Beam-averaged Column Densities Research Articles

Astronomical CH3+ rovibrational assignments

Context. The methyl cation (CH3+) has recently been discovered in the interstellar medium through the detection of 7 μm (1400 cm−1) features toward the d203-506 protoplanetary disk by the JWST. Line-by-line spectroscopic assignments of these features, however, were unsuccessful due to complex intramolecular perturbations preventing a determination of the excitation and abundance of the species in that source. Aims. Comprehensive rovibrational assignments guided by theoretical and experimental laboratory techniques provide insight into the excitation mechanisms and chemistry of CH3+ in d203-506. Methods. The rovibrational structure of CH3+ was studied theoretically by a combination of coupled-cluster electronic structure theory and (quasi-)variational nuclear motion calculations. Two experimental techniques were used to confirm the rovibrational structure of CH3+:(1) infrared leak-out spectroscopy of the methyl cation, and (2) rotationally resolved photoelectron spectroscopy of the methyl radical (CH3). In (1), CH3+ ions, produced by the electron impact dissociative ionization of methane, were injected into a 22-pole ion trap where they were probed by the pulses of infrared radiation from the FELIX free electron laser. In (2), neutral CH3, produced by CH3NO2 pyrolysis in a molecular beam, was probed by pulsed-field ionization zero-kinetic-energy photoelectron spectroscopy. Results. The quantum chemical calculations performed in this study have enabled a comprehensive spectroscopic assignment of the v2+ and v4+ bands of CH3+ detected by the JWST. The resulting spectroscopic constants and derived Einstein A coefficients fully reproduce both the infrared and photoelectron spectra and permit the rotational temperature of CH3+ (T = 660 ± 80 K) in d203-506 to be derived. A beam-averaged column density of CH3+ in this protoplanetary disk is also estimated.

First extragalactic detection of a phosphorus-bearing molecule with ALCHEMI: Phosphorus nitride (PN)

Context. Phosphorus (P) is a crucial element for life given its central role in several biomolecules. P-bearing molecules have been discovered in different regions of the Milky Way, but not yet towards an extragalactic environment. Aims. We searched for P-bearing molecules outside the Milky Way towards the nearby starburst Galaxy NGC 253. Methods. Using observations from the ALMA Comprehensive High-resolution Extragalactic Molecular Inventory (ALCHEMI) project, we used the MAdrid Data CUBe Analysis package to model the emission of P-bearing molecules assuming local thermodynamic equilibrium (LTE) conditions. We also performed a non-LTE analysis using SpectralRadex. Results. We report the detection of a P-bearing molecule, phosphorus nitride (PN), for the first time in an extragalactic environment, towards two giant molecular clouds (GMCs) of NGC 253. The LTE analysis yields total PN beam-averaged column densities N = (1.20 ± 0.09) × 1013 cm−2 and N = (6.5 ± 1.6) × 1012 cm−2, which translate into abundances with respect to H2 of χ = (8.0 ± 1.0) × 10−12 and χ = (4.4 ± 1.2) × 10−12. We derived a low excitation temperature of Tex = (4.4 ± 1.3) K towards the GMC with the brightest PN emission, which indicates that PN is sub-thermally excited. The non-LTE analysis results in column densities consistent with the LTE values. We also searched for other P-bearing molecules (PO, PH3, CP, and CCP), and upper limits were derived. The derived PO/PN ratios are < 1.3 and < 1.7. The abundance ratio between PN and the shock-tracer SiO derived towards NGC 253 follows the same trend previously found towards Galactic sources. Conclusions. Comparison of the observations with chemical models indicates that the derived molecular abundances of PN in NGC 253 can be explained by shock-driven chemistry followed by cosmic-ray-driven photochemistry.

Detection of OH 18 cm Emission from Comet C/2020 F3 NEOWISE Using the Arecibo Telescope

Abstract We report the detection of emission from the OH 18 cm Λ-doublet transitions toward Comet C/2020 F3 NEOWISE using the Arecibo Telescope. The antenna temperatures are 113 ± 3 mK for the 1667 MHz line and 57 ± 3 mK for the 1665 MHz line. The beam-averaged OH column density (centered on the comet nucleus) derived from the 1667 transition is N OH = (1.11 ± 0.06) × 1013 cm−2. We implemented the Haser model to derive an OH production rate. The estimated OH production rate using the 1667 transition is Q OH = (3.6 ± 0.6) × 1028 s−1, a factor of 2.4 lower than optically derived values for the same observing day, the difference of which is likely explained by quenching.

