Bimodal Pore Research Articles

Influence of Starting Composition and Gelation Temperature on the Ratio between Meso‐ and Macropore Volume in Silica Xerogels with Bimodal Pore Structure

Influence of Starting Composition and Gelation Temperature on the Ratio between Meso‐ and Macropore Volume in Silica Xerogels with Bimodal Pore Structure

Encapsulation of cobalt molybdate on modified hierarchical porous TS-1 zeolite catalyst for efficient oxidative desulfurization of fuel

Morphological modulation of heterogeneous catalysts has been shown to be a useful strategy for adjusting the concentration or intrinsic activity of active sites and their catalytic activity in catalysis. Herein, a hierarchical porous TS-1-supported cobalt molybdate catalyst (CoMoO4/TS-1-DR) was obtained through a facile dissolution-regrowth strategy. In an oxidative desulfurization reaction using O2 as the oxidant, the as-prepared catalyst demonstrated exceptional performance compared to the supported catalyst prepared via the impregnation method due to the bimodal pore architecture presented. Moreover, in situ CoMoO4 synthesis lowers active site leaching, thus showing better reaction stability. After 7 recycles, the removal rate of DBT still remained at 88.8%. This work offers a generic in situ encapsulation strategy for designing hierarchical porous zeolite catalysts and the synthesis of loaded metal oxides.

Mechanical properties of teguline clay pellet mixtures during continuous oedometric compression

Clay pellet mixtures are generally compressed to improve their engineering performance. Deepening the comprehension of the mechanical properties of these mixtures in the complete compression process facilitates the benefit to the engineering design and their utilization. In this study, the effects of soil grain size distribution, water content and dry density on the mechanical properties and microstructure of Teguline clay pellet mixtures during a continuous oedometric compression process are explored. Three types of soil pellet mixtures, including mixture A (grain size ≤5 mm), mixture B (≤ 0.4 mm) and mixture C (2–5 mm), were prepared with different water contents of 7%, 8% and 12% respectively. Subsequently, continuous oedometeric compression was undertaken to explore their mechanical behaviours of the soil pellet mixtures. After that, the microstropic structures of the compacted pellet mixtures were investigated using mercury intrusion porosimetry (MIP). The results indicated that mixture A has a minimal initial packing density of pellet mixtures, while mixture C has a maximum one at the initial compression stage. After completion of compression, the compression curves of the pellet mixtures tended to converge uniformity at a semilogarithm coordinate as the vertical stress increased. All of the compression curves presented a concave shape at the plastic compression stage, which is significantly influenced by grain size distribution and water content. In contrast, the elastic compression and rebound behaviours are little affected by the grain size distribution and water content. As far as the microstructure is concerned, compacted samples prepared by mixture A or C presented a unimodal pore structure, while those by mixture B showcased a bimodal pore structure. In comparison with the unimodal pore distribution of the undisturbed stiff clay, the compacted samples displayed a pseudo-unimodal pore distribution because the inter-aggregate pores still existed. A double tangent method was proposed to determine the delimiting pore diameter of the pseudo-unimodal pore distribution curves and found that the delimiting pore diameter decreased with the increase of dry density and water content. Moreover, the inflexion point for the pore diameter of compacted samples prepared by coarse soil was larger than that of fine soil. Combining this work with previous research, it was found that the high compression of coarse soil easily causes the pseudo-unimodal shape, which is also impacted by water content and particle properties. This work could help deepen the understanding of the mechanical characteristics and microstructure of the stiff clay pellet mixtures during continuous oedometric compression.

Unveiling the potential of desert sand-derived mesoporous silica supported nickel-based catalysts for co-production of H2 and carbon nanomaterials via methane cracking

