Average Mercury Concentration Research Articles

Soil and Urine Mercury Levels in Secocha: A Case Study of Artisanal and Small-Scale Gold Mining in Peru

In recent decades, artisanal and small-scale gold mining (ASGM) has spurred population and economic growth in the small rural communities in which it is located, along with causing contamination of the soil, air, and water with grave effects on human health due to the uncontrolled use of mercury for gold processing activities. This study analyzes the levels of mercury in Secocha, an ASGM community in Arequipa, Peru. A total of 44 soil samples were taken from two ASGM commercial-extractive zones (n = 18) and non-processing urban zones (n = 26). Soil mercury analysis with atomic absorption spectrometry revealed average mercury levels of 86.11 mg/kg in commercial-extractive zone I, where ore processing has occurred for about 17 years, and mercury levels of 43.81 mg/kg in commercial-extractive zone II, where processing has occurred for about 7 years. In the urban zone, the average mercury level was 9.53 mg/kg. The average mercury concentrations for each zone exceed the relevant environmental quality standards established by the Peruvian Ministry of the Environment. In addition, urine samples were obtained from 15 miners and 15 people from the general urban population (non-miners). The average mercury level in the urine of miners was 7.04 µg/L, and in the urine of non-miners it was 0.49 µg/L. In both cases, the mercury urine level did not exceed the limits established by WHO and the Peruvian Ministry of Health, though miners’ elevated levels do raise concerns.

Measuring Total Mercury Level in Local Food Fish Bangamary (Macrodon ancylodon) in Guyana

This research conducted in 2019 at the University of Guyana investigated the content of methylmercury in local food fish Macrodon ancylodon locally known as Bangamary. A total of 24 samples of M. ancylodon was purchased from the Meadow Bank Wharf in Guyana for analysis of total mercury level. Additionally, the size frequency at which mercury concentration is the highest was also evaluated. The results indicated that total mercury concentration in each sample of M. ancylodon was less than 0.5 mg/kg. With an average total mercury content of 0.10 mg/kg, adults had the greatest total mercury content, followed by juveniles (0.06 mg/kg) and young (0.02 mg/kg). This may be attributed to the carnivorous diet of M. ancylodon and the fact that the fish species is usually captured in the estuarine regions of the Demerara and Essequibo Rivers. These waterways are linked to mining areas in Guyana's interior region that discharge mercury contaminated water, which could be the reason why mercury is bioaccumulating in the tissue of the Bangamary.

Potential Bioabsorbent Extract of Skin and Leaves Ananas Comosus on reduction of Copper, Mercury, and Lead in Anadara granosa

Kenjeran sea waters were polluted by several types of heavy metals such as copper (0.015mg/L), lead (0, 0036 mg/L), and mercury (0.001mg/L). Consuming Anadara granosa containing heavy metals exceeding the standard is very dangerous. The purpose of this study was to determine the effect of pineapple leaf and peel extract on reducing levels of copper, lead, and mercury in Anadara granosa in Kenjeran. Methods: Treatment without giving pineapple leaf and peel extract (Control) and treatment with pineapple leaf and peel extract using 0% and 3% concentrations. The results of heavy metal levels were in the form of numbers indicating the content of heavy metal levels in Anadara granosa determined in mg/kg using AAS. Results: The average copper concentration of 0% was 5.037mg/kg, and the 3% concentration was 2.563mg/kg, the average lead concentration at 0% concentration was 2.4333mg/kg and the concentration of 3% is 1.4433mg/kg, the average mercury concentration of 0% is 0.963mg/kg, and the concentration of 3% is 0.323mg/kg (4) Conclusion: there is an effect of pineapple peel and leaf extract on the decrease in copper levels by 50.88%, lead levels by 59%, and 33.54% decrease in mercury levels.