First detection of doubly deuterated methyl acetylene (CHD2CCH and CH2DCCD)★.

We report the first detection in space of the two doubly deuterated isotopologues of methyl acetylene. The species CHD2CCH and CH2DCCD were identified in the dense core L483 through nine and eight, respectively, rotational lines in the 72-116 GHz range using the IRAM 30m telescope. The astronomical frequencies observed here were combined with laboratory frequencies from the literature measured in the 29-47 GHz range to derive more accurate spectroscopic parameters for the two isotopologues. We derive beam-averaged column densities of (2.7 ± 0.5) × 1012 cm-2 for CHD2CCH and (2.2 ± 0.4) × 1012 cm-2 for CH2DCCD, which translate to abundance ratios CH3CCH/CHD2CCH = 34 ± 10 and CH3CCH/CH2DCCD = 42 ± 13. The doubly deuterated isotopologues of methyl acetylene are only a few times less abundant than the singly deuterated ones, concretely around 2.4 times less abundant than CH3CCD. The abundances of the different deuterated isotopologues with respect to CH3CCH are reasonably accounted for by a gas-phase chemical model in which deuteration occurs from the precursor ions C3H6D+ and C3H5D+, when the ortho-to-para ratio of molecular hydrogen is sufficiently low. This points to gas-phase chemical reactions, rather than grain-surface processes, as responsible for the formation and deuterium fractionation of CH3CCH in L483. The abundance ratios CH2DCCH/CH3CCD = 3.0 ± 0.9 and CHD2CCH/CH2DCCD = 1.25 ± 0.37 observed in L483 are consistent with the statistically expected values of three and one, respectively, with the slight overabundance of CHD2CCH compared to CH2DCCD being well explained by the chemical model.

Central molecular zones in galaxies:12CO-to-13CO ratios, carbon budget, andXfactors

We present ground-based measurements of 126 nearby galaxy centers in12CO and 92 in13CO in various low-Jtransitions. More than 60 galaxies were measured in at least four lines. The average relative intensities of the first fourJ12CO transitions are 1.00:0.92:0.70:0.57. In the first threeJtransitions, the average12CO-to-13CO intensity ratios are 13.0, 11.6, and 12.8, with individual values in any transition ranging from 5 to 25. The sizes of central CO concentrations are well defined in maps, but poorly determined by multi-aperture photometry. On average, theJ = 1−012CO fluxes increase linearly with the size of the observing beam. CO emission covers only a quarter of the HI galaxy disks. Using radiative transfer models (RADEX), we derived model gas parameters. The assumed carbon elemental abundances and carbon gas depletion onto dust are the main causes of uncertainty. The new CO data and published [CI] and [CII] data imply that CO, C°, and C+each represent about one-third of the gas-phase carbon in the molecular interstellar medium. The mean beam-averaged molecular hydrogen column density isN(H2) = (1.5 ± 0.2)×1021cm−2. Galaxy center CO-to-H2conversion factors are typically ten times lower than the “standard” Milky WayX°disk value, with a meanX(CO) = (1.9 ± 0.2)×1019cm−2/K km s−1and a dispersion 1.7. The corresponding [CI]-H2factor is five times higher thanX(CO), withX[CI] = (9 ± 2)×1019cm−2/K km s−1. No unique conversion factor can be determined for [CII]. The low molecular gas content of galaxy centers relative to their CO intensities is explained in roughly equal parts by high central gas-phase carbon abundances, elevated gas temperatures, and large gas velocity dispersions relative to the corresponding values in galaxy disks.

