration efficiency of the Int-Cs&CuO cellulose filter against PM0.3 particles was minimally impacted, showcasing a decrease of only 1.3 %. Notably, the filter exhibited complete biodegradation in composted soil within approximately 2 months.

Synergistic biodegradation of trichloroethylene-contaminated soil using Typha angustifolia L. and an anaerobic degrading bacterial consortium

Plant-microorganism combined bioremediation is a highly efficient and environmentally sustainable method for the remediation of contaminated soils. Despite its potential, the synergistic effects of wetland plants and anaerobic microbial consortium on the removal of chlorinated hydrocarbons (CAHs) from soil remain inadequately understood. In this study, an anaerobic bacterial consortium, capable of completely dechlorinating trichloroethylene (TCE), was enriched and screened from long-term CAH-contaminated soil. Subsequently, the combined effects of the wetland plant Typha angustifolia L. and the degrading bacterial consortium on the removal of TCE from soil were investigated, along with the underlying microbial mechanisms. The results demonstrated that the bacterial consortium was able to completely convert 0.5 mM TCE to vinyl chloride (VC) within 7 days, and subsequently degrade VC to ethylene within 48 days. The integration of Typha angustifolia L. with the degrading bacterial consortium significantly enhanced both the removal and complete dechlorination of TCE from the soil compared to either treatment alone. Furthermore, this combination substantially increased the diversity and richness of soil bacterial communities, enriched dechlorinating microorganisms, and elevated the relative abundance of dehalogenating enzymes and peroxidases involved in pollutant degradation. In addition, the combination resulted in a more complex soil bacterial community, closer microbial interactions, and a more stable microbial co-occurrence network. This study extends the scope of plant-microorganism combined bioremediation for CAH- contaminated soils.

Extension of shelf life of tomato (Solanum lycopersicum L.) by using a coating of polyhydroxybutyrate-carboxymethyl cellulose-pectin-thymol conjugate.

This study targets explicitly finding an alternative to petroleum-based plastic films that burden the environment, which is a high priority. Hence, polymeric films were prepared with carboxymethyl cellulose (CMC) (4%), pectin (2%), and polyhydroxybutyrate (PHB) (0.5%) with different concentrations of thymol (0.3%, 0.9%, 1.8%, 3%, and 5%) and glycerol as a plasticizer by solution casting technique. The prepared films were tested for mechanical, optical, antimicrobial, and antioxidant properties. Film F5 (CMC+P+PHB+0.9%thymol) showed an excellent tensile strength of 15MPa, Young's modulus of 395MPa, antioxidant activity (AA) (92%), rapid soil biodegradation (21 days), and strong antimicrobial activity against bacterial and fungal cultures such as Klebsiella pneumoniae, Staphylococcus aureus, Escherichia coli, Aspergillus niger, and Aspergillus flavus. The thymol content increase in films F6 (1.8%), F7 (3%), and F8 (5%) displayed a decrease in mechanical properties due to thymol's hydrophobicity. For shelf life studies on tomatoes, F2, a film without thymol (poor antimicrobial and antioxidant activities), F5 (film with superior mechanical, optical, antimicrobial, and antioxidant properties), and F7 (film with low mechanical properties) were selected. Film F5 coatings on tomato fruit enhanced the shelf life of up to 15 days by preventing weight loss, preserving firmness, and delaying changes in biochemical constituents like lycopene, phenols, and AA. Based on the mechanical, optical, antimicrobial, antioxidant, and shelf life results, the film F5 is suitable for active food packaging and preservation. PRACTICAL APPLICATION: The developed active biodegradable composite can be utilized as a coating to extend the shelf life of fruits and vegetables. These coatings are easy to produce and apply, offering a sustainable solution to reduce food waste. On an industrial scale, they can be applied to food products, ensuring longer freshness without any technical challenges.

