Geochemical analysis in terms of major, trace and rare earth elements of the Neo-Proterozoic arenites of Rewa and Bhander Groups of the Vindhyan Supergroup from Murwara, Katni district, M.P., has been carried out to determine the provenance, weathering and tectonic setting. The arenites are rich in SiO2 content but less in Na2O, K2O and CaO contents, suggesting the dominance of quartz and less amount of feldspars and rock fragments. Geochemically, these rocks are classified as quartz arenites to sub litharenite to sub-arkose. The CIA (75-98) and PIA values for these arenites and A-CN-K diagram indicates a high intensity of weathering in the source area. High LREE/HREE ratios, negative Eu anomaly and La/Sc, Th/Sc, Th/Co and Cr/Th ratio values suggest felsic source of these arenites. The discriminant diagram for these arenites indicates a quartzose sedimentary provenance. Ni vs TiO2 and Th/Sc vs Sc bivariate plots indicate that the felsic rocks have been the source rock for these arenites. The discrimination diagrams based on log (K2O+Na2O) vs SiO2 and Fe2O3+MgO vs TiO2 contents show a passive margin setting. Whereas the results of new discriminant function multi-dimensional diagram for the high silica arenites reveals a change from collision to continental rift setting