Organic molecules in the protoplanetary disk of DG Tauri revealed by ALMA

Context. Planets form in protoplanetary disks and inherit their chemical compositions. Aims. It is thus crucial to map the distribution and investigate the formation of simple organics, such as formaldehyde and methanol, in protoplanetary disks. Methods. We analyze ALMA observations of the nearby disk-jet system around the T Tauri star DG Tau in the o − H2CO 31, 2 − 21, 1 and CH3OH 3−2, 2 − 4−1, 4 E, 50, 5 − 40, 4 A transitions at an unprecedented resolution of $ {\sim}0{{\overset{\prime\prime}{.}}}{15} $, i.e., ∼18 au at a distance of 121 pc. Results. The H2CO emission originates from a rotating ring extending from ∼40 au with a peak at ∼62 au, i.e., at the edge of the 1.3 mm dust continuum. CH3OH emission is not detected down to an rms of 3 mJy beam−1 in the 0.162 km s−1 channel. Assuming an ortho-to-para ratio of 1.8−2.8 the ring- and disk-height-averaged H2CO column density is ∼0.3−4 × 1014 cm−2, while that of CH3OH is < 0.04−0.7 × 1014 cm−2. In the inner 40 au no o − H2CO emission is detected with an upper limit on its beam-averaged column density of ∼0.5−6 × 1013 cm−2. Conclusions. The H2CO ring in the disk of DG Tau is located beyond the CO iceline (RCO ∼ 30 au). This suggests that the H2CO abundance is enhanced in the outer disk due to formation on grain surfaces by the hydrogenation of CO ice. The emission peak at the edge of the mm dust continuum may be due to enhanced desorption of H2CO in the gas phase caused by increased UV penetration and/or temperature inversion. The CH3OH/H2CO abundance ratio is < 1, in agreement with disk chemistry models. The inner edge of the H2CO ring coincides with the radius where the polarization of the dust continuum changes orientation, hinting at a tight link between the H2CO chemistry and the dust properties in the outer disk and at the possible presence of substructures in the dust distribution.

Circumnuclear Multiphase Gas in the Circinus Galaxy. II. The Molecular and Atomic Obscuring Structures Revealed with ALMA

Abstract We used the Atacama Large Millimeter/Submillimeter Array (ALMA) to map the CO(3–2) and [C i](1–0) lines, as well as their underlying continuum emission, from the central ∼200 pc region of the Circinus galaxy that hosts the nearest type 2 Seyfert-class active galactic nucleus (AGN), with a spatial resolution of ∼6–15 pc. The lines and continuum-emitting regions consist of a circumnuclear disk (CND; 74 pc × 34 pc) and spiral arms. The distribution of the continuum emission revealed a temperature-dependent dust geometry and possibly polar dust elongation in the torus region. The molecular mass of the CND is , with a beam-averaged H2 column density of ∼5 × 1023 cm−2 toward the AGN position, which contributes significantly to the nuclear obscuration. The [C i](1–0)/CO(3–2) ratio at the AGN position is unusually high, suggesting an X-ray-dominated region-type chemistry. We decomposed the observed velocity fields into rotational and dispersion components, and revealed a multiphase dynamic nature in the r ≲ 10 pc torus region, i.e., the diffuse atomic gas is more spatially extended along the vertical direction of the disk than the dense molecular gas. Through comparisons with our model predictions based on the radiation-driven fountain scheme, we indicate that atomic outflows are the driver of the geometrical thickness of the atomic disk. This supports the validity of the radiation-driven fountain scheme in the vicinity of this AGN, which would explain the longstanding mystery of the physical origin of the AGN torus.

Discovery of Interstellar Isocyanogen (CNCN): Further Evidence that Dicyanopolyynes are Abundant in Space.

It is thought that dicyanopolyynes could be potentially abundant interstellar molecules, although their lack of dipole moment makes it impossible to detect them through radioastronomical techniques. Recently, the simplest member of this chemical family, cyanogen (NCCN), was indirectly probed for the first time in interstellar space through the detection of its protonated form toward the dense clouds L483 and TMC-1. Here we present a second firm evidence of the presence of NCCN in interstellar space, namely the detection of the metastable and polar isomer isocyanogen (CNCN). This species has been identified in L483 and tentatively in TMC-1 by observing various rotational transitions in the λ 3 mm band with the IRAM 30m telescope. We derive beam-averaged column densities for CNCN of 1.6 × 1012 cm-2 in L483 and 9 × 1011 cm-2 in TMC-1, which imply fractional abundances relative to H2 in the range (5 - 9) × 10-11. While the presence of NCCN in interstellar clouds seems out of doubt owing to the detection of NCCNH+ and CNCN, putting tight constraints on its abundance is still hampered by the poor knowledge of the chemistry that links NCCN with NCCNH+ and especially with CNCN. We estimate that NCCN could be fairly abundant, in the range 10-9-10-7 relative to H2, as other abundant nitriles like HCN and HC3N.

