Bed Of Glass Beads Research Articles

Hydrate formation from liquid CO2 in a glass beads bed

CO 2 sequestration in marine sediments as solid hydrates is a potential way to capture and store anthropogenic CO 2 . In this study, hydrate formation from liquid CO 2 in marine sediments was simulated in a glass beads bed, and the factors affecting the kinetics of hydrate formation were investigated. The results indicated that the rapid initial hydrate formation with a high driving force always increases the mass transfer resistance, which slows down hydrate growth. The final ratio of water conversion is higher under conditions of low temperature and higher pressure. A smaller particle size is conductive to initial CO 2 hydrate growth, but the water conversion ratio in a bed with larger particles is slightly higher. Compared with other factors, the change in water saturation has an obvious effect on the final water conversion. To inhibit the initial hydrate formation during the injection process, in this paper, a kinetic inhibitor is proposed for pre-injection into marine sediments. This work shows that at a low pressure, a low-concentration inhibitor has an obvious inhibition effect on hydrate growth. However, at a high pressure, it is necessary to increase the concentration of inhibitor to produce an obvious inhibition effect.

Rheological effects of a gas fluidized bed emulsion on falling and rising spheres

To enable the mechanistic description of the mixing of larger particles in gas-fluidized beds in models (e.g. fuel particles in combustors), knowledge about the rheology of the bed emulsion is required. Here, it is crucial to determine the drag on large fuel-alike particles.This work presents the experimental work on the fate of 13 different solid spheres falling or rising through a bed of air and glass beads at minimum fluidization. The trajectories of the tracer are highly resolved (sampling rate of 200 Hz) by means of magnetic particle tracking, this previously unmet accuracy allows disclosing the complex rheological behavior of gas-solids fluidized bed emulsions in terms of drag on immersed objects. The trajectories reveal that none of the tracers reach terminal velocity during their fall and rise through the bed. The shear stress is obtained through the drag force by solving the equation of motion for the tracer. The data reveal particularities of the bed rheology and clear differences of its effect on rising and falling particles. When studying the shear stress over the characteristic shear rate of each tracer, it can be seen that the stress of the bed on the tracers is dominated by a yield stress, with a somewhat smaller contribution of the shear stress. For rising tracers this last contribution is almost negligible.The falling tracers show strong interaction with the bed emulsion, resulting in a fluctuating shear stress, which increases with tracer size and density. The stagnation of some tracers at low shear rates reveals a viscoplastic behavior of the bed emulsion, exhibiting a typical yield stress that showing a clear dependence on the tracer diameter and buoyant density. The concept of yield gravity is used in order to introduce a normalized shear stress which provides additional verification of the experimental observations in relation to the influence of tracer size and relative density on the shear stress.

Velocity characterization of solids in binary fluidized beds

Owing to challenges in velocimetry techniques, flow hydrodynamics of binary fluidized beds have remained largely unexplored. Thus, the present study seeks to address unraveling the velocity distributions in the binary fluidized bed of glass beads (0.5 and 2 mm) in fluidized with 10, 30, and 40% of coarser fractions. In order to decipher the velocity distributions, RPT was implemented, which yielded velocity distributions of both the 0.5 and 2 mm fractions. Distinct features of solids flow were observed with varying bed compositions. The mean velocity of finer flotsam (0.5 mm particles) fractions were found to diminish upon increasing the jetsam fraction (2 mm) due to variation in bed voidage. On the contrary, an enhanced coarser fraction of 2 mm particles in the bed diminished solids’ fluctuation, which led to a corresponding reduction in the RMS velocities. Similar trends were also noted when solids’ diffusivity was estimated for various bed compositions. Finally, the efficacy of this technique was independently verified qualitatively through mixing patterns obtained from ‘bed freezing’.

Kinetic Modeling of Gas Phase Sugar Cracking to Glycolaldehyde and Other Oxygenates

Sugars can be cracked in a fluidized bed of glass beads to glycolaldehyde and various other oxygenate products that are valuable molecules on their own or as platform molecules for conversion into ...

