Big Datasets Research Articles

Elevating Facial Expression Detection: Empowered by VGG-19 and Weight-Normalized Gradient Boost Algorithm

Facial expression recognition termed as FER, is one of the vital tasks which is able in mimicking the human ability and wellness. Face expression and other gestures delivered via face are some of the important aspects of conveying non-verbal communications which plays a vital role in interpersonal relations. This domain has a higher scope of research due to enhancing computer vision and human-computer interaction. With respect and consideration to these domain interest, DL has gained a reasonable approach in performing FER. Some of the state-of-art approaches encompassing the ML approaches have faced several cases of laybacks such as overfitting, computational complexity, less adaptable to higher and big datasets. Thus, considering these laybacks and in achieving accurate FER in aspects of bringing proximal levels of FER, the current approach deployed DL methods for both feature extraction from the input image and in classifying them. Deep multi-level feature extraction is performed using the VGG-19 model and Weight Normalized gradient boosting algorithm is adapted for classifying these expressions using the FER13 dataset. This dataset constitutes the input images, which are in ranges of 28,709 sample image data and about 3,589 image data for test. These input images are initially pre-processed for obtaining better accuracy rates when performing feature extraction and classifications. The complete model in effective FER is evaluated using the performance metrics comprising Accuracy (98%), Recall (99%), F1-score (98%) and the precision rates (97%). This analysis of the performance will aid in affirming the overall efficacy of the proposed system.

DeePathNet: a transformer-based deep learning model integrating multi-omic data with cancer pathways.

Multi-omic data analysis incorporating machine learning has the potential to significantly improve cancer diagnosis and prognosis. Traditional machine learning methods are usually limited to omic measurements, omitting existing domain knowledge, such as the biological networks that link molecular entities in various omic data types. Here we develop a Transformer-based explainable deep learning model, DeePathNet, which integrates cancer-specific pathway information into multi-omic data analysis. Using a variety of big datasets, including ProCan-DepMapSanger, CCLE, and TCGA, we demonstrate and validate that DeePathNet outperforms traditional methods for predicting drug response and classifying cancer type and subtype. Combining biomedical knowledge and state-of-the-art deep learning methods, DeePathNet enables biomarker discovery at the pathway level, maximizing the power of data-driven approaches to cancer research. DeePathNet is available on GitHub at https://github.com/CMRI-ProCan/DeePathNet.

AI-driven automatic generation and rendering of game characters

Abstract. This paper provides a comprehensive review of AI-driven techniques for the automatic generation and rendering of game characters, with a particular focus on Generative Adversarial Networks (GANs) and Variational Autoencoders (VAEs). GANs, using adversarial training approaches, have revolutionized character development by producing incredibly realistic and aesthetically pleasing gaming characters. VAEs, despite frequently encountering issues like image blurriness, provide an alternate strategy that emphasizes diversity and originality in the generated content. Additionally, conditional models that enable more individualized and regulated character generation are explored, as well as hybrid models that combine the best features of both GANs and VAEs. The difficulties with mode collapse in GANs and the requirement for big datasets for both GANs and VAEs are also covered, along with some possible fixes like transfer learning and semi-supervised learning strategies. This analysis emphasizes the growing significance of AI-driven game character generation in the gaming industry by highlighting its current state, problems, and future directions.

Deep semantics-preserving cross-modal hashing

Cross-modal hashing has been paid widespread attention in recent years due to its outstanding performance in cross-modal data retrieval. Cross-modal hashing can be decomposed into two steps, i.e., the feature learning and the binarization. However, most existing cross-modal hash methods do not take the supervisory information of the data into consideration during binary quantization, and thus often fail to adequately preserve semantic information. To solve these problems, this paper proposes a novel deep cross-modal hashing method called deep semantics-preserving cross-modal hashing (DSCMH), which makes full use of intra and inter-modal semantic information to improve the model's performance. Moreover, by designing a label network for semantic alignment during the binarization process, DSCMH's performance can be further improved. In order to verify the performance of the proposed method, extensive experiments were conducted on four big datasets. The results show that the proposed method is better than most of the existing cross-modal hashing methods. In addition, the ablation experiment shows that the proposed new regularized terms all have positive effects on the model's performances in cross-modal retrieval. The code of this paper can be downloaded from http://www.scholat.com/laizhihui.