Mercury in the feathers of Golden eagle (Aquila chrysaetos) from Western Carpathian, Slovakia

In this study, mercury (Hg) concentrations were detected in feathers of golden eagle (Aquila chrysaetos), a bird that typically inhabits alpine and forest areas. The mercury rates in feathers were compared in two groups of eagles: first, estimated home range (breeding, hunting, etc.) was located only in forest and lowland meadow habitats; second, the home range also included alpine habitats—rocks and meadows. Consequently, mercury concentration based on the feather typology were observed and the mercury levels in feathers were also compared among different Slovak Western Carpathian districts. It was found that there was no significant difference between groups classified by elevation level, which we attribute to the fact that eagle hunting territories are broad, so that alpine-dwelling and forest-dwelling eagles do not only reflect the pollution of the environments they typically inhabit. Non-significant differences were found also within different feather types, which means that the type of feather is not crucial for tracking mercury in eagle feathers. As the measurement of feather appears to be a simple and non-invasive method, the detection of non-significant differences in diverse types of golden eagle feathers provides useful knowledge for the future environment monitoring. The average mercury concentration measured in eagle samples was lower than the mercury concentration causing health complications among birds of prey. Our assumption that due to past mining activity in the Spiš region, the highest concentration in this region would be observed was confirmed.

Assessment of Soil Pollution by Heavy Metals in the Market Gardening Areas of Korsimoro

The aim of this study was to assess heavy metal soil pollution in market garden areas in the commune of Korsimoro. The analysis focused mainly on zinc (Zn), nickel (Ni), chromium (Cr), copper (Cu), lead (Pb), cadmium (Cd), cobalt (Co), arsenic (As) and mercury (Hg). Composite samples of soil labels s1 to s21 were taken from the market garden site around the dam at a depth of 0-20 cm. A total of 21 soil samples were taken. The soil samples were analysed using inductively coupled plasma mass spectrometry (ICP/MS) at the Bureau of Mines and Geology of Burkina Faso laboratory (BUMIGEB).
 The enrichment factor (EF), contamination factor (CF), géoaccumulation index (Igeo) and pollution load index (PLI) were determined from the metal concentrations obtained.
 The average concentrations of heavy metals vary as follows:
 Cd > Co > Cr > Zn > Ni > Cu > Hg > Pb > As.
 The average concentrations of cadmium (587.039mg/kg±20.546), mercury (29.048mg/kg±20,647), nickel (60.037 mg/kg±14,615) and cobalt (575.956mg/kg±66,693) exceed the WHO limit values for agricultural soils.
 The calculated CF values show very high contamination of Co, Cd and Hg, considerable contamination of Cu, Cr, Zn, Ni and As, and no contamination of Pb.
 The EF values show very severe enrichment for cobalt (Co), followed by overall extremely severe enrichment for cadmium (Cd) and mercury (Hg).
 The calculated Igeo indicates extreme cadmium, mercury and cobalt contamination.
 The calculated PLI values are all greater than one. These results show that all the soils are polluted.
 The index determination approach makes it possible to predict the extent of soil pollution by the heavy metals considered in our study.

In Search of Mercury Lost from Sediments in a Previously Contaminated Coastal Area, Harboøre Tange, Denmark

Concentrations of mercury in sediment and benthic invertebrate fauna of Nissum Broad, North-western Jutland, Denmark were investigated. The western coast of Nissum Broad is Harboøre Tange, along which heavy mercury contamination - caused by discharge from production of mercury containing seed dressers in the 1950 and 1960s – was documented in the 1980s. Recent investigations showed marked decreases in mercury contamination in the near shore sediments along Harboøre Tange since the 1980s and the present investigation was initiated to learn if the loss of mercury from Harboøre Tange had led to an increased mercury contamination in the neighbouring marine area, Nissum Broad. Mercury concentrations in the surface sediment correlated with the content of organic matter and the slope of the regression is a good indicator for the degree of mercury contamination. Average mercury concentrations in the upper 5 cm of the sediments ranged between 0.9 and 71 ng g− 1 dry weight (dw) with only 1 station exceeding the Background Assessment Concentration of 70 ng g− 1 dw. Average mercury concentrations in blue mussels Mytilus edulis (169–260 ng g− 1 dw) and periwinkles Littorina littorea (66–203 ng g− 1 dw) exceeded those in uncontaminated areas and the Environmental Quality Standard of approximately 100 ng g− 1 dw. Present sediment mercury concentrations in Nissum Broad are approximately half of what they were in the 1980s, rendering it unlikely that mercury lost from Harboøre Tange has been deposited there. Sediment and organism concentrations did not show any correlation.

