Biocomposites Of Poly Research Articles

Multilayer biocomposites of PLA woven fabric and PBS sheets using compression molding process

AbstractBiocomposite materials play an important role to replace the conventional polymer composites in the issue of serious environmental problems from the end‐used products. The relationship between the design and construction of biocomposites structure and their properties is an important factor to the composite application. In this study, the biocomposites of poly(butylene succinate) (PBS) reinforced with poly(lactic acid) (PLA) woven fabric to improve mechanical properties of PBS matrix was fabricated by compression molding process. The plain weave PLA woven fabrics showed higher tensile strength (28.9%) and modulus (21.5%) than the twill 2/2 weave pattern. However, the flexural strength and modulus of composites reinforced with multi‐layers PLA woven fabric are higher than the one‐layer reinforcement (57% and 31%, respectively). The impact and peel strength of PLA twill 2/2 weave biocomposite are higher than the plain weaving. The mechanical property of matrix reinforced with plain structure was found to increase on the vertical axis while the twill weaving showed the increase on horizontal axis adhesion between the reinforced PLA woven fabric and the PBS matrix.

Structural and mechanical properties of biodegradable poly(lactic acid) and pectin composites: using bionucleating agent to improve crystallization behavior

Biocomposites of poly(lactic acid) (PLA) and pectin, which are low-cost organic materials, were prepared using an internal mixing machine in various pectin contents, i.e., 2, 4, 6 and 8% w/w. When pectin was added as a nucleating agent, the mechanical properties of the biocomposites, such as tensile and impact testing, were considerably improved, particularly following the annealing process. In addition, the PLA–pectin annealed at 4% w/w showed the highest strength and thermal stability. This can be explained by the fact that PLA containing 4% pectin by weight had the best dispersion, as indicated by scanning electron microscopy (SEM) and synchrotron-based 2D chemical mapping FT-IR. Moreover, pectin not only serves as a reinforcing material to improve mechanical characteristics but also aids in the crystallization of PLA, which was confirmed by in situ synchrotron-based wide-angle X-ray scattering (SR-WAXS). The crystallization rate and crystallinity were maximum at 8% w/w pectin addition according to the SR-WAXS results. This shows that pectin dispersion is the most important factor in determining the mechanical and thermal properties of biocomposites.

Effects of a poly(hydroxyalkanoate) elastomer and kraft pulp fibres on biocomposite properties and three-dimensional (3D) printability of filaments for fused deposition modelling

Three-dimensional (3D) printing is a useful technique that allows the creation of objects with complex structures by deposition of successive layers of material. These materials are often from fossil origin. However, efforts are being made to produce environmentally friendly materials for 3D printing. The addition of lignocellulosic fibres to a polymer matrix is one of the alternatives to replace, for instance, glass fibres in composites as reinforcing materials. The fields of biocomposites and 3D printing open innovative application areas for pulp fibres from the pulp and paper industry. In this work, biocomposites of poly(lactic acid) (PLA), poly(hydroxyalkanoate) (PHA) and kraft pulp fibres were prepared in order to find a suitable formulation for filaments for 3D printing. The effect of two different types of kraft fibres (bleached (B) and unbleached (U)) and of PHA on the mechanical and thermal properties of the biocomposites was assessed. The addition of 30% kraft fibres to PLA resulted in an increase of the tensile modulus from 3074 to ∼4800 MPa. In the case of biocomposites containing PHA (50% PLA/20% PHA/30% kraft) the increase in modulus was more moderate (PLA+PHA+U: 3838 MPa, and PLA+PHA+B: 3312 MPa). The tensile strength of PLA (66 MPa) increased to 77 MPa in PLA+kraft biocomposites, while a reduction in strength was observed for PLA+PHA+U (43 MPa) and PLA+PHA+B (32 MPa). Filaments prepared with PLA, PHA and bleached and unbleached pulp fibres showed similar printability of complex geometries, demonstrating that unbleached pulp fibres could also be utilized in the preparation of biocomposites with good mechanical performance and 3D printing properties.

Grafted Lactic Acid Oligomers on Lignocellulosic Filler towards Biocomposites.

