Coupling Behavior Research Articles

Modeling and Compensation of Stiffness-Dependent Hysteresis Coupling Behavior for Parallel Pneumatic Artificial Muscle-Driven Soft Manipulator

Modeling and Compensation of Stiffness-Dependent Hysteresis Coupling Behavior for Parallel Pneumatic Artificial Muscle-Driven Soft Manipulator

Fully coupled thermal-structural-vibration characteristics of 3-axis machine tools with complex hybrid linear axis-spindle systems considering structural nonlinearities

For machine tools composed of functional components bonded by joints with structural nonlinearities, the load- and temperature-dependent nonlinear restoring force,stiffness, and frictional heat generationfrom the jointdetermine its complex dynamic fully coupled thermal-structural-vibration characteristics. In response, in this work, considering the vibration feedback dominated by the structural vibration and employing a partition-based closed-loop iterative algorithm, a fully coupled thermal-structural-vibration model that characterizes the nonlinear coupling between temperature and mechanical fields is developed with the joint as the link. The multi-body dynamics model of the whole machine tool, considering the flexibility of the screw shaft, spindle, and joint nonlinearity, characterizes the milling dynamics influenced by structural vibration and regeneration effects. The global thermal resistance network model with dynamic heat flux, viscosity-temperature effect, and time-varying thermal resistanceis establishedto characterize the thermal characteristics. The partition-based closed-loop iterative algorithm is employed to realize the multi-field coupling and consider the moving heat source and the load distribution change caused by the reciprocating moving joint. Considering the changes in contact angle and contact deformation caused by preload, dynamic load, and thermal effect, load- and temperature-dependent nonlinear joint restoring force and stiffnessare developed. Based on the viscosity-temperature effects and the change of contact friction caused by thermal expansion and dynamic load, the load- and temperature-dependent nonlinear joint frictional heat generation is calculated. The milling load from tool-workpiece interaction is calculated, and the influence of multi-field coupling on regenerative chatter is explored. The proposed model was experimentally verified, andthe effectof parameterswas numerically investigated. The results show that the dynamic milling load excites the whole machine tool vibration, and for every 10 μm increase in cutting depth, the radial amplitude of the tool nose increased by at least 1 μm. The nonlinear coupling between temperature and mechanical field significantly affects the system response, and the joint contact stiffness dominates the multi-field coupling behavior.

Modelling and theoretical research on transient lubrication and wear coupling behavior of main bearing during start-up of low-speed diesel engine

This study endeavors to establish a transient mixed lubrication model for time-varying wear of main bearings under dynamic loading conditions during the startup process. This model accounts for variations in oil film thickness attributable to deformation, wear profiles, and journal misalignment throughout the operational cycle. The evolution of main bearing lubrication characteristics during the startup process was analyzed, as well as the evolution of wear profiles and their effects on lubricating properties under different numbers of startups. The results indicate that as the number of startup cycles increases, the wear rate gradually levels off. With increasing startup times, there is a decrease in contact pressure and a slight reduction in oil film pressure, resulting in enhanced lubricating performance. Furthermore, the influence of startup duration on wear is significantly greater than that of radial clearance.

Coupling analysis between wave resonance in the moonpool and heave motion of the twin hulls with mooring effect

Fluid resonance in the moonpool formed by two identical rectangular hulls in water waves is investigated by employing the Computational Fluid Dynamics (CFD) package OpenFOAMⓇ. The influence of vertical stiffness on the behavior of moonpool resonance coupling with the heave motion response is presented. Numerical simulations show that the free surface oscillation in the moonpool exhibits a two-peak variation with the incident wave frequency, defined as the first and second peak frequencies. A local Keulegan–Carpenter (KC) number is introduced for describing the influence of fluid viscosity and flow rotation on the fluid resonance and heave motion resonance. At the first peak frequency, the free surface oscillation and heave motion response show an in-phase relationship, where increase in the vertical stiffness can increase the relative motion between them. This finally leads to an increase in the KC number, indicating the increased effect of energy dissipation with increase in the vertical stiffness. At the second peak frequency with an out-of-phase relationship between the free surface oscillation and heave motion response, the variation of the KC number is not sensitive to the vertical stiffness. Correspondingly, the influence of energy dissipation is not strongly dependent on the vertical stiffness.

