BCS Bose–Einstein Condensation Crossover Research Articles

Resonant multi-gap superconductivity at room temperature near a Lifshitz topological transition in sulfur hydrides

The maximum critical temperature for superconductivity in pressurized hydrides appears at the top of superconducting domes in Tc vs pressure curves at a particular pressure, which is not predicted by standard superconductivity theories. The high-order anisotropic Van Hove singularity near the Fermi level observed in band-structure calculations of pressurized sulfur hydride, typical of a supermetal, has been associated with the array of metallic hydrogen wire modules forming a nanoscale heterostructure at an atomic limit called the superstripe phase. Here, we propose that pressurized sulfur hydrides behave as a heterostructure made of a nanoscale superlattice of interacting quantum wires with a multicomponent electronic structure. We present first-principles quantum calculation of a universal superconducting dome where Tc amplification in multi-gap superconductivity is driven by the Fano–Feshbach resonance due to a configuration interaction between open and closed pairing channels, i.e., between multiple gaps in the BCS regime, resonating with a single gap in the BCS–Bose–Einstein condensation crossover regime. In the proposed three dimensional phase diagram, the critical temperature shows a superconducting dome where Tc is a function of two variables: (i) the Lifshitz parameter (η) measuring the separation of the chemical potential from the Lifshitz transition normalized by the inter-wire coupling and (ii) the effective electron–phonon coupling (g) in the appearing new Fermi surface including phonon softening. The results will be of help for material design of room-temperature superconductors at ambient pressure.

Screening masses of photons interacting with a two-species fermionic system in relativistic BCS–BEC crossover

We address the behavior of Debye and Meissner masses of photons in a condensate of fermion pairs in the presence of number density asymmetry. Our formalism applies to a two-species fermionic system with number density asymmetry in BCS–Bose–Einstein condensation (BEC)–relativistic BEC crossover and with variable rapidity. Our results recover the known results of the photon self-energy in the ultrarelativistic limit and the superfluid density in the nonrelativistic limit. We further consider the electromagnetic stability of the condensate and show that the Meissner mass squared can become negative in the weakly coupling BCS regime and the strongly coupling relativistic BEC regime. The electromagnetic instability is compared to the mechanical stability discussed in previous works.

Ginzburg–Landau expansion in BCS–BEC crossover region of disordered attractive Hubbard model

We have studied disorder effects on the coefficients of Ginzburg - Landau (GL) expansion for attractive Hubbard model within the generalized DMFT+Sigma approximation for the wide region of the values of attractive potential U - from the weak-coupling limit, where superconductivity is described by BCS model, towards the strong coupling, where superconducting transition is related to Bose - Einstein condensation (BEC) of compact Cooper pairs. For the case of semi-elliptic initial density of states disorder influence on the coefficients A and B before the square and the fourth power of the order parameter is universal for at all values of electronic correlations and is related only to the widening of the initial conduction band (density of states) by disorder. Similar universal behavior is valid for superconducting critical temperature T_c (the generalized Anderson theorem) and specific heat discontinuity at the transition. This universality is absent for the coefficient C before the gradient term, which in accordance with the standard theory of "dirty" superconductors is strongly suppressed by disorder in the weak-coupling region, but can slightly grow in BCS - BEC crossover region, becoming almost independent of disorder in the strong coupling region. This leads to rather weak disorder dependence of the penetration depth and coherence length, as well as the slope of the upper critical magnetic field at T_c, in BCS - BEC crossover and strong coupling regions.

Effect of the particle-hole channel on BCS-Bose-Einstein condensation crossover in atomic Fermi gases.

BCS–Bose-Einstein condensation (BEC) crossover is effected by increasing pairing strength between fermions from weak to strong in the particle-particle channel, and has attracted a lot of attention since the experimental realization of quantum degenerate atomic Fermi gases. Here we study the effect of the (often dropped) particle-hole channel on the zero T gap Δ(0), superfluid transition temperature Tc, the pseudogap at Tc, and the mean-field ratio 2Δ(0)/, from BCS through BEC regimes, using a pairing fluctuation theory which includes self-consistently the contributions of finite-momentum pairs and features a pseudogap in single particle excitation spectrum. Summing over the infinite particle-hole ladder diagrams, we find a complex dynamical structure for the particle-hole susceptibility χph, and conclude that neglecting the self-energy feedback causes a serious over-estimate of χph. While our result in the BCS limit agrees with Gor’kov et al., the particle-hole channel effect becomes more complex and pronounced in the crossover regime, where χph is reduced by both a smaller Fermi surface and a big (pseudo)gap. Deep in the BEC regime, the particle-hole channel contributions drop to zero. We predict a density dependence of the magnetic field at the Feshbach resonance, which can be used to quantify χph and test different theories.