Lactic acid oligomers (OLAs) were in situ synthesized from lactic acid (LAc) and grafted onto chokeberry pomace (CP) particleboards by direct condensation. Biocomposites of poly (lactic acid) (PLA) and modified/unmodified CP particles containing different size fractions were obtained using a mini-extruder. To confirm the results of the grafting process, the FTIR spectra of filler particles were obtained. Performing 1HNMR spectroscopy allowed us to determine the chemical structure of synthesized OLAs. The thermal degradation of modified CP and biocomposites were studied using TGA, and the thermal characteristics of biocomposites were investigated using DSC. In order to analyse the adhesion between filler particles and PLA in biocomposites, SEM images of brittle fracture surfaces were registered. The mechanical properties of biocomposites were studied using a tensile testing machine. FTIR and 1HNMR analysis confirmed the successful grafting process of OLAs. The modified filler particles exhibited a better connection with hydrophobic PLA matrix alongside improved mechanical properties than the biocomposites with unmodified filler particles. Moreover, a DSC analysis of the biocomposites with modified CP showed a reduction in glass temperature on average by 9 °C compared to neat PLA. It confirms the plasticizing effect of grafted and ungrafted OLAs. The results are promising, and can contribute to increasing the use of agri-food lignocellulosic residue in manufacturing biodegradable packaging.

Filler Content Effect on Water Uptake and Thermal Stability of Poly(3‐Hydroxybutyrate‐Co‐3‐Hydroxyhexanoate)/Microcrystalline Cellulose Biocomposites

AbstractIn this study, biocomposites of poly(3‐hydroxybutyrate‐co‐3‐hydroxyhexanoate) (PHBHHx)/cellulose microcrystalline (MCC) extracted from olive husk flour are prepared by melt compounding at various filler content ratios, i.e., 10, 20, and 30 wt%. The effect of the MCC content on the morphology, thermal stability, crystallinity, and water uptake of the PHBHHx biocomposites is investigated. The results showed that the addition of MCC to PHBHHx decreased the thermal stability of the biocomposites compared to that of neat polymer, however more pronounced at a higher filler content. This is due probably to the tendency of MCC particles to agglomerate, inducing heterogeneities and defects within the polymer matrix observed by scanning electron microscopy. Furthermore, both crystallinity and water uptake after 24 h of immersion increased with the filler content.

Influence of Hydroxyapatite Surface Functionalization on Thermal and Biological Properties of Poly(l-Lactide)- and Poly(l-Lactide-co-Glycolide)-Based Composites.

Novel biocomposites of poly(L-lactide) (PLLA) and poly(l-lactide-co-glycolide) (PLLGA) with 10 wt.% of surface-modified hydroxyapatite particles, designed for applications in bone tissue engineering, are presented in this paper. The surface of hydroxyapatite (HAP) was modified with polyethylene glycol by using l-lysine as a linker molecule. The modification strategy fulfilled two important goals: improvement of the adhesion between the HAP surface and PLLA and PLLGA matrices, and enhancement of the osteological bioactivity of the composites. The surface modifications of HAP were confirmed by attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), TGA, and elemental composition analysis. The influence of hydroxyapatite surface functionalization on the thermal and in vitro biological properties of PLLA- and PLLGA-based composites was investigated. Due to HAP modification with polyethylene glycol, the glass transition temperature of PLLA was reduced by about 24.5 °C, and melt and cold crystallization abilities were significantly improved. These achievements were scored based on respective shifting of onset of melt and cold crystallization temperatures and 1.6 times higher melt crystallization enthalpy compared with neat PLLA. The results showed that the surface-modified HAP particles were multifunctional and can act as nucleating agents, plasticizers, and bioactive moieties. Moreover, due to the presented surface modification of HAP, the crystallinity degree of PLLA and PLLGA and the polymorphic form of PLLA, the most important factors affecting mechanical properties and degradation behaviors, can be controlled.

Preparation and Properties of Biocomposite Films Based on Poly(vinyl alcohol) Incorporated with Eggshell Powder as a Biological Filler

Biocomposites of poly(vinyl alcohol) (PVA) incorporated with eggshell powder (ESP) were prepared by solution blending and casting into films. The effects of ESP content (0–50 wt% of dry PVA basis) on structure and properties of the resultant PVA/ESP composite films were systematically evaluated. Fourier transform infrared spectroscopy and scanning electron microscopy suggested a strong adhesion and the well-dispersion of ESP particles in the PVA matrix due to the hydrogen-bonding interactions. The incorporation of opaque, hydrophobic and stable ESP in the composite films could consequently decreased their transparency and hydrophilicity while improving their thermal stability. Optimal ESP content in the composite films was found to be 30 wt% in terms of their mechanical and water vapor barrier properties, showing a tensile strength of 38.78 MPa, elongation at break of 165.9%, and water vapor permeability of 1.229 × 10–12 g cm/cm2 s Pa, respectively. However, overloading of ESP in the composite films might produce some aggregations and thus have negative effects on their performance. These results indicated that ESP was an excellent biological filler for PVA to prepare composite films with improved properties, which might hold the potential as biodegradable materials for packaging applications.