Solid/liquid hybrid lubrication behaviors of amorphous carbon film coupling with nonpolar and polar base oils

The amorphous carbon film (a-C) has aroused intensive interest in solid-oil hybrid lubrication design due to its low friction, high wear resistance, and good chemical inertness. However, the solid/liquid hybrid lubrication behaviors and mechanisms of a-C films when coupled with nonpolar and polar oils of similar viscosity are still insufficiently understood and ambiguous to date. In this study, we compared the lubrication properties of nonpolar paraffin oil and polar polyether oils with different molecular structures when combined with a-C film. The results demonstrated that the lubrication performance of polyether oils coupled with a-C film surpassed that of paraffin oil across various lubrication regimes. Notably, the stable superlubricity (friction coefficient<0.01) was achieved under mixed lubrication regime on the a-C film when coupled with polyethylene glycol (PEG) oil after a prolonged sliding duration. The tribo-induced formation of carbon quantum dots (CQDs) at the steel/a-C friction interface lubricated by PEG oils was firstly observed. The hydroxylation of the counter ball surface and the fabrication of CQDs might jointly contribute to the achievement of the robust superlubricity of the PEG oil/a-C film hybrid lubrication system.

Neo-Hookean modeling of nonlinear coupled behavior in circular plates supported by micro-pillars

In the contemporary era, the enhancement of wearable capacitive sensors is achieved through the utilization of polymeric micropillars as filler materials between electrode plates. To gain a deeper understanding of the dynamic response of the system, nonlinear coupled governing equations of a circular microplate motion resting on an array of polymeric micropillars have been derived. These equations are used to model the system’s behavior. In addition, the squeezing motion of the micro-pillars is characterized using the incompressible Neo-Hookean model. Both static and dynamic responses, including transient and steady-state solutions, are investigated in detail by discretizing over spatial coordinates using a weak formulation approach. A frequency response analysis is conducted using a continuation-based method. This entails expanding the steady-state solution using a Fourier transform and employing the energy balance principle. The unknown coefficients of the expansion series are calculated using a gradient descent-based learning approach that is physically motivated. Furthermore, a dynamic step size strategy for frequency increments is employed to effectively follow the solution path. This strategy is implemented via the ARC length method. In this study, we examine the impact of varying PDMS (polydimethylsiloxane) hydrogel mechanical and geometrical configurations. It can be reasonably concluded that the mechanical properties of the pillars and the geometrical configuration of the circular plate and micropillars have a significant impact on the maximum tolerable pressure, fast transient response, and frequency response analysis.

Determination of cyclic behavior of various cross-section composite column-beam connections reinforced with FRP composite using FEM analysis and ML models

ABSTRACT This study examined the cyclic behavior of glass-fiber-reinforced polymer composite column-beam connectors in various diameters. Mean learning (XGBoost and the random forest algorithm) and numerical methods were used to identify the data collected experimentally due to the rotation behavior. The initial sample had a column length of 1200 mm and a cross-section of 80 × 80 mm, with a beam section measuring 80 × 160 mm. The second sample had a 100 × 100 mm column and a beam section measuring 100 × 200 and 1200 mm, respectively. For the third sample, the column’s dimensions were 130 × 130 mm in cross-section and 1200 mm in length, and the beam was 130 × 260 mm. Spruce wood is used to make glulam components for columns and beams. Following the creation of the column-beam connections, glass-based fiber-reinforces polymer (FRP) fabric was used to wrap the column-beam connections that needed strengthening. The cyclic behavior of the reinforced reference samples and the samples with reinforced column-beam joint areas was examined. The column-beam connection with code C13B13-R has the most load-carrying capacity (13.9 kN), while the beam with code C08B08-UR has the lowest load-carrying capacity (03.4 kN). Examining the table reveals that the findings of the numerical analysis and the experiment provide comparable conclusions. When comparing experimental and numerical results, similar values are found for stiffness values (R 2 of 0.99), load-bearing capacity (R 2 of 0.99), and energy consumption capacity (R 2 of 0.99). With R 2 of 0.9978, RMSE of 0.01017, and MAE of 0.01043, the random forest approach identified the stiffness values in the model with the best accuracy. It has been shown that the seismic behavior of column-beam couplings built with these materials may be studied with mean learning models and numerical analysis, instead of demanding and time-consuming experimental studies.