Mixed dimensional assembly of biodegradable and antifouling wood-based covalent organic framework composite membranes for rapid and efficient dye/salt separation

Manipulating materials of different dimensions into heterogeneous nanofiltration membranes with unique physicochemical properties and molecular sieving channels provides an effective way for accurate and fast molecular separation. Here we introduce a heterogeneous structure hybrid connection strategy to fabricate biodegradable wood-based covalent organic framework (COF) composite membranes. As a proof of concept, 3D Picea jezoensis (Siebold & Zucc.) Carrière was selected as the substrate of the membrane and in situ growth of 2D iCOF selective layers. Effective modulation of iCOF layers by 1D sulfonated polyaryletherketone (SPEEK-Na) using the “needle and thread” method. The rearrangement of the above multidimensional materials formed charge-regulated properties of laminar nano-channels and smooth hydrophilic contact area, thereby endowing specific molecular transport pathways and sieving capability for efficient dye/salt separation under ultra-low pressure of 0.5 bar. The wood-based heterostructured membranes exhibited high dye rejection (>97 %), low salt rejection (<10 %), and high permeance (172.34 L m−2 h−1 bar−1), which is superior to many reported dye/salt separation membrane materials. In addition, the system exhibited a certain degree of operational stability, good antifouling, and soil biodegradability. Overall, this work enables the design and fabrication of heterostructured separation membranes to be obtained from nature and used in nature, resulting in efficient and sustainable water purification applications.

Effect of Different Ratios of Polyvinyl Alcohol‐Gum Odina for the Preparation and Characterization of Biodegradable Composite Films

ABSTRACTThis research investigates the production of biodegradable films using a combination of gum odina (GO) and polyvinyl alcohol (PVA) with varied ratio. The study focuses on the chemical, physical, and mechanical properties of PVA‐GO composite films, emphasizing how versatile and biodegradable they may be for a range of packaging applications. Solvent‐cast PVA‐GO films with different ratios are subjected to a methodical analytical process to determine several parameters like mechanical qualities, thermal stability, biodegradability in soil, contact angle, transparency, water vapor permeability, moisture content, thickness, density, water solubility, microstructure, and FTIR analysis. The outcomes demonstrate that GO improves UV barrier qualities and water vapor permeability. Additionally, the films showed notable biodegradability, acceptable thermal stability, and mechanical qualities. In short, PVA‐GO films can provide an eco‐friendly packing substitute with adaptable qualities fit for a range of uses. Therefore, this research may further contribute promising information in the field of biodegradable packaging materials in the future.

Development, Soil Biodegradation, and Kinetics Evaluation of Starch-Based Bioplastic from Sechium edule and Phaseoulus vulgaris

Development, Soil Biodegradation, and Kinetics Evaluation of Starch-Based Bioplastic from Sechium edule and Phaseoulus vulgaris

Enhanced indigenous bacteria-mediated bioremediation of aged petroleum-contaminated soil by Fenton pretreatment: Synergistic effect of soil environmental improvement and microbial community response

Due to the harsh soil environment and low microbial activity, the efficacy of indigenous bacteria-mediated bioremediation is often limited in aged petroleum-contaminated soils. In this study, Fenton pretreatment (H2O2: 200 ∼ 600 mmol/kg, H2O2: Fe2+ = 100: 1) was applied to improve the aged soil environment and rebuild the microbial community to enhance subsequent bioremediation. After pretreated by 400 mmol/kg H2O2 and 4 mmol/kg Fe2+ (T2), the removal efficiency of total petroleum hydrocarbons (TPHs) was elevated to 93.27 %, equivalent to 1.96-fold of the natural attenuation (CK). Additionally, the half-life of biodegradation was shorted to 45.57 d, representing a decrease to 0.29-fold that of CK. Correlation analysis revealed a radar plot comprising five indicators, including bacterial quantification (BQ), dehydrogenase (DHA), polyphenol oxidase (PPO), permeability coefficient (K), and bulk density coefficient (γ), all of which exhibited positive correlations with TPHs degradation. Compared to CK, Fenton pretreatment increased the richness and evenness of the microbial community during incubation, thus facilitating TPHs biodegradation. Moreover, Fenton pretreatment accelerated the shift of the dominant genus in T2 from Pseudomonas (0.599) to Pseudomonas (0.258), Nocardioides (0.109), Dietzia (0.157), and Stenotrophomonas (0.120) throughout the incubation. Based on the analysis of Kyoto Encyclopedia of Genes and Genomes (KEGG), the metabolism and enzymatic functional genes related to the biodegradation of petroleum hydrocarbons in T2 were enhanced during incubation, accounting for the high removal efficiency of TPHs. These findings demonstrated that moderate Fenton pretreatment was an effective approach to stimulate indigenous bacteria for the enhanced biodegradation of aged petroleum-contaminated soil.

