Abstract We report on the influence of photoelectron diffraction effects on magnetic circular dichroism in angular distribution as measured using core-level photoelectron spectroscopy. As an example system we study the effect by measuring azimuthal angle scans of the 4d core-level on a thick Gd(0001) film grown on W(110). In particular, for photoelectron emission in off-normal directions we observe deviations from the pure atomic picture which can be interpreted in terms of a multiple scattering theory. We also evaluate different measuring methods to see their influence on the angular behavior. Using high resolution data we can even study the state-specific contributions to the magnetic dichroism signal. The knowledge of these effects should help in interpreting absolute dichroism values on the basis of sum rules.
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