Small mammals as a bioindicator of mercury in a biodiversity hotspot – The Hengduan Mountains, China

Due to toxicities, capacities for long-range transportation, bioaccumulation, and biomagnification, mercury (Hg) presents a unique concern to wildlife in remote ecosystems, including “the roof of the world”. Large carnivorous predators are thought to be exposed to elevated Hg due to their high trophic positions, but the direct assessment for Hg contamination is a challenge. Given the poorly understood Hg exposure in these carnivores, establishing a reliable and straightforward assessment would be essential to identify targeted species at Hg exposure risk for effective conservation, particularly in fragile biodiversity hotspots. Small mammals are abundant and serve as prey for large top predators. Combined with local observations, we provided an assessment to estimate the daily Hg exposure via consumption of small mammals for large carnivorous mammals recorded in the Hengduan Mountains, a world biodiversity hotspot, China. Within an altitude span from 2043 to 4251 m a.s.l., the average topsoil total mercury concentration (hereafter [THg]) was 44.65 ± 25.80 μg/kg (mean ± sd; 10.54 – 135.15 μg/kg, n = 41), while the hair [THg] in small mammals was 104.66 ± 91.96 μg/kg (mean ± sd; 7.73 to 385.70 μg/kg, n = 13). Furthermore, the daily intake of Hg was calculated among the 22 investigated/historical-recorded carnivore mammals belonging to 5 families. We found a large variance in daily intake of Hg via small mammals: Felidae (median: 205.93 μg/day) > Ursidae (135.02 μg/day) > Canidae (92.92 μg/day) > Viverridae (19.88 μg/day) > Mustelidae (7.18 μg/day). Specifically, Tiger Panthera tigris was found with the highest Hg daily intake (1701.39 μg/day) via consuming small mammals, while species belonging to Mustelidae generally have low Hg daily intake (<3 μg/day). This study provides a feasible approach to identifying species at environmental Hg risk in this fragile remote high-elevation region. The limitations and future improvements were discussed.

Effects of Age, Fulton's Condition Index (K) and Muscle Fat on Total Mercury Content in Raw, Pre-Canning and Canned Samples of Atlantic Bluefin Tuna (Thunnus thynnus).

A total of 30 samples of Atlantic bluefin tuna were analysed for total mercury concentration. Relationships between total mercury content and age, Fulton's condition index (K) and fat content were statistically evaluated. The effect of muscle status (raw, pre-canning, canned) on mercury content was also investigated. The average total mercury content was: 1.185 ± 0.662 mg/kg in raw, 1.481 ± 0.893 mg/kg in pre-canning and 1.393 ± 0.882 mg/kg in canned samples, respectively. Canning promotes a statistically significant increase in the concentration of mercury. The weight of fish, K and fat content are useful tools to estimate the mercury accumulation in Atlantic bluefin tuna. The results of the present study represent a contribution to the assessment of the EU mercury levels in Atlantic bluefin tuna.

МОНИТОРИНГ ФОНОВОГО СОДЕРЖАНИЯ РТУТИ В БИОСИСТЕМЕ И ОРГАНИЗМЕ ДЕТСКОГО НАСЕЛЕНИЯ НИЖНЕГО ТЕЧЕНИЯ РЕКИ АМУР

Study Objective: to determine the mercury content in the body of children as well as in soil and river fish to assess the level of risk of adverse effects on a human body. Study Design: analytical observational, cross-sectional study. Materials and Methods. A quantitative analysis of mercury in hair of conditionally healthy children (n=62), the upper layer of soil (n=15) taken on the territory of the former cellulose and cardboard manufacturing plant (CCMP) located in one of the cities of the Khabarovsk region and in fish (n=27) living in the Amur river downstream was performed using inductively coupled plasma mass spectrometry. The relationship between the level of mercury and cognitive abilities of adolescents was studied. Study Results. An average content of mercury in the upper layer of the soil was 0.85 mg/kg; with the maximum value of the mass fraction of mercury 1.25 mg/kg, the mercury concentration was 8.5-12.5 times higher than the Russian background value. When determining the concentration of mercury in the fish muscle tissue – the main source of organic mercury for children, it was revealed that the content of mercury in the tissues of predatory fish ranged from 0.47-0.52 mg/kg, while the mercury level in non-predatory fish was 0.24 mg/kg. The average mercury content in hair of adolescence was 0.47±0.05 mg/kg and 0.19±0.02 mg/kg in 6-7-year-old children, and it did not exceed the critical level. Conclusion. It was found out that the content of mercury in the soil had significantly decreased compared to 2009, but the level remains above the Russian background value. Mercury content in part of the fish muscle living in the Amur River downstream was higher in predatory species. The concentration of mercury in the children organism permanently living on the territory of anthropogenic pollution did not exceed the threshold level, but the detected background values may have contributed to concentration decrease.