The emergence of green finance a conceptual framework for environmental sustainability: innovation viewpoint

Background of the study This study intends to contribute to the continuing discussion about green economic growth by objectively investigating the consequences of clean energy generation, cutting-edge green practices, and ethical business on global sustainability. This study also examines how green finance laws effectively handle the financial limitations that companies face when pursuing green innovation. Green finance enables the development and implementation of sustainable business models, investments, trade, economic, environmental, and social projects through the effective utilization of financial resources. Methods This article offers a complete evaluation of the current state and advancements in green finance research using a mixed-methods approach, which includes bibliometric and qualitative analysis. We analysed a big dataset of research papers after entering the keywords into the Scopus database. Results This study found that green bank products include green securities, investments, climate financing, carbon finance, insurance, credit, and infrastructure bonds. Sustainability, sustainable development, investments, environmental economics, sustainable finance, green bonds, and the green economy dominate as a most prevalent theme. China has the strongest bibliometric linkages to other nations, followed by the US and UK. This study also examines whether green finance policies address firm financial restrictions while pursuing green innovation. VOS-viewer generates co-authorship-based keyword occurrence links and network maps. Conclusion Green finance strives to increase funding flows to sustainable development goals while mitigating environmental and social hazards. “Going green,” pricing, forecasting, modelling, picking the most efficient tool, and influencing investor behaviour toward environmentally friendly operations are all challenges. Environmental policies, interest rates, religion, risks, social inclusion, and banking laws all have an impact on bank green financing initiatives. The study’s main contribution is an overview of green finance breakthroughs for sustainability, which may help scholars and practitioners understand the trend and future research directions.

The Impact of Big Data and Predictive Analytics on U.S. Healthcare Delivery: Opportunities, Challenges, and Future Directions

Healthcare, like many other industries, has been significantly influenced by big data and predictive analytics. The vast volume, velocity, and variety of information within big data sets have transformed the way we approach patient care and medical innovation. From predicting disease outbreaks to delivering personalized treatment plans, big data analytics offers immense potential for revolutionizing healthcare. This review explores the significant impact of big data and predictive analytics on the U.S. healthcare system. It delves into hospitals' ability to effectively leverage complex information and assess the potential benefits they may reap from successful implementation. The introduction defines big data and predictive analytics in the context of healthcare and outlines the paper's objectives. It further discusses the evolution of big data and analytics in healthcare, its key applications, and the challenges it presents. Additionally, we explore potential solutions and ethical considerations surrounding big data analytics in healthcare. Overall, this paper underscores the transformative power of big data and predictive analytics in revolutionizing U.S. healthcare delivery and improving patient outcomes.

Site selection for biomass-solar hybrid renewable energy facilities: Spatial modelling based on fuzzy logic-geographic information systems

The aim of this study is to propose a fuzzy logic-geographic information systems (GIS) based spatial model within the context of hybrid renewable energy, rural areas, and spatial planning approach in the site selection process of renewable energy facilities. In this context, potential suitability index and site selection suitability index for biomass-solar hybrid renewable energy facilities are determined within the spatial model, through a case study conducted in Türkiye. The study involves a two-stage process: the first stage focuses on establishing the national-level potential, and the second stage involves site selection in areas with high potential. Suitable locations are determined based on the optimal suitability index values, which are derived from fuzzy logic operators including AND, OR, SUM, PRODUCT, and GAMMA, applied in the GIS. The study results indicate that by assigning different γ values to the fuzzy GAMMA operator, results for the fuzzy AND (γ = 0.45–0.60), fuzzy OR (γ = 1.00), fuzzy SUM (γ = 1.00), and fuzzy PRODUCT (γ = 0.00–0.15) operators can be obtained. Furthermore, as the γ value increases, the suitability index also rises, and the optimal site selection occurs at γ = 0.90. The performance of the fuzzy GAMMA operator in big data sets and two-stage processes demonstrates its applicability in site selection.