Chemical Survey toward Young Stellar Objects in the Perseus Molecular Cloud Complex

Chemical diversity of the gas in low-mass protostellar cores is widely recognized. In order to explore its origin, a survey of chemical composition toward 36 Class 0/I protostars in the Perseus molecular cloud complex, which are selected in an unbiased way under certain physical conditions, has been conducted with IRAM 30 m and NRO 45 m telescope. Multiple lines of C2H, c-C3H2 and CH3OH have been observed to characterize the chemical composition averaged over a 1000 au scale around the protostar. The derived beam-averaged column densities show significant chemical diversity among the sources, where the column density ratios of C2H/CH3OH are spread out by 2 orders of magnitude. From previous studies, the hot corino sources have abundant CH3OH but deficient C2H, their C2H/CH3OH column density ratios being relatively low. In contrast, the warm-carbon-chain chemistry (WCCC) sources are found to reveal the high C2H/CH3OH column density ratios. We find that the majority of the sources have intermediate characters between these two distinct chemistry types. A possible trend is seen between the C2H/CH3OH ratio and the distance of the source from the edge of a molecular cloud. The sources located near cloud edges or in isolated clouds tend to have a high C2H/CH3OH ratio. On the other hand, the sources having a low C2H/CH3OH ratio tend to be located in inner regions of the molecular cloud complex. This result gives an important clue to an understanding of the origin of the chemical diversity of protostellar cores in terms of environmental effects.

Detection of interstellar HCS and its metastable isomer HSC: new pieces in the puzzle of sulfur chemistry.

We present the first identification in interstellar space of the thioformyl radical (HCS) and its metastable isomer HSC. These species were detected toward the molecular cloud L483 thanks to observations carried out with the IRAM 30m telescope in the λ 3 mm band. We derive beam-averaged column densities of 7 × 1012 cm-2 for HCS and 1.8 × 1011 cm-2 for HSC, which translate to fractional abundances relative to H2 of 2 × 10-10 and 6 × 10-12, respectively. Although the amount of sulfur locked by these radicals is low, their detection allows to put interesting constraints on the chemistry of sulfur in dark clouds. Interestingly, the H2CS/HCS abundance ratio is found to be quite low, ~ 1, in contrast with the oxygen analogue case, in which the H2CO/HCO abundance ratio is around 10 in dark clouds. Moreover, the radical HCS is found to be more abundant than its oxygen analogue, HCO. The metastable species HOC, the oxygen analogue of HSC, has not been yet observed in space. These observational constraints are confronted with the outcome of a recent model of the chemistry of sulfur in dark clouds. The model underestimates the fractional abundance of HCS by at least one order of magnitude, overestimates the H2CS/HCS abundance ratio, and does not provide an abundance prediction for the metastable isomer HSC. These observations should prompt a revision of the chemistry of sulfur in interstellar clouds.

The Seahorse Nebula: New views of the filamentary infrared dark cloud G304.74+01.32 from SABOCA, Herschel, and WISE