Charge transfer and bipolar charging of particles in a bubbling fluidized bed

Particle–particle and particle–wall collisions in gas–solid fluidized beds lead to charge accumulation on particles. This work evaluated the effect of fluidization time on charge transfer and bipolar charging (charge separation) and their influence on hydrodynamic structures in a fluidized bed. Experiments were performed with glass beads and polyethylene particles in a glass column. The pressure fluctuations and net electrostatic charge of particles were measured during fluidization. Wavelet and short-time Fourier transforms were used to analyze pressure fluctuations. The results revealed that bipolar charging is the dominant tribocharging mechanism in a bed of glass beads. Bipolar charging in a bed of particles with a narrow size distribution does not affect either hydrodynamic structures or the transition velocity to the turbulent regime. A large difference between the work functions of the wall and particle in the bed of polyethylene particles leads to high charge transfer. Formation of a stagnant particle layer on the wall eventually causes the energy of macro-structures to increase to its maximum. At longer fluidization times, the macro-structural energy decreases and bubbles shrink until the electrostatic charge reaches the equilibrium level. These results well describe the effect of fluidization time on hydrodynamic structures.

Thermal Cracking of Sugars for the Production of Glycolaldehyde and Other Small Oxygenates.

Thermal cracking of sugars for production of glycolaldehyde, a potential renewable platform molecule, in yields up to 74 % with up to 95 % carbon recovered in the condensed product is demonstrated using glucose as the feed. The process involves spraying an aqueous sugar solution into a fluidized bed of glass beads. Continuous operation is carried out for more than 90 h with complete conversion and stable product selectivity. Besides glycolaldehyde, the other identified condensed products are pyruvaldehyde (9 %), formaldehyde (7 %), glyoxal (2 %), acetol (2 %), and acetic acid (1 %). The effects of temperature, glucose feed concentration, and type of sugar feedstock are investigated. Cracking the monosaccharides fructose and xylose leads to very different product distributions from glucose, but similar carbon recovery. A reaction network in agreement with the main observed products from cracking of monosaccharide sugars is proposed.

Bedforms Produced on a Particle Bed by Vertical Oscillations of a Plate.

We describe a new mechanism that produces bedforms and characterize the conditions under which it operates. The mechanism is associated with pressure gradients generated in a fluid saturated particle bed by a plate oscillating in the water above it. These vertical pressure gradients cause oscillatory bed failure. This facilitates particle displacement in its interior and transport at and near its surface that contribute to the formation of a heap under the plate. Flows over erodible beds generally cause shear stresses on the bed and these induce bed failure. Failure driven by pressure gradients is different from this. We report on bedforms in a bed of glass beads associated with such fluctuating pressure gradients. We measure the development of the profiles of heaps as a function of time and determine the tangential and normal motion of areas on the beds surface and estimate the depth of penetration of the tangential transport. The measurements compare favorably with a simple model that describes the onset of failure due to oscillations in pressure.

Frictional hysteresis and particle deposition in granular free-surface flows

Shallow granular avalanches on slopes close to repose exhibit hysteretic behaviour. For instance, when a steady-uniform granular flow is brought to rest it leaves a deposit of thickness $h_{stop}(\unicode[STIX]{x1D701})$ on a rough slope inclined at an angle $\unicode[STIX]{x1D701}$ to the horizontal. However, this layer will not spontaneously start to flow again until it is inclined to a higher angle $\unicode[STIX]{x1D701}_{start}$, or the thickness is increased to $h_{start}(\unicode[STIX]{x1D701})>h_{stop}(\unicode[STIX]{x1D701})$. This simple phenomenology leads to a rich variety of flows with co-existing regions of solid-like and fluid-like granular behaviour that evolve in space and time. In particular, frictional hysteresis is directly responsible for the spontaneous formation of self-channelized flows with static levees, retrogressive failures as well as erosion–deposition waves that travel through the material. This paper is motivated by the experimental observation that a travelling-wave develops, when a steady uniform flow of carborundum particles on a bed of larger glass beads, runs out to leave a deposit that is approximately equal to $h_{stop}$. Numerical simulations using the friction law originally proposed by Edwards et al. (J. Fluid Mech., vol. 823, 2017, pp. 278–315) and modified here, demonstrate that there are in fact two travelling waves. One that marks the trailing edge of the steady-uniform flow and another that rapidly deposits the particles, directly connecting the point of minimum dynamic friction (at thickness $h_{\ast }$) with the deposited layer. The first wave moves slightly faster than the second wave, and so there is a slowly expanding region between them in which the flow thins and the particles slow down. An exact inviscid solution for the second travelling wave is derived and it is shown that for a steady-uniform flow of thickness $h_{\ast }$ it produces a deposit close to $h_{stop}$ for all inclination angles. Numerical simulations show that the two-wave structure deposits layers that are approximately equal to $h_{stop}$ for all initial thicknesses. This insensitivity to the initial conditions implies that $h_{stop}$ is a universal quantity, at least for carborundum particles on a bed of larger glass beads. Numerical simulations are therefore able to capture the complete experimental staircase procedure, which is commonly used to determine the $h_{stop}$ and $h_{start}$ curves by progressively increasing the inclination of the chute. In general, however, the deposit thickness may depend on the depth of the flowing layer that generated it, so the most robust way to determine $h_{stop}$ is to measure the deposit thickness from a flow that was moving at the minimum steady-uniform velocity. Finally, some of the pathologies in earlier non-monotonic friction laws are discussed and it is explicitly shown that with these models either steadily travelling deposition waves do not form or they do not leave the correct deposit depth $h_{stop}$.

