Autogenous Shrinkage Research Articles

Autogenous shrinkage and cracking of ultra-high-performance concrete with soda residue as an internal curing agent

Autogenous shrinkage and cracking of ultra-high-performance concrete with soda residue as an internal curing agent

Exploring the role of SAP chemical composition in the internal curing of high-performance cementitious materials

This study investigates the impact of the chemical composition of superabsorbent polymers (SAPs) on their effectiveness in internal curing within high-performance cementitious materials. Although the use of commercial SAPs in cementitious systems has been widely researched, there is still no consensus on how different SAP structures influence material properties. For the first time, this research employs photoinitiated free radical polymerization technology to synthesize three structurally distinct SAPs: SAP with sulfonic acid groups (PAMPS), SAP with amide groups (PAM), and SAP with carboxyl groups (PAAs). The effects of these SAPs on the cement hydration process and microstructure were examined by analyzing their water absorption behavior in cement filtrate. The residual cation content on the SAP surface was evaluated using EDS, while XRD and TGA were used to study how SAP structure affects cement hydration products. Furthermore, the impact of these SAPs on the strength and autogenous shrinkage of the material was investigated. The results indicate that PAMPS, with its sulfonic acid groups, exhibited stable water absorption performance in the alkaline cement environment, promoting hydration reactions and increasing the formation of needle-shaped C-S-H. This stability contributed to mitigating the negative effects on mechanical properties. While the inclusion of SAPs generally reduced the strength of the cement matrix, PAMPS was the most effective in mitigating autogenous shrinkage, achieving a shrinkage mitigation efficiency of 86 %. These findings highlight the importance of SAP chemical structure in influencing cement hydration and material performance, offering insights for the development of effective internal curing agents to enhance high-performance concrete.

Optimization design of ultra-fine supplementary cementitious materials ultra-high performance concrete mix proportion based on orthogonal experiment

Traditional ultra-high performance concrete has problems such as high viscosity, high early-age autogenous shrinkage, and high heat release during early hydration. In recent years, with the development of ultra-fine grinding technology, ultra-fine supplementary cementitious materials (USCMs) have received widespread attention, which have higher pozzolanic activity than traditional supplementary cementitious materials. This study investigated the effects of water-binder ratio, silica fume content, and ultra-fine supplementary cementitious materials (USCMs) content on the workability, mechanical properties, and early-age autogenous shrinkage of ultra-high performance concrete (UHPC) based on orthogonal experiments. In orthogonal experiments, multiple factors and levels were introduced, and a combination of range analysis, variance analysis, and multi-factor interaction analysis were combined to determine the optimization level range of each factor. The results showed that the water-binder ratio had the greatest impact on the fluidity, compressive strength, and autogenous shrinkage of UHPC; The content of silica fume had the greatest impact on the flexural strength of UHPC. Compared with the control group, USCMs can significantly improve the workability and rheological properties of UHPC, reduce early hydration heat release, and inhibit the autogenous shrinkage of UHPC.

Effects of Superabsorbent Polymer and Natural Zeolite on Shrinkage, Mechanical Properties, and Porosity in Ultra-High Performance Concretes