Context. Filamentary molecular clouds, such as many of the infrared dark clouds (IRDCs), can undergo hierarchical fragmentation into substructures (clumps and cores) that can eventually collapse to form stars. Aims. We aim to determine the occurrence of fragmentation into cores in the clumps of the filamentary IRDC G304.74+01.32 (hereafter, G304.74). We also aim to determine the basic physical characteristics (e.g. mass, density, and young stellar object (YSO) content) of the clumps and cores in G304.74. Methods. We mapped the G304.74 filament at 350 μm using the Submillimetre APEX Bolometer Camera (SABOCA) bolometer. The new SABOCA data have a factor of 2.2 times higher resolution than our previous Large APEX BOlometer CAmera (LABOCA) 870 μm map of the cloud (9″ vs. 19 .̋ 86). We also employed the Herschel far-infrared (IR) and submillimetre, and Wide-field Infrared Survey Explorer (WISE) IR imaging data available for G304.74. The WISE data allowed us to trace the IR emission of the YSOs associated with the cloud. Results. The SABOCA 350 μm data show that G304.74 is composed of a dense filamentary structure with a mean width of only 0.18 ± 0.05 pc. The percentage of LABOCA clumps that are found to be fragmented into SABOCA cores is 36% ± 16%, but the irregular morphology of some of the cores suggests that this multiplicity fraction could be higher. The WISE data suggest that 65% ± 18% of the SABOCA cores host YSOs. The mean dust temperature of the clumps, derived by comparing the Herschel 250, 350, and 500 μm flux densities, was found to be 15.0 ± 0.8 K. The mean mass, beam-averaged H2 column density, and H2 number density of the LABOCA clumps are estimated to be 55 ± 10M⊙, (2.0 ± 0.2) × 1022 cm-2, and (3.1 ± 0.2) × 104 cm-3. The corresponding values for the SABOCA cores are 29 ± 3M⊙, (2.9 ± 0.3) × 1022 cm-2, and (7.9 ± 1.2) × 104 cm-3. The G304.74 filament is estimated to be thermally supercritical by a factor of ≳ 3.5 on the scale probed by LABOCA, and by a factor of ≳ 1.5 for the SABOCA filament. Conclusions. Our data strongly suggest that the IRDC G304.74 has undergone hierarchical fragmentation. On the scale where the clumps have fragmented into cores, the process can be explained in terms of gravitational Jeans instability. Besides the filament being fragmented, the finding of embedded YSOs in G304.74 indicates its thermally supercritical state, although the potential non-thermal (turbulent) motions can render the cloud a virial equilibrium system on scale traced by LABOCA. The IRDC G304.74 has a seahorse-like morphology in the Herschel images, and the filament appears to be attached by elongated, perpendicular striations. This is potentially evidence that G304.74 is still accreting mass from the surrounding medium, and the accretion process can contribute to the dynamical evolution of the main filament. One of the clumps in G304.74, IRAS 13039-6108, is already known to be associated with high-mass star formation, but the remaining clumps and cores in this filament might preferentially form low and intermediate-mass stars owing to their mass reservoirs and sizes. Besides the presence of perpendicularly oriented, dusty striations and potential embedded intermediate-mass YSOs, G304.74 is a relatively nearby (d ~ 2.5 kpc) IRDC, which makes it a useful target for future star formation studies. Owing to its observed morphology, we propose that G304.74 could be nicknamed the Seahorse Nebula.

Testing the variability of the proton-to-electron mass ratio from observations of methanol in the dark cloud core L1498

The dependence of the proton-to-electron mass ratio, mu, on the local matter density was investigated using methanol emission in the dense dark cloud core L1498. Towards two different positions in L1498, five methanol transitions were detected and an extra line was tentatively detected at a lower confidence level in one of the positions. The observed centroid frequencies were then compared with their rest frame frequencies derived from least-squares fitting to a large data set. Systematic effects, as the underlying methanol hyperfine structure and the Doppler tracking of the telescope, were investigated and their effects were included in the total error budget. The comparison between the observations and the rest frame frequencies constrains potential mu variation at the level of Dmu/mu < 6 x 10^(-8), at a 3 sigma confidence level. For the dark cloud we determine a total CH3OH (A+E) beam averaged column density of 3-4 x 10^(12) cm(-2) (within roughly a factor of two), an E- to A-type methanol column density ratio of N(A-CH3OH)/N(E-CH3OH) = 1.00 +/- 0.15, a density of n(H2) = 3 x 10^5 cm^(-3) (again within a factor of two), and a kinetic temperature of Tkin = 6 +/- 1 K. In a kinetic model including the line intensities observed for the methanol lines, the n(H2) density is higher and the temperature is lower than that derived in previous studies based on different molecular species; the intensity of the 1_0 --> 1_-1 E line strength is not well reproduced.

