In certain extreme environments, the bearing capacity of concrete structures diminishes significantly as temperatures soar, simultaneously exposing them to a heightened risk of brittle cracking. The paper aims to elucidate the fracture toughness of waterborne polyurethane modified concrete (WPMC) at different temperatures. Furthermore, a predictive model for the fracture toughness of WPMC, which incorporates both temperature and the waterborne polyurethane (WP) content, is proposed. The flexural strength and fracture toughness of WPMC were tested separately at 20℃, 40℃, 60℃, and 80℃. Utilizing digital image correlation (DIC) technology, the bottom longitudinal strain of WPMC under flexural loading was analyzed. The impact of temperature and WP content on the energy absorption capacity and deformation behavior of WPMC exposed to extreme environment was also investigated. By introducing the microstructural parameters C and Cw to characterize the elastic and plastic deformations of WPMC before and after cracking, a fitting model between the microstructural parameters and temperature, WP content was established. This model enables the prediction of the fracture toughness KIC of WPMC at different temperatures by measuring Fmax.
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