Non-equilibrium Properties of a Pumped-Decaying Bose-Condensed Electron–Hole Gas in the BCS–BEC Crossover Region

We theoretically investigate a Bose-condensed exciton gas out of equilibrium. Within the framework of the combined BCS-Leggett strong-coupling theory with the non-equilibrium Keldysh formalism, we show how the Bose-Einstein condensation (BEC) of excitons is suppressed to eventually disappear, when the system is in the non-equilibrium steady state. The supply of electrons and holes from the bath is shown to induce quasi-particle excitations, leading to the partial occupation of the upper branch of Bogoliubov single-particle excitation spectrum. We also discuss how this quasi-particle induction is related to the suppression of exciton BEC, as well as the stability of the steady state.

BCS–BEC crossover of spin imbalanced Fermi gases with Rashba spin–orbit coupling

We study the BCS–Bose Einstein Condensation (BEC) crossover of a three-dimensional spin polarized Fermi gas with Rashba spin–orbital coupling (SOC). At finite temperature, the effects of non-condensed pairs due to the thermal excitation are considered based on the G0G pair fluctuation theory. These fluctuations generate a pseudogap even persistent above Tc. Within this framework, the Sarma state or the spin polarized superfluid state and polarized pseudogap state are explored in detail. The resulting Tc curves show that the enhancement of pairing due to the SOC roughly cancels out the suppression of pairing due to the population imbalance. Thus we observed that in a large portion of the parameter space, the polarized superfluid state are stabilized by the SOC.

Density and spin linear response of atomic Fermi superfluids with population imbalance in the BCS–BEC crossover

We present a theoretical study of the density and spin (representing the two components) linear response of Fermi superfluids with tunable attractive interactions and population imbalance. In both linear response theories, we find that the fluctuations of the order parameter must be treated on equal footing with the gauge transformations associated with the symmetries of the Hamiltonian so that important constraints including various sum rules can be satisfied. Both theories can be applied to the whole BCS–Bose–Einstein condensation crossover. The spin linear responses are qualitatively different with and without population imbalance because collective-mode effects from the fluctuations of the order parameter survive in the presence of population imbalance, even though the associated symmetry is not broken by the order parameter. Since a polarized superfluid becomes unstable at low temperatures in the weak and intermediate coupling regimes, we found that the density and spin susceptibilities diverge as the system approaches the unstable regime, but the emergence of phase separation preempts the divergence.

FUNDAMENTAL CONSTRAINTS ON LINEAR RESPONSE THEORIES OF FERMI SUPERFLUIDS ABOVE AND BELOW Tc

We present fundamental constraints required for a consistent linear response theory of fermionic superfluids and address temperatures both above and below the transition temperature Tc. We emphasize two independent constraints, one associated with gauge invariance (and the related Ward identity) and another associated with the compressibility sum rule, both of which are satisfied in strict BCS theory. However, we point out that it is the rare many body theory which satisfies both of these. Indeed, well studied quantum Hall systems and random-phase approximations to the electron gas are found to have difficulties with meeting these constraints. We summarize two distinct theoretical approaches which are, however, demonstrably compatible with gauge invariance and the compressibility sum rule. The first of these involves an extension of BCS theory to a mean field description of the BCS-Bose Einstein condensation crossover. The second is the simplest Nozieres Schmitt–Rink (NSR) treatment of pairing correlations in the normal state. As a point of comparison we focus on the compressibility κ of each and contrast the predictions above Tc. We note here that despite the compliance with sum rules, this NSR based scheme leads to an unphysical divergence in κ at the transition. Because of the delicacy of the various consistency requirements, the results of this paper suggest that avoiding this divergence may repair one problem while at the same time introducing others.