Time-lapse imaging of particle invasion and deposition in porous media using in situ X-ray radiography

Abstract This paper introduces time-lapse radiography as an in situ technique to image and quantify changes in the internal structure of a porous medium with sub-second temporal resolution. To demonstrate the technique's potential, an experiment was performed using a model system involving flow of a suspension containing ground marble particles through a porous bed of compacted glass beads housed within a pressurized flow rig. During the experiment, particle deposition occurred both within the internal porous structure and on its surface (forming a filter cake). The volume of particles deposited was derived from changes in the grey scale of the radiographs. At the initial stages of the experiment, the volume of particles deposited internally was seen to increase linearly with time. The subsequent growth and compaction of an external filter cake decreased the rate of internal particle deposition. The filter cake's structure was observed to fail owing to increasing stress at higher pressures. The demonstrative experiment illustrates the potential of time-lapse radiography as a new tool to elucidate mechanisms underpinning formation damage, and to optimise drilling fluids and enhanced oil recovery (EOR). A critical assessment of the technique's advantages and limitations to characterise particulate behaviour within porous media is included.

Screw‐generated forces in granular media: Experimental, computational, and analytical comparison

This study presents an experimental, computational, and analytical comparison of a submerged, double‐helix Archimedes screw generating propulsive force against a bed of glass beads. Three screws of different pitch lengths were studied. Each screw was tested at six speeds in approximately 10 trials for a total of 180 experimental trials. These experiments were then replicated in EDEM, a discrete element method (DEM) software program. DEM simulation results for thrust forces in the 30–120 rpm regime had a 5%–20% inflation of forces compared to experimental results. These simulations were then compared with resistive force theory (RFT) plate approximation of the screw geometries. We analyze a superposition‐based partition approach to the full‐length screws as well as force generation in shortened, one‐ and two‐blade screws. We find that the force generation is dependent on the flow patterns and cannot be reduced to partitioned approximations as with simple intruders. © 2018 American Institute of Chemical Engineers AIChE J, 65: 894–903, 2019

Autofluidization of collapsing bed of fine particles: Implications for the emplacement of pyroclastic flows

Long runout distances of fines-rich pyroclastic flows may be partly attributed to high gas pore pressure that reduces interparticle friction. Here we examine the generation of pore pressure caused by collapse of granular materials into ambient air, which may occur at the impact zone of a fountain collapse or when pyroclastic flows bypass topographic breaks or propagate over a rough substrate. We carried out laboratory experiments, which consisted of collapse of beds of glass beads in a vertical column where pressure sensors measured the air pore pressure at different levels. The collapse height, the bed thickness and temperature as well as the particle size were systematically changed. Measurements revealed a first overpressure phase, both at different heights in the initial bed and at column base, when the particles began to fall and forced the air beneath to ascend through the bed. Even at low collapse height of 20 cm, the maximum pore pressure compensated almost completely the bed lithostatic pressure provided the particle size was <337 μm, meaning that the material was fully fluidized. Particles then accumulated at column base and formed and aggrading deposit, in which a second peak of overpressure was measured before pore pressure diffused slowly. The overpressure was high when the particles were small enough (<100–200 μm) but it was poorly developed or even absent when the particle size was increased. The duration of pressure diffusion at end of this second phase increased with the square of the thickness of the aggrading deposit and decreased strongly with increasing particle size. Additional experiments with ignimbrite material showed similar behavior but with a much longer duration of final pressure diffusion. At high temperature (up to 200 °C), overpressure during the first phase could overpass the bed lithostatic pressure. This suggested thermal pressurization of the ambient cold air, which expanded rapidly when percolating through the hot material. We conclude that fluidization of hot fines-rich pyroclastic flows can be easily achieved when the granular material collapses into the ambient air.