The low water-to-binder ratio of ultra-high performance concrete (UHPC) often causes shrinkage and cracking due to early-age self-desiccation. This leads to significant initial dimensional instability, which may compromise structural integrity. As a promising solution, internal curing agents such as superabsorbent polymers (SAP) and natural zeolite have the potential to mitigate shrinkage and achieve self-stressing properties. This research aims to provide a comprehensive comparison between SAP and zeolite's effects within a consistent UHPC formulation. Six UHPC mixtures (including the reference mixture) were designed: three with SAP dosages of 0.2%, 0.4%, and 0.6% by cement mass, and two with zeolite replacing silica fume at 25% and 50% by mass. Various testing methods, including autogenous and drying shrinkage assessment, heat of hydration and thermogravimetric analysis, compressive strength evaluation, mercury intrusion porosimetry (MIP), nuclear magnetic resonance (NMR), were employed to assess the mixtures at different stages of curing. The result reveals that the incorporation of SAP and zeolite in the mixtures significantly reduces UHPC's early-age autogenous shrinkage. Moreover, SAP and zeolite additions impact mechanical properties, demonstrating that a balance between shrinkage control and compressive strength can be reached, through an optimization of the additions to achieve the desired performance. Microstructural analysis through MIP and NMR reveals increased overall porosity of the UHPC with SAP and zeolite, suggesting that low-field NMR can be a valuable tool for complementing conventional test methods. The outcome of this study provided valuable insights into optimizing the balance between durability and mechanical performance, paving the way for more sustainable and cost-effective applications of UHPC in modern construction practices.

Effect of Olive Waste Ash as a Partial Replacement of Cement on the Volume Stability of Cement Paste

Over the last decades, concrete has been excessively prone to cracks resulting from shrinkage. These dimensional changes can be affected by the incorporation of supplementary cementitious materials. This work used olive waste ash (OWA), which could substantially tackle this problem and achieve sustainability goals. For this issue, five cement paste mixes were prepared by replacing cement with OWA at different percentages varying from 0 to 20% by weight with a constant increment of 5%. The water-to-cement ratio was 0.45 for all mixes. Compressive strength and flexural strength were investigated at 7, 28, and 90 days. In addition, three shrinkage tests (drying, autogenous, and chemical) and expansion tests were also conducted for each mix and measured during 90 days of curing. The experimental findings indicated that there was a loss in compressive and flexural strength in the existence of OWA. Among all mixes containing OWA, the samples incorporating 10% OWA exhibited maximum strength values. Furthermore, the chemical and autogenous shrinkage decreased with the incorporation of OWA. However, the drying shrinkage decreased at lower levels of substitutions and increased at higher replacement levels. In addition, there was a growth in expansion rates for up to 10% of OWA content, followed by a decrease at higher levels (beyond 10%). Additionally, correlations between these volumetric stability tests were performed. It was shown that a positive linear correlation existed between chemical shrinkage and autogenous and drying shrinkage; however, there was a negative relationship between chemical shrinkage and expansion.

The effect of copper slag as a precursor on the mechanical properties, shrinkage and pore structure of alkali-activated slag-copper slag mortar

Copper slag, an industrial by-product produced in large quantities during copper smelting and refining, has the potential to be used as an alternative precursor for alkali-activated materials. This approach not only reduces the environmental impact of copper slag but also addresses the growing scarcity of conventional precursors, such as ground granulated blast furnace slag. In this research, copper slag was used as an alternative precursor for alkali-activated slag-copper slag mortars. Sodium hydroxide and water glass served as the activators. The workability, mechanical properties, autogenous shrinkage and drying shrinkage were investigated to evaluate the influence of copper slag content. Furthermore, the reaction products and pore structure of hardened mortar were analysed to gain deeper insights into its performance. The results show that the incorporation of copper slag effectively prolongs the setting time and increases the fluidity. Copper slag reduces the autogenous shrinkage, but it also results in an undesirable increase in drying shrinkage. While copper slag delays strength development and reduces the strength, incorporating copper slag at a 50 % ratio still results in strength comparable to that of mortars utilizing 100 % ground granulated blast furnace slag as the precursor. The incorporation of copper slag alters the composition of calcium aluminosilicate hydrate and promotes the formation of ferro-silicate. Although it reduces the proportion of macropores in the total pore volume, it simultaneously increases the amount of capillary pores. Copper slag alters pore solution, and although heavy metal leaching remains minimal, risks in complex environments require further study.