Distribution of Mercury in Drained Peatlands as the Effect of Secondary Transformation of Soil Organic Matter

Peat organic soils play a major role in the accumulation of soil organic matter (SOM) and the mercury (Hg) cycle. Large mercury resources in peatlands can be a source of methylmercury for many decades and centuries, even if deposition is significantly reduced. The organic matter of peatland soils drained for agricultural use is subject to secondary transformation, which may affect the accumulation and resources of mercury. The aim of our work is to assess the secondary transformation of organic matter in the soils of drained peatlands of the temperate climate zone and to examine whether it affects mercury resources and profile distribution in organic soils. Field research was conducted in peatlands located in eastern Poland. In the present study, evaluation of secondary transformations occurring after drainage was based on observations of soil morphological characteristics, physical and chemical properties as well as fractional composition of organic matter of the identified soil horizons (to depth 70 cm). Standard cold vapor atomic absorption spectrometry (CV-AAS) was used to measure the total mercury content. In our research, we found a significant effect of the secondary transformation of organic matter occurring in drained peatlands of the temperate climate zone on the total mercury content and stock in soils. The highest content and differentiation of mercury occurred in murshic horizons (up to a maximum depth of 43 cm). The average mercury content of the distinguished soil horizons is grouped in the following series (in μg kg−1): M1 (212.0) &gt; M2 (182.8) &gt; M3 (126.3) &gt; Pt (84.9). The mercury stock, up to a depth of 70 cm in the tested soils, ranged from 17.5 to 39.6 mg m−2. As much as 82.2% of soil mercury was found in the upper murshic horizons. We found strong correlations between soil properties characteristically variable in the secondary transformation process and total mercury content. The increased content of humic substances in murshic horizons caused a significant increase in the total mercury content. Our research is of great importance for soil monitoring, as the amount of determined mercury was greatly influenced by the depth of sampling (up to 25 cm). The results of the research should be taken into account when planning the restoration of peatlands of the temperate climate zone. There is a potential risk that elevated mercury concentrations in the upper murshic horizons may be a source of methylmercury for a long period of time. In peat soils with a high concentration of mercury, the risk of contamination with this toxic metal should be determined before re-irrigation.

Enrichment of Sulfate, Acidity and Mercury in Native outcropcoal, Southwest China.

The coal found in the Longtan Formation of the Late Permian is widely distributed in Southwest China, including the northwestern Guizhou, southeastern Sichuan, and northern Yunnan regions. This coal typically has a high sulfur content. Eighty-two coal samples were collected from the coal strata in 11 counties spanning this area, including underground mine coal, native outcrop coal and man-made outcrop coal. The mercury, total fluorine, total sulfur, and sulfate contents and pH values were determined. The results showed that the average mercury content in native outcrop coal was 2233ng/g, whereas that in underground mine coal was 306ng/g, and the relative enrichment factor could reach 6.6. There was no significant difference in the total fluorine content among the three types of coals; furthermore, the total sulfur content in native outcrop coal and man-made outcrop coal was higher than that in underground mine coal because of the local policy, which strictly prohibits the mining of high-sulfur coal. Native outcrop coal is acidic, with a total average pH of 3.54 and an average sulfate content as high as 13,390μg/g. In contrast, underground coal is almost neutral (average pH 7.33), with a low sulfate content (average 3221μg/g). These characterizations indicate that native outcrop coal has been subjected to long-term weathering and the mercury enrichment is likely due to migration, oxidation, and precipitation of Hg from the underground coal seam and enriched in loose and pulverized coal particles. Further investigation is needed to determine whether other outcrop areas are affected by this phenomenon.