A Comparative Analysis of Machine Learning Algorithms for Big Data Applications in Predictive Analytics

As the volume and complexity of data continue to grow, predictive analytics has emerged as a vital tool for extracting actionable insights from big data, driving decision-making across various domains such as healthcare, finance, and e-commerce. However, selecting an appropriate machine learning algorithm for predictive analytics applications is challenging due to differences in algorithmic performance, computational requirements, and scalability, especially in the context of big data. This paper provides a comprehensive comparative analysis of popular machine learning algorithms utilized in predictive analytics, specifically focusing on their effectiveness and feasibility in big data environments. The study categorizes algorithms based on learning types—supervised, unsupervised, and reinforcement learning—and evaluates their performance across multiple dimensions: prediction accuracy, computational efficiency, scalability, and suitability for real-time analytics. Through a detailed analysis of algorithms, including linear regression, decision trees, support vector machines, neural networks, and clustering techniques, we assess each method’s strengths and limitations in handling large datasets. Additionally, the study introduces a series of metrics, such as accuracy, F1-score, and training time, as benchmarks for assessing the algorithms’ predictive capabilities and computational viability. A hypothetical case study demonstrates the application of these algorithms on a sample big data set, providing insights into their real-world performance across different predictive analytics scenarios. Visual data representations, including comparative tables and performance graphs, offer a clearer perspective on the trade-offs among algorithm choices. The findings highlight that while certain algorithms like random forests and neural networks achieve higher accuracy in prediction tasks, they may also require substantial computational resources, posing limitations for real-time processing in big data applications. This paper concludes with recommendations for selecting machine learning algorithms based on specific predictive analytics objectives, data characteristics, and processing requirements. Furthermore, it discusses the challenges associated with implementing these algorithms in big data contexts and explores potential advancements, such as the integration of deep learning and the use of distributed computing, as promising directions for enhancing predictive analytics performance in future applications.

Spatial data mining-focused research on image processing techniques for remotely sensed images

ABSTRACT Spatial data mining is an important approach for collecting useful data from big datasets, especially remotely sensed images. This study tackles issues in environmental monitoring and management using sophisticated image processing. The Horse Herd Optimization-based VGG19 (HHO-VGG19) is proposed to improve land cover classification, recognition of objects, detection of changes, and detection of anomalies. The study used the BCDD dataset, which was scaled to 512 × 512 pixels, then applied Z-score normalization and extracted features using Principal Component Analysis (PCA). The VGG19 architecture was enhanced by utilizing Horse Herd Optimization to enhance image classification efficiency. The HHO-VGG19 model surpasses conventional techniques, with F1-score of 92%, a recall of 94%, an accuracy of 98.5%, and a 30-second execution time reduction. The findings indicate the efficiency of integrating sophisticated image processing with spatial data mining, giving an effective tool for remote sensing image processing in environmental uses including tracking ecosystems and handling of natural resources.

Geoinference of author affiliations using NLP-based text classification

Author affiliations are essential in bibliometric studies, requiring relevant information extraction from free-text affiliations. Precisely determining an author’s location from their affiliation is crucial for understanding research networks, collaborations, and geographic distribution. Existing geoparsing tools using regular expressions have limitations due to unstructured and ambiguous affiliations, resulting in erroneous location identification, especially for unconventional variations or misspellings. Moreover, their inefficient handling of big datasets hampers large-scale bibliometric studies. Though machine learning-based geoparsers exist, they depend on explicit location information, creating challenges when detailed geographic data is absent. To address these issues, we developed and evaluated a natural language processing model to predict the city, state, and country from an author’s free-text affiliation. Our model automates location inference, overcoming drawbacks of existing methods. Trained and tested with MapAffil, a publicly available geoparsed dataset of PubMed affiliations up to 2018, our model accurately retrieves high-resolution locations, even without explicit mentions of a city, state, or even country. Leveraging NLP techniques and the LinearSVC algorithm, our machine learning model achieves superior accuracy based on several validation datasets. This research demonstrates a practical application of text classification for inferring specific geographical locations from free-text affiliations, benefiting researchers and institutions in analyzing research output distribution.

New insights on genetic background of major diabetic vascular complications

BackgroundBy 2045, it is expected that 693 million individuals worldwide will have diabetes and with greater risk of morbidity, mortality, loss of vision, renal failure, and a decreased quality of life due to the devastating effects of macro- and microvascular complications. As such, clinical variables and glycemic control alone cannot predict the onset of vascular problems. An increasing body of research points to the importance of genetic predisposition in the onset of both diabetes and diabetic vascular complications.ObjectivesPurpose of this article is to review these approaches and narrow down genetic findings for Diabetic Mellitus and its consequences, highlighting the gaps in the literature necessary to further genomic discovery.Material and methodsIn the past, studies looking for genetic risk factors for diabetes complications relied on methods such as candidate gene studies, which were rife with false positives, and underpowered genome-wide association studies, which were constrained by small sample sizes.ResultsThe number of genetic findings for diabetes and diabetic complications has over doubled due to the discovery of novel genomics data, including bioinformatics and the aggregation of global cohort studies. Using genetic analysis to determine whether diabetes individuals are at the most risk for developing diabetic vascular complications (DVC) might lead to the development of more accurate early diagnostic biomarkers and the customization of care plans.ConclusionsA newer method that uses extensive evaluation of single nucleotide polymorphisms (SNP) in big datasets is Genome-Wide Association Studies (GWAS).