The role of Rh spacer layer thickness on the noncollinear interlayer exchange coupling

Abstract The relationship between noncollinear interlayer exchange coupling (IEC) and magnetic anisotropic behavior in Fe/Rh/Fe trilayers is studied in detail by using magneto-optical Kerr effect (MOKE) and anisotropic magnetoresistance (AMR) techniques. It is found that the Rh spacer layer thickness strongly affects IEC and magnetic anisotropy in these trilayers. The role of Rh spacer layer thickness is shown in the oscillatory behavior in the magnitude of the magnetic anisotropy, the transition from uniaxial to four-fold anisotropy, the shift of easy axis for magnetic anisotropy, and the unusual increase in the sheet resistance. As an outcome of this study, we discuss the underlying mechanism based on the noncollinear IEC across the Fe/Rh/Fe interlayer. As a result, it has been shown that the noncollinear IEC can be controlled by the various Rh spacer thicknesses among nonmagnetic transition layers.

Experimental and numerical investigations into torsional-flexural behaviours of railway composite sleepers and bearers

Abstract Fibre-reinforced foamed urethane (FFU) composite sleepers and bearers are safety-critical components installed in complex railway switches and crossings. Not only does they need to provide vertical track support, the composite sleepers and bearers must also endure longitudinal and lateral actions stemming from complex wheel and rail interactions. In reality, the railway bearers at crossing noses are susceptible to coupling torsional-flexural loading. The complex non-linear behaviours have never been investigated numerically nor experimentally. It is thus necessary to comprehend torsional-flexural behaviours of FFU composite sleepers and bearers through finite element and experimental approaches. 3D finite element modelling of FFU composite beams have been established to predict the non-linear coupling behaviours. Three specimens of FFU beams have been prepared for robust experiments under each load case. Our studies exhibit excellent agreement between numerical and experimental results. The ductile failure behaviours (post yield point) have been observed from the experiments. Considerable effects of load eccentricity on the flexure–torsion behaviours of the composite members can also be noted. In addition, the load-eccentricity curves have been identified to portray the non-linear behaviour of the railway components under coupling flexural and torsional loadings. The new insights considering their load–displacement relationships, modes of failure and damage, flexural and torsional interactions are the precursors for railway engineers to design and adopt FFU composite sleepers and bearers in practice where complex wheel/rail interface generally causes coupling torsional and vertical loading conditions.

Hydro-Thermal Coupled Behaviors in Free Zones and Matrix of Porous Media: Insights from a Micro-Continuum Transport Approach

Hydro-Thermal Coupled Behaviors in Free Zones and Matrix of Porous Media: Insights from a Micro-Continuum Transport Approach

Non-monotonic effect of differential stress and temperature on mechanical property and rockburst proneness of granite under high-temperature true triaxial compression

Complicated geological conditions such as high geo-stress and high ground temperatures often have a significant impact on the mechanical behavior and failure potential of hard rocks in deep engineering. This study aims to investigate the mechanical behaviors and rockburst proneness of granite under high differential stress and high temperatures in deep-buried high-temperature tunnels. A comprehensive experimental study was conducted on the coupling behavior of granite under high-temperature and high differential stress by true triaxial compression tests. The strength and failure mechanism of granite as well as their relationship with high temperature and high differential stress were revealed. The rockburst proneness of granite from a deep-buried high geothermal tunnel was assessed based on the rock's ultimate energy storage characteristics. It shows the strength, failure mechanisms, and rockburst proneness of granite, are significantly correlated to the granite high-temperature high-stress conditions. The temperatures extend the strengthening range of the intermediate principal stress on the true triaxial peak strength of the granite. With increasing temperature and differential stress, secondary vertical cracks develop quickly to induce the macroscopic failure of granite. Under high temperatures, the failure of granite changes from compressive-shear failure to tensile-shear failure at low differential stress. High temperature coupled with high differential stress strengthens approximately 1.14 times the rockburst proneness of granite. The results are important for the safe construction, and disaster assessment of deep-buried high geothermal tunnels.

Automatic shock excitation system for dynamic calibration of six-axis force/torque sensor

The coupling behavior between the six-axis force/torque (F/T) sensor and the mechanical environment introduces variations in the dynamic parameters obtained through different calibration methods and devices, which poses challenges in proposing dynamic performance criteria. This paper presents a comprehensive automatic calibration system for determining the dynamic characteristics of the six-axis F/T sensor. Impulse force generators (IFGs), positioned at various orientations, apply three mutually orthogonal directional force and torque components to the sensor using a cruciform artifact. The system ensures repeatable impulse excitation by maintaining consistent spring compression in the IFG, measured by the displacement control system's grating ruler. The pulse width and frequency response function (FRF) are determined based on the response signal without measuring the input signal. The calibration frequency and the impact force magnitude can be controlled by selecting appropriate system parameters. Compared to manual impulse hammers, IFGs exhibit superior features such as high bandwidth, repeatability, and controllable force amplitude. They provide high-quality impulse excitation with calibration frequencies and forces up to 30 kHz and 2500 N or even higher, respectively. Furthermore, a linear relationship between peak value of impulse excitation and spring compression is studied to ensure effective excitation application. The consistency of dynamic calibration results of the six-axis F/T sensor verifies the effectiveness of this automatic calibration system.