Characteristics of Mercury Fluxes between Soil and Air in the Farming-Pastoral Ecotone of Songnen Grassland

In order to understand the characteristics and influencing factors of surface release fluxes in the typical agro-pastoral mosaic region of the Songnen grasslands of northern China, this study selected two sample plots to, respectively, represent the L. chinensis covered grassland (L), and the Z. mays covered fields (Z) in the Waizi area of Changling County, with western Jilin Province as the study area. This study investigated the atmospheric mercury (Total Gaseous Mercury (TGM)) concentrations, surface soil mercury concentrations, the gaseous elemental mercury exchange fluxes, and related environmental factors. The results showed that the TGM concentrations in two sample plots in the study area were basically the same during the summer and autumn months, but were higher in summer than in autumn, and there was a clear diurnal pattern. The average mercury concentrations in the surface soil were also higher in summer than in autumn. Furthermore, the surface soil has a clear mercury release process, and the mercury release were higher in the sheep grass field than the maize field during the same season. The mercury release fluxes in each site within the ecotone were related to the solar radiation and soil temperature values, and the effects of them on the soil mercury release were independent from one another.

Mercury in Selected Abiotic and Biotic Elements in Two Lakes in Poland: Implications for Environmental Protection and Food Safety

Mercury, which tends to bioaccumulate and biomagnify in aquatic food webs, poses a potential health risk to wildlife and to consumers of predatory fish in particular. Its concentration in biota can be high even at low environmental concentrations. Therefore, the aim of this study was to determine mercury in both abiotic (water and sediment) and biotic elements (common reed (Phragmites australis) and fish: pike (Esox lucius), bream (Abramis brama) and roach (Rutilus rutilus)) in the context of assessing the pollution of two lakes in Poland and the safety of fish consumers. The possibility of Hg biomagnification in fish was also considered. Mercury was determined by means of cold vapor atomic absorption spectrometry (CVAAS). The concentrations of Hg in water and bottom sediments of Lake Ińsko were lower than in Lake Wisola. In the bottom sediments of both lakes, a positive correlation was found between the Hg content and organic matter. The concentration of mercury in the organs of common reed did not exceed 0.017 mg/kg dry weight (dw), and its distribution can be presented as follows: root > leaves > stems > rhizomes. In fish organs from both lakes, the average mercury content did not exceed 0.086 mg/kg of wet weight (ww) and in most cases it was the highest in pike. Higher values were only observed in the muscles and skin of roach. This indicates a lack of biomagnification in the relationships between planktivorous-predatory and benthivores-predatory fish. Based on the maximum levels of mercury in fish and the calculated parameters, i.e., estimated daily intake (EDI), target hazard quotient (THQ) and tolerable weekly intake (TWI), the muscles of the examined fish were found to be safe for consumption. The average dietary exposure to total mercury (THg) and methylmercury (MeHg) was below 0.3% of the TWI.

Heavy metals pollution and potential ecological health risk assessment in the Yangtze River reaches

Since the construction of the Three Gorges Project, great changes have taken place in the hydrological situation along the Yangtze River and its tributaries. This paper analyzes the content level, temporal and spatial changes and potential ecological risk trends of heavy metal pollutants in surface sediments from 2015 to 2020. The results showed that the average contents of copper (Cu), lead (Pb), manganese (Mn), arsenic (As) and mercury (Hg) in the sediments along the Yangtze River were 23.2∼50.3 mg/kg, 19.6∼65.7 mg/kg, 154.3∼996.8 mg/kg, 6.98∼20.65 mg/kg, 0.198∼0.492 mg/kg, respectively. The average content of Cu, Pb, Mn, As and Hg in sediments of it’s tributaries was 22.3∼29.5 mg/kg, 15.3∼36.7 mg/kg, 456.3∼1123.4 mg/kg, 7.37∼17.15 mg/kg, 0.209∼0.345 mg/kg, respectively. There were obvious differences in the content of heavy metals in the surface sediments of the left and right banks of local river sections along the Yangtze River. The content of heavy metals in surface sediments along the Yangtze River and its tributaries fluctuated to a certain extent in different water periods. The contents of Cd, Cr, Cu, Pb, As and Hg in the back muscle tissue of seven main economic fishes were determined. The results showed that the contents of Cd, Cr, Cu, Pb, As and Hg were 0.02∼2.53 mg/kg, ND∼2.75 mg/kg, 0.0003∼4.1 mg/kg, ND∼1.03 mg/kg, ND∼0.03 mg/kg, ND∼0.03 mg/kg, respectively. Pb and Cd were the main elements of heavy metal pollution in Yangtze River fish. Crucian fish was the most polluted by heavy metals, while grass fish was the least. Various evaluations show that the heavy metals in the surface sediments along the Yangtze River and its main tributaries were generally at a medium enrichment level, and the potential ecological risk index of heavy metals except Ganjiang River changes little during most periods. The potential ecological risk index of heavy metals in Ganjiang River was at relatively high level in 2017, but declined and tended to be stable after 2017.