Developing Big Data anomaly dynamic and static detection algorithms: AnomalyDSD spark package

BackgroundAnomaly detection is the process of identifying observations that differ greatly from the majority of data. Unsupervised anomaly detection aims to find outliers in data that is not labeled, therefore, the anomalous instances are unknown. The exponential data generation has led to the era of Big Data. This scenario brings new challenges to classic anomaly detection problems due to the massive and unsupervised accumulation of data. Traditional methods are not able to cop up with computing and time requirements of Big Data problems. MethodsIn this paper, we propose four distributed algorithm designs for Big Data anomaly detection problems: HBOS_BD, LODA_BD, LSCP_BD, and XGBOD_BD. They have been designed following the MapReduce distributed methodology in order to be capable of handling Big Data problems. ResultsThese algorithms have been integrated into an Spark Package, focused on static and dynamic Big Data anomaly detection tasks, namely AnomalyDSD. Experiments using a real-world case of study have shown the performance and validity of the proposals for Big Data problems. ConclusionsWith this proposal, we have enabled the practitioner to efficiently and effectively detect anomalies in Big Data datasets, where the early detection of an anomaly can lead to a proper and timely decision.

Computational Analysis of T-Cell Receptor Repertoire Workflow: From T-Cell Isolation to Bioinformatics Analysis.

The T-cell receptor (TCR) is the key molecule involved in the adaptive immune response. It is generated by the V(D)J recombination, responsible of the enormous diversity of the TCR repertoire, a crucial feature determining the individual capability to response to antigens and to build immunological memory. A pivotal role in the recognition of antigen is played by the hypervariable complementarity-determining region 3 (CDR3) of the V-beta chain of TCR. Investigating the CDR3 supports the understanding of the adaptive immune system dynamics in physiological processes, such as immune aging, and in disease, especially autoimmune disorders in which T cells are main actors. High-throughput sequencing (HTS) paved the way for a great progress in the investigation of TCR repertoire, enhancing the read depth in the process of library generation of sequencing and the number of samples that can be analyzed simultaneously. Therefore, the leverage of big datasets stressed the need to develop computational approach, by bioinformatics, to unravel the characteristics of the TCR repertoire.

Optimisation of Sentiment Analysis for E-Commerce

Sentiment analysis is widely used today to make data-driven decisions in different industries, starting from marketing and including brand management, reputation monitoring, and customer satisfaction analysis. Its growing importance is closely linked with so-called ‘word-of-mouth’ communication, from reading online reviews to writing comments on social networks. Effective separation of sentiments ensures that companies' responses are timely and critical patterns are seen in big data sets. Statistical measures, information gain, correlation-based approaches, etc, have been employed for the feature selection. Still, the problem associated with text data mining is that they don’t convey the text's relative difficulty and additional features. To fill this gap, our research proposes a new feature selection technique through Ant Colony Optimization (ACO) and K Nearest Neighbour (KNN) performed on 28,000 customer reviews in different product categories. The results, therefore, showed an overall accuracy of 80.1%, with the Support Vector Machine (SVM) set at 80.5% on each selected feature, which was slightly higher than the Convolutional Neural Network (CNN), which scored a 78.41% accuracy. SVM remains on the mark of 83%, and for CNN, the rate achieved on the same was 80.8% when both were applied to the entire dataset. These facts rejected the infallibility of the simple and complex algorithms used singly in the sentiment classification, indicating that more sophisticated algorithms like ACO and KNN can provide business solutions to improve their service delivery based on customers’ feedback.