Embracing Nature's Clockwork: Crafting Plastics for Degradation in Plant Agricultural Systems.

In the 21st century, global agriculture confronts the urgent challenge of increasing food production by 70% by 2050 while simultaneously addressing environmental and health concerns. Plastics, integral to agricultural innovation, present sustainability challenges due to their non-biodegradable nature and contribution to pollution. This perspective examines the transition to bioplastics, emphasizing their bio-based origin and their crucial characteristic of being readily biodegradable in the soil. Key bioplastics such as poly(lactic acid) (PLA), polyhydroxyalkanoates (PHAs), and biomass-derived polymers are discussed, particularly regarding the microplastic generation in soil resulting from their use in specific applications like mulch films, delivery systems, and soil conditioners. Embracing bioplastics signifies a significant step forward in achieving sustainable agriculture and addressing plastic waste. However, it is highlighted that while some bioplastics can be recovered and recycled, special applications where the plastic is in intimate contact with soil pose challenges for recovery. In these cases, that represent more than the 50% of plastics used in agriculture, meticulous design for biodegradation in soil synchronized with agricultural cycles is necessary. This approach ensures minimal environmental impact and promotes a circular approach to plastic use in agriculture.

Functional pH-sensitive film based on pectin and whey protein for grape preservation and shrimp freshness monitoring

A pH-sensitive film was prepared from pectin (P) and whey protein (W), incorporating anthocyanin-rich purple sweet potato extract (PPE) as the pH indicator. The effect of PPE content on the structure and properties of the films and the pH indicating function were determined and evaluated for shrimp freshness and grape preservation. The solubility (60.23 ± 7.36 %) and water vapor permeability (0.15 ± 0.04 × 10−11 g·cm/(cm2·s·Pa)) of the pectin/whey protein/PPE (PW-PPE) film with 500 mg/100 mL PPE were the lowest of the films tested and much lower than PW films without PPE. PW-PPE films were non-cytotoxic and had excellent biodegradability in soil. Grapes coated with PW-PPE film had reduced weight loss from water evaporation, and decay during storage was inhibited. The total color change (ΔE) of the PW-PPE films had a strong linear correlation with the pH of shrimps during storage. PW-PPE films have application potential to monitor the real-time freshness of meat and extend the shelf life of fruit.

Biodegradable active films based on Chlorella biomass and cellulose nanocrystals isolated from hemp stalk fibers

Cellulose nanocrystals (CNC)-reinforced biopolymers have emerged as a widely embraced approach for enhancing the characteristics of biopolymers due to their exceptional properties. Biocomposite (Chl-CNC) films were fabricated by blending Chlorella biomass and varying concentrations of CNCs via a solution casting technique. CNCs were effectively isolated from hemp stalk fibers, as confirmed by structural, surface, thermal, and morphological analysis. The crystallinity of films increased by CNC incorporation, which was confirmed by the XRD. The presence of molecular interactions between CNC and protein-rich Chlorella biomass was illustrated with the FTIR analysis. These interactions enhanced the physicochemical properties of the films. Further, films demonstrated a high level of soil biodegradation in the 42 days, while their total phenolic, chlorophyll, carotenoid contents, and antibacterial activity were unaffected by the incorporation of CNCs. The Chl-CNC films, regardless of CNC addition, indicated antimicrobial activity toward Escherichia coli but not Staphylococcus aureus. These results indicate that developed biobased and biodegradable Chl-CNC films could be highly beneficial in active food packaging applications.