Heat transfer research on the cooling process of waxy crude oil storage in the vault tank based on VOF model

This paper focuses on the static cooling process for waxy crude oil stored in dome roof tanks. For the three phases of gas on top, liquid crude oil, and bottom water in storage tank, the VOF method is used to describe the evolution of physical quantities at the “oil–water”/“oil–gas” interface. The porous medium method is used to quantitatively characterize the sol–gel conversion process for waxy crude oil. A physical and mathematical models are established to describe the flow-heat transfer coupling behavior of the three-phase medium of crude oil, gas on top, and water at the bottom of the dome roof tank. In terms of the overall cooling process,The gas at the top of the tank has the simplest and fastest physical field evolution. It has the most uneven distribution (average temperature variance of 4 °C2), the strongest flow (average flow velocity of 0.4 m/s), the highest cooling rate (0.632 °C/h), and the lowest temperature (14.84 °C at the end). Its physical field is influenced by both the atmosphere and crude oil. The evolution of the physical field of crude oil is the most complex. It lags behind the gas at the top of tank and is directly effectted by it. Based on the evolution characteristics of the flow field of crude oil, the cooling process is divided into three stages: Stage I (0–––10 h) is the stage of convection generation and evolution in the crude oil region; Stage II (10 h − 34 h) is the stage of convection stability in the crude oil region; Stage III (after 35 h) is the stage of flow field transformation of crude oil. In stages I and II, the flow and momentum exchange at the oil–gas interface are significant. Crude oil is jointly influenced by the natural convection of the gas at the top of the tank and its own natural convection, forming a counterclockwise large vortex structure. The low-temperature area is near the central axis boundary of storage tank, oil–gas interface, and tank wall. The high-temperature area is within a range of 0.1 m − 3.3 m from the tank wall. After entering stage III, the flow and momentum exchange at the oil–gas interface weaken. The flow field of crude oil is only controlled by its own natural convection and transforms into a clockwise large vortex dominated. The low-temperature area is concentrated in the enclosed area of “oil–gas interface − tank wall” and “oil–water interface − tank wall”. The temperature field changes accordingly. Eventually, the high-temperature area is concentrated in the area slightly above the center of the tank. The physical field evolution of bottom water lags behind crude oil and is most unstable. Its cooling rate is 0.164 °C/h, slightly higher than crude oil’s 0.157 °C/h. The temperature is always slightly lower (33.47 °C at the end), and the physical field is the most uniform (average temperature variance of 0.0003 °C2), affected by the tank bottom environment and liquid crude oil.

A multi-level-variable correlated mechanistic model system for irradiation-induced multi-scale volume growths of U-10Mo/Zr dispersion nuclear fuels

Irradiation-induced volumetric deformations in dispersion nuclear fuels arouse a critical concern in nuclear fuel design. Utilizing the concepts from mesomechanics and homogenization, a multi-level-variable correlated mechanistic model system called the Dispersion Fuel Swelling Analysis Model System (DFSAMS) is developed for the irradiation-induced multi-scale volume growths of U-10Mo/Zr dispersion nuclear fuels. These models could directly correlate the macroscopic irradiation-induced volume growth strain with the dynamically varying multi-level information, including the obtained particle volume fractions, the current porosities of recrystallized zones of fuel grains, the macroscale porosities of fuel particles, the average numbers of fission gas atoms within fuel bubbles, the average bubble pressures and the macroscale pressures of fuel particles related to the macroscale hydrostatic pressures of dispersion fuels. The obtained theoretical results align favorably with finite element predictions and a diverse range of experimental data, demonstrating the effectiveness of the newly developed model system. It is indicated that: (1) the irradiation creep performance of the Zr matrix becomes the predominant factor influencing the macroscale volume growth deformations of U-10Mo/Zr dispersion fuels, due to the differed resistance to volumetric deformations of U-10Mo particles; (2) the as-fabricated bubbles of fuel particles will gradually decrease in size under the macroscale hydrostatic pressures due to the irradiation creep deformations occurring in the surrounding solid skeleton, contributing negatively to the macroscale volumetric expansion of U-10Mo/Zr dispersion fuels, especially in cases with higher initial porosity. The important theoretical models are supplied here for efficient numerical simulation of the irradiation-induced thermal-mechanical coupling behaviors in U-10Mo/Zr dispersion fuel elements.