Characterization of Natural Composites Fabricated from Abutilon-Fiber-Reinforced Poly (Lactic Acid)

In recent decades, natural-fiber-reinforced poly (lactic acid) (PLA) composites have received a great deal of attention. In this study, biocomposites of poly (lactic acid) and abutilon fibers are prepared by using melt blending and an extruder. The effects of fiber additions on rheological, thermomechanical, thermal, and morphological properties are investigated using a rheometer, dynamic mechanical analysis (DMA), differential scanning calorimeter (DSC), TGA, and SEM, respectively. The DSC results indicate that the fibers acted as a nucleating agent, which led to enhancing the crystallization of PLA. The results also reveal that the thermal stability of PLA was improved by abutilon fibers. Moreover, higher values of storage modulus are observed, which are attributed to strong interfacial adhesion. In addition, thetan delta isreduced upon the addition of fiber content into the PLA matrix, which restricts the mobility of PLA polymer molecules in the presence of the fibers. The improvement of the properties and energy absorption capabilities of such biocomposites signifies the great potential of abutilon fibers as reinforcement in green composites.

Biocomposites based on PCL and macaiba fiber. Detailed characterization of main properties

Biocomposites of poly (ε-caprolactone)/Macaiba (PCL/MF) upon fiber addition ranging from 10% to 20% were successfully extruded and thoroughly characterized by torque rheometry, thermogravimetry (TG), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), contact angle, heat deflection temperature (HDT), scanning electron microscopy (SEM), mechanical properties in tension, flexural and impact. No degradation evidences were verified during processing and all PCL/MF biocomposites presented higher thermal stability related to neat PCL. Narrower crystallization peaks were shifted to higher temperatures suggesting Macaiba fiber nucleating effect whereas its oil may be acted as plasticizer for PCL changing to lower or higher the mechanical properties depending on the investigated parameter. Throughout this work is shown MF provides a sustainable alternative to PCL biocomposites with wider applications.

Manufacturing and characterization of plates for fracture fixation of bone with biocomposites of poly (lactic acid-co-glycolic acid) (PLGA) with calcium phosphates bioceramics

Commercially, there are several plates and screws for bone fracture fixation made with PLA, however, its long degradation time and lack of integration with bone structure, provides interest in research using polymers with faster degradation, such as PLGA, and together with bioceramics, in order to improve bioactivity in bone regeneration. Based on this, in this study, bone fracture fixation plates composed of PLGA polymer matrix and combinations of 5 and 10%wt. of bioceramics were processed by microinjection. The bioceramics used comprehend nanostructured hydroxyapatite (n-HA), β-tricalcium phosphate (β-TCP) and calcium phosphate with ion substitution of magnesium (Mg-Ca/P) and strontium (Sr-Ca/P). The introduction of bioceramics modified thermal and mechanical properties of the polymer. The TGA analysis showed that there was a variation on the ceramic's mass inserted in relation to the expected values (5% and 10%wt.) in all groups of biocomposites. In general, Tg values obtained by DMA were slightly increased in almost all the biocomposites. The storage modulus (E') of biocomposites was higher for almost all groups of inserted ceramics, with exception of 5%n-HA. In the flexural tests, the biocomposites obtained a great dispersion in average values of fracture loading, presented lower values in relation to pure PLGA. There were difficulties in the processing of biocomposites with Mg-Ca/P and Sr-Ca/P, a factor that can be attributed to lack of homogeneity in the material mixing process. The results suggest modifications in thermal and mechanical properties of the PLGA plates with the bioceramics insertion and provide improvement understanding about of manufactured composites with PLGA and bioceramics.

