Banded Iron Research Articles

Flotation of a South African Low-Grade Banded Iron Formation (BIF)

AbstractDue to declining iron ore grades, low-grade ores with complex mineralogy, namely, banded iron formation (BIF), are being explored to maximize iron ore resources and increase the life of mine. Flotation is the standard global process used for the beneficiation of BIF ores, as it is a complex ore reserve, and liberation is typically achieved below 1 mm. This study focuses on flotation of a South African BIF evaluating its response to different collectors, as well as effect of grind. Since flotation is an expensive process and South Africa ranks high on the production cost curve, pre-concentration via gravity or magnetic separation is performed prior to flotation. Thus, flotation was also performed on a gravity concentrate to determine if a grade suitable for steelmaking (~ 63%) is achievable. The results indicate that the use of an alkyl ether amine-based collector partially neutralized with acetic acid is suitable for separation of hematite from illite and quartz at high pH values. Further optimization tests are being pursued to improve overall recovery and grade.

The Geological Characteristics, Resource Potential, and Development Status of Manganese Deposits in Africa

Manganese is a critical metal extensively used in steel production, battery manufacturing, and the chemical industry. Manganese deposits are widely distributed globally, with African manganese deposits holding a particularly significant position. This study provides a comprehensive overview of the current status of manganese resources in Africa and analyzes the main types and genesis of the deposits. It also explores the significance of African manganese resources within the global manganese industry and examines the exploration, development, production, and trade status of African manganese ore, revealing dynamic changes and trends within the industry. Africa plays a key role in global manganese resources, with its reserves and resources accounting for 69% and 51% of the global totals, respectively. South Africa is the largest manganese producer, while Gabon and Ghana are also important countries in terms of manganese resources. Based on the host rock and genetic types, African manganese deposits primarily include banded iron formation (BIF)-hosted, black shale-hosted, karst-hosted, and volcanic sedimentary deposits. Additionally, manganese exploration projects in Africa are active, with significant production growth in South Africa and Gabon, and Africa’s standing in the global manganese market is steadily increasing. Trade data also indicate that South Africa dominates manganese exports in Africa and globally. Despite fluctuations in global export volumes, African manganese exports remain high. The prospects for Africa’s manganese industry are promising, and further strengthening of manganese exploration and development will help enhance Africa’s influence in the global manganese market, making a more significant contribution to global industrial and economic development.

Precambrian banded iron formations: paleoecological and paleobiological aspects

Precambrian banded iron formations: paleoecological and paleobiological aspects

Lithogeochemistry of the Shurlovaara banded iron formation, Kostomuksha Greenstone Belt, Karelian Craton, Russia

Lithogeochemistry of the Shurlovaara banded iron formation, Kostomuksha Greenstone Belt, Karelian Craton, Russia

Inhibition of phototrophic iron oxidation by nitric oxide in ferruginous environments

Anoxygenic phototrophic Fe(II) oxidizers (photoferrotrophs) are thought to have thrived in Earth’s ancient ferruginous oceans and played a primary role in the precipitation of Archaean and Palaeoproterozoic (3.8–1.85-billion-year-old) banded iron formations (BIFs). The end of BIF deposition by photoferrotrophs has been interpreted as the result of a deepening of water-column oxygenation below the photic zone, concomitant with the proliferation of cyanobacteria. However, photoferrotrophs may have experienced competition from other anaerobic Fe(II)-oxidizing microorganisms, altering the formation mechanism of BIFs. Here we utilize microbial incubations to show that nitrate-reducing Fe(II) oxidizers metabolically outcompete photoferrotrophs for dissolved Fe(II). Moreover, both experiments and numerical modelling show that the nitrate-reducing Fe(II) oxidizers inhibit photoferrotrophy via the production of toxic intermediates. Four different photoferrotrophs, representing both green sulfur and purple non-sulfur bacteria, are susceptible to this toxic effect despite having genomic capabilities for nitric oxide detoxification. Indeed, despite nitric oxide detoxification mechanisms being ubiquitous in some groups of phototrophs at the genomic level (for example, Chlorobi and Cyanobacteria) it is likely that they would still be affected. We suggest that the production of reactive nitrogen species during nitrate-reducing Fe(II) oxidation in ferruginous environments may have inhibited the activity of photoferrotrophs in the ancient oceans and thus impeded their role in the precipitation of BIFs.

