Biodegradable Lubricants Research Articles

Next-generation drilling fluids for horizontal and multilateral wells: A conceptual approach

The development of next-generation drilling fluids is crucial for the success of horizontal and multilateral wells, which pose unique challenges such as torque and drag, hole cleaning difficulties, and wellbore instability. This review explores the evolving role of drilling fluids, focusing on the desired properties required to address these challenges, including enhanced cuttings transport, reduced torque and drag, and improved wellbore stability. Furthermore, the paper discusses innovative additives, such as nanoparticles, high-performance polymers, and biodegradable lubricants, which are key to optimizing fluid performance. Environmental considerations and the chemical and mechanical interactions between fluid components are also analyzed. Finally, the paper examines future trends in drilling technology, highlighting the expected benefits of next-generation fluids and identifying potential challenges for future research and development. These advanced fluids are positioned to revolutionize drilling efficiency while maintaining sustainability in increasingly complex drilling environments.

Synthesis of Bio lubricant from Bhallataka oil

The demand for a renewable and biodegradable lubricant as a substitute for fossil fuel-based lubricant has increased due to strong environmental concerns and expanding regulations over contamination and pollution in the environment. This study investigated the potential of using Semecarpus anacardium L.f. oil, which was identified as a potential raw material for biodiesel, as a feed stock for bio lubricants. Epoxidation and hydrolysis reactions were used to synthesize bio-lubricant. Epoxidized SA L.f oil was made using peroxyformic acid, which was produced on the spot by reacting hydrogen peroxide and formic acid with sulfuric acid acting as a catalyst. The oxirane value of the oil was 3.77, indicating that the unsaturated bonds were almost entirely converted to oxirane, while the iodine value decreased from 90.7 to 2.01 mg I2/g. ESAO

Experimental Study on Tribological, Rheological and Bio-degradability Characteristics of Canola Oil with TiO2 Nanoparticles as Bio-nanolubricants

In response to growing environmental concerns about the adverse effects of conventional lubricants, there has been a surge in the demand for eco-friendly alternatives. Biodegradable lubricants, crafted from renewable sources, represent a sustainable solution to address these environmental apprehensions. This research describes the tribological, rheological properties and biodegradability of rapeseed oil with 0.25 to 1.25 weight percent TiO2 nanoparticles as additives. The lubricant samples were prepared using a magnetic stirrer and an ultrasonic device. Friction and wear properties such as coefficient of friction and wear scar diameter were determined using a four-ball tester. In comparison with SAE20W40, samples 1 (0.25 weight percentage of TiO2) and sample 2 (0.5 weight percentage of TiO2) shown remarkably improved tribological performance, with 73.32% and 66.76% decreases in coefficient of friction (COF), respectively. Shear stress, shear rate and dynamic viscosity are analyzed using a rheometer. The acquired results are juxtaposed with both pure canola oil and various mineral oils for comparison. The nano-lubricant synthesized in this study emerges as a viable alternative to SAE10, DXT3 (steering fluid), and SAE20W50 grade oils, demonstrating lower friction and a reduced wear scar diameter. Biodegradability tests were performed on all generated samples using the Biochemical Oxygen Demand (BOD) apparatus, and all samples exhibited a BOD to Chemical Oxygen Demand (COD) ratio better than 0.5, indicating biocompatibility. The findings of the research investigation indicate that the combination of canola oil with TiO2 blends holds significant promise as an alternative to conventional synthetic lubricant oils.

Selection of a Base Vegetable Oil for the Development of a Biodegradable Lubricant Using the TOPSIS Method

Selection of a Base Vegetable Oil for the Development of a Biodegradable Lubricant Using the TOPSIS Method

A review of biodegradable lubricants 1. caracterization, current status, and future improvement trends

A review of biodegradable lubricants 1. caracterization, current status, and future improvement trends

Anion Architecture Controls Structure and Electroresponsivity of Anhalogenous Ionic Liquids in a Sustainable Fluid.