Biocomposites of poly(lactic acid) and lactic acid oligomer‐grafted bacterial cellulose: It's preparation and characterization

ABSTRACTThis work demonstrates the synthesis of lactic acid oligomer‐grafted‐untreated bacterial cellulose (OLLA‐g‐BC) by in situ condensation polymerization which increased compatibilization between hydrophobic poly(lactic acid) (PLA) and hydrophilic BC, thus enhancing various properties of PLA‐based bionanocomposites, indispensable for stringent food‐packaging applications. During the synthesis of OLLA‐g‐BC, hydrophilic BC is converted into hydrophobic due to structural grafting of OLLA chains with BC molecules. Subsequently, bionanocomposites films are fabricated using solution casting technique and characterized for structural, thermal, mechanical, optical, and gas‐barrier properties. Morphological images showed uniform dispersion of BC nanospheres in the PLA matrix, which shows strong filler–matrix interaction. The degradation temperatures for bionanocomposites films were above PLA processing temperature indicating that bionanocomposite processing can be industrially viable. Bionanocomposites films displayed decrease in glass transition (Tg) and ~20% improvement in elongation with 10 wt % fillers indicating towards plasticization of PLA. PLA/OLLA‐g‐BC films showed a slight reduction in optical transparency but had excellent UV‐blocking characteristics. Moreover, dispersed BC act as blocking agents within PLA matrix, reducing the diffusion through the bionanocomposite films which showed ~40% improvement in water‐vapor barrier by 5 wt % filler addition, which is significant. The reduced Tg, improved elongation combined with improved hydrophobicity and water‐vapor barrier make them suitable candidate for flexible food‐packaging applications. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47903.

Kinetic Analysis on Thermal Decomposition of Poly(lactic acid) Toughened by Calcium Sulfate Whiskers

AbstractThe biocomposites of poly (lactic acid) (PLA) involving 15 % mass fraction of calcium sulfate whiskers (CSW) were prepared via melt-blending technology, in an effort of toughening PLA and enhancing the thermal stability. The morphological structure, impact toughness, thermal stability as well as kinetic analysis on thermal decomposition for PLA/CSW composites were performed thoroughly. The results showed that CSW was organized successfully via silanization, helping to form well-bonded interfaces, and accordingly, the impact toughness increased remarkably. The thermal stability was enhanced by adding whiskers, leading to increased decomposition temperature and decreased mass conversion rate. Kinetic analysis revealed the great dispersions on the reaction order and activation energy. Though, in comparison to pure PLA, the reaction order of PLA/CSW composites increased based on calculation methods except for Carrasco's, the activation energy of the composites declined independently of the applied mathematical models, meaning that thermal decomposition of PLA phase was accelerated by the introduced CSW.

Effect of cellulose nanofibers from cassava pulp on physical properties of poly(lactic acid) biocomposites

Biocomposites of poly(lactic acid) (PLA) and cellulose nanofibers (CNFs) extracted from cassava pulp were successfully prepared by melt mixing in an internal mixer. CNFs were prepared from cassava pulp by submitting to alkali hydrolysis, bleaching treatment, and acid hydrolysis. The compatibility between CNFs and PLA matrix was improved using glycidyl methacrylate (GMA) grafted PLA (PLA-g-GMA) as an effective compatibilizer. Higher elongation at break and impact strength of PLA/PLA-g-GMA/CNFs biocomposites was achieved compared to that of neat PLA. PLA-g-GMA shows a strong effect on the crystallization behavior of the biocomposites. The PLA/PLA-g-GMA/CNFs biocomposites induce cold crystallization to take place at lower temperature. Higher degree of crystallinity of PLA/PLA-g-GMA/CNFs biocomposites was obtained compared to PLA/CNFs biocomposites. The mechanical and thermal properties of PLA/CNFs biocomposites at various ratios were investigated. With increasing CNFs contents, the modulus of the biocomposites increases. Thermal stability of PLA/CNFs and PLA/PLA-g-GMA/CNFs biocomposites did not change significantly compared to that of neat PLA.