Extraction of value and impact from IoT big data sets: A qualitative exploration of current methodologies and future directions

Integrating the Internet of Things (IoT) with big data analytics has created transformative opportunities across various domains, including smart cities, healthcare, and industrial automation. However, the challenges of extracting value from the vast and heterogeneous IoT data sets are significant. This study aims to explore methods for maximizing value extraction from IoT-generated big data and evaluate their impact on decision-making processes. A systematic literature review was conducted, and an exploratory qualitative methodology was employed to assess existing frameworks and propose improvements. The results highlight the importance of edge computing, machine learning algorithms, and data processing architectures in managing IoT data effectively. Additionally, the study identifies gaps in current research and suggests future directions to enhance the practical application of IoT big data analytics.

A Novel Approach to Confidentiality Preservation in Big Data Using Distinct Contextual Sensitivity Hashing

Despite the rapid development of technological innovations (IT), hypersensitive large-scale data assembling and efficiency have gotten better. To preserve the confidentiality of patients in the field of health care, it is necessary to reduce redundant confidential data whereas implementing hazardous big data sets which need to be discovered with the goal to gather appropriate data. Over the past decade, an array of preserving confidentiality approaches has been implemented employed by employing the quasi-identifier (QI) with application which includes healthcare services. Nevertheless, because of the enormous quantity of the majority of databases, protecting confidentiality across near-identifiers remains challenging in situations of enormous amounts of data. Because of datasets evolving constantly, traditional methods experience more time utilisation and reduced knowledge utility. In this paper, researchers present an advantageous Distinct Contextual Highly sensitive with Hellinger Convolutional Learner (DCS-HCL) technique that preserves anonymity yet optimising the value of information across enormous medical databases. In the beginning a Distinct Impact Contextual Delicate Hashing, or framework is generated using the input that has been provided Massive Dataset, and this model examines each of the distinct and affect variables prior implementing the results to Contextual Sensitivity Hashing. This serves as a basis enabling the development of highly computationally effective anonymous information through correlating associated QI-classes. For the purpose of preserve the confidential nature associated with personal data that is unstructured, an Hellinger Convolutional Neuro Security Conservation algorithm has been provided. This is accomplished through modifying CNN's algorithms strength and biases simultaneously processing QI-class data to maximize correctness and reduce data loss. The assessment's outcomes indicate that the approach we propose surpasses conventional approaches when it comes to of execution time, resource utility, loss of information, and correctness towards maintaining confidentiality using large-volume unorganized information sets.

Making the most of big qualitative datasets: a living systematic review of analysis methods.

Qualitative data provides deep insights into an individual's behaviors and beliefs, and the contextual factors that may shape these. Big qualitative data analysis is an emerging field that aims to identify trends and patterns in large qualitative datasets. The purpose of this review was to identify the methods used to analyse large bodies of qualitative data, their cited strengths and limitations and comparisons between manual and digital analysis approaches. A multifaceted approach has been taken to develop the review relying on academic, gray and media-based literature, using approaches such as iterative analysis, frequency analysis, text network analysis and team discussion. The review identified 520 articles that detailed analysis approaches of big qualitative data. From these publications a diverse range of methods and software used for analysis were identified, with thematic analysis and basic software being most common. Studies were most commonly conducted in high-income countries, and the most common data sources were open-ended survey responses, interview transcripts, and first-person narratives. We identified an emerging trend to expand the sources of qualitative data (e.g., using social media data, images, or videos), and develop new methods and software for analysis. As the qualitative analysis field may continue to change, it will be necessary to conduct further research to compare the utility of different big qualitative analysis methods and to develop standardized guidelines to raise awareness and support researchers in the use of more novel approaches for big qualitative analysis. https://osf.io/hbvsy/?view_only=.

EstuarySAT Database Development of Harmonized Remote Sensing and Water Quality Data for Tidal and Estuarine Systems.