Dineutron correlations and BCS–BEC crossover in nuclear matter with the Gogny pairing force

The dineutron correlations and the crossover from superfluidity of neutron Cooper pairs in the $^1S_0$ pairing channel to Bose-Einstein condensation (BEC) of dineutron pairs in both symmetric and neutron matter are studied within the relativistic Hartree-Bogoliubov theory, with the effective interaction PK1 of the relativistic mean-field approach in the particle-hole channel and the finite-range Gogny force in the particle-particle channel. The influence of the pairing strength on the behaviors of dineutron correlations is investigated. It is found that the neutron pairing gaps at the Fermi surface from three adopted Gogny interactions are smaller at low densities than the one from the bare nucleon-nucleon interaction Bonn-B potential. From the normal (anomalous) density distribution functions and the density correlation function, it is confirmed that a true dineutron BEC state does not appear in nuclear matter. In the cases of the Gogny interactions, the most BEC-like state may appear when the neutron Fermi momentum $k_{Fn}\thicksim0.3 \rm{fm^{-1}}$. Moreover, based on the newly developed criterion for several characteristic quantities within the relativistic framework, the BCS-BEC crossover is supposed to realize in a revised density region with $k_{Fn}\in[0.15,0.63] \rm{fm^{-1}}$ in nuclear matter.

Theories of Linear Response in BCS Superfluids and How They Meet Fundamental Constraints

We address the importance of symmetry and symmetry breaking on linear response theories of fermionic BCS superfluids. The linear theory of a noninteracting Fermi gas is reviewed and several consistency constraints are verified. The challenge to formulate linear response theories of BCS superfluids consistent with density and spin conservation laws comes from the presence of a broken U(1)$_{\textrm{EM}}$ symmetry associated with electromagnetism (EM) and we discuss two routes for circumventing this. The first route follows Nambu's integral-equation approach for the EM vertex function, but this method is not specific for BCS superfluids. We focus on the second route based on a consistent-fluctuation-of-the order-parameter (CFOP) approach where the gauge transformation and the fluctuations of the order parameter are treated on equal footing. The CFOP approach allows one to explicitly verify several important constraints: The EM vertex satisfies not only a Ward identity which guarantees charge conservation but also a $Q$-limit Ward identity associated with the compressibility sum rule. In contrast, the spin degrees of freedom associated with another U(1)$_z$ symmetry are not affected by the Cooper-pair condensation that breaks only the U(1)$_{\textrm{EM}}$ symmetry. As a consequence the collective modes from the fluctuations of the order parameter only couple to the density response function but decouple from the spin response function, which reflects the different fates of the two U(1) symmetries in the superfluid phase. Our formulation lays the ground work for application to more general theories of BCS-Bose Einstein Condensation crossover both above and below $T_c$.

Pairing Fluctuations, the BCS–BEC Crossover and Strong Disorder in Superconductors

The mean field theory due to Bardeen, Cooper, and Schrieffer (BCS) provides the conceptual foundation of our understanding of superconductivity, but many examples over the last few decades have forced condensed matter physicists to extend the BCS framework. In particular, the extension to strong coupling, the BCS to Bose–Einstein condensation (BEC) crossover, requires the treatment of amplitude and phase fluctuations above the mean field state. Similarly, the presence of disorder can lead to strong inhomogeneity in the pairing amplitude, enhance phase fluctuations, and suppress the transition temperature. Finally, magnetic scattering quickly leads to a gapless superconducting state and then the loss of order. All of these involve physics beyond the BCS scenario. We employ a real space method that reduces to inhomogeneous mean field theory in the ground state, but fully retains the amplitude and phase fluctuations of the pairing field at finite temperature. This paper reviews some of our work in the weak to strong coupling (BCS–BEC) crossover, the disorder driven superconductor-insulator transition, and the role of magnetic impurities.