Effects of micrometre-sized graphite flake to reinforce the performances of poly(lactic acid) thermoplastic biocomposites

Biocomposites of poly(lactic acid) (PLA) and micrometre-sized graphite (GP) flake powder with 0–30 wt% GP contents have been prepared using extrusion moulding followed by compression moulding. The pure PLA and PLA-GP composites (PGC) have been examined by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy (RS), X-ray diffraction (XRD) technique, scanning electron microscopy (SEM), transmission electron microscopy (TEM), mechanical and micromechanical testing, differential thermal analysis (DTA) and thermogravimetric analysis (TGA). FTIR spectra confirm the physical bond formation between GP and PLA. RS distinguishes the D-band spectra of pure PLA and PGC. XRD shows a partially crystalline structure in the PLA. SEM and TEM exhibit a clear dispersion of GP particles in PLA matrix at lower loading and aggregates at higher loading. With an increase of filler content, the tensile and flexural strengths decrease, but the Young’s and tangent moduli are observed to increase by 58% and 77%, respectively. These increments represent an increase in the stiffness of the materials and are found to be consistent with the theoretical values. A decrease in microhardness with increase in filler content is also observed. Both the DTA and TGA reveal an increased thermal stability of the composites.

Morphological structure, impact toughness, thermal property and kinetic analysis on the cold crystallization of poly (lactic acid) bio-composites toughened by precipitated barium sulfate

The bio-composites of poly (lactic acid) (PLA) involving a varied mass fraction of precipitated barium sulfate (BaSO4) were prepared via melt-compounding and subsequent injection molding. The morphologies, impact toughness and thermal properties of the composites were investigated carefully, and the toughening mechanism was emphasized by a combination of BaSO4 content and the crystallization ability. Results showed that an adequate amount of BaSO4 could disperse homogeneously in PLA matrix with well-bonded interfaces. The impact toughness was increased significantly by 52.7% due to added inorganic particles as well as the increased actual crystallinity of the composites. The added BaSO4 let the cold crystallization occur earlier (shifting to low temperature) while suppressing the cold crystallinity of PLA phase. Such inhibition effects derived from the increased inorganic filler were then further explored and confirmed by the kinetic analysis on the cold crystallization under non-isothermal conditions. Indeed, the added BaSO4 increased the crystallization half-time and crystallization parameter of F(T) based on Mo equation. Moreover, the activation energy on cold crystallization was strengthened along with the increasing BaSO4. It seemed that there is little change in the reaction order of PLA/BaSO4 bio-composites, following the unique reaction thermal decomposition, whereas the activation energies were decreased steadily based on Carrasco method.

Preparation, characterization, and antimicrobial activity of poly(γ-glutamic acid)/chitosan blends

Biocomposites of poly(γ-glutamic acid) (PGA) were prepared by a two-screw extruder using chitosan (CS) as the block with glycerol and with/without water and acetic acid as additives. The influences of the CS content and various additives on the properties of PGA/CS blends were investigated. The results of mechanical tests demonstrated that the elongation at break of the blends decreased with increasing quality proportion of CS. Fourier transform infrared spectroscopy revealed that there were ionic interactions in the blends. Thermodynamic characterizations and dynamic mechanical analyses indicated that the glass-transition temperature of the blends decreased with increasing CS proportion and was obviously influenced by additives. X-ray diffractograms indicated that selecting a suitable solvent is beneficial to the blending of raw materials. Morphology analysis showed that the two kinds of substrates exhibited different miscibilities under different conditions. In addition, the antibacterial activities of the blends against Escherichia coli were not obvious because of their limited solubility. Therefore, the PGA/CS blends appear to have potential as a new biomaterial.

Biodegradation of Poly (3-hydroxybutyrate) /Eggshellsystems

In this work, biocomposites of poly (3-hydroxybutyrate) (PHB) / calcium carbonate from Rhea Americana eggshells were prepared and the effects of the addition of the inorganic filler in the polymeric matrix were assessed. The residue (powder) of the eggshell calcined at 400 oC or in natura was inserted into a PHB solution for preparation of films via casting. Powder samples were characterized by X-Ray Fluorescence (XRF), X-Ray diffraction (XRD) and Thermogravimetry (TG/DTG) and films were characterized by X-Ray diffraction (XRD), Scanning Electron Microscopy (SEM) and biodegradation tests according to the ASTM G 160-03 norm: the results were reported as weight loss and visual inspection by optical microscopy (OM). From the results of the XDR, it was perceived that the peaks in the diffractograms of the powder obtained by milling the Rhea Americana eggshells corresponded to the diffraction patterns of the Calcite crystals, which is a calcium carbonate polyform, and that the calcination preserved the crystalline structure, maintaining the calcium carbonate in the samples. For the biocomposites, a peak characteristic to the calcium carbonate in 29.57o was detected, indicating the insertion of the filler to the polymer matrix. Through SEM the presence of small agglomerates, probably due to polymer particles that were not dissolved, was observed for the pure PHB film. With the addition of the filler in natura a greater porosity was formed in the surface of the biocomposite films, and with the calcined filler, homogeneous films with reduced porosity were obtained. From the weight loss and OM results, it was observed that the filler inserted into the polymeric matrix catalyzes the biodegradation process up to 60 days evaluation in different ways, depending on the type of sample used.