Ferrimagnetic half metals TaMnZ (Z = As, Sb, Bi) for thermoelectric and spintronic applications – Material computations

Half metals possess coupling behavior of metals and semiconductors with wide heat transport and spin transport properties. This research article covers the structural, mechanical, electronic, magnetic and thermoelectric properties of the half Heusler alloys TaMnZ (Z = As, Sb, Bi). The equilibrium lattice constants and corresponding ground state energies show that the studied alloys are stable in the ferrimagnetic cubic phase. The band dispersion plots suggest that the compounds TaMnAs, TaMnSb and TaMnBi are half metals with indirect band gap having the band gap energies of 1.13 eV, 1.24 eV and 1.12 eV respectively in the spin down channel. As the materials have 100 % spin polarization with an integer magnetic moment of −1 μB, they are suitable for making spintronic devices such as spin transistors and spin-flip flops. The temperature-dependent thermoelectric properties of the alloys have been studied by classical Boltzmann theory. The materials have low lattice thermal conductivity which was confirmed by Slack’s equation. The obtained thermoelectric figure of merit for p-type TaMnAs, TaMnSb and TaMnBi is 0.7, 0.6 and 0.8 respectively at 1200 K. Similarly, the figure of merit obtained for n-type TaMnAs, TaMnSb and TaMnBi is 0.6, 0.64 and 0.8 respectively at the same temperature. The favourable heat and spin transport properties of these alloys show that they are the potential characters to figure out better thermoelectric and spintronic performance.

Direct Detection of the Magnetic Force and Field Coupling of Electronic Spins Using Photoinduced Magnetic Force Microscopy.

The intrinsic spin of the electron and its associated magnetic moment can provide insights into spintronics. However, the interaction is extremely weak, as is the case with the coupling between an electron's spin and a magnetic field, and it poses significant experimental challenges. Here we demonstrate the direct measurement of polarized single NV- centers and their spin-spin coupling behaviors in diamond. By using photoinduced magnetic force microscopy, we obtain the extremely weak magnetic force coupling originating from the electron spin. The polarized spin state of NV- centers, transitioning from |0⟩ to |±1⟩, and their corresponding Zeeman effect can be characterized through their interaction with a magnetic tip. The result presents an advancement in achieving electron spin measurements by magnetic force, avoiding the need for manufacturing conductive substrates. This facilitates a better understanding and control of electron spin to novel electronic states for future quantum technologies.

Numerical tests on dynamic response of pile-supported reclaimed embankment for high-speed railway in saturated soft ground using soil–water coupling elastoplastic FEM

High-speed train (HST) running in the saturated soft ground induces significant vibration that may threaten the running safety and serviceability of high-speed railway (HSR). Extensive studies have been conducted on the dynamic responses of HSR, yet, the soil–water coupling and plastic behavior in the saturated soft ground are rarely considered, and thus the build-up of excess pore water pressure (EPWP) and displacement cannot be accurately calculated. In this study, 2D soil–water coupling elastoplastic FEM was employed to investigate HST induced vibration in the pile-supported embankment using FE code called DBLEAVES. Dynamic soil stress, EPWP, acceleration and displacement under different cases were numerically analyzed in detail. Numerical tests confirm that liquid phase in soft ground plays important influence on the dynamic responses that vertical acceleration and displacement will be overestimated while the horizontal acceleration and displacement as well as EPWP will be underestimated if soil–water coupling is not considered. Single-phase analysis also exaggerates the acceleration attenuation and underestimate the vibration amplification in soft ground. The existence of piles can induce significant soil arching effect in the embankment, the distributions of vertical acceleration and EPWP are partitioned sharply by the piles while vertical displacement in soft ground becomes more uniform along the depth direction within the pile reinforced area. The existence of piles also induces stronger vibration beneath the pile end so that larger EPWP is generated below the pile end than around the pile body. The main influence area due to HST vibration for pile-supported embankment is overall 20 m away from the centerline of HSR track, therefore, it is reasonable to improve the ground by properly increasing the number of pile within this area. When the number of pile is determined, increasing the length of pile or reducing the pile spacing are two effective ways to mitigate the dynamic response.