Nutrient removal efficacy and microbial dynamics in constructed wetlands using Fe(III)-mineral substrates for low carbon-nitrogen ratio sewage treatment.

This study evaluated the roles of two common sources of Fe(III)-minerals-volcanic rock (VR) and synthetic banded iron formations from waste iron tailings (BIF-W)-in vertical flow-constructed wetlands (VFCWs). The evaluation was conducted in the absence of critical environmental factors, including Fe(II), Fe(III), and soil organic matter (SOM), using metagenomic analysis and integrated correlation networks to predict nitrogen removal pathways. Our findings revealed that Fe(III)-minerals enhanced metabolic activities and cellular processes related to carbohydrate decomposition, thereby increasing the average COD removal rates by 10.7% for VR and 5.90% for BIF-W. Notably, VR improved nitrogen removal by 1.70% and 5.40% compared to BIF-W and the control, respectively. Fe(III)-mineral amendment in bioreactors also improved the retention of denitrification and nitrification bacteria (phylum Proteobacteria) and anammox bacteria (phylum Planctomycetes), with increases of 3.60% and 3.20% using VR compared to BIF-W. Metagenomic functional predictionindicated that the nitrogen removal mechanisms in VFCWs with low C/N ratios involve simultaneous partial nitrification, ANAMMOX, and denitrification (SNAD). Network-based analyses and correlation pathways further suggest that the advantages of Fe(III)-minerals are manifested in the enhancement of denitrification microorganisms. Microbial communities may be activated by the functional dissolution of Fe(III)-minerals, which improves the stability of SOM or the conversion of Fe(III)/Fe(II). This study provides new insights into the functional roles of Fe(III)-minerals in VFCWs at the microbial community level, and provides a foundation for developing Fe-based SNAD enhancement technologies.

Gold Mineralisation and their Lithological Controls at Nagavi Area, Gadag Schist Belt, in Karnataka, India

Dharwar craton is located in southern India is part of the Dharwar-Singhbhum proto-continent and is known for its complex tectonic and structural controls. It’s made up of two distinct parts, Western Dharwar Craton (WDC) and the Eastern Dharwar Craton (EDC) house several schist belts. Many of these schist belts, such as the Kolar schist belt, Hutti schist belt, Chitradurga schist belt and the Gadag schist belt, are auriferous. In such schist belts, gold occurs in association with sulphides such as pyrite, pyrrhotite, arsenopyrite and chalcopyrite. Gold mineralization in these belts is found to occur in different lithologies. The Gadag schist belt is composed dominantly of metabasalt in its western half and meta sediments in the eastern half. Quartz-carbonate veins are observed to cut across these lithologies as well as the Banded Iron Formations (BIFs). This paper aimed to study the gold mineralization in different lithologies of the Gadag schist belt and found that metabasalts and BIFs are the dominant rocks hosting gold. It is also observed that mineralization is strata-bound. Most of the places’ auriferous sheared zones were observed in the study area. In Nagavi area, BIF hosted gold mineralization is observed, and major gold concentration varies from <21 to <26 ppb (parts per billion). Pyrite occurs as characteristic cubic crystals and as clusters of small grains. In carbonated sheared anorthosite, the rock is fine to medium-grained and in-equigranular. It consists of simple to polysynthetically twinned subhedral (100-200 by 400-600 μm) laths (~40-45%) set in a groundmass of irregular anhedral grains of secondary carbonate (~35-40%), chlorite (~8-10%), opaque (~5-7%) and accessory epidote and quartz.

Geochemistry and conditions of formation of Mesoarchean banded iron formations (BIF-1) from the Kostomuksha Greenstone belt, Karelian Craton

Three variably old groups of banded iron formation (BIF) are known in the Kostomuksha Greenstone belt (KGB) of the Karelian Craton. This paper deals with the earliest of them, Mesoarchean (2.87–2.81 Ga) – BIF-1. BIF-1 occurs among the komatiite-basalt unit of the KGB. BIF-1 consists mainly of quartz and magnetite, with varying amounts of amphibole, biotite, and garnet; they contain 48.3-58.6 SiO2 and 21.34–33.82 wt. %, Fe2O3T, suggesting that the rocks are BIF. BIF-1 of the KGB, as well as most Archean BIFs, contain high Fe2O3T, concentration, display a contrasting positive Eu anomaly, lost of Ce anomaly, the depletion of LREE relative to HREE. However, they stand out among other BIFs with high Al2O3, TiO2, MgO, K2O, Cr, Ni, Zr, Ba, Cu and Zn concentrations. BIF-1 was formed in a marine basin in an anoxic atmosphere due to hydrothermal fluids, the proportion of which varies from 20 to 80 %, and a terrigenous component derived mainly from basalts, komatiites, and dacites in host rocks. Mesoarchean BIF-1 of the KGB s was formed in a small rift within an oceanic volcanic plateau, the formation of which is associated with the influence of a mantle plume on the oceanic lithosphere.