Three nonhalogenated ionic liquids (ILs) dissolved in 2-ethylhexyl laurate (2-EHL), a biodegradable oil, are investigated in terms of their bulk and electro-interfacial nanoscale structures using small-angle neutron scattering (SANS) and neutron reflectivity (NR). The ILs share the same trihexyl(tetradecyl)phosphonium ([P6,6,6,14]+) cation paired with different anions, bis(mandelato)borate ([BMB]-), bis(oxalato)borate ([BOB]-), and bis(salicylato)borate ([BScB]-). SANS shows a high aspect ratio tubular self-assembly structure characterized by an IL core of alternating cations and anions with a 2-EHL-rich shell or corona in the bulk, the geometry of which depends upon the anion structure and concentration. NR also reveals a solvent-rich interfacial corona layer. Their electro-responsive behavior, pertaining to the structuring and composition of the interfacial layers, is also influenced by the anion identity. [P6,6,6,14][BOB] exhibits distinct electroresponsiveness to applied potentials, suggesting an ion exchange behavior from cation-dominated to anion-rich. Conversely, [P6,6,6,14][BMB] and [P6,6,6,14][BScB] demonstrate minimal electroresponses across all studied potentials, related to their different dissociative and diffusive behavior. A mixed system is dominated by the least soluble IL but exhibits an increase in disorder. This work reveals the subtlety of anion architecture in tuning bulk and electro-interfacial properties, offering valuable molecular insights for deploying nonhalogenated ILs as additives in biodegradable lubricants and supercapacitors.

Viscoelastic Water-Based Lubricants with Nopal Cactus Mucilage as Green Metalworking Fluids

Recent green manufacturing demands have boosted the development of new biodegradable lubricants to replace petroleum-based lubricants. In this regard, water-based lubricants have been at the vanguard of recent research for a wide range of industrial applications, including metalworking fluids (MWFs). In this work, we present an experimental investigation on the performance of novel green MWFs based on aqueous nopal mucilage solutions. For this, fully biodegradable solutions with different mucilage concentrations (2.29, 4.58, and 6.85 mg/mL) were evaluated in terms of rheological, tribological, thermal stability, and turning (minimum quantity lubrication) performance and compared to a commercial semisynthetic oil-based MWF (Cimstar 60). Mucilage solutions exhibited viscoelastic shear-thinning behavior, which was enhanced along with mucilage concentration. The solution with the highest mucilage content studied resulted in the lowest wear, friction, and temperature in comparison to the other solutions and neat water in extreme pressure four-ball tests and a similar level of lubricity as compared to the commercial MWF in cutting tests. This performance is associated with the enhanced viscosity and elasticity of the solution, as well as the contents of lipids with fatty acids in the mucilage. Overall, the present results reveal the relevance of the viscoelastic behavior of the lubricant, elasticity in particular, in lubrication processes and point to nopal mucilage as an effective green additive to produce innocuous MWFs.

Extraction of biodiesel from pomelo peel and investigation of its efficiency as a lubricant in water-based drilling fluid

Abstract Reducing friction between drill string and wellbore wall is one of the key functions of drilling fluid which may result from tight holes, key seats, differential sticking, or cutting build up along the drill string. However due to growing environmental concerns, biodegradable lubricants which are also cost-efficient are appreciated and mandated in many countries. This study discusses the performance analysis of biodegradable biodiesel produced from pomelo peels and Petroleum-based lube oil as drilling fluid lubricants. The test samples comprise 700 mL of water + 10 % bentonite + 3 % barite + 0.25 % CaCO3 + 0.25 % KOH + 1 % CMC + lubricant. Two sets of lubricants were utilized to prepare 10 samples of drilling fluid, one set with petroleum-based lubricant and other with biodiesel. Essential oil was extracted from pomelo peel with the help of the Clevenger apparatus. The oil was then converted to biodiesel through the process of transesterification. Biodiesel properties were tested for the ASTM standards. Both sets of drilling fluid samples were tested for their rheological, filtration and lubricating properties and from the results obtained it can be concluded that both type of lubricating agents have almost negligible impact on rheological and filtration loss properties. However, the lubricity coefficient values drastically decreased as we increased the lubricant content, which is an indication that biodiesel extracted from pomelo peel acts as a better lubricant. The values of the lubricity coefficient for biodiesel based drilling fluid also fell well within the advised range (<0.30). We can therefore draw the conclusion that biodiesel made from pomelo peel can replace petroleum-based lubricants while also lowering the environmental concerns related to lubricants.