Bamboo fiber-enhanced UHPC: Early hydration and microstructural/mesoscale analysis

This study investigates the impact of incorporating bamboo fibers, a natural and renewable material, into ultra-high performance concrete (UHPC) on its early hydration, mechanical properties, internal relative humidity, autogenous shrinkage, and microstructure. The results show that adding bamboo fibers significantly improves various UHPC properties. Bamboo fibers regulate hydration and prolong the hydration process through their water absorption and retention abilities. With a fiber content of 1.0 vol percent (vol%), the compressive strength increases by 10.2 %, reaching 97.1 MPa, and at 2.0 vol%, flexural strength and toughness increase by 37.9 % and 739.5 %, respectively. Additionally, bamboo fibers help maintain internal relative humidity above 98 % during the first 7 days of curing and reduce autogenous shrinkage by up to 55.9 %. The fibers also optimize the microstructure by minimizing voids, with a 1.0 % fiber content reducing the void ratio to 1.64 %. This reduces large voids and improves the material's density. Overall, bamboo fibers show great promise in enhancing UHPC's structural performance and environmental adaptability while being a sustainable and cost-effective material.

Early-age shrinkage behavior of cement mixtures regulated with metakaolin-based internal conditioning

Shrinkage occurs in concrete during its hardening and strength gain process leading to undesired deformation, cracking, and decreases in strength and durability. While metakaolin-based internal conditioning (MIC) has been validated as a promising technique for modifying cement and mitigating alkali-silica reactions in concrete, its impact on the early-age shrinkage behavior of cement remains unexplored. This study delves into the effects of MIC and its coupling with lithium on the chemical shrinkage, autogenous shrinkage, and drying shrinkage of portalnd cement incorporating 30 % metakaolin with varying degrees of saturation (50 %, 75 %, and 100 %). The results indicate that the hydration of cement can be substantially enhanced by MIC with 29.0 % more heat released and a 32.3 % decrease in calcium hydroxide content. As a result of the enhanced hydration, cement with MIC yielded increased chemical shrinkage. Compared with dry MK, the autogenous shrinkage and drying shrinkage of cement were decreased by 38.0 % and 11.0 %, respectively, in the presence of MIC. A synergistic effect between MIC and lithium was suggested by the higher efficacy in suppressing autogenous shrinkage.

Mechanical and autogenous shrinkage properties of coarse aggregate ultra-high performance concrete (CA-UHPC): The effect of mineral admixtures

To reduce the shrinkage and explore the best content of mineral admixtures of coarse aggregate ultra-high performance concrete (CA-UHPC), this study conducted 12 groups of autogenous shrinkage, basic material properties (compressive strength, tensile strength, and flowability), and X-ray diffraction experiments on CA-UHPC with coarse aggregate and different amounts of mineral admixtures (slag powder, limestone powder). The effects of coarse aggregate and mineral admixtures on the autogenous shrinkage and basic material properties of CA-UHPC were analyzed, and the measured values of CA-UHPC autogenous shrinkage strain were compared with the theoretical values calculated by six commonly used concrete shrinkage prediction models. The experimental results show that under the condition of 15 % coarse aggregate content and no steam curing, a CA-UHPC with a compressive strength greater than 110 MPa, a tensile strength greater than 11 MPa, a flowability greater than 290 mm, and an autogenous shrinkage of less than 700 after 120d can be obtained. The mineral admixture has a significant impact on the fundamental properties of CA-UHPC. The compressive strength, tensile strength, and flowability of CA-UHPC with 15 % limestone powder and 15 % S95 slag powder increased by 6.6 %, 5.4 %, and 27.6 % compared to UHPC with only coarse aggregate added, and the autogenous shrinkage after 120 days decreased by 10.5 %. However, when the dosage of limestone powder and S95 slag powder exceeds 30 %, the tensile and compressive strength of CA-UHPC will rapidly decrease. This study also revised the GL 2000 shrinkage prediction model based on the CA-UHPC autogenous shrinkage test results, introduced the influence coefficient of mineral admixture content on autogenous shrinkage strain, and established a theoretical calculation model suitable for CA-UHPC autogenous shrinkage strain.