This study investigates the replacement of a costly commercial silicate source with locally abundant desert sand in the United Arab Emirates (UAE), for synthesizing mesoporous silica. Hydrothermal synthesis methods were employed to develop various mesoporous materials having different pore geometries, namely MCM41-S, SBA15-S and MCF-S, using desert sand as a silica source. These materials were then impregnated with 15 wt% NiO (∼13 wt% Ni) by sono-wet impregnation technique. All Ni-based silica supported catalyst demonstrated enhanced stability at 550 °C during the reaction. It was observed that the synthesized MCF-S proves to be a highly efficient catalyst support, as Ni/MCF-S, for the catalytic decomposition of methane (CDM), exhibiting the highest methane conversion (60 %), which is 1.4–2.1 times higher than the Ni-based classic-structured mesoporous siliceous supported catalysts, such as SBA15-S and MCM41-S. In particular, the H2 yield (62 %) of the Ni/MCF-S catalyst was 1.40 and 2.38 times higher than that of the Ni/SBA15-S and Ni/MCM41-S catalysts, respectively. To understand the observed differences, a detailed characterization of the physicochemical properties of these materials was conducted. The results revealed that the macro/mesopores size (4–60 nm) and bimodal sinusoidal pore geometry of MCF-S, played a critical role in enhancing Ni particle dispersion, resulting in the highest active Ni metal surface area (7.66 m2/gcat) and contributing to the improved catalytic activity of Ni catalysts in methane cracking.

Effects of Remolding Water Content and Compaction Degree on the Dynamic Behavior of Compacted Clay Soils

The stable and safe operation of highway/railway lines is largely dependent on the dynamic behavior of subgrade fillings. Clay soils are widely used in subgrade construction and are compacted at different remolding water contents and compaction degrees, depending on the field conditions. As a result, their dynamic behaviors may vary, which have not been fully investigated until now. To clarify this aspect, a series of cyclic triaxial tests were carried out in this study with three typical remolding water contents (w = 19%, 24%, and 29%), corresponding to the optimum water content as well as its dry and wet sides, and two compaction degrees (Dc = 0.8 and 0.9), which were selected according to the field-testing data. Scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) tests were also conducted on typical samples to investigate the corresponding soil fabric variations. The findings indicate the following: (a) The soil fabric at the optimum remolding water content and its dry side was characterized by a clay aggregate assembly with a bimodal pore size distribution. In contrast, the soil fabric on the wet side of the optimum water content consisted of dispersed clay particles with a unimodal pore size distribution. (b) As the compaction degree increased, to ensure the optimum water content and its dry side, large pores were compressed to make them smaller, while small pores remained unchanged. Comparatively, all the pores on the wet side were compressed to make them smaller. (c) For each compaction degree, as the remolding water content increased, a non-monotonic changing pattern was identified for both the permanent strain and resilient modulus; the permanent strain first decreased and then increased, while, for the resilient modulus, an initial increasing trend and then a decreasing trend were identified. In addition, a larger changing rate of the permanent strain (resilient modulus) was observed on the dry side, indicating a larger effect of the remolding water content. (d) For each remolding water content, as the compaction degree increased, the permanent strain exhibited a decreasing trend, but an increasing trend was identified for the resilient modulus. Moreover, the rate of change in the permanent strain (resilient modulus) on the dry side of the optimum water content was larger than that on the wet side. In contrast, the minimum rate of change was identified at the optimum water content. The obtained results allowed for the effects of the remolding water content and compaction degree on the dynamic behavior to be analyzed, and they helped guide the construction and maintenance of the subgrade.

Fabrication of porous high-entropy Mn-Fe-Co-Ni-Cu-Zn alloys by vapor phase dealloying

Porous multicomponent 3d transition-metal (TM) alloys were fabricated by eliminating Zn from rapidly quenched ribbons with distinct compositions, TM7Zn93 and TM4Zn96 (TM – a mixture of Mn, Fe, Co, Ni, and Cu) using vapor phase dealloying (VPD). Phase composition and microstructure of the ribbons in an as-quenched state and resulting porous materials were investigated in detail by S/TEM-EDS, XRD, SEM, and EDXRF methods. In the as-quenched state, the majority of the alloy is composed of the CoZn13 type structure (C2/m space group). Atomically resolved EDS mapping clarified the chemical site occupancy of the TM elements in the structure. The resulting fabricated porous high-entropy alloys (HEA) have a spongy microstructure with a bimodal pore size and their surface area was estimated at 2–4 m2/g. Analysis of pore size distribution revealed their macro-mesoporous structure. The formation of the solid solution with the FCC (Fm3̅m space group) crystal structure during VPD was confirmed by XRD data. STEM-EDS analysis revealed the existence of several FCC solid solution phases within the porous HEA. A nanoscale elemental/phase separation into Co- and Cu-rich FCC solid solution regions with coherent interfaces across the individual crystalline grains has been found. A general route to prepare porous HEA using rapid solidification and vapor phase dealloying has been discussed.