Variational Monte Carlo Study of Spin-Gapped Normal State and BCS–BEC Crossover in Two-Dimensional Attractive Hubbard Model

We study properties of normal, superconducting (SC) and CDW states for an attractive Hubbard model on the square lattice, using a variational Monte Carlo method. In trial wave functions, we introduce an interspinon binding factor, indispensable to induce a spin-gap transition in the normal state, in addition to the onsite attractive and intersite repulsive factors. It is found that, in the normal state, as the interaction strength $|U|/t$ increases, a first-order spin-gap transition arises at $|U_{\rm c}|\sim W$ ($W$: band width) from a Fermi liquid to a spin-gapped state, which is conductive through hopping of doublons. In the SC state, we confirm by analysis of various quantities that the mechanism of superconductivity undergoes a smooth crossover at around $|U_{\ma{co}}|\sim |U_{\rm c}|$ from a BCS type to a Bose-Einstein condensation (BEC) type, as $|U|/t$ increases. For $|U|<|U_{\ma{co}}|$, quantities such as the condensation energy, a SC correlation function and the condensate fraction of onsite pairs exhibit behavior of $\sim \exp(-t/|U|)$, as expected from the BCS theory. For $|U|>|U_{\ma{co}}|$, quantities such as the energy gain in the SC transition and superfluid stiffness, which is related to the cost of phase coherence, behave as $\sim t^2/|U|\propto T_{\rm c}$, as expected in a bosonic scheme. In this regime, the SC transition is induced by a gain in kinetic energy, in contrast with the BCS theory. We refer to the relevance to the pseudogap in cuprate superconductors.

Relativistic description of BCS–BEC crossover in nuclear matter

We study theoretically the di-neutron spatial correlations and the crossover from superfluidity of neutron Cooper pairs in the S01 pairing channel to Bose–Einstein condensation (BEC) of di-neutron pairs for both symmetric and neutron matter in the microscopic relativistic pairing theory. We take the bare nucleon–nucleon interaction Bonn-B in the particle–particle channel and the effective interaction PK1 of the relativistic mean-field approach in the particle–hole channel. It is found that the spatial structure of neutron Cooper pair wave function evolves continuously from BCS-type to BEC-type as density decreases. We see a strong concentration of the probability density revealed for the neutron pairs in the fairly small relative distance around 1.5 fm and the neutron Fermi momentum kFn∈[0.6,1.0] fm−1. However, from the effective chemical potential and the quasiparticle excitation spectrum, there is no evidence for the appearance of a true BEC state of neutron pairs at any density. The most BEC-like state may appear at kFn∼0.2 fm−1 by examining the density correlation function. From the coherence length and the probability distribution of neutron Cooper pairs as well as the ratio between the neutron pairing gap and the kinetic energy at the Fermi surface, some features of the BCS–BEC crossover are seen in the density regions, 0.05 fm−1<kFn<0.7(0.75) fm−1, for the symmetric nuclear (pure neutron) matter.

Applying BCS–BEC crossover theory to high-temperature superconductors and ultracold atomic Fermi gases (Review Article)

This review is written at the time of the twentieth anniversary of the discovery of high-temperature superconductors, which nearly coincides with the important discovery of the superfluid phases of ultracold trapped fermionic atoms. We show how these two subjects have much in common. Both have been addressed from the perspective of the BCS—Bose–Einstein condensation (BEC) crossover scenario, which is designed to treat short coherence length superfluids with transition temperatures which are “high” with respect to the Fermi energy. A generalized mean field treatment of BCS–BEC crossover at general temperatures T, based on the BCS–Leggett ground state, has met with remarkable success in the fermionic atomic systems. Here we summarize this success in the context of four different cold atom experiments, all of which provide indications, direct or indirect, for the existence of a pseudogap. This scenario also provides a physical picture of the pseudogap phase in the underdoped cuprates which is a central focus of high Tc research. We summarize successful applications of BCS–BEC crossover to key experiments in high Tc systems, including the phase diagram, specific heat, and vortex core STM data, along with the Nernst effect, and exciting recent data on the superfluid density in very underdoped samples.

BCS–BEC crossover in a trapped gas of Fermi atoms with a Feshbach resonance

We present a theoretical study of the BCS–BEC (Bose–Einstein condensation) crossover in a trapped gas of Fermi atoms including the effect of a Feshbach resonance. Going past the simple mean field approximation, we include the effect of fluctuations in the strong coupling limit involving two kinds of Bose molecules, i.e., Feshbach molecules associated with the resonance and preformed Cooper-pairs in which the pairing interaction is mediated by Feshbach quasi-molecules. The superfluid phase transition is shown to change continuously from the BCS-type to a BEC of these two kinds of Bosons, as the threshold energy of the Feshbach resonance is lowered.