Enhancing mechanism of mechanical properties of lightweight and high-strength concrete prepared with autoclaved silicate lightweight aggregate

Lightweight aggregate concrete (LAC) possesses the merits of low density, excellent thermal insulation performance and outstanding seismic performance. However, the practical application in structural engineering is limited because its mechanical properties are weaker than those of ordinary aggregate concrete. It was found that the compressive strength of high-strength concrete prepared by autoclaved silicate lightweight aggregate (cloud concrete stone) was higher than that of ordinary aggregate high-strength concrete, and it showed significant lightweight and high-strength characteristics. To reveal the enhancing mechanism of the mechanical properties of high-strength concrete prepared by cloud concrete stone (CCS), this research examines the internal curing effect of CCS and the mechanical performances of the interfacial transition zones (ITZ). The influences of the elastic modulus of CCS, the shape of aggregate and fracture patterns on the mechanical properties of concrete are simulated via the discrete element method. The findings suggest that the internal curing effect of CCS delays the onset of capillary stress and mitigates autogenous shrinkage. The homogeneousness, elastic modulus, and fracture toughness of ITZ around CCS aggregate are superior than that ITZ around ordinary gravel in high-strength concrete. Furthermore, the small difference in elastic modulus between CCS aggregate and cement matrix is advantageous for preventing microcracks during compression tests. The round shape of the aggregate also mitigates the development of microcracks caused by the stress concentration effect. These three reasons contribute to the enhancement of mechanical properties in lightweight and high-strength concrete. The innovation of this research is that the intrinsic relationship between CCS aggregate and concrete’s mechanical properties is thoroughly revealed from the aspects of the characteristics of the interface transition zone, the morphology of the aggregate and the elastic modulus of aggregate. That provides a theoretical basis for the application of light aggregate in high-strength structural concrete.

Advanced moisture control in porous aggregates for improved lightweight high-performance concrete

The porous lightweight aggregates in concrete experience a process of water absorption and desorption. This study aims to improve the performance of water-sensitive low water/binder (w/b) systems by effectively utilizing these water regulations. The effects of expanded shale (ES) substitutions and saturation levels (dry, half saturation, and saturation) on the fresh and hardened properties of mixtures with a w/b of 0.18 were investigated. The results indicated that, during the fresh stage, water absorption reduced workability and shortened the setting time. In the hardening stage, the released water improved hydration, increased internal relative humidity, and caused volumetric expansion, which reduced autogenous shrinkage. A comprehensive evaluation revealed that the optimal condition for ES was half-saturation with 4.0 wt.% pre-absorbed water. This condition achieved the best internal curing effect, improved workability, and optimal structural efficiency (strength/density). This study provides practical insights for the effective integration of porous aggregates in the mixture design and engineering applications.

Synthesis of a chitosan-based superabsorbent polymer and its influence on cement paste

To address the challenge of adaptability between cement-based materials and conventional superabsorbent polymers (sodium polyacrylate, Na-PA), a chitosan-based superabsorbent polymer (CSP) with high salt and alkaline resistance was synthesized, and the optimal synthesis process was determined by a single-factor method. The macroscopic performance and microstructure of CSP and Na-PA were compared, and their influences on cement paste were studied. The results show that CSP exhibits a gradual swelling process during water absorption, which is independent of the solution environment. The poriferous structure of CSP allows it to form a network composed of gel membranes. The introduction of amide group enhances the resistance of CSP to salt and alkaline conditions. The autogenous shrinkage of cement paste is mitigated by CSP, with a superior effect compared to Na-PA. The longer desorption time of CSP allows it to promote cement hydration for a longer period, reducing the loss of compressive strength. The heat release, chemically bound water and hydration products (portlandite and amorphous substances) of CSP pastes are higher than those of Na-PA pastes. The water desorption from CSP fills some middle capillary pores and mesopores, leading to the pores in the hardened cement paste being more concentrated in smaller sizes.