An Investigation into Electrolytes and Cathodes for Room-Temperature Sodium–Sulfur Batteries

In the pursuit of high energy density batteries beyond lithium, room-temperature (RT) sodium–sulfur (Na-S) batteries are studied, combining sulfur, as a high energy density active cathode material and a sodium anode considered to offer high energy density and very good standard potential. Different liquid electrolyte systems, including three different salts and two different solvents, are investigated in RT Na-S battery cells, on the basis of the solubility of sulfur and sulfides, specific capacity, and cyclability of the cells at different C-rates. Two alternative cathode host materials are explored: A bimodal pore size distribution activated carbon host AC MSC30 and a highly conductive carbon host of hollow particles with porous particle walls. An Na-S cell with a cathode coating with 44 wt% sulfur in the AC MSC30 host and the electrolyte 1M NaFSI in DOL/DME exhibited a specific capacity of 435 mAh/gS but poor cyclability. An Na-S cell with a cathode coating with 44 wt% sulfur in the host of hollow porous particles and the electrolyte 1M NaTFSI in TEGDME exhibited a specific capacity of 688 mAh/gS.

Improving Pore Characteristics, Mechanical Properties and Thermal Performances of Near-Net Shape Manufacturing Phenolic Resin Aerogels.

Thermally stable high-performance phenolic resin aerogels (PRAs) are of great interest for thermal insulation because of their light weight, fire retardancy and low thermal conductivity. However, the drawbacks of PRA synthesis, such as long processing time, inherent brittleness and significant shrinkage during drying, greatly restrict their wide applications. In this work, PRAs were synthesized at ambient pressure through a near-net shape manufacturing technique, where boron-containing thermosetting phenolic resin (BPR) was introduced into the conventional linear phenolic resin (LPR) to improve the pore characteristics, mechanical properties and thermal performances. Compared with the traditional LPR-synthesized aerogel, the processing time and the linear shrinkage rate during the drying of the PRAs could be significantly reduced, which was attributed to the enhanced rigidity and the unique bimodal pore size distribution. Furthermore, no catastrophic failure and almost no mechanical degradation were observed on the PRAs, even with a compressive strain of up to 60% at temperatures ranging from 25 to 200 °C, indicating low brittleness and excellent thermo-mechanical stability. The PRAs also showed outstanding fire retardancy. On the other hand, the PRAs with a density of 0.194 g/cm3 possessed a high Young's modulus of 12.85 MPa and a low thermal conductivity of 0.038 W/(m·K).

Study on environmental characteristics of sustainable biomimetic soil preparation and its application in gangue reclamation

To address the key challenges in achieving large-scale ecological reclamation of coal gangue in situ, this study utilized loess from a mining area in Northwest China to prepare a biomimetic soil. A new inorganic curing agent (ISA) was developed using coal-based solid waste and cement. The study investigates the influence of different ISA dosages and their interaction with Polyacrylamide (PAM) on the environmental characteristics of biomimetic soil, including geotechnical, ecological, and heavy metal stabilization properties. Results indicate that the addition of ISA significantly enhanced the geotechnical performance of the in-situ soil, with unconfined compressive strength exceeding 350 kPa when ISA content was above 6 %. Soil evaporation experiments and soil water characteristic curve tests demonstrated that a 6 % ISA dosage combined with 0.05 ‰ PAM could maintain soil's good water retention capability while preserving a bimodal pore structure. The biomimetic soil exhibited effective stabilization of heavy metals, including Pb, Zn, Cu, and As. The particles of PAM and the hydration products of ISA not only filled soil pores and increased soil strength but also adsorbed, encapsulated, and immobilized heavy metals. “Biomimetic soil-gangue” leaching test results confirmed that the gangue samples treated with biomimetic soil met the standards for Class III underground water in China regarding heavy metal leaching values. This study provides an effective solution for the large-scale in-situ disposal and resource utilization of gangue in Northwestern mining areas of China.