Investigating wall-to-bed heat transfer in view of a continuous temperature swing adsorption process

Heat transfer between bubbling fluidized beds and immersed heat exchanger surfaces is studied in view of continuously operated temperature swing adsorption processes for post-combustion CO2 capture. A novel heat transfer measurement test device was used to measure wall-to-bed heat transfer coefficients. The present work focuses on the comparison of experimentally obtained and calculated heat transfer coefficients. Heat transfer at horizontal single tubes and tube bundles immersed in fluidized particle beds of glass beads with 140μm and 200μm in Sauter mean diameter is investigated. It is shown that the experimental results for single tubes are in mediocre agreement to established mathematical models, such as the ones proposed by Natusch et al. (1975) and Molerus et al. (1995), and that heat transfer is significantly influenced by the tube diameter. The model by Petrie et al. (1968) was considered to take the effect of the tube diameter into account, which lead to promising results. Furthermore, measured heat transfer coefficients at tube bundles of different geometries are compared to predictions using the models by Natusch et al. (1975) and Lechner et al. (2013). Some of the tube bundle reduction factors predicted by the model by Lechner et al. (2013) are larger than one, which stands in contrast to the finding that the highest heat transfer coefficients occur at single tubes. However, both models lead to adequate results when calculating heat transfer coefficients for different tube bundle geometries.

On the use of a powder rheometer to characterize the powder flowability at low consolidation with torque resistances

The Anton Paar Powder Cell was used to measure the torque necessary to rotate an impeller in beds of glass beads, sand and alumina powders aerated between no aeration to the minimum for fluidization. Measured torque values depend on the material tested, on the air flow rate applied, on the impeller depth and on the height of the impeller blade. The effect of the impeller depth is linear for low impeller depth and is less than linear at high depth values. A model was developed for the interpretation of the experimental results based on the idea that the material is shearing on the surface described by the impeller rotation. The model allows to estimate an effectiveness of the impeller in the torque determination and also to predict the torque for the impeller at the at deepest positions at which the wall effects have to be considered. © 2017 American Institute of Chemical Engineers AIChE J, 2017

Pattern transition, microstructure, and dynamics in a two-dimensional vibrofluidized granular bed.

Experiments are conducted in a two-dimensional monolayer vibrofluidized bed of glass beads, with a goal to understand the transition scenario and the underlying microstructure and dynamics in different patterned states. At small shaking accelerations (Γ=Aω^{2}/g<1, where A and ω=2πf are the amplitude and angular frequency of shaking and g is the gravitational acceleration), the particles remain attached to the base of the vibrating container; this is known as the solid bed (SB). With increasing Γ (at large enough shaking amplitude A/d) and/or with increasing A/d (at large enough Γ), the sequence of transitions/bifurcations unfolds as follows: SB ("solid bed") to BB ("bouncing bed") to LS ("Leidenfrost state") to "2-roll convection" to "1-roll convection" and finally to a gas-like state. For a given length of the container, the coarsening of multiple convection rolls leading to the genesis of a "single-roll" structure (dubbed the multiroll transition) and its subsequent transition to a granular gas are two findings of this work. We show that the critical shaking intensity (Γ_{BB}^{LS}) for the BB→LS transition has a power-law dependence on the particle loading (F=h_{0}/d, where h_{0} is the number of particle layers at rest and d is the particle diameter) and the shaking amplitude (A/d). The characteristics of BB and LS states are studied by calculating (i) the coarse-grained density and temperature profiles and (ii) the pair correlation function. It is shown that while the contact network of particles in the BB state represents a hexagonal-packed structure, the contact network within the "floating cluster" of the LS resembles a liquid-like state. An unsteadiness of the Leidenfrost state has been uncovered wherein the interface (between the floating cluster and the dilute collisional layer underneath) and the top of the bed are found to oscillate sinusoidally, with the oscillation frequency closely matching the frequency of external shaking. Therefore, the granular Leidenfrost state is a period-1 wave as is the case for the BB state.