Effect of PVA fibers grafted with MWCNTs on the shrinkage behaviors of engineered geopolymer composite (EGC)

Geopolymer have been considered as a promising alternative for the development of high-ductility and eco-friendly engineered materials. In this study, modified PVA fibers grafted with MWCNTs(PM) are used as additives to investigate their impact on the drying shrinkage, autogenous shrinkage and chemical shrinkage of Engineered Geopolymer Composites(EGC). Additionally, various micro-structure techniques, including X-ray Diffraction(XRD) and Scanning Electron Microscopy(SEM), are employed to examine the morphology and chemical composition of EGC. The experimental findings indicates that PVA fibers and MWCNTs both help to mitigate the drying shrinkage and autogenous shrinkage of the EGC. When the PVA fiber content is 2.0 % and the MWCNT content is 1.0 ‰, the 90-day drying shrinkage and autogenous shrinkage values of the EGC are minimized, reducing by 31.67 % and 34.16 %, respectively, in comparison to the control group. However, the incorporation of MWCNTs increases the chemical shrinkage of the geopolymer matrix, with the chemical shrinkage value reaching its maximum when the MWCNT content is 1.0 ‰. Micro-structural analysis reveals that the inclusion of PM leads to an improvement in the quantity of reaction products without affecting their type. Furthermore, the incorporation of PM refines the overall pore structure, restricts the crack development and enhances the interfacial bonding effect of EGC. Notably, a correction prediction model for drying shrinkage strain and autogenous shrinkage strain, incorporating the influence coefficients of PVA fibers and MWCNTs, is constructed under constant humidity and temperature conditions. This significantly improves the prediction accuracy of drying shrinkage and autogenous shrinkage of EGC.

Autogenous shrinkage prediction models and microstructure of UHPC with single or binary addition of an expansive agent and steel fibers

The low water/binder ratio of ultra-high performance concrete (UHPC) often results in its high autogenous shrinkage. Our study explored the effect of the single or binary addition of a CaO-based expansive agent (CEA) and steel fibers on flowability, compressive strength, flexural strength, microstructure, and autogenous shrinkage of UHPC. X-ray diffraction (XRD), thermogravimetric (TG) analysis, scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP) were applied to reveal the effects of CEA and steel fibers on hydration products and microstructure characteristics of UHPC. Experimental results show that the autogenous shrinkage of UHPC decreased markedly with the single or binary addition of CEA and steel fibers. Relative to the control group, autogenous shrinkage of UHPC with 2.5% dosage of single steel fibers, 6% dosage of single CEA, and binary addition of 2.5% steel fibers and 6% CEA decreased 17.8%, 10.9%, and 30.8% at 180 days, respectively. Steel fibers could enhance the mechanical performance of UHPC; nevertheless, they would decrease the flowability of UHPC. Meanwhile, the addition of CEA in the UHPC mixture not only maintained the mechanical properties and flowability but also decreased the autogenous shrinkage. Diffraction peak intensity and endothermic peak of Ca(OH)2 and the pore volume of 10–50 nm diminished with the content of CEA; however, that of C-S-H gel and ettringite increased. The prediction accuracy of nine shrinkage models (FHWA model, Lee model, Yoo model, JSCE model, B4 model, JonassonH model, Eurocode 2 model, CEB model, and DilgerW model) is analyzed with RE, Rnew2, and autogenous shrinkage of UHPC in this paper.