Facile one-step synthesis of in situ WO3@Gr nanorods as an efficient material for antimicrobial and decoloration applications

This work examined the synthesis, antibacterial activity, and decolourisation of WO3@Graphene nanorods (WO3@Gr NR). WO3@Gr NR nanocomposite was in situ produced via a facile one-step hydrothermal process employing sodium tungstate dihydrate and exfoliated graphene as precursors. The resulted NR exhibited an average diameter of 13 nm, a large specific surface area of 53.3 m2 g−1, and a bimodal pore size distribution with an average pore size of 5.5 nm. The optical bandgap is extrapolated to be 2.75 eV. Graphene was shown to be responsible for the sample’s elaborate visible-light absorption, which improved adsorption and the ability to harvest visible light. WO3@Gr NR are more efficient against E. coli than S. aureus, killing up to 52% and 39% of cells, respectively, after two hours of treatment. When used in conjunction with invisible light, the NR killed E. coli and S. aureus by 78 and 62%, respectively. The bactericidal activity of photoinduced WO3@Gr NR was evaluated against P. aerugunosa, E. faecalis, E. coli, and S. aureus. The photocatalytic constant rates of organic dye methylene blue (MB) were determined to be 0.01 min−1. An IC50 (50% cell growth inhibition) value of 97 (μg ml−1) was determined for the nanocomposite against human liver cancer cell lines (HepG2). Our findings suggest that this nanorod may be utilised to degrade bacteria and organic colours in wastewater simultaneously while posing no risk to human health.

Trans-electrode pressure of gas-diffusion electrodes significantly influencing the electrochemical hydrogen peroxide production

Hydrogen peroxide (H2O2) synthesis by electrochemical two-electron oxygen reduction has garnered increasing interest as a wide range of potential applications. Gas diffusion electrodes (GDEs) can effectively promote the H2O2 production efficiency by overcoming the oxygen mass transfer limitations but strongly influenced by the electrowetting process along the long-term operation. In this study, the effect of trans-electrode pressure (TEP) of GDE cathode on the electrowetting process was further elucidated. We controlled the TEP values of four types of GDEs: two Ni-based GDEs and two carbon cloth GDEs prepared by hot-pressing or brushing carbon black. SBA-15 was further used to regulate the microstructure of one Ni-based GDE. It was found that an optimal range of TEP occurred for all tested GDEs in terms of the max. concentration, the yield efficiency, the energy consumption, and the stability because TEP may change the triple-phase interface and influence the anti-electrowetting effect. The porosity of hot-pressed Ni GDE can maintain the TEP window and thus enhance the production of H2O2, likely via creating oxygen-containing functional groups and a bimodal pore structure on the electrode, revealed with several characterization techniques including SEM, CA, XPS, Raman spectra, CV and EIS. The porous Ni GDE presented an efficient and stable production of H2O2 for 10 cycles: yielding H2O2 at 4393.2–4602.2 mmol m−2 h−1 with current efficiencies of 94.2–98.7%. The best accumulated H2O2 concentration can reach up to 3.58 ωt% H2O2 at 10 h. The results provide an important reference for the industrial scaleup of electro-production of H2O2 with GDEs.

Directional saturation of a strongly bimodal pore size distribution carbon interlock fabric: Measurement and multiphase flow modeling

This study focuses on the analysis of the directionality of saturation of materials with bimodal pore size distributions. The material studied is an anisotropic carbon interlock with highly contrasted dual-scale porosity, with heavy warp and light weft tows. Experimentally, 6 configurations are tested using injection combined with dielectric sensors to measure saturation times and unsaturated lengths. The experimental results show that this material has a high contrast in dual-scale porosity and the unsaturation is anisotropic. In parallel, a two-phase flow in porous media continuum model is developed within the OpenFOAM® toolbox of libraries to simulate the transient impregnation. The need to use a tensorial relative permeability and its alignment with the saturated permeability is analyzed by a numerical multiphase mesoscale flow model. The combined experimental and numerical analysis paves the way for a methodology to analyze the saturation of various bimodal pore size distribution materials.