Cellulose nanofiber powered interface engineering strategy to manufacture mechanically stable, moldable, recyclable, and biodegradable cellulose foam

In this work, an ingenious and energy-efficient interface engineering strategy is developed to manufacture pulp cellulose foam via incorporating cellulose nanofiber/alkyl ketene dimer (CNF/AKD) Pickering emulsions. In this strategy, CNF/AKD emulsion can uniformly anchor onto pulp microfiber surface, not only achieving interfacial exoskeleton reinforcement, but also enabling low energy surface, which facilitates the direct and large-scale production of lightweight pulp/CNF/AKD (PCA) foam by oven drying without requiring any harmful crosslinking chemistries. By simply regulating the mass fractions of CNF and AKD in emulsion, the prepared PCA foams can achieve excellent and tunable 3D porous structure, mechanical performance, water resistance and wet stability. The dry compressive modulus and wet compressive modulus underwater of PCA foams with low density of 0.09 g/cm3 can reach 0.67 and 0.57 MPa, respectively. Even 1 week in water, the compressive modulus still retains 76.2 % of initial modulus. Notably, the proposed interface engineering strategy provides remarkable formability, moldability and structural designability, enabling cellulose foam to be customized into complex and delicate 3D macroscopic structures for different scenarios. Furthermore, the PCA foam displays economically feasible closed-loop recyclability by easy hot-water disintegration and natural biodegradability in soil. Therefore, this work proves a cost-effective and viable interface engineering strategy for scalable production of lightweight, mechanically stable, recyclable, biodegradable cellulose foams with high environmental benefits and low petrochemical consumption.

Biobased Polybutyrolactam Nanofiber with Excellent Biodegradability and Cell Growth for Sustainable Healthcare Textiles.

The white pollution caused by unsustainable materials is a significant challenge around the globe. Here, a novel and fully biobased polybutyrolactam (PBY) nanofiber membrane was fabricated via the electrospinning method. As-spun PBY nanofiber membranes have good thermal stability, high porosity of up to 71.94%, and excellent wetting behavior. The biodegradability in soil, UV aging irradiation, and seawater was investigated. The PBY nanofiber membrane is almost completely degraded in the soil within 80 days, showing excellent degradability. More interestingly, γ-aminobutyric acid, as a healthcare agent with intrinsic hypotensive, tranquilizing, diuretic, and antidiabetic efficacy, can be detected in the degradation intermediates. In addition, the PBY nanofiber membrane also exhibits antibacterial ability against Escherichia coli. As a fully biomass-derived material, the PBY membrane has excellent biodegradable performance in various environments as well as negligible cytotoxicity and commendable cell proliferation. Our PBY nanofiber membrane shows great potential as biodegradable packaging and in vitro healthcare materials.

Impact on the incorporation of metals in physicochemical and antimicrobial properties in films based on arrowroot starcha

New biodegradable packaging has been developed from renewable sources, mainly of vegetable origin. Arrowroot starch has been recently used to produce high-quality biodegradable films capable of behaving well when incorporating oils, extracts, metal, and metal nanocomposites. The study aimed to verify the impact of incorporating metals in the sulfate and chloride forms in a biopolymeric matrix from arrowroot starch in terms of biodegradability, physicochemical and microbiological parameters. Different arrowroot films were produced to incorporate solutions with a concentration of 1 Mol L-1 of sulfate and chloride metals. The action of biodegradability in soil, UV transmittance, and visible light were observed in UV-Vis spectrophotometry and antimicrobial action on Escherichia coli, Staphylococcus aureus, Salmonella serovar Typhimurium, and Salmonella serovar Enteritidis. Good results were obtained, such as biodegradability time between 81.70 to 100 % (30 days), a low transmission rate of UV radiation and visible light between 250 to 890 nm, high capacity for bacterial inhibition between 22.08 to 10.05 mm for E. coli, among 25.59 to 11.10 mm for S. aureus, between 22.14 to 11.66 mm for S. serovar Typhimurium and between 21.11 to 8.26 mm for S. serovar Enteritidis. It is concluded that the biodegradable films of arrowroot starch incorporated with metals showed potential in all the evaluated tests, thus characterizing possible new products for different uses, such as low time available in the environment, preservation of the characteristics of special products, and antimicrobial capacity.

