Back Reflector Design Research Articles

Nanomolded buried light-scattering (BLiS) back-reflectors using dielectric nanoparticles for light harvesting in thin-film silicon solar cells

The article presents a nanoparticle-based buried light-scattering (BLiS) back-reflector design realized through a simplified nanofabrication technique for the purpose of light-management in solar cells. The BLiS structure consists of a flat silver back-reflector with an overlying light-scattering bilayer which is made of a TiO2 dielectric nanoparticles layer with micron-sized inverted pyramidal cavities, buried under a flat-topped silicon nanoparticles layer. The optical properties of this BLiS back-reflector show high broadband and wide angular distribution of diffuse light-scattering. The efficient light-scattering by the buried inverted pyramid back-reflector is shown to effectively improve the short-circuit-current density and efficiency of the overlying n-i-p amorphous silicon solar cells up to 14% and 17.5%, respectively, compared to the reference flat solar cells. A layer of TiO2 nanoparticles with exposed inverted pyramid microstructures shows equivalent light scattering but poor fill factors in the solar cells, indicating that the overlying smooth growth interface in the BLiS back-reflector helps to maintain a good fill factor. The study demonstrates the advantage of spatial separation of the light-trapping and the semiconductor growth layers in the photovoltaic back-reflector without sacrificing the optical benefit.

Silver versus white sheet as a back reflector for microcrystalline silicon solar cells deposited on LPCVD‐ZnO electrodes of various textures

AbstractWe compare the performance of two back reflector designs on the optoelectrical properties of microcrystalline silicon solar cells. The first one consists of a 5‐µm‐thick low‐pressure chemical vapor deposition (LPCVD)‐ZnO electrode combined with a white sheet; the second one incorporates an Ag reflector deposited on a thin LPCVD‐ZnO layer (with thickness below 200 nm). For this latter design, the optical loss in the nano‐rough Ag reflector can be strongly reduced by smoothing the surface of the thin underlying ZnO layer, by means of an Ar‐plasma treatment. Because of its superior lateral conductivity, the thin‐ZnO/Ag back reflector design provides a higher fill factor than the dielectric back reflector design. When decreasing the roughness of the front electrode with respect to our standard front LPCVD‐ZnO layer, the electrical cell performance is improved; in addition, the implementation of the thin‐ZnO/Ag back reflector leads to a significant relative gain in light trapping. Applying this newly optimized combination of front and back electrodes, the conversion efficiency is improved from 8.9% up to 9.4%, for cells with an active‐layer thickness of only 1.1 µm. We thereby highlight the necessity to optimize simultaneously the front and back electrodes. Copyright © 2014 John Wiley & Sons, Ltd.

Back-reflector design in thin-film silicon solar cells by rigorous 3D light propagation modeling

Purpose – The purpose of this paper is to find an optimized thin-film amorphous silicon solar cell design by numerically optimizing the light trapping efficiency of a pyramid-structured back-reflector using a frequency-domain finite element Maxwell solver. For this purpose short circuit current densities and absorption spectra within the investigated solar cell model are systematically analyzed. Furthermore, the authors employ a topology simulation method to accurately predict the material layer interfaces within the investigated solar cell model. The method simulates the chemical vapor deposition (CVD) process that is typically used to fabricate thin-film solar cells by combining a ballistic transport and reaction model (BTRM) with a level-set method in an iterative approach. Predicted solar cell models are far more realistic compared to solar cell models created assuming conformal material growth. The purpose of the topology simulation method is to increase the accuracy of thin-film solar cell models in order to facilitate highly accurate simulation results in solar cell design optimizations. Design/methodology/approach – The authors perform numeric optimizations using a frequency domain finite element Maxwell solver. Topology simulations are carried out using a BTRM combined with a level-set method in an iterative fashion. Findings – The simulation results reveal that the employed pyramid structured back-reflectors effectively increase the light path in the absorber mainly by exciting photonic waveguide modes. In using the optimization approach, the authors have identified solar cell models with cell periodicities around 480 nm and pyramid base widths around 450 nm to yield the highest short circuit current densities. Compared to equivalent solar cell models with flat back-reflectors, computed short circuit current densities are significantly increased. Furthermore, the paper finds that the solar cell models computed using the topology simulation approach represent a far more realistic approximation to a real solar cell stack compared to solar cell models computed by a conformal material growth assumption. Research limitations/implications – So far in the topology simulation approach the authors assume CVD as the material deposition process for all material layers. However, during the fabrication process sputtering (i.e. physical vapor deposition) will be employed for the Al:ZnO and ITO layers. In the framework of this ongoing research project the authors will extend the topology simulation approach to take the different material deposition processes into account. The differences in predicted material interfaces will presumably be only minor compared to the results shown here and certainly be insignificant relative to the differences the authors observe for solar cell models computed assuming conformal material growth. Originality/value – The authors systematically investigate and optimize the light trapping efficiency of a pyramid nano-structured back-reflector using rigorous electromagnetic field computations with a 3D finite element Maxwell solver. To the authors’ knowledge such an investigation has not been carried out yet in the solar cell research literature. The topology simulation approach (to the best of the authors’ knowledge) has previously not been applied to the modelling of solar cells. Typically a conformal layer growth assumption is used instead.