Water retention behavior and shear strength of artificially cemented granite residual soil subjected to free drying

Artificially cemented soils have been widely used as filling materials in highway and railway construction. The shear strength evolution of filling materials upon moist variation can determine the stability of subgrade and embankments. This study conducted water retention tests, MIP tests, and multi-stage triaxial shear tests on cement-treated granite residual soil (GRS) to determine its water retention curve (WRC) upon free drying, pore structure, and peak shear strength qf, respectively. The water retention behavior and shear strength evolution upon free drying were modeled based on the dual-porosity structure of cement-treated GRS and the effective stress principle, respectively. Results show that the drying-WRC is bimodal and higher cement dosage yields a more severe decrease in the water retention capacity within a specific suction range. For a given confining pressure, the peak shear strength qf increased with increasing cement dosage or suction value s. The peak shear strength qf also solely depends on the suction value in the peak stress state. In addition, the cement-treated GRS has a bimodal pore size distribution curve, and its macro- and micro-void ratios remain almost unchanged after free drying. The bimodal drying-WRC of the cement-treated GRS can be modeled by differentiating the water retention mechanisms in macro- and micro-pores. Moreover, using the macro-pore degree of saturation as the effective stress parameter χ = SrM, the qf–pf′ relationship (where pf′ is the effective mean pressure at failure) under various suction and stress conditions can be unified, and the qf–s relationships at various net confining pressures σ3,net can be well reproduced. These findings can help design subgrade and embankments constructed by artificially cemented GRS and assess their safe operation upon climate change.

Quantitative characterization of crude oil mobilization in microscopic pores during forward and reverse flooding in tight sandstone reservoirs using various fracturing fluid systems

In the transition from conventional to unconventional oil and gas exploration, the focus on tight sandstone reservoirs has grown due to their complex microscopic pore structures, narrow pore throats, and high capillary pressures. These characteristics often lead to the retention of fracturing fluids post-fracturing, hindering fluid recovery and reducing crude oil extraction efficiency. To address these issues, this study employed a combination of microscopic displacement experiments and nuclear magnetic resonance (NMR) analyses to investigate oil displacement mechanisms at the microscale in tight sandstone reservoirs. The experimental setup involved testing three core samples using distinct fracturing fluid systems: a guar gum-based system (System I), an EM30+ + guar gum water-based system (System II), and a CNI (Carbon Nanotechnologies Inc) nano variable-viscosity slick water-based system (System III). The study aimed to assess the impact of these different fracturing fluid systems on oil displacement efficiency in both forward and reverse directions. Results revealed that forward oil displacement efficiencies for Systems I to III were 26.86%, 33.3%, and 33.43%, respectively. In contrast, reverse displacement efficiencies were slightly higher at 28.9%, 37.5%, and 38.34%. Overall, Systems II and III outperformed System I in terms of oil displacement efficiency. The study also found that in cores with large pores, forward displacement predominantly mobilized crude oil, while reverse displacement was more effective in smaller pores. This trend was consistent in cores exhibiting bimodal pore distributions. However, in unimodal cores, small pores were significantly impacted in both directions. Notably, System III demonstrated a remarkable efficiency in mobilizing crude oil within smaller pores.

Hydromechanical coupling in unsaturated clayey rocks with double porosity based on a multiscale homogenization procedure

Shales and clay rocks are porous media with multiscale microstructures used in many engineering applications. Intact clay rocks often exhibit a bimodal pore size distribution in which the nanopores are related to the interlayer spacing in the clay platelet and the micropores are related to the interparticle pores between clay particles. The double-porosity microstructure has significant implications for the hydromechanical behavior of these rocks especially in unsaturated conditions. In this study, we develop a double-porosity hydromechanical framework incorporating a homogenization scheme to simulate fluid flow and elastic deformation in anisotropic clay rocks. The homogenization scheme provides an enriched description of the elastic behavior of clay rocks during changes in the degree of saturation by bridging the nano, micro, and macroscale characterizations. We also model the nanopores and micropores as two independent pore networks with distinct fluid flow mechanisms and permeabilities. The proposed framework is cast into a three-field mixed finite element formulation for solving fully coupled flow and deformation problems. Numerical examples of free and confined swelling in Opalinus clay samples are presented to demonstrate the impacts of a multiscale microstructure on wetting processes in clay rocks.

