The process of urbanization and urban growth has resulted in rapid, uncontrolled conversion of natural land cover and spreading of impervious concrete surfaces in many parts of the world leading to serious environmental concerns. There are a myriad of micro climatic effects due to urban growth. One of the significant consequences is the rising urban temperature. Urban surface temperature responds to changes in land use/land cover dynamics and urban expansion. This would ultimately lead to local climatic changes and would accentuate global warming. Geo spatial technology provides sophisticated tools for analyzing urban features and micro climates. Land surface temperature (LST) or the radiant energy from earth surface can be calculated using thermal bands of satellite data. Kochi, the largest urban agglomeration in Kerala, is undergoing hasty developments and land modifications. This study attempts to monitor changes in land surface temperature from 2000 to 2020 along with changes in built up and vegetation cover. The results revealed that the average surface temperature of Kochi recorded an increase of 0.60C and the loss of green cover has contributed to the increased temperature. Moreover, the LST exhibits a strong positive correlation with built up land expansion. The study findings stand helpful for urban planning and sustainable development of the city.