Numerical modelling of autogenous shrinkage of rice husk ash blended cement mortar

Addition of rice husk ash (RHA) is an effective internal curing method to mitigate self-desiccation and autogenous shrinkage of hydrating cementitious materials. Although a certain number of experimental researches on this topic have been carried out, a comprehensive study about numerical simulation of mitigating effect of RHA on autogenous shrinkage of cementitious materials is still scarce. In this study, a numerical model of autogenous shrinkage of rice husk ash blended cement mortar was proposed. The proposed numerical model was based on Pickett model and improved by taking visco-elastic behaviour of rice husk ash blended cementitious materials into account. Final setting time, chemically bound water, compressive strength, internal relative humidity (RH) and autogenous shrinkage of pure Portland cementitious materials and rice husk ash blended cementitious materials were experimentally studied. Liquid absorption capacity and water vapour desorption isotherm of rice husk ash were also measured. The comparison between the simulated and measured autogenous shrinkage showed that the autogenous shrinkage of rice husk ash blended cement mortar can be predicted accurately with the proposed numerical model.

Influence of fly ash and granulated blast furnace slag on autogenous shrinkage and drying shrinkage of cement-based materials mixed with alkali accelerator and alkali-free accelerator

Shotcrete shrinkage and cracking are getting more threatening due to its high content of cementitious materials, small aggregate particle size and a large amount of accelerator, which poses a great threat to the construction safety of engineering structures. This paper studies the volume stability of cement mortar with different contents of fly ash (FA) and granulated blast furnace slag (GBFS) (10%/20%/30%) under the condition that the dosage of alkali liquid accelerator is 4% and that of the alkali-free liquid accelerator is 7%. This work is designed to provide a guidance for the basic research and practical application. By comparing the autogenous shrinkage, drying shrinkage, mass loss caused by drying condition, and internal humidity change of drying condition of cement mortar within 180 days of age. Combined with MIP analysis, XRD hydration product analysis, and SEM hydration product morphology analysis, the results show that both fly ash and granulated blast furnace slag can reduce the autogenous shrinkage and drying shrinkage of cement mortar mixed with accelerator to a certain extent, and the shrinkage reduction effect of FA is more prominent. The reduction effect of GBFS is more obvious at high dosages. Adding FA and high content of GBFS can increase the mass loss of cement mortar under drying shrinkage conditions. The high content of mineral admixtures will exacerbate the rate of decrease in the internal humidity of the cement mortar. The reasons for the reduction of autogenous shrinkage and drying shrinkage of cement mortar mixed with accelerators due to the addition of FA and GBFS are: the early activity of the two mineral admixtures is low, and the hydration process is slow. And the reduction of pore size with the range of 5-50nm leads to the reduction of capillary tensile stress and the weakening of the driving force for shrinkage deformation. Among them, the shrinkage reduction effect of fly ash is more pronounced. Therefore, mineral admixture can be used to replace a certain amount of cement in actual shotcrete construction, so as to increase the volume stability of shotcrete.

Mechanical and shrinkage properties of cellulose nanocrystal modified alkali-activated fly ash/slag pastes

Alkali-activated materials based on fly ash (FA) and ground granulated blast furnace slag (GGBFS) offer lower carbon footprints but face challenges like low tensile strength and shrinkage susceptibility. This research explores the potential of cellulose nanocrystals (CNC) as additives to enhance the mechanical and shrinkage properties of alkali-activated fly ash/slag (AAFS) pastes to advance sustainable construction materials. A comprehensive examination is conducted on the impact of different contents of CNC (0.05 %, 0.1 %, 0.2 %, and 0.3 % by mass of FA + GGBFS) on the properties of AAFS pastes with two different alkaline activator contents (4 % and 8 % by mass of FA + GGBFS). It is found that incorporating 0.3 % CNC into AAFS pastes respectively improves the 28-day compressive and flexural strengths by 18.54 % and 60.87 % (8 % alkaline activator) and by 16.99 % and 50.12 % (4 % alkaline activator), and reduces the autogenous shrinkage and drying shrinkage by 26.42 % and 50.32 % (8 % alkaline activator) and by 11.74 % and 22.05 % (4 % alkaline activator). Also, the flexural/compressive strength ratio of AAFS pastes is increased with increasing CNC content. The microstructural analysis shows increased hydration product formation and a smoother, more compact morphology in CNC-modified samples, which together with water retention and distribution effect and nano-reinforcing effect of CNC explains the improvements in mechanical properties and volume stability. The research findings highlight the great potential of CNC as a reinforcing agent for sustainable construction materials, aligning with the demand from industries for eco-friendly alternatives to traditional cementitious materials.