Deterioration of volcanic tuffs from rock dwellings in Brhlovce (Slovakia) induced by freeze-thaw cycling studied by non-destructive tests and µCT visualization

The aim of this paper is to evaluate the effect of freeze-thaw-induced weathering of volcanic tuffs from the rock dwellings in the village of Brhlovce (Slovakia) based on a non-destructive and experimental study of tuff pore space properties. Traditional techniques for characterization of the porosity and pore size distribution and new experimental techniques like spontaneous imbibition (pore interconnection) or indicative rock pore structure method (pore size distribution) were compared with pore network models acquired by X-ray computed microtomography before and after freeze-thaw cycling in a custom-built thermodilatometer VLAP04. The results offer insight into how frost weathering altered the pore network of volcanic tuffs. Brhlovce tuffs are highly susceptible to frost damage due to their high porosity, pore interconnectivity, and bimodal pore size distribution pattern, where nanometric-sized micropores predominate over larger micrometric-sized capillary pores. Poromechanical principles were applied to confirm that ice crystallization initiates in well-connected micropores with a corresponding crystallization pressure below 10 MPa. After undergoing 100 freeze-thaw cycles with temperature oscillations ranging from − 10 to 10 °C, there was a significant increase in total porosity, pore interconnectivity, and rock permeability. Additionally, the pore size distribution was altered. These parameters influence the transport of fluids and the moisture regime in rock masses, which can serve as a precursor to physical and chemical weathering processes

Nanocomposite Methacrylated Silk Fibroin-Based Scaffolds for Bone Tissue Engineering.

The treatment of bone defects is a clinical challenge. Bone tissue engineering is gaining interest as an alternative to current treatments, with the development of 3D porous structures (scaffolds) helpful in promoting bone regeneration by ensuring temporary functional support. In this work, methacrylated silk fibroin (SilMA) sponges were investigated as scaffolds for bone tissue engineering by exploiting the combination of physical (induced by NaCl salt during particulate leaching) and chemical crosslinking (induced by UV-light exposure) techniques. A biomimetic approach was adopted to better simulate the extracellular matrix of the bone by introducing either natural (mussel shell-derived) or synthetic-origin hydroxyapatite nanoparticles into the SilMA sponges. The obtained materials were characterized in terms of pore size, water absorption capability and mechanical properties to understand both the effect of the inclusion of the two different types of nanoparticles and the effect of the photocrosslinking. Moreover, the SilMA sponges were tested for their bioactivity and suitability for bone tissue engineering purposes by using osteosarcoma cells, studying their metabolism by an AlamarBlue assay and their morphology by scanning electron microscopy. Results indicate that photocrosslinking helps in obtaining more regular structures with bimodal pore size distributions and in enhancing the stability of the constructs in water. Moreover, the addition of naturally derived hydroxyapatite was observed to be more effective at activating osteosarcoma cell metabolism than synthetic hydroxyapatite, showing a statistically significant difference in the AlamarBlue measurement on day 7 after seeding. The methacrylated silk fibroin/hydroxyapatite nanocomposite sponges developed in this work were found to be promising tools for targeting bone regeneration with a sustainable approach.

Wood-inspired metamaterial catalyst for robust and high-throughput water purification

Continuous industrialization and other human activities have led to severe water quality deterioration by harmful pollutants. Achieving robust and high-throughput water purification is challenging due to the coupling between mechanical strength, mass transportation and catalytic efficiency. Here, a structure-function integrated system is developed by Douglas fir wood-inspired metamaterial catalysts featuring overlapping microlattices with bimodal pores to decouple the mechanical, transport and catalytic performances. The metamaterial catalyst is prepared by metal 3D printing (316 L stainless steel, mainly Fe) and electrochemically decorated with Co to further boost catalytic functionality. Combining the flexibility of 3D printing and theoretical simulation, the metamaterial catalyst demonstrates a wide range of mechanical-transport-catalysis capabilities while a 70% overlap rate has 3X more strength and surface area per unit volume, and 4X normalized reaction kinetics than those of traditional microlattices. This work demonstrates the rational and harmonious integration of structural and functional design in robust and high throughput water purification, and can inspire the development of various flow catalysts, flow batteries, and functional 3D-printed materials.