Researchers and environmental managers need big datasets spanning long time periods to accurately assess current and historical water quality conditions in fresh and estuarine waters. Using remote sensing data, we can survey many water bodies simultaneously and evaluate water quality conditions with greater frequency. The combination of existing and historical water quality data with remote sensing imagery into a unified database allows researchers to improve remote sensing algorithms and improves understanding of mechanisms causing blooms. We report on the development of a water quality database "EstuarySAT" which combines data from the Sentinel-2 multi-spectral instrument (MSI) remote sensing platform and water quality data throughout the coastal USA. EstuarySAT builds upon an existing database and set of methods developed by the creators of AquaSat, whose region of interest is primarily larger freshwater lakes in the USA. Following the same basic methods, EstuarySAT utilizes open-source tools: R v. 3.24+ (statistical software), Python (dynamic programming environment), and Google Earth Engine (GEE) to develop a combined water quality data and remote sensing imagery database (EstuarySAT) for smaller coastal estuarine and freshwater tidal riverine systems. EstuarySAT fills a data gap that exists between freshwater and estuarine water bodies. We are able to evaluate smaller systems due to the higher spatial resolution of Sentinel-2 (10 m pixel image resolution) vs. the Landsat platform used by AquaSat (30 m pixel resolution). Sentinel-2 also has a more frequent revisit (overpass) schedule of every 5 to 10 days vs. Landsat 7 which is every 17 days. EstuarySAT incorporates publicly available water quality data from 23 individual water quality data sources spanning 1984-2021 and spatially matches them with Sentinel-2 imagery from 2015-2021. EstuarySAT currently contains 299,851 matched observations distributed across the coastal USA. EstuarySAT's primary focus is on collecting chlorophyll data; however, it also contains other ancillary water quality data, including temperature, salinity, pH, dissolved oxygen, dissolved organic carbon, and turbidity (where available). As compared to other ocean color databases used for developing predictive chlorophyll algorithms, this coastal database contains spectral profiles more typical of CDOM-dominated systems. This database can assist researchers and managers in evaluating algal bloom causes and predicting the occurrence of future blooms.

Analysis of Road Roughness and Driver Comfort in 'Long-Haul' Road Transportation Using Random Forest Approach.

Global trade depends on long-haul transportation, yet comfort for drivers on lengthy trips is sometimes neglected. Rough roads have a major negative influence on driver comfort and increase the risk of weariness, distracted driving, and accidents. Using Random Forest regression, a machine learning technique well-suited to examining big datasets and nonlinear relationships, this study examines the relationship between road roughness and driver comfort. Using the MIRANDA mobile application, data were gathered from 1,048,576 rows, including vehicle acceleration and values for the International Roughness Index (IRI). The Support Vector Regression (SVR) and XGBoost models were used for comparative analysis. Random Forest was preferred because of its ability to be deployed in real time and use less memory, even if XGBoost performed better in terms of training time and prediction accuracy. The findings showed a significant relationship between driver discomfort and road roughness, with rougher roads resulting in increased vertical acceleration and lower comfort levels (Road Roughness: SD-0.73; Driver's Comfort: Mean-10.01, SD-0.64). This study highlights how crucial it is to provide smooth surfaces and road maintenance in order to increase road safety, lessen driver weariness, and promote long-haul driver welfare. These results offer information to transportation authorities and policymakers to help them make data-driven decisions that enhance the efficiency of transportation and road conditions.

Information-theoretic quantities as effective descriptors of electrophilicity and nucleophilicity in density functional theory.

Electrophilicity and nucleophilicity are two vastly important chemical concepts gauging the capability of atoms in molecules to accept and donate the maximal number of electrons. In our earlier studies, we proposed to simultaneously quantify them using the Kullback-Leibler divergence from the information-theoretic approach in density functional theory. However, several issues with this scheme remain to be clarified such as its general validity, predictability, and relationship with other information-theoretic quantities. In this work, we revisit the matter with bigger datasets and deeper theoretical insights. Five information-theoretic quantities including Kullback-Leibler divergence, Hirshfeld charge, Ghost-Berkowitz-Parr entropy, and second and third orders of relative Onicescu information energy are found to be reliable and robust descriptors of electrophilicity and nucleophilicity propensities. Employing these five descriptors, we design a list of new compounds and predict their electrophilicity and nucleophilicity scales. This work should markedly improve our confidence and capability in applying information-theoretic quantities to evaluate electrophilicity and nucleophilicity propensities and henceforth pave the route for more applications of these quantities from information-theoretic approach in density functional theory in the future. All structures were fully optimized at the M06-2X/6-311 + G(d) level of DFT functional using the Gaussian 16 package (version C01) with integration grids and tight self-consistent-field convergence. The solvent effect was taken into account by using the implicit solvent model (CPCM) in the CH2Cl2 solvent, and all 3D contour surfaces of Fukui function, local temperature, and ITA (information-theoretic approach) quantities were generated by GaussView. The Multiwfn 3.8 program was used to calculate the ITA indexes and atomic charges.