Thermal Stability of Plasticized Durian Skin Fibre Biocomposite

Packaging is an essential component in food industries. Packaging protects food from spoilage between processing and usage by the consumer. In this study, biocomposites of poly(lactic acid) (PLA) reinforced with durian skin fibre (DSF) were prepared by extrusion and compression moulding. Epoxidized palm oil (EPO) was added into PLA/DSF biocomposite as a plasticizer. The results showed that the thermal stability of PLA/DSF biocomposite with EPO has not much difference compared to without EPO. The degradation time of PLA/DSF biocomposite also faster after it was disposed to the landfill as it took around 65 days to degrade. Fourier transform infrared (FTIR) confirmed the stability of EPO where the oxirane group of EPO existed in the PLA/DSF biocomposite. Therefore, PLA/DSF biocomposite with addition of EPO can be effectively used for food packaging application.

The intumescent flame‐retardant biocomposites of poly(lactic acid) containing surface‐coated ammonium polyphosphate and distiller's dried grains with solubles (DDGS)

SummaryThis work aims to develop the poly(lactic acid) (PLA) biocomposites with high flame‐retardant performance, which can be applied in electronic and electrical devices as well as automotive parts. First, an intumescent flame retardant composed of ammonium polyphosphate (APP) as the acid source and the blowing agent, and the distiller's dried grains with solubles (DDGS) as the natural charring agent was designed. The surfaces of DDGS and APP were coated by degradable polymeric flame‐retardant resorcinol di(phenyl phosphate) (RDP), and the coating effects were analyzed. And then the flame‐retardant biocomposites of PLA with RDP‐coated DDGS (C‐DDGS) and RDP‐coated APP (C‐APP) were prepared. The limited oxygen index value of the biocomposites with loading of 15 wt% C‐DDGS and 15 wt% C‐APP reached 32.0%, and UL‐94 V‐0 was attained. The biocomposites also had good mechanical properties and the tensile strength of this sample reached about 57 MPa. Finally, the char residues after burning were analyzed and the flame‐retardant mechanism was discussed.

Biocomposites of Poly(Lactic Acid) and Cellulose Nanofibers from Cassava Pulp

Cellulose nanofibers (CNFs) were used as biobased fillers to prepare poly(lactic acid) (PLA)-based biocomposites. Cellulose nanofibers were extracted from cassava pulp (CP) by acid hydrolysis method. Before submitted to acid treatment, CP was pre-treated by alkali and bleaching treatments. The biocomposites were prepared by melt mixing, followed by hot melt pressing. In order to improve the compatibility of CNFs with PLA matrix, glycidyl methacrylate (GMA) grafted poly (lactic acid) (PLA-g-GMA) was used as a compatibilizer. PLA-g-GMA was prepared by grafting of GMA onto PLA chain via melt mixing using an internal mixer. Transmission electron microscopy (TEM) micrograph shows that most nanofibers with the diameter in the range of 10-30 nm and immeasurable length were obtained. The appearance of two new peaks at 49.07 and 44.71 ppm in the carbon-13 nuclear magnetic resonance (13C-NMR) spectrum of PLA-g-GMA, which represent the carbons of the epoxy group of GMA, confirms that GMA was successfully grafted onto PLA chain. The morphology of biocomposites, characterized by scanning electron microscopy (SEM), reveals that without using PLA-g-GMA, the poor dispersion of CNFs in PLA matrix was observed. In contrast to that, with using PLA-g-GMA, the dispersion of CNFs in PLA matrix was improved. Moreover, the impact strength results show that by incorporating 1.0 wt% CNFs into PLA matrix and using PLA-g-GMA as a compatibilizer, the impact strength of biocomposites was slightly enhanced compared to that of pure PLA.