Rheological properties of water-based amino acid ionic liquids

The rheological properties and zero-shear viscosity of water-based lubricants (WBLs) containing amino acid ionic liquids (AAILs) were investigated using both equilibrium (EMD) and non-equilibrium molecular dynamics (NEMD) simulations. We also performed experimental measurements to validate the simulations. The simulations demonstrated that adding AAIL additives to water increased both the shear viscosity and zero-shear viscosity. We added tetrabutylphosphonium (P4444) as a cation and three different amino acids, serine (Ser), lysine (Lys), or phenylalanine (Phe), as anions. We varied the AAIL concentration from 5 to 10 wt. % for tetrabutylphosphonium-serine (P4444-Ser) ionic liquid additives, showing that AAILs increased water viscosity by 68%–125%, depending on concentration. The P4444-Ser WBLs also exhibited a significantly higher first normal stress difference than water, meaning they could support more load in lubrication. The improved rheology persisted over a wide range of shear rates up to ∼1011 s−1. We have extracted full rheological parameters by fitting data into Cross, Carreau–Yasuda, and Eyring models, including zero-shear viscosity and critical shear rates of onset shear thinning. The experimental values of zero-shear viscosity were close to zero-shear viscosity results obtained from fitting NEMD results to these models, demonstrating the high fidelity of the molecular model. We explored the formation of hydration shells around amino acid anions as a marker for low friction behavior. These findings suggest that AAIL WBLs can be potentially low-friction and biodegradable lubricants in tribological applications.

A review of biodegradable lubricants 3. Caracterization, current status, and future improvement trends

A review of biodegradable lubricants 3. Caracterization, current status, and future improvement trends

A review of biodegradable lubricants 2. caracterization, current status, and future improvement Trends

A review of biodegradable lubricants 2. caracterization, current status, and future improvement Trends

Selective Catalytic Hydrogenation of Vegetable Oils over Copper-Based Catalysts Supported on Amorphous Silica

This work aims to study the selective catalytic hydrogenation of vegetable oils to maximize oleic acid content and expand the range of non-edible uses. Oleic acid (C18:1) is suitable for use as a biodegradable lubricant and is a building block in producing polymers and plastics from renewable resources. The challenge is the synthesis of heterogeneous catalysts, allowing for a maximum yield of C18:1 and low formation of the corresponding saturated acid (stearic acid). New copper-based catalysts on silica were synthesized via two synthesis methods: hydrolysis precipitation and ammonia-evaporation. Experimental tests were carried out at a lab scale operating in a semi-batch mode. The best conversion reached 90% for C18:3 and 80% for C18:2 HP Cu-silica catalyst results, the best candidate for an industrial case study. Good results were obtained in the selectivities of oleic acid production and cis/trans isomers ratio. The modified return on the investment of the designed hydrogenation plant provides the revenues of the capital costs in less than one year.

Surfactant free enhancement to thermophysical and tribological performance of bio-degradable lubricant with nano-friction modifier for sustainable end milling of Incoloy 925

An efficient method of lubrication and cooling for green machining is nanofluid minimum quantity lubrication (NMQL). Compared to other vegetable-based oils, coconut oil has the highest viscosity index, lubricity, and oxidative characteristics, making it a popular trending lubricant for decreasing friction. However, its performance at higher temperatures degrades owing to higher saponification value. In order to improve its performance, the solid nano-friction modifier (hBN) is dispersed in it, and the colloid is called a nanofluid. UV–Vis–NIR spectrophotometer, HR-TEM, and FTIR spectroscopy characterize nanofluid. The stability of nanofluid at 0.3 vol% of hBN has been observed to be the highest compared to other volume fractions. Compared to coconut oil, prepared nanofluid is superior in terms of increased thermal conductivity, thermal stability, and viscosity for all the tested temperature ranges. Nanofluid shows increased viscosity index (VI) by 20%, reduced contact angle by 45%, and lower coefficient of friction (COF) by 32% compared to coconut oil. Further performance of this modified biodegradable nanofluid under Minimum quantity lubrication (MQL) on end milling of Incoloy 925 has been studied. In order to compare the machining performance under different cutting environments, cutting temperature, cutting force, specific cutting energy, power consumption, carbon emission, chip morphology, surface topology/topography, and tool wear were evaluated. Finally, sustainability assessments for different cutting environments have been performed. Biodegradable oil-based NMQL-assisted machining has performed better than dry and MQL-assisted machining.