Geology of the Eastern Barberton Greenstone Belt, South Africa: Early Deformation and the Role of Large Meteor Impacts

The eastern Barberton Greenstone Belt (BGB) includes four stratigraphic and structural divisions: from northwest to southeast, the Mlumati, Manzimnyama, and Paulus Synclines and the Emlembe Belt. All are made up largely of sedimentary rocks of the Fig Tree Group separated by antiformal belts of sheared Onverwacht Group komatiitic rocks. Fig Tree rocks in the Mlumati and Manzimnyama Synclines are mostly chemically precipitated banded iron formation (BIF) and banded ferruginous chert (BFC) with a major siliciclastic unit, the Gelegela Grit, composed of quartz-poor (<5% monocrystalline quartz, Qm) volcaniclastic sandstone showing abundant ~3.445–3.455 Ga detrital zircons. The Paulus Syncline is dominated by shale containing in the upper half chert-clast conglomerate and sparse lithic sandstone (Qm<10%) but includes near the middle lenticular units up to unit 30 m thick of quartz-rich (Qm >50%) sandstone. The Emlembe Belt consists largely of chert-clast conglomerate and quartz-bearing (Qm = 10–50%) sandstone. The Paulus and Emlembe belts show detrital zircon age peaks at ~3.295–3.275 Ga and ~3.445–3.455 Ga. While exhibiting overall similar stratigraphic development and detrital zircon ages, Fig Tree rocks in these belts show contrasting compositions and sediment sources. They do not represent parts a single basin or fairway of sediment transport and deposition. Fig Tree siliciclastic rocks mark the first deformation, uplift, and erosion in the BGB. However, the thinness of Fig Tree strata, mostly less than 1000 m, and rapid facies changes argue that deformation involved local uplifts and small basins that accumulated thin sedimentary sequences. We suggest that early Fig Tree deformation is consistent with crustal disruption triggered by large meteor impacts, starting perhaps as early as ~3.277 Ga but certainly by ~3.260 Ga. The Fig Tree Group may record a cluster of impacts that fragmented and destabilized a long-lived crust followed during later or post-Fig Tree time by tectonic uplift and orogeny.

A ~957 Ma Metamorphism in the Mesoarchaean Hindoli Group Supracrustal Rocks from the Jahazpur Shear Zone, East Rajasthan (India): Constraints from Sm-Nd Dating and Phase Equilibria Modeling

ABSTRACT A petrological-chronological investigation of the Hindoli Group of rocks within the Jahazpur Shear Zone in the eastern segment of the Aravalli Delhi Fold Belt (ADFB), NW India, has been conducted. We infer two stages of deformation (D1 and D2) and metamorphism (M1 and M2) for the garnet - muscovite - biotiteschists interleaved with meta dolomite, Banded Iron Formation (BIF) amphibolite, and foliated granite. The D2 deformation corresponds to the northeast-trending Jahazpur shear zone on a regional scale. Garnet porphyroblasts, syntectonic with the D2 deformation, are chemically zoned with spessartine-rich cores. Geothermobarometry and pseudosection analyses yield peak P-T conditions of ~7.5 kbar, 580°C, followed by decompression and cooling along a clockwise P-T path. The Sm-Nd isotope analysis of the whole rock yields a date of ~3.0 Ga from an amphibolite. This data is interpreted as the age of formation of the litho-units of the Hindoli Group. Sm-Nd analyses of garnet grains yield an age of ~957 Ma. This date corresponds with the age of nucleation of the Jahazpur shear zone. A good correlation is established between the Neoproterozoic crustal segments of the Jiangnan Fold Belt of the South China Craton and that of the ADFB during the formation of the Rodinia Supercontinent.