Energy harvesting from transverse galloping using a two-degree-of-freedom flow energy harvester

Abstract A two degree-of-freedom (2-DOF) galloping piezoelectric energy harvesting system where both oscillators are excited by the incoming flow is studied in this paper. A coupled lumped-parameter model is developed to simulate the electro-fluid-structural coupling behaviour assuming a quasi-steady aerodynamic flow field. The differential equations governing the dynamics of the lumped system are converted into nonlinear algebraic equations employing the harmonic balance method (HBM) and then solved using Newton’s method. The approximate analytical solutions are compared to the solutions obtained by numerical integration, and the results agree, both qualitatively and quantitatively. The solutions were subsequently used to investigate the effects of the bluff body dimension, mechanical, electrical, aerodynamic, and electromechanical parameters on the performance of the harvester and to illustrate how to optimise some of these parameters to reduce the cut-in wind speed and maximise the power output of the energy harvester. It will be shown that the energy harvesting performance could be significantly improved by introducing piezoelectric transducers on both oscillators and including both masses in the incoming flow. A comparative study between the proposed 2-DOF flow energy harvesting system, a single-degree-of-freedom (SDOF) galloping piezoelectric energy harvester (GPEH), and other configurations of 2-DOF GPEH shows that the present 2-DOF GPEH generates the largest power peak.

Analytical model of curvic coupling and application in nonlinear vibration analysis of a squeeze film damper - rolling bearing - rotor system

The curvic coupling has been extensively employed in the rotor system of aero-engine. Effects of the radical slip of the teeth and damping are usually neglected in the traditional models of the curvic coupling. Additionally, there are only a few researches on the vibration characteristics of the rotor system with curvic coupling, squeeze film damper (SFD) and rolling bearing. In this paper, an analytical model of the curvic coupling is proposed. The nonlinear vibration analysis of a SFD - rolling bearing - rotor system with curvic coupling is furtherly carried out. The Jenkins element is adopted to simulate the dynamic behaviors of the curvic coupling in the model. The hysteresis curves of the analytical model show good agreement with the results of the three-dimensional (3D) finite element (FE) simulation. After that, the dynamic equation of a SFD - rolling bearing - rotor system with curvic coupling is formulated. Subsequently, detailed parametric analyses, including preload, number of teeth and pressure angle, are conducted to investigate the vibration characteristics of the rotor system. Results show that the curvic coupling mainly produces stiffness loss and damping at the interface of the curvic coupling. The motion stability of the rotor system can be enhanced by increasing the preload, number of teeth at multiple curvic couplings and pressure angle. Moreover, the vibration level of the rotor system initially decreases and then increases as the number of the teeth and pressure angle increase. Finally, the numerical results are validated to be reasonable by an experimental study.

Activated carbon-mediated arsenopyrite oxidation and arsenic immobilization: ROS formation and its role

The oxidative dissolution of arsenopyrite (FeAsS) is a significant source of arsenic contamination in nature. Activated biochar (AC), a widely used environmental remediation agent, is prevalent in ecosystems and participated in various geochemical processes of arsenic and iron-containing sulfide minerals. However, the impact of AC-arsenopyrite association on reactive oxidation species (ROS) generation and its contribution to As transformation were rarely explored. Here, ROS formation and the redox conversion of As during the interaction between AC and arsenopyrite were investigated. AC-mediated arsenopyrite oxidation was a two-stage process. At stage I, the heterogeneous electron transfer from arsenopyrite facilitated O2 reduction on AC, enhancing arsenopyrite dissolution and ROS formation. TBA, PBQ and catalase inhibited 86.40 %, 79.39 % and 49.66 % of As(III) oxidation, respectively, indicating indicated that HO˙, (O2•)- and H2O2 were responsible for As(III) oxidation. However, at stage II, the mobility of As was highly restricted, especially increasing AC addition. Besides adsorption, AC retained appreciable As through catalyzing insoluble ferric arsenate formation and growth by promoting Fe(II) and As(III) oxidation and functioning as nuclei. These findings deepen our understanding of the coupling behavior of AC-arsenopyrite and its influence on geochemical cycling of arsenic in mined surroundings, which has important implications for mitigating arsenic pollution.