Green Tribology: A Review of Biodegradable Lubricants—Properties, Current Status, and Future Improvement Trends

Green Tribology: A Review of Biodegradable Lubricants—Properties, Current Status, and Future Improvement Trends

Kinetic study on the production of biodegradable lubricant by enzymatic transesterification of high oleic palm oil

Kinetic studies are necessary to identify inhibitors of lipase enzyme deactivation in reaction systems because varying substrate concentrations can affect the enzyme's catalytic activity. The present study aimed to analyze the reaction kinetics of palm-based polyol ester production catalyzed by commercial lipase Novozyme 435 (N435). The enzymatic transesterification reaction was performed in a solvent-free medium. The effect of substrates concentration, specifically high oleic palm methyl ester (HO-PME) and trimethylolpropane (TMP), on the kinetic constant was studied at the initial reaction rate. The study was conducted based on the Ping-pong Bi-bi model, assuming that both substrates could inhibit the reaction. The reaction was carried out at 70 °C and 15.25 mbar with a 3 % (w/w) N435 enzyme load to investigate the effect of various HO-PME and TMP concentrations. The kinetic constants obtained are as follows: Km(HOPME) = 61.112 mol/L, Km(TMP) = 0.336 mol/L, Ki(HOPME)= 0.002 mol/L, Ki(TMP) = 2.415 mol/L and Vmax = 17.24 mol/L.hr. The results implied that N435 has higher affinity towards TMP than HO-PME. Inhibition constant indicated a lower inhibitory function of the TMP than HO-PME (Ki(TMP) >Ki(HOPME)). The reaction kinetics obtained in this study agreed well with the model used with TMP and HO-PME as competitive inhibitor during enzymatic transesterification.

Thermal Transport and Physical Characteristics of Silver-Reinforced Biodegradable Nanolubricant

In this investigation, the thermal transport behavior of biodegradable lubricant reinforced with silver nanostructures (AgNs) at various filler fractions of 0.01, 0.05, 0.10, and 0.20 weight percent was evaluated over a temperature scan analysis, ranging from room temperature up to 60 °C. The experimental results revealed significant gradual enhancements in thermal conductivity as AgNs concentration and evaluating temperatures were increased. These improvements showed the important role of nanostructures’ interaction within the biodegradable lubricant. The thermal conductivity performance improved for nanolubricants ranging from 6.5% at 30 °C and 0.20 wt.% AgNs content up to a maximum 32.2%, which was obtained at 60 °C with 0.20 wt.% AgNs concentration. On the other hand, the thermal stability of reinforced lubricants was assessed through thermogravimetric kinetics analyses. The predictive curves resulting from the analyses indicated that there is an enhancement in both the onset temperature for decomposition and the percentage conversion under isothermal conditions for lubricants reinforced with AgNs. Specifically, the results show that the required temperature to achieve a 5% conversion is 100 °C higher than that calculated for bare lubricant. Moreover, the predictive analyses indicate that there is a delay in the decomposition time at isothermal conditions.

Effects of 2,6-di-tert-butyl-hydroxytotulene and mineral-lubricant base oils on microbial communities during lubricants biodegradation

2,6-Di-tert-butyl-hydroxytotulene (BHT) is an additive commonly used in the manufacturing of lubricants to improve their antioxidant properties. However, in this study, we found that BHT affects the biodegradation of bio-lubricants by influencing the microbial community during the degradation of bio-lubricants. Specifically, BHT was found to reduce bacterial richness in activated sludge, but it increased the relative abundance of Actinobacteria (from 21.24% to 40.89%), Rhodococcus (from 17.15% to 31.25%), Dietzia (from 0.069% to 6.49%), and Aequorivita (from 0.90% to 1.85%). LEfSe analysis and co-occurrence network analysis suggested that Actinobacteria could be potential biomarkers and keystone taxa in microbial communities. Using the MetaCyc pathway database, the study found that BHT interfered with cellular biosynthetic processes. Additionally, the study also showed that mineral-lubricant base oils, which are difficult to degrade, significantly altered the diversity and composition of the microbiome. Overall, the findings demonstrate that BHT and mineral-lubricant base oils can substantially alter bacterial richness, structure, and function, potentially contributing to the difficulty in degrading lubricants. These findings have implications for the development of more biodegradable lubricants and the management of industrial waste containing lubricants.