Deriving Flow Velocity and Initial Concentration From Liesegang‐Like Patterns

AbstractZebra rocks, characterized by their striking reddish‐brown stripes, rods, and spots of hematite (Fe‐oxide), showcase complex self‐organized patterns formed under far‐from‐equilibrium conditions. Despite their ease of recognition, the underlying mechanisms of pattern‐forming processes remain elusive. We introduce a novel advection‐dominated phase‐field model that effectively replicates the Liesegang‐like patterns observed in Zebra rocks. This numerical model leverages the concept of phase separation, a well‐established principle governing Liesegang phenomena in a two‐dimensional setting. Our findings reveal that initial solute concentration and fluid flow velocity are critical determinants in pattern morphologies. We quantitatively explain the spacing and width of a specific Liesegang‐like pattern category. Furthermore, the model demonstrates that vanishingly low initial concentrations promote the formation of oblique patterns, with inclination angles influenced by rock heterogeneity. Additionally, we establish a quantitative relationship between band thickness and geological parameters for orthogonal bands. This enables the characterization of critical geological parameters based solely on static patterns observed in Zebra rocks, providing valuable insights into their formation environments. The diverse patterns in Zebra rocks share similarities with morphologies observed on early Earth and Mars, such as banded iron formations and hematite spherules. Our model, therefore, offers a plausible explanation for the formation mechanisms of these patterns and presents a powerful tool for deciphering the geochemical environments of their origin.

Y-Ho fractionation during basalt alteration in hydrothermal system: An implication for superchondritic Y/Ho signature recorded in Precambrian banded iron formations

The concentration of rare earth elements (REE) in Precambrian sedimentary rocks is widely used to estimate their depositional environment. Specifically, superchondritic Y/Ho value is a powerful indicator for determining whether a sedimentary rock was deposited in a marine environment. Currently, superchondritic Y/Ho value in seawater is believed to result from the preferential adsorption of Y onto Fe-Mn oxides. In modern oceans, Fe-Mn oxides are considered the sink for subchondritic Y/Ho value. On the contrary, Precambrian banded iron formations (BIFs) display superchondritic Y/Ho value, suggesting that Precambrian seawater also possessed a superchondritic Y/Ho value. However, Precambrian BIFs cannot account for the sink of subchondritic Y/Ho value. Thus, other processes must have been responsible for maintaining the superchondritic Y/Ho value of Precambrian seawater. A hydrothermal experiment involving mid-ocean ridge basalt (MORB) and a Cl-rich fluid was conducted at 300 °C and 500 bars to assess the role of basalt-hosted hydrothermal systems on the Y/Ho value of seawater. Over time, the fluid's Ca concentration increased while Na decreased, suggesting plagioclase albitization occurred. The REE pattern of the reacted fluids exhibited superchondritic Y/Ho values up to 63.2. Based on the presence of positive Eu anomaly and the degree of light REE depletion, the REE in the hydrothermal fluids was mainly sourced from plagioclase during albitization. The superchondritic Y/Ho values in the fluids can be explained by the preferential leaching of these elements due to differences in chloride complexing strength between REE. Subchondritic Y/Ho values observed in Precambrian hydrothermally altered basalts may be interpreted as remnants generating superchondritic Y/Ho values in coexisting Precambrian hydrothermal fluids. Therefore, we believe that the superchondritic Y/Ho value of Precambrian seawater was maintained by basalt-hosted hydrothermal system.

Source and age of the Ngaye banded iron formations, Adamawa Yadé Domain, Central Cameroon: Constraints from whole-rock geochemistry and U-Pb zircon geochronology

The Ngaye inlier of the Adamawa Yadé Domain is located in the Central African Fold Belt, adjacent to the Nyong Complex at the northern margin of the Congo craton, in central Cameroon. This area consists of metamorphosed granite-greenstone associations comprising amphibole- and pyroxene-rich banded iron formations (BIFs), amphibolites, and migmatitic gneisses. This study reports detailed petrographic, whole-rock geochemical, and LA-ICP-MS U-Pb zircon data for the Ngaye BIFs and associated amphibolites to better constrain their source, tectonic setting, and age. Amphibole-rich BIFs exhibit high REE-Y content and uncommon LREE-enriched patterns. In contrast, pyroxene-rich BIFs display combined low REE-Y content, seawater-like patterns, and positive Eu anomalies, suggesting a mixture of seawater and hydrothermal fluids during their deposition. The geochemical data of associated amphibolites suggest a back-arc setting for the Ngaye metavolcanosedimentary sequence, similar to that of the Nyong Complex. LA-ICP-MS U-Pb zircon dating of amphibole-rich BIFs indicate a maximum depositional age of ca. 2186 Ma and subsequent metamorphism at ca. 2038 Ma, overlapping with that of metavolcanosedimentary sequences from the Nyong Complex. Neoproterozoic age of ca. 598 Ma obtained for these BIFs is interpreted as the Pan-African metamorphic/hydrothermal imprint. This finding suggests that the post-depositional fluid overprint was probably related to the regional Pan-African tectono-thermal event.