The role of oxide interlayers in back reflector configurations for amorphous silicon solar cells

Thin oxide interlayers are commonly added to the back reflector of thin-film silicon solar cells to increase their current. To gain more insight in the enhancement mechanism, we tested different back reflector designs consisting of aluminium-doped zinc oxide (ZnO:Al) and/or hydrogenated silicon oxide (SiOx:H) interlayers with different metals (silver, aluminium, and chromium) in standard p-i-n a-Si:H solar cells. We use a unique inverse modeling approach to show that in most back reflectors the internal metal reflectance is lower than expected theoretically. However, the metal reflectance is increased by the addition of an oxide interlayer. Our experiments demonstrate that SiOx:H forms an interesting alternative interlayer because unlike the more commonly used ZnO:Al it can be deposited by plasma-enhanced chemical vapour deposition and it does not reduce the fill factor. The largest efficiency enhancement is obtained with a double interlayer of SiOx:H and ZnO:Al.

Investigation of the impact of the rear-dielectric/silver back reflector design on the optical performance of thin-film silicon solar cells by means of detached reflectors

Thin-film silicon solar cells often rely on a metal back reflector separated from the silicon layers by a thin rear dielectric as a back reflector (BR) design. In this work, we aim to obtain a better insight into the influence of the rear-dielectric/Ag BR design on the optical performance of hydrogenated microcrystalline silicon (µc-Si:H) solar cells. To allow the application of a large variety of rear dielectrics combined with Ag BRs of diverse topographies, the solar cell is equipped with a local electrical contact scheme that enables the use of non-conductive rear dielectrics such as air or transparent liquids of various refractive indices n. With this approach, detached Ag BRs having the desire surface texture can be placed behind the same solar cell, yielding a direct and precise evaluation of their impact on the optical cell performance. The experiments show that both the external quantum efficiency and the device absorptance are improved with decreasing n and increasing roughness of the BR. Calculations of the angular intensity distribution of the scattered light in the µc-Si:H are presented. They allow for establishing a consistent picture of the light trapping in the solar cell. Copyright © 2013 John Wiley & Sons, Ltd.

Study of detached back reflector designs for thin‐film silicon solar cells

AbstractWe present a precise and flexible method to investigate the impact of diverse detached reflector designs on the optical response of p–i–n thin‐film silicon solar cells. In this study, the term detached reflectors refers to back reflectors that are separated from the silicon layers by an intermediate rear dielectric of several micrometers. Based on the utilization of a highly conductive n‐doped layer and a local electrical contact scheme, the method allows the use of non‐conductive rear dielectrics such as air or transparent liquids. With this approach, diverse combinations of back reflector and rear dielectric can be placed behind the same solar cell, providing a direct evaluation of their impact on the device performance. We demonstrate the positive effect of a rear dielectric of low refractive index on the light trapping and compare the performance of solar cells with an air/Ag and a standard ZnO/Ag back reflector design. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Study of thin-film silicon solar cell back reflectors and potential of detached reflectors

Abstract The back reflector of thin-film silicon solar cells often consists of a textured metal surface separated from the silicon layers by a thin dielectric layer (e.g. ZnO). Despite the high reflectivity of the textured ZnO/Ag back reflector, parasitic absorption losses exist in both the ZnO and Ag layers. In order to better understand the origin of the optical losses at the rear side of thin-film silicon solar cells and study the potential of alternative back reflector designs, a new method is introduced. This method is based on the utilization of a highly conductive n-layer and a local electrical contacting scheme allowing the use of nonconductive rear dielectric layers or media. In this contribution, the cell absorption and the quantum efficiency of microcrystalline p-i-n solar cells with ZnO/Ag and SiO 2 /Ag back reflectors as well as with a textured Ag back reflector separated from the n-layer by an air gap of a few micrometers are compared.

Compact high‐efficiency nonimaging back reflector design for filament light sources

When filament light sources are used in nonimaging luminaires that are intended to ensure prescribed angular control and high optical efficiency, a 3-D back reflector must often be incorporated, so as to redirect rays emitted by the filaments that would otherwise miss the luminaire entrance aperture. The glass envelope precludes the filaments from filling the luminaire entrance aperture. The introduction of a back reflector can serve to create a virtual light source, away from the actual grid of filaments, which mitigates the problem. The back reflector should be compact, with high radiative efficiency, namely, a small number of reflections while accommodating all rays. We develop a new nonimaging back reflector design comprised of multiple rotated elliptical arcs in a rotationally symmetric device that is a good compromise.