Mercury geochemistry of marine sediments from the eastern Laptev Sea: The spatial distribution, levels, and contamination assessment

Twenty-seven sediment samples from the eastern Laptev Sea were analyzed for mercury and total organic carbon as well as grain-size distribution. The average total mercury (THg) concentrations in sediments are 29 ± 14 μg kg−1. A significant correlation of THg content with total organic carbon and clay and silt fractions was shown. The 210Pb-dated sediment core was used to evaluate the contamination degree and flux of THg in sediments from the eastern Laptev Sea. The average sedimentation rate for the all dated intervals was 0.17 cm/year. The THg flux increased from 20 to 28 μg/m2/year in the period of 1892–1950 to 53–59 μg/m2/year in the modern period of 2011–2015. According to various indices, the ecological risk from THg in studied sediment was low.

Determination of metal(oids) in different traditional flat breads distributed in Isfahan city, Iran: Health risk assessment study by latin hypercube sampling.

This survey was conducted to assess the metal(oids) content in 93 samples of bread, including barbari, lavash, and tafton, using inductive couple plasma/optical emission spectroscopy (ICP-OES) method and atomic absorption spectroscopy (AAS). The amounts of measured element were compared with the permissible limit set for bread by FAO/WHO and Iranian National Standardization Organization (INSO). The limit of detection (LOD) was ranged from 6.6 × 10-5 to 2.1 × 10-2 mg l-1 with recoveries ranged from 92% to 102%. The average concentrations of aluminum (Al), arsenic (As), boron (B), cadmium (Cd), iron (Fe), mercury (Hg), magnesium (Mg), sodium (Na), lead (Pb), and zinc (Zn) in bread were 29.88 ± 8, 0.03 ± 0.004, 12.77 ± 3.70, 0.01 ± 0.006, 34.16 ± 8.95, 0.01 ± 0.008, 346.07 ± 36.08, 3314.81 ± 317.19, 0.24 ± 0.11, and 19.65 ± 4.66 mg Kg-1, respectively. Amounts of As, Cd, Hg, Mg, Pb, and Zn were lower, and those of Al, Fe, and Na were higher than the permissible limits defined by FAO/WHO. The Latin Hyper Cube (LHC) sampling results revealed that children were exposed to higher non-carcinogenic risk and adults were more threatened by carcinogenic risk. It is recommended to control the entrance of metals in bread in the farm-to-fork chain in order to prevent probable future health challenges.

Mercury Contents in the Liver, Kidneys and Hair of Domestic Cats from the Warsaw Metropolitan Area

Mercury is a highly toxic element subject to bioaccumulation, increasing its harmful effects on living organisms over time. In the present study, total mercury contents were determined in the liver, kidneys and hair of cats from Warsaw and its suburban areas. The study took into account the influence of the age, sex and living conditions of the animals. Samples were obtained between 2014 and 2016, and mercury contents were determined by atomic absorption spectrometry (AAS). The average mercury concentrations in the tissues studied were 0.025, 0.026 and 0.030 mg∙kg−1 in the hair, kidneys and livers of the individuals tested, respectively. Higher values were recorded in animals from the city area, and an increase in this metal with the age of the cats was also found. The average contents of mercury in the tissues studied were within the range of the recommended reference values, which in this case indicates low environmental exposure of animals to mercury.