Development of a Chitosan‐Based Food Packaging Film with the Incorporation of Pectin and Silver Nanoparticles for Improved Antibacterial and Physical Properties

AbstractThis research incorporated grapefruit peel‐derived Pectin and Silver nanoparticles (AgNPs) into the Chitosan‐based bio‐packaging film to improve its antibacterial efficacy and physical properties such as moisture content, swelling degree, and biodegradability in soil. Systematic investigations revealed that preservative films made from Chitosan 1.75 wt %, Pectin 0.55 wt %, and AgNP 31 ppm have shown a 17.5‐fold reduction in swelling degree in water compared to Chitosan films. At the same time, the anti‐gram‐positive and anti‐gram‐negative bacteria capacity, the ability to retain moisture, and biodegradability in soil, have been enhanced. Low swelling degrees provided better barrier performance, extending the shelf life of packaged products by preventing the ingress of oxygen, and water vapor; on the other hand, higher moisture content improved the flexibility and handling characteristics of packaging films, making them easier to manipulate during packaging processes. These findings herald a sustainable option for eco‐friendly food packaging, a critical step toward minimizing plastic waste and strengthening food preservation procedures using Chitosan‐based antibacterial films enhanced with natural additives.

Development, characterization and application of chitosan/locust bean gum based multifunctional green food packaging containing Koelreuteria paniculata Laxm. bracts extract and Ti-carbon dots

Multifunctional green food packaging films were developed by incorporating Koelreuteria paniculata Laxm. bract extract (KBE) and bio-waste-derived Ti-doped carbon dots (Ti-CDs) into a chitosan/locust bean gum (CG) matrix for the first time. Results from FTIR and XRD demonstrated the precise bonding of Ti-CDs to CG through a Schiff base reaction and hydrogen bonding, while KBE was effectively immobilized within the film matrix via hydrogen bonding. SEM and TGA analysis demonstrated enhanced thermal stability and density of the films. Addition of Ti-CDs synergistically improved the barrier properties and mechanical strength of the films through enhanced hydrogen bonding and Schiff base reactions. Specifically, the incorporation of 3 wt% Ti-CDs increased the oxygen barrier properties, tensile strength, water resistance, and vapor permeability of CG films by approximately 1.18, 0.75, and 1.51 times, respectively. Furthermore, the antimicrobial and antioxidant capabilities were significantly improved with the addition of KBE to films. The CG-3%CDs-KBE film coating effectively prolonged the shelf life of strawberries. Additionally, these films exhibited superior pH responsiveness and ammonia-sensitivity, enabling visual monitoring of shrimp freshness during storage. Importantly, CG-3%CDs-KBE films exhibited biodegradability in soil and displayed good biosafety. Overall, these findings underscore the promising potential of CG-3%CDs-KBE films as multifunctional green food packaging materials.

A biodegradable multifunctional pectin–montmorillonite fertilizer coating: Controlled-release, water-retention and soil-cementation

Coated fertilizers have been widely used to improve fertility in barren land. However, improving soil structure and water-retention capacity is also essential for arid and semi-arid areas with sandy soils to promote crop growth. Most currently available coated fertilizers rarely meet these requirements, limiting their application scope. Therefore, this study “tailored” pectin–montmorillonite (PM) multifunctional coatings for arid areas, featuring intercalation reactions and nanoscale entanglement between pectin and montmorillonite via hydrogen bonding and electrostatic and van der Waals forces. Notably, PM coatings have demonstrated an effective “relay” model of action. First, the PM-50 coating could act as a “shield” to protect urea pills, increasing the mechanical strength (82.12 %). Second, this coating prolonged the release longevity of urea (<0.5 h to 15 days). Further, the remaining coating performed a water-retention function. Subsequently, the degraded coating improved the soil properties. Thus, this coating facilitated the growth of wheat seedlings in a simulated arid environment. Moreover, the cytotoxicity test, life cycle assessment, and soil biodegradation experiment showed that the PM coating exhibited minimal environmental impact. Overall, the “relay” model of PM coating overcomes the application limitations of traditional coated fertilizers and provides a sustainable strategy for developing coating materials in soil degradation areas.