U-Pb zircon and Sm-Nd geochronology of the dom Silvério group, SE Brazil: Implications for the evolution of the superposed Araçuaí and Minas-Bahia orogens

The Araçuaí orogen, the South American portion of the Brasiliano/Pan-African Araçuaí-West Congo orogenic system (AWCO), formed during the Ediacaran-Cambrian assembly of West-Gondwana. The basement of a substantial portion of the Araçuaí orogen comprises Archean and Paleoproterozoic rocks involved in the 2.1–2.0 Ga Minas-Bahia orogen. The Dom Silvério Group, which consists of mica schists containing layers and lenses of mafic, ultramafic, and Mn-rich rocks, as well as quartzites, graphite schists, marbles, and banded iron formations, defines a ca. 10 km-wide and 150 km-long belt in the southwestern portion of the Araçuaí orogen. This succession, currently interpreted as deep marine deposits or an ocean-floor assemblage of uncertain age - Paleoproterozoic or Neoproterozoic-, potentially records processes involved in critical evolutionary stages of the superposed Minas-Bahia and Araçuaí orogens. Aiming to characterize the age and tectonic significance of the Dom Silvério Group, we performed a geochronological and geochemical investigation on samples collected from selected lithotypes. U-Pb (LA-ICP-MS) determinations on detrital zircons revealed two distinct age spectra. Zircons extracted from the lower Dom Silvério schists define a spectrum characterized predominantly by Neoproterozoic age clusters with a maximum depositional age of 601 ± 10 Ma. Quartzites from the lower and upper sections of the group do not contain zircons younger than 1.9 Ga and show unimodal age distributions around 2067 Ma. The maximum depositional age estimated for these rocks is 2020 ± 6 Ma. The spectrum of the lower section schist indicates the turbidites of the Ediacaran Salinas Formation as their most probable correlative. In contrast, the quartzites and schists of lower and upper sections correlate with the Orosirian Itacolomi Group, the post-collisional assembly of the Minas-Bahia orogen. Sm-Nd isotope analyses and whole-rock geochemistry allow the discrimination of two generations of mafic rocks. The older generation, showing TDM model ages = 1.92 to 3.6 Ga and ƐNd(t) = -12.93 to +4.63, represents components of the basement. The younger generation, with TDM model ages = 1.0 Ga to 1.25 Ga and ƐNd(t) = +0.05 to +2.29, is similar to the ophiolitic rocks that occur imbricated with Ediacaran metasedimentary successions in the central portion of the Araçuaí orogen defining the Ribeirão da Folha accretionary belt. They show Th/Yb and Nb/Yb ratios of the EMORB-OIB mantle array and Nb/Y and Zr/Y ratios compatible with OIB and oceanic plateau basalts. The Dom Silvério Group is thus a complex that involves members of the Araçuaí and Minas-Bahia orogens. Their Ediacaran components materialize the southern extension of the Ribeirão da Folha accretionary wedge and, as such, provide further evidence for oceanic consumption during the development of the southern Araçuaí orogen.

Determination of the banded iron formation sources in the Lanling area of Western Shandong of the North China Craton through rare earth element testing

Determination of the banded iron formation sources in the Lanling area of Western Shandong of the North China Craton through rare earth element testing

Snapshot of a Paleoarchean seafloor: Evidence from 3.43-3.35 Ga Strelley Pool chert-pebble conglomerate for deposition, silicification, and erosion of hydrothermal greenalite-apatite precipitates