Probing non polar interstellar molecules through their protonated form: Detection of protonated cyanogen (NCCNH+).

Cyanogen (NCCN) is the simplest member of the series of dicyanopolyynes. It has been hypothesized that this family of molecules can be important constituents of interstellar and circumstellar media, although the lack of a permanent electric dipole moment prevents its detection through radioastronomical techniques. Here we present the first solid evidence of the presence of cyanogen in interstellar clouds through the detection of its protonated form toward the cold dark clouds TMC-1 and L483. Protonated cyanogen (NCCNH+) has been identified through the J = 5 - 4 and J = 10 - 9 rotational transitions using the 40m radiotelescope of Yebes and the IRAM 30m telescope. We derive beam averaged column densities for NCCNH+ of (8.6 ± 4.4) × 1010 cm-2 in TMC-1 and (3.9 ± 1.8) × 1010 cm-2 in L483, which translate to fairly low fractional abundances relative to H2, in the range (1-10) × 10-12. The chemistry of protonated molecules in dark clouds is discussed, and it is found that, in general terms, the abundance ratio between the protonated and non protonated forms of a molecule increases with increasing proton affinity. Our chemical model predicts an abundance ratio NCCNH+/NCCN of ~ 10-4, which implies that the abundance of cyanogen in dark clouds could be as high as (1-10) × 10-8 relative to H2, i.e., comparable to that of other abundant nitriles such as HCN, HNC, and HC3N.

A13CO SURVEY OF INTERMEDIATE-MASS STAR-FORMING REGIONS

We have conducted a 13CO survey of a sample of 128 infrared color-selected intermediate-mass star-forming region (IM SFR) candidates. We utilized the Onsala 20 m telescope to observe 13CO (1–0) toward 67 northern IM SFRs, used the 12 m Atacama Pathfinder Experiment telescope to observe 13CO (2–1) toward 22 southern IM SFRs, and incorporated an additional 39 sources from the Boston University Five College Radio Astronomy Observatory Galactic Ring Survey which observed 13CO (1–0). We detect 13CO (1–0) in 58 of the 67 northern sources and 13CO (2–1) in 20 of the 22 southern sources. The mean molecular column densities and 13CO linewidths in the inner Galaxy are higher by factors of 3.4 and 1.5, respectively, than the outer Galaxy. We attribute this difference to molecular clouds in the inner Galaxy being more massive and hosting star forming regions with higher luminosities on average than the outer Galaxy. IM SFRs have mean a molecular column density of 7.89 × 1021 cm−2, a factor of 3.1 lower than that for a sample of high-mass regions, and have a mean 13CO linewidth of 1.84 km s−1, a factor of 1.5 lower than that for high-mass regions. We demonstrate a correlation between 13CO linewidth and infrared luminosity as well as between molecular column density and infrared luminosity for the entire sample of intermediate-mass and high-mass regions. IM SFRs appear to form in distinctly lower-density environments with mean linewidths and beam-averaged column densities a factor of several lower than high-mass star-forming regions.

Discovery of interstellar ketenyl (HCCO), a surprisingly abundant radical.

We have conducted radioastronomical observations of 9 dark clouds with the IRAM 30m telescope. We present the first identification in space of the ketenyl radical (HCCO) toward the starless core Lupus-1A and the molecular cloud L483, and the detection of the related molecules ketene (H2CCO) and acetaldehyde (CH3CHO) in these two sources and 3 additional dark clouds. We also report the detection of the formyl radical (HCO) in the 9 targeted sources and of propylene (CH2CHCH3) in 4 of the observed sources, which extends significantly the number of dark clouds where these molecules are known to be present. We derive a beam-averaged column density of HCCO of ~ 5 × 1011 cm-2 in both Lupus-1A and L483, which means that the ketenyl radical is just ~10 times less abundant than ketene in these sources. The non-negligible abundance of HCCO found implies that there must be a powerful formation mechanism able to counterbalance the efficient destruction of this radical through reactions with neutral atoms. The column densities derived for HCO, (0.5-2.7) ×1012 cm-2, and CH2CHCH3, (1.9-4-2) ×1013 cm-2, are remarkably uniform across the sources where these species are detected, confirming their ubiquity in dark clouds. Gas phase chemical models of cold dark clouds can reproduce the observed abundances of HCO, but cannot explain the presence of HCCO in Lupus-1A and L483 and the high abundances derived for propylene. The chemistry of cold dark clouds needs to be revised in the light of these new observational results.