Long-range transport of atmospheric speciated mercury from the eastern waters of Taiwan Island to northern South China Sea

This study explored the temporospatial distribution, gas-particle partition, and pollution sources of atmospheric speciated mercury (ASM) from the eastern offshore waters of the Taiwan Island (TI) to the northern South China Sea (SCS). Both gaseous and particulate mercury were simultaneously sampled at three remote sites in four seasons. The average concentrations of gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate bound mercury (PBM) were 2.05 ± 0.45 ng/m3, 19.17 ± 5.39 pg/m3, and 0.11 ± 0.06 ng/m3, respectively. The concentrations of GEM and PBM in the cold seasons were higher than those in the warm seasons, but those of GOM had an opposite trend. In terms of gas-solid partition, ASM was apportioned as 91.3–97.3% of GEM and 2.7–8.7% of GOM and PBM. The average concentrations of GEM, GOM, and PBM at the Green Island (GI) were 2.21 ± 0.47 ng/m3, 22.31 ± 5.35 pg/m3, and 0.12 ± 0.06 ng/m3; those at the Kenting Peninsula (KT) were 2.11 ± 0.43 ng/m3, 20.57 ± 4.38 pg/m3, and 0.11 ± 0.06 ng/m3; and those at the Dongsha Islands (DS) were 1.84 ± 0.40 ng/m3, 15.19 ± 3.58 pg/m3, and 0.08 ± 0.05 ng/m3, respectively. Overall, the spatial distribution of ASM concentrations showed the order as: GI > KT > DS. Air masses blown mainly from the West Pacific Ocean (WPO) and SCS in summer showed the lowest ASM concentrations. Oppositely, high ASM concentrations were commonly observed in spring and winter when polluted air masses were blown by Asian Northeastern Monsoons (ANMs). The transport routes of polluted air masses were originated mainly from North China, Central China, Northeast China, Korea and Japan, and mostly passed through the urban and industrial regions in the northeastern Asian countries.

Analysis of the results of research into the mercury content in fish and seafood during import-export operations in Ukraine for 2019–2021

The article presents the results of research on the determination of mercury in fish muscles and seafood, conducted based on the State Research Institute for Laboratory Diagnostics and Veterinary-Sanitary Examination by the Atomic Absorption Spectrometry Laboratory as systematic research in the period from 2019 to 2021. Mercury content in fish muscles was determined by atomic absorption spectrometry with direct sample injection. The study was carried out using a Milestone DMA-80 atomic absorption spectrophotometer (Italy). Certified standard samples (MERK) of mercury ion solution composition with an accredited value of 1.0 mg/cm2 were used to construct the calibration curves. The detection limits of mercury in fish and seafood are determined according to the validation data: the LOD detection limit is 0.1 μg/kg, and the LOQ detection limit is 5.0 μg/kg. During the studied period, research was carried out on 3368 samples of fish products: 2587 samples of sea fish, 161 samples of freshwater fish, 130 samples of other types of fish and seafood – 490 pieces, of which four examples of sea fish, namely fish of the tuna family, were found to exceed the maximum permissible level of mercury, which is 0.12% of the total number of studied samples. The mercury content in tuna muscles ranged from 0.356 to 1.889 mg/kg, 1.8 times higher than the MDR. It was found that the average mercury content in the muscles of freshwater fish was 0.006–0.315 mg/kg, which is significantly lower than the average mercury concentration in marine fish. The mercury concentration in the muscles of other types of fish and seafood was 0.008–0.472 mg/kg and did not exceed the regulated norms.

Avian influenza antibody prevalence increases with mercury contamination in wild waterfowl.

Environmental contamination is widespread and can negatively impact wildlife health. Some contaminants, including heavy metals, have immunosuppressive effects, but prior studies have rarely measured contamination and disease simultaneously, which limits our understanding of how contaminants and pathogens interact to influence wildlife health. Here, we measured mercury concentrations, influenza infection, influenza antibodies and body condition in 749 individuals from 11 species of wild ducks overwintering in California. We found that the odds of prior influenza infection increased more than fivefold across the observed range of blood mercury concentrations, while accounting for species, age, sex and date. Influenza infection prevalence was also higher in species with higher average mercury concentrations. We detected no relationship between influenza infection and body fat content. This positive relationship between influenza prevalence and mercury concentrations in migratory waterfowl suggests that immunotoxic effects of mercury contamination could promote the spread of avian influenza along migratory flyways, especially if influenza has minimal effects on bird health and mobility. More generally, these results show that the effects of environmental contamination could extend beyond the geographical area of contamination itself by altering the prevalence of infectious diseases in highly mobile hosts.