A gently aerated bed of glass beads sorts objects by density

A gently aerated bed of glass beads sorts objects by density

Preparation of stable food-grade double emulsions with a hybrid premix membrane emulsification system

In this study we demonstrate that food-grade double emulsions can be successfully prepared using a hybrid premix emulsification system. A coarse emulsion containing beetroot juice as inner water phase, sunflower oil as oil phase and 0.5% or 1.0% whey protein isolate solution as outer water phase was prepared using a rotor stator system. This emulsion was further refined, using a bed of glass beads (diameter 71μm), through which the emulsion was pushed at different applied pressure (200–500kPa) and number of passes (1–5). All applied pressures lead to much smaller droplets while the juice remained encapsulated (>98%). The viscosity of the emulsions increased due to swelling of the internal water phase, and this implies that it is possible to encapsulate the components efficiently at relatively low internal water phase fraction at which the emulsions can be handled easily, while allowing them to obtain their final viscosity later.

A gently aerated bed of glass beads sorts objects by density

A gently aerated bed of glass beads sorts objects by density

Nanoparticle diffusion in crowded and confined media.

We identify distinct mechanisms controlling slowing of nanoparticle diffusion through complex media featuring both rigid geometrical confinement and soft mobile crowders. Towards this end, we use confocal microscopy and single particle tracking to probe the diffusion of 400 nm nanoparticles suspended in Newtonian water, in a Newtonian glycerol/water mixture, or in a non-Newtonian polymer solution through a model porous medium, a packed bed of microscale glass beads. The mobility of nanoparticles, as quantified by the long-time diffusion coefficient extracted from the particle mean-squared displacement, slows as the average pore size of the packed bed media decreases for both Newtonian and non-Newtonian solutions. The distribution of particle displacements is non-Gaussian, consistent with the spatial heterogeneity of the geometrical confinement imposed by the packed bed. The slowing of nanoparticle mobility in all solutions follows the predictions of models that describe hydrodynamic interactions with the packed bed. In non-Newtonian solutions, depletion interactions due to the polymers near the glass beads result in temporary adsorption of particles onto the bead surface, as indicated by a stretched-exponential distribution of residence times. Our results therefore suggest that the confined diffusive dynamics of nanoparticles in polymer solutions is controlled by two competing mechanisms: hydrodynamic interactions between particles and spatial obstacles, which dictate the long-time slowing of diffusion, and depletion interactions between particles and confining walls due to the macromolecules, which control transient adsorption and hence alter the statistics of the short-time motion.

An experimental procedure to estimate tube erosion rates in bubbling fluidised beds

We studied the erosion rate of a horizontal plaster tube in a cold-model bubbling fluidised bed of 510μm glass beads at different fluidisation velocities and at ambient pressure and temperature. To this end, we developed a new experimental procedure based on the cyclic immersion of a cylindrical probe in a bed kept at incipient fluidisation (U=1.03 Umf) and we compared the obtained results with those achieved during experiments with the same probe immersed at a fixed position inside the fluidised bed operated in bubbling regime. The new procedure was meant to simulate the impact of the bubbles wake with the probe, providing a simplified physical model for erosion in the bed. We also interpreted the experimental results in light of existing models to describe the overall erosion rate. The analysis of data indicated a clear correlation among surface erosion and bubble wake dynamics. Besides, the new procedure provided a way to address the angular profile of tube erosion caused by the exposure to the wake of a single rising bubble. Once multiplied by the product between bubble frequency and wake length, these data allow reconstructing the angular erosion rate profiles in the range of the fluidisation velocity investigated. This result finds confirmation in the analysis of the pertinent literature concerning the drag coefficients of a horizontal tube immersed in dense and dilute granular flows.

Monitoring Electrostatics and Hydrodynamics in Gas–Solid Bubbling Fluidized Beds Using Novel Electrostatic Probes

The ability of recently developed novel electrostatic probes to monitor particle charge density and hydrodynamics in freely bubbling two- and three-dimensional fluidized beds of glass beads and polyethylene particles is demonstrated. Particle charge density and bubble properties in the beds were altered by abruptly changing superficial gas velocity or by impulsively adding antistatic agent to the bed. The probes were then utilized to quantitatively monitor the particle charge density and bubble rise velocity. The current signals from the probes responded quickly and significantly to abrupt changes in the superficial gas velocity. By analyzing time-series signals from the probes, the particle charge density and the bubble rise velocity deduced from the probes were found to be of similar order of magnitudes and changed consistently with those obtained from Faraday cup and video measurements. Charge densities from the Faraday cup decreased when an antistatic agent was added, as registered by the probe.