How to Calculate Molecular Column Density

The calculation of the molecular column density from molecular spectral (rotational or ro-vibrational) transition measurements is one of the most basic quantities derived from molecular spectroscopy. Starting from first principles where we describe the basic physics behind the radiative and collisional excitation of molecules and the radiative transfer of their emission, we derive a general expression for the molecular column density. As the calculation of the molecular column density involves a knowledge of the molecular energy level degeneracies, rotational partition functions, dipole moment matrix elements, and line strengths, we include generalized derivations of these molecule-specific quantities. Given that approximations to the column density equation are often useful, we explore the optically thin, optically thick, and low-frequency limits to our derived general molecular column density relation. We also evaluate the limitations of the common assumption that the molecular excitation temperature is constant and address the distinction between beam-averaged and source-averaged column densities. As non-LTE approaches to the calculation of molecular spectral line column density have become quite common, we summarize non-LTE models that calculate molecular cloud volume densities, kinetic temperatures, and molecular column densities. We conclude our discussion of the molecular column density with worked examples for C18O, C17O, N2H+, NH3, and H2CO. Ancillary information on some subtleties involving line profile functions, conversion between integrated flux and brightness temperature, the calculation of the uncertainty associated with an integrated intensity measurement, the calculation of spectral line optical depth using hyperfine or isotopologue measurements, the calculation of the kinetic temperature from a symmetric molecule excitation temperature measurement, and relative hyperfine intensity calculations for NH3 are presented in appendices. The intent of this document is to provide a reference for researchers studying astrophysical molecular spectroscopic measurements.

Extended warm gas in Orion KL as probed by methyl cyanide

In order to study the temperature distribution of the extended gas within the Orion Kleinmann-Low nebula, we have mapped the emission by methyl cyanide (CH3CN) in its J=6_K-5_K, J=12_K-11_K, J=13_K-12_K, and J=14_K-13_K transitions at an average angular resolution of ~10 arcsec (22 arcsec for the 6_K-5_K lines), as part of a new 2D line survey of this region using the IRAM 30m telescope. These fully sampled maps show extended emission from warm gas to the northeast of IRc2 and the distinct kinematic signatures of the hot core and compact ridge source components. We have constructed population diagrams for the four sets of K-ladder emission lines at each position in the maps and have derived rotational excitation temperatures and total beam-averaged column densities from the fitted slopes. In addition, we have fitted LVG model spectra to the observations to determine best-fit physical parameters at each map position, yielding the distribution of kinetic temperatures across the region. The resulting temperature maps reveal a region of hot (T > 350 K) material surrounding the northeastern edge of the hot core, whereas the column density distribution is more uniform and peaks near the position of IRc2. We attribute this region of hot gas to shock heating caused by the impact of outflowing material from active star formation in the region, as indicated by the presence of broad CH3CN lines. This scenario is consistent with predictions from C-shock chemical models that suggest that gas-phase methyl cyanide survives in the post-shock gas and can be somewhat enhanced due to sputtering of grain mantles in the passing shock front.

Detection of Methyl Formate in the Second Torsionally Excited State (υt = 2) in Orion KL