Utilization of construction and demolition waste in ultra-high performance concrete: Macro-micro properties and environmental impacts

To further improve the utilization of recycled fine aggregates (RFA) obtained from construction and demolition in ultra-high performance concrete (UHPC), this work aims to adopting the nano-silica (NS) to develop a UHPC incorporating RFA with high strength and low shrinkage. A series of experiment evaluation on the workability, compressive strength, autogenous shrinkage and resistance to chloride penetration of UHPC are conducted. The hydration products, pore structure, and microstructure of UHPC are analyzed using isothermal calorimetry, thermogravimetric analysis, scanning electron microscopy, and mercury intrusion porosimetry, respectively. Results indicate that the addition of RFA decreases the flowability and early compressive strength of UHPC. However, it effectively mitigates autogenous shrinkage and compensates for the later-stage strength loss. NS significantly enhances the early compressive strength and resistance to chloride penetration in UHPC containing RFA. The combined incorporation of 20 % RFA and 3 % NS leads to 65.6 % reduction in the autogenous shrinkage within 7 days, 12.1 % improvement in compressive strength and 16.5 % decrease chloride diffusion coefficient of UHPC specimens at 28 days. Furthermore, the synergistic effects of RFA and NS promote the cement hydration, reduce the porosity and further refine the pore structure, and improve the interface transition zone in UHPC. This provides valuable insights for advancing the development of environmentally sustainable which collaborative utilization of RFA and NS in the manufacture of UHPC with reducing carbon footprint.

Optimized mix design method of ultra-high performance concrete (UHPC) and effect of high steel fiber content: Mechanical performance and shrinkage properties

In this study, UHPC was successfully prepared based on the Modified Andreason and Andersen (MAA) model (distribution modulus m= 0.23 was confirmed) and Excel solver tool. Subsequently, the effect of steel fiber content (0%–6% by volume) on the mechanical properties and shrinkage properties was investigated. It was found that the compressive and flexural strengths increased significantly with the increase of steel fiber content from 0 % to 5 %, but decreased when it exceeded 5 %. The split tensile strength was always increased. In addition, the plastic shrinkage, autogenous shrinkage, and drying shrinkage of UHPC were reduced by 18.3%–67.4 %. It indicated that incorporating higher content of steel fiber into UHPC could enhance mechanical strength, but the mixing approach should be optimized when content of steel fiber exceeds 5%. In addition, the prevalence of steel fiber agglomeration was shown under X-CT, but the agglomeration of steel fiber still led to an increase in UHPC properties within a certain range. The air content of UHPC with 6 % fiber content is 3.5 %, which shows the reasonableness and good performance of the mix proportion calculated by the Excel solver demonstrated in the article. The article can lay a light on the industrial design and preparation of UHPC.

A hydro-thermo-chemo-mechanical model for slag-blended cementitious systems at early ages

A comprehensive hydro-thermo-chemo-mechanical model for predicting the early-age properties development of slag-blended cementitious systems is presented in this study. A new kinetic evolution for slag reaction that takes into account the heterogeneous nucleation effect and induction time of slag was proposed, with which the model effectively quantifies the contributions of slag to the hydration, energy exchange and mass conversation within blended systems. This paper provides a thorough documentation of input parameters, fundamental equations, and constitutive laws associated with the model. The hydro-thermo-chemo-mechanical model successfully predicts the heat release, hydration degrees of cement and slag, self-desiccation, basic creep and autogenous shrinkage in slag-blended cementitious systems. The predictions align well with the experimental observation obtained from this work and reported works in the literature, validating the accuracy and reliability of the proposed model in capturing and explaining the complex early-age behaviors of slag-blended cementitious systems.