Some of the oldest, well-preserved exhalative sedimentary rocks (ferruginous cherts and jaspilites) occur in volcanic-dominated Paleoarchean sequences in the northern Pilbara Craton, Australia. Jaspilites contain fine-grained hematite particles that have been interpreted to have formed following seawater oxidation of vent-derived Fe2+(aq) by photoautotrophs. However, recent studies suggest that most of the iron in the jaspilites was originally deposited as Fe(II)-rich silicates such as greenalite, sparking renewed debate about how iron was precipitated in the early oceans. Here we show that rounded clasts of dusty ferruginous chert in basal conglomerates of the 3.43–3.35 Ga Strelley Pool Formation, North Pole Dome, Pilbara Craton, Australia, contain abundant nanoparticles of greenalite and apatite that are texturally, mineralogically and chemically near-identical to occurrences in Neoarchean banded iron formations in the Hamersley Group, Australia. Hematite where present occurs in trace amounts and its distribution along the edges of clasts implies that at least some of the hematite formed during weathering. The greenalite-rich clasts display a pronounced positive shale-normalized Eu anomaly, small positive Y anomaly and lack a positive La anomaly, features typical of Paleoarchean exhalites. The co-occurrence of greenalite- and apatite-rich chert-pebbles with clasts of hydrothermal black chert and silicified felsic volcaniclastic sedimentary rocks points to a volcanically active provenance with vigorous hydrothermal activity, consistent with derivation from the underlying 3.43 Ga Panorama Formation. We argue that the greenalite and apatite nanoparticles precipitated during mixing between hydrothermal vent fluids and anoxic seawater and were silicified on the seafloor. The round to oval shape of the chert clasts indicates that the silica cement had recrystallized prior to erosion, consistent with the presence of polygonal shrinkage structures in the dusty chert clasts. Our findings imply that greenalite, contrary to recent suggestions, not only formed in Paleoarchean seawater, but was also stable during deposition, diagenesis, and resedimentation. The precipitation and non-dissolution of apatite nanoparticles in Paleoarchean seawater points to elevated phosphate concentrations, whereas the absence of primary hematite is consistent with models advocating a role for abiotic iron deposition during the Archean.

A billion-year shift in the formation of Earth’s largest ore deposits

Banded iron formations (BIFs) archive the relationship between Earth's lithosphere, hydrosphere, and atmosphere through time. However, constraints on the origin of Earth's largest ore deposits, hosted by BIFs, are limited by the absence of direct geochronology. Without this temporal context, genetic models cannot be correlated with tectono-thermal and atmospheric drivers responsible for BIF upgrading through time. Utilizing in situ iron oxide U-Pb geochronology, we provide a direct timeline of events tracing development of all the giant BIF-hosted hematite deposits of the Hamersley Province (Pilbara Craton, Western Australia). Direct dating demonstrates that the major iron ore deposits in the region formed during 1.4 to 1.1 Ga. This is one billion to hundreds of millions of years later than previous age constraints based upon 1) the presence of hematite ore clasts in conglomerate beds deposited before ~1.84 Ga, and 2) phosphate mineral dating, which placed the onset of iron mineralization in the Province at ~2.2 to 2.0 Ga during the great oxidation event. Dating of the hematite clasts verified the occurrence of a ~2.2 to 2.0 Ga event, reflecting widespread, but now largely eroded iron mineralization occurring when the Pilbara and Kaapvaal cratons were proximal. No existing phosphate mineral dates overlap with obtained hematite dates and therefore cannot be related to hematite crystallization and ore formation. New geochronology conclusively links all major preserved hematite deposits to a far younger (1.4 to 1.1 Ga) formation period, correlated with the amalgamation of Australia following breakup of the Columbia supercontinent.

A case-history using gravity data to validate alternate interpretations of the material below a deep seismic reflector in the Matheson area of Ontario, Canada

Gravity data are ‘nonunique’ in that a gravity anomaly can be explained by many bodies with different properties. Similarly, in seismic data, the strength of a reflection is dependent on the product of the density and the seismic velocity, so the nature of a reflection cannot be used to determine the density below an interface when the velocity is unknown. In a previous gravity study, we had concentrated on shallow features (model α), which implicitly assumed that a number of deeper reflections were due to an anomalous layer, thick enough to cause reflections from its upper and lower surfaces that do not cancel and that the density above and below this thick layer were the same. An alternate possibility is that the material below some of the reflections is lower density material called the Deloro assemblage. In order to test this hypothesized model (model β), we reinterpreted the seismic sections and repeated the gravity study. In order to allow for the deeper low-density material and account for some shallower reflectors having Deloro below, we had to make the Porcupine assemblage, which is shallow and even lower density than the Deloro, thinner in places. We found that the gravity data could be explained with the Deloro assemblage below the reflectors. The top of this hypothesized Deloro assemblage varies from 7.5 km in the east to 3 km in the west of the study area. Both models and are consistent with the gravity and seismic data, but model is also consistent with the Deloro being mapped outcropping to the west of the study area and a strong reflector (a banded iron formation) often being observed at the top of the Deloro. Our case study illustrates that modelling and interpretation should often be revised when new information becomes known.