Optimization of the process variables on biodegradable industrial lubricant basestock synthesis from Jatropha curcas seed oil via response surface methodology

The synthesis of biolubricants from renewable feedstocks is currently gaining attention. Over 95% of the market is comprised of lubricants made from petroleum. Due to their limited biodegradability and high eco-toxicity, lubricants generated from petroleum constitute a significant environmental hazard. As pollution levels increase and oil supplies decline, there is a rising need to develop biobased alternatives. Manufacturing cleaner fuel products will mitigate the negative environmental impact of greenhouse gas emissions, which contribute to global warming. Jatropha curcas seed oil is an efficient renewable feedstock for biolubricant synthesis. This study optimized the process variables on biodegradable lubricant basestock production from J. curcas seed oil. A central composite design was used to maximize the chemical interaction between J. curcas methyl ester and ethylene glycol (EG) as a polyol. A total of 20 experimental runs were done to examine reaction temperature, time, and the ethylene glycol to fatty acid methyl ester (EG-to-FAME) molar ratio. A statistical model indicated that the maximum conversion yield of jatropha biolubricant (JBL) would be 92.48% under the following optimum reaction conditions: 128.95°C, 202.40 min, and ethylene glycol to fatty acid methyl ester (EG-to-FAME) molar ratio of 3.87:1. At these optimum conditions, an average jatropha biolubricant (JBL) yield of 94.12% was achieved under experimental conditions, and this value was well within the range predicted (92.48%) by the model. The quadratic model predicted the biolubricant output (R2 = 0.9919). The synthesized biolubricant met the requirements of Viscosity Grade 46 (ISO VG 46) set by the International Organization for Standardization.

Pengaruh Penambahan Nano-Aditif Ke Dalam Fluida Polyolester Terhadap Gesekan Dan Keausan Material AISI52100 Vs Cast Iron

Synthetic lubricants have environment problems because they are difficult to decompose and be-come pollutant materials when disposed into the environment. Therefore, there is an increasing demand for biodegradable lubricants. One of the methods to achieve biodegradability of a lubricant is by using eco-friendly base material and nanoparticles from organic materials as additives, such as nanofibers, cellulose and graphene nanoplatelets. In previous studies, it has been confirmed that applying bacterial cellulose at various volume percentages into polyester (POE) oil has reduced friction and wear of the material up 49%. Other studies also mentioned that the addition of several layers of graphene as an additive to Polyalphaolefin (PAO) oil have decreased the value of the fric-tion coefficient from 0.15 to 0.08. In this study, due to their desirable properties, the bacterial cellu-lose (BC) and graphene nanopartcles were used as additives in polyester (POE) oil. Four types of lubricant specimens with different additive content were prepared for the study. The friction tests were carried out using a reciprocating pin on disk type tribometer at temperatures of 65°±3°C and 27°C. The results indicated improvements in the tribological properties; 60% friction reduction at temperature of 65°±3°C and 66.7% at a temperature of 27°C, with the presence of both BC and graphene in POE compared to those without the additives. In addition, the wear analysis from the results of micro-surface observation of the specimen indicates the reduction of the specific wear rate values as the effect of additives. It is found that the specific wear rate decreased from 6.09×10-6 mm3/N.m to 4.82×10-7 mm3/N.m at 65°±3°C and from 1.57×10-6 mm3/N.m to 2.38×10-7 mm3/N.m at 27°C with the presence of both BC and graphene in POE compared to those without the addi-tives.

Chemical modification of waste cooking oil for the biolubricant production through transesterification process

Concerns and restrictions around contamination and environmental pollution are developing. The production of waste cooking oil and the pollution brought on by mineral oils are two important issues. The FSSAI's new standards state that cooking oil that contains more than 25% polar compounds is inappropriate for use and should be discarded. Therefore, both issues can be resolved with the aid of chemical modifications to waste cooking oil. Waste cooking oils are an attractive alternative to mineral oils because they are biodegradable and renewable sources of lubricants. The goal of the current research work is to create an environmentally friendly lubricant through transesterification reaction. Fatty acid methyl esters (FAMEs) of WCO with various alcohols (1-Heptanol, 2-Ethyl-1-Hexanol & Neopentyl Glycol) with diverse branching were used to create bio lubricant. As a heterogeneous catalyst, zinc acetate was used to carry out the reaction. Complex esters, which have been produced, have the potential to be used as biodegradable lubricants in industrial lubricant applications. Using the GC-MS technique, the structure of the generated bio lubricant was examined. The structural modification of waste cooking oil resulted in improvement in both physicochemical and tribological properties. The created bio lubricant had improved flash and fire points as well as a superior viscosity index (>120). The generated bio lubricant possesses friction characteristics that are comparable to those of commercial mineral oil-based lubricants. According to the results of this study, waste cooking oil lubricant has a lot of potential for use as a base stock due to its favorable biodegradability and tribological performance.