Abstract We report on the detection of rotational transitions of methyl formate (HCOOCH$ _{3}$ ) in the second torsionally excited state ($ v_{\rm t}$$ =$ 2) of the methyl internal rotation in Orion Kleinmann–Low (KL). Recent progress in the microwave spectroscopy of methyl formate in laboratories and sensitive radioastronomical observations have made it possible to assign $ \sim$ 20 emission lines to methyl formate in the $ v_{\rm t}$$ =$ 2 state. The beam-averaged column density obtained with the Nobeyama 45 m radiotelescope is (3.0 $ \pm$ 1.5) $ \times$ 10$ ^{14}$ cm$ ^{-2}$ in this state. In addition to this state, we also observed lines in the ground and the first torsionally excited states ($ v_{\rm t}$$ =$ 0 and 1) in Orion KL. The obtained rotational temperatures for the $ v_{\rm t}$$ =$ 0 and 1 states are 43 $ \pm$ 9 and 53 $ \pm$ 8 K, respectively. The column densities for the $ v_{\rm t}$$ =$ 0 and 1 states are (3.8 $ \pm$ 1.2) $ \times$ 10$ ^{15}$ and (9.8 $ \pm$ 2.3) $ \times$ 10$ ^{14}$ cm$ ^{-2}$ , respectively, which are 13 and 3 times the column density in the $ v_{\rm t}$$ =$ 2 state. Data of these three states can be explained by a single vibrational temperature of 124 $ \pm$ 5 K, which is significantly higher than the rotational temperatures. As excitation mechanisms, there are two possibilities: collision with H$ _2$ and pumping by far-infrared radiation from star-formation activities. Considering the temperature difference and Einstein's $ A$ coefficients of the torsional states, we cannot rule out either of these possibilities. This detection further indicates that many more unidentified lines in Orion KL will be due to low-lying excited states of methyl formate and other organic molecules.

THE MAGNETIZED ENVIRONMENT OF THE W3(H 2 O) PROTOSTARS

We present the first interferometric polarization map of the W3(OH) massive star-forming region observed with the Submillimeter Array (SMA) at 878 mum with an angular resolution of 1.5 (about 3 \times 10 AU). Polarization is detected in the W3(H2O) hot core, an extended emission structure in the north-west of W3(H2O), and part of the W3(OH) ultracompact HII region. The W3(H2O) hot core is known to be associated with a synchrotron jet along the east-west direction. In this core, the inferred magnetic field orientation is well aligned with the synchrotron jet and close to the plane of sky. Using the Chandrasekhar-Fermi method with the observed dispersion in polarization angle, we estimate a plane-of-sky magnetic field strength of 17.0 mG. Combined with water maser Zeeman measurements, the total magnetic field strength is estimated to be 17.1 mG, comparable to the field strength estimated from the synchrotron model. The magnetic field energy dominates over turbulence in this core. In addition, the depolarization effect is discerned in both SMA and JCMT measurements. Despite the great difference in angular resolutions and map extents, the polarization percentage shows a similar power-law dependence with the beam averaged column density. We suggest that the column density may be an important factor to consider when interpreting the depolarization effect.

A 95 GHz CLASS I METHANOL MASER SURVEY TOWARD A SAMPLE OF GLIMPSE POINT SOURCES ASSOCIATED WITH BGPS CLUMPS

We report a survey with the Purple Mountain Observatory (PMO) 13.7-m radio telescope for class I methanol masers from the 95 GHz (8_0 - 7_1 A^+) transition. The 214 target sources were selected by combining information from both the Spitzer GLIMPSE and 1.1 mm BGPS survey catalogs. The observed sources satisfy both the GLIMPSE mid-IR criteria of [3.6]-[4.5]>1.3, [3.6]-[5.8]>2.5, [3.6]-[8.0]>2.5 and 8.0 um magnitude less than 10, and also have an associated 1.1 mm BGPS source. Class I methanol maser emission was detected in 63 sources, corresponding to a detection rate of 29% for this survey. For the majority of detections (43), this is the first identification of a class I methanol maser associated with these sources. We show that the intensity of the class I methanol maser emission is not closely related to mid-IR intensity or the colors of the GLIMPSE point sources, however, it is closely correlated with properties (mass and beam-averaged column density) of the BGPS sources. Comparison of measures of star formation activity for the BGPS sources with and without class I methanol masers indicate that the sources with class I methanol masers usually have higher column density and larger flux density than those without them. Our results predict that the criteria log(S_{int})<-38.0+1.72log(N_{H_{2}}^{beam}) and log(N_{H_{2}}^{beam})>22.1, which utilizes both the integrated flux density (S_{int}) and beam-averaged column density (N_{H_{2}}^{beam}) of the BGPS sources, are very efficient for selecting sources likely to have an associated class I methanol maser. Our expectation is that searches using these criteria will detect 90% of the predicted number of class I methanol masers from the full BGPS catalog (~ 1000), and do so with a high detection efficiency (~75%).