Coexistence of Algoma- and Superior-type BIFs in back-arc systems: Evidence from Xincai, North China Craton

Superior-type and Algoma-type banded iron formations (BIFs) generally developed in distinct tectonic environments and have unique geological characteristics. Superior-type BIFs were deposited on passive continental shelves or intracratonic basins and are laterally extensive, whereas Algoma-type BIFs were formed near volcanic arcs and spreading centers. Here, we present a case where late Archean (∼2.5 Ga) Superior- and Algoma-type BIFs co-developed in a back-arc setting at Xincai, along the southern margin of the North China Craton. The Algoma-type BIFs at Xincai exhibit high Ge/Si ratios (4.84 to 8.84) and a broad range of εNd(t) values (−7.2 to +1.2). These geochemical signatures, along with similar εNd(t) values (+1.2) in contemporaneous amphibolites, indicate a significant influence of hydrothermal fluids associated with submarine volcanism. In contrast, the Superior-type BIFs at Xincai are characterized by positive La anomalies, low Ge/Si ratios (0.21 to 4.60) and narrow range of εNd(t) values (−6.1 to −1.0) suggesting a major contribution from terrigenous sources. The coexistence of Algoma- and Superior-type BIF types at Xincai is related to the interplay of multiple fluid systems in a back-arc environment. The Algoma-type BIFs formed from the confluence of hydrothermal fluids originating from enriched subcontinental lithospheric mantle (high Ge/Si and low εNd(t)) with those emanating from the adjacent back-arc spreading centers (depleted mantle like—high Ge/Si and εNd(t)). On the other hand, the Superior-type BIFs formed near the continental margins of the back-arc basins, where surface seawater carrying terrigenous substances (low Ge/Si and εNd(t)) mixed with hydrothermal fluids from the back-arc spreading centers. The distinct co-existence of Algoma- and Superior-type BIFs at Xincai underscores the dynamic nature of back-arc environments as crucibles for diverse BIF mineralization processes, offering new perspectives on the contributions of submarine volcanic activity and terrigenous inputs to the BIFs.

Recycling and reuse of waste banded iron formation as fine aggregate in the production of lightweight foamed concrete: Fresh-state, mechanical, thermal, microstructure and durability properties assessment

This study investigates the possibility of using BIFs as sustainable fine aggregates to produce lightweight foam concrete (LWFC) by replacing sand with 5, 10, 15, 20, and 25 % banded iron formations (BIFs). The fresh concrete properties, such as slump flow, density, and setting time, as well as its mechanical properties, including compressive strength, splitting strength, and flexural strength, were investigated. The thermal conductivity, specific heat, porosity, gas permeability, pore distribution, and sorptivity were measured to determine durability and thermal performance. Microstructural analysis of the mixes was performed using SEM, energy-dispersive X-ray spectroscopy (EDX), and mapping. The results recommended a 10 % replacement ratio to achieve an increased compressive strength ratio of 55.88 % compared to the control mix at 7 days (d). The strength at later ages increased compared to that of the control mix by 33.9 %, 30 %, 42.48 %, and 42.4 % at 14, 28, 56, and 180 d, respectively. In addition, the flexure increased by 42.7 % at 7 d, 49.6 % at 14 d, and 45.6 % at 28 d compared to the control mix. In addition, the UPV also increased gradually from 2757 to 3699 km/s with increase in BIFs content. Furthermore, the porosity decreased at 7 d, 14 d, 28 d, and 90 d. Moreover, chloride penetration decreased by 2.5 %, where an improvement in thermal conductivity was achieved with BIFs to 0.342 W/mK compared to that of the control mix. In addition, a reduction in the specific heat of the material from 1042 J/kg K to 1007 J/kg K was observed. SEM showed a better arrangement of pores when BIFs were utilized compared with that of control mix without BIFs. In conclusion, the incorporation of waste BIFs as fine aggregates in lightweight foam concrete demonstrates a promising potential for enhancing the mechanical and thermal properties of construction materials, paving the way for durable building materials in the construction industry.