Effect of Initial Conditions on the Pore Structure and Bimodal Soil–Water Characteristic Curve of Compacted Granite Residual Soil

Granite residual soil typically forms complex pore structures and exhibits high water sensitivity due to physical and chemical weathering processes. Changes in initial compaction conditions significantly affect the mechanical and hydraulic properties of in situ granite residual soil subgrades, with these variations fundamentally related to changes in pore structure and soil–water characteristics. This study investigates the pore structure and bimodal soil–water characteristic curve (SWCC) of a compacted granite residual soil through laboratory tests and mercury intrusion porosimetry tests. Nine initial conditions were selected based on potential in situ compaction conditions of subgrades, and their effects on the pore size distribution (PSD) and SWCC were thoroughly analyzed. The results show strong correlations between bimodal pore structure and SWCC. The size and volume of inter-aggregate pores exhibit noticeable changes with initial conditions, affecting SWCC within the low and middle suction range. Conversely, the intra-aggregate pores, which constitute over 60% of the pore structures, remain nearly intact across different initial conditions, resulting in similar SWCCs within the high suction range. As the compaction energy increases, the inter-aggregate pores are compressed and lead to a higher water retention capacity. In addition, as the compaction water content increases, the SWCC becomes less sensitive to compaction energy after the aggregates in the pore structure are fully saturated. Additionally, a three-dimensional bimodal SWCC equation is proposed and validated using test data with an R2 value above 0.98. These findings offer valuable insights for the design and quality control of granite residual soil subgrades.

Pore Structure Characteristics of Shale Oil Reservoirs with Different Lithofacies and Their Effects on Mobility of Movable Fluids: A Case Study of the Chang 7 Member in the Ordos Basin, China

The Chang 7 member of the Triassic Yanchang Formation in the Ordos Basin is a significant continent shale oil reservoir in China. Therefore, conducting an in-depth investigation into the pore structure and fluid mobility characteristics of the Chang 7 shale oil reservoir holds immense importance for advancing shale oil exploration. This study conducts a detailed analysis of the pore structures and their impact on fluid mobility of the Chang 7 shale oil reservoir using multiple methodologies, i.e., a cast thin section, scanning electron microscopy (SEM), X-ray diffraction (XRD), high-pressure mercury injection (HPMI), low-temperature nitrogen adsorption (LTNA), and nuclear magnetic resonance (NMR). The results show that the sandstone in the Yanwumao area of the Chang 7 shale oil reservoir consists mainly of lithic arkose and feldspathic litharenite, which can be classified into three lithofacies (massive fine-grained sandstone (Sfm), silt-fine sandstone with graded bedding (Sfgb), and silt-fine sandstone with parallel bedding (Sfp)). Moreover, three pore structures (Type I, II, and III), and four pore spaces (nanopores, micropores, mesopores, and macropores) can be characterized. Pore structure Type I, characterized by large pores, exhibits bimodal pore diameter curves, resulting in the highest levels of movable fluid saturation (MFS) and movable fluid porosity (MFP). Pore structure Type II demonstrates unimodal pore structures, indicating robust connectivity, and higher MFS and MFP. Pore structure Type III primarily consists of dissolved and intercrystalline pores with smaller pore radii, a weaker pore configuration relationship, and the least fluid mobility. Furthermore, a correlation analysis suggests that the pore structure significantly impacts the fluid flowability in the reservoir. Favorable petrophysical properties and large pores enhance fluid flowability. Micropores and mesopores with high fractal dimensions have a greater impact on reservoir fluid mobility compared to macropores and nanopores. Mesopores mainly control MFS and MFP, while micropores govern the shift from bound fluid to movable fluid states. Among the lithofacies types, the Sfm lithofacies exhibit the highest fluid mobility due to their significant proportion of macropores and mesopores, whereas the Sfgb lithofacies have lower values because they contain an abundance of micropores. The Sfp lithofacies also dominate macropores and mesopores, resulting in medium fluid mobility levels. This study combines lithofacies types, micro-reservoir pore structure characteristics, and mobile fluid occurrence characteristics to better understand the dominant reservoir distribution characteristics of the Chang 7 shale oil reservoirs in the Ordos Basin and provide theoretical information for further optimization of production strategies.