Attractive Forces Research Articles

Incongruous Harmonics of Vibrating Solid‐Solid Interface

AbstractDeconvoluting the vibrations and harmonics in solid‐solid interfaces is crucial for designing materials with improved performance, durability, and functionality. The measured vibrating microcantilever signal in the dynamic atomic force microscopy (AFM) encompasses a multitude of distinct signatures reflecting a diverse array of material properties. Nevertheless, uncertainties persist in decoding these signatures, primarily arising from the interplay between attractive and repulsive forces. Consequently, it is challenging to correlate the generated harmonics within the solid‐solid interfaces with the imaged phase and topography of materials, as well as the occasional observed contrast reversal. In this study, the vibration harmonics produced at solid‐solid interfaces are correlated, linking them to short‐range nano‐mechanical characteristics through a comprehensive blend of theory, simulation, and experimental methods. These findings shed light on the roots of harmonic generation and contrast reversals, opening avenues for designing innovative materials with customized properties.

Self-Generated Ions Modify the Pair Interaction and the Phase Separation of Chemically Active Colloids.

Chemically active colloids that release/consume ions are an important class of active matter, and exhibit interesting collective behaviors such as phase separation, swarming, and waves. Key to these behaviors is the pair-wise interactions mediated by the concentration gradient of self-generated ions. This interaction is often simplified as a pair-wise force decaying at 1/r2, where r is the interparticle distance. Here, we show that this simplification fails for isotropic and immotile active colloids with net ion production, such as Ag colloids in H2O2. Specifically, the production of ions on the surface of the Ag colloids increases the local ion concentration, c, and attenuates the pair-wise interaction force that scales with ∇c/c. As a result, the attractive force between an Ag colloid and its neighbor (active or passive) decays at 1/r or 1/r2 for small or large r, respectively. In a population, the attraction of a colloid by a growing cluster also scales with ∇c/c, so that medium-sized clusters grow fastest, and that the cluster coarsening slows with time. These results, supported by finite element and Brownian dynamic simulations, highlight the important role of self-generated ions in shaping the collective behavior of chemically active colloids.

Cc¯ and bb¯ suppression in the glasma

This study investigates the evolution and dissociation dynamics of cc¯ and bb¯ pairs within the preequilibrium, gluon-dominated stage of high energy nuclear collisions. An attractive potential made of a perturbative Coulomb-like term and of a confining term is used to simulate the attractive strong force in the pairs. Besides, we implement the interaction of the pairs with the evolving glasma fields by virtue of the Wong equations. The interaction with the classical color fields dominates the dynamics, causing an increase in pair separation and subsequent dissociation. The observed finite probability of dissociation for these states reveals the intricate interplay between quantum chromodynamics (QCD) dynamics and the suppression of cc¯ and bb¯ states during the preequilibrium stage. The research highlights differences between cc¯ and bb¯ pairs, revealing the role of quark flavor in the dissociation process. Dissociation spectra analysis indicates a peak shift toward higher momentum, reflecting a slight energy gain by the pairs. This investigation provides valuable insights into the complex dynamics of cc¯ and bb¯ pairs in the glasma, which may help in better interpretation of experimental results on further integration with subsequent phases of the created matter. Published by the American Physical Society 2024

Analysis of Macromolecular Size Distributions in Concentrated Solutions

AbstractThe solution state of macromolecules in concentrated solutions impacts fields ranging from cell biology, to colloid chemistry and engineering of protein pharmaceuticals. Dependent on the interplay between repulsive and weakly attractive forces, proteins may exhibit oligomerization, aggregation, crystallization, liquid‐liquid phase separation, or the formation of multiprotein complexes. The particle size‐distribution is a key characteristic, but difficult to determine when interparticle distances are on the order of their size and macromolecular motion is coupled through hydrodynamic interactions. Here we extend sedimentation velocity analytical ultracentrifugation to measure macromolecular size distributions under these conditions: We apply results from statistical fluid mechanics for the concentration‐dependence of hindered settling and diffusion, embedded in a mean‐field approximation that can resolve coupled sedimentation and diffusion processes of different sized species given experimental sedimentation data. This is combined with a description of transient optical aberrations from lensing in the refractive index gradients associated with sedimentation boundaries (Wiener skewing). We demonstrate this approach in the application to protein solutions with macromolecular volume fractions up to ≈10 %, for example, resolving monomers and dimers of albumin at 140 mg/ml. This enables size‐distribution analysis of proteins at concentrations of therapeutic antibody formations and close to physiological concentration in serum and cells.

About tautochronic movements

It is shown that a material point, under the influence of an attractive linear force and a repulsive force inversely proportional to the cube of the distance from the center of attraction, performs a periodic motion, the period of which does not depend on the initial data (tautochronic motion). The problem is reduced to a nonlinear autonomous second-order equation, the general solution of which is expressed in terms of elementary functions. It has also been proven that for other power laws of repulsive force, except for degrees 0, 1 and –3, the movement of a material point is not tautochronous.

Effects of liquid fraction and contact angle on structure and coarsening in two-dimensional foams

Aqueous foams coarsen with time due to gas diffusion through the liquid between the bubbles. The mean bubble size grows, and small bubbles vanish. However, coarsening is little understood for foams with an intermediate liquid content, particularly in the presence of surfactant-induced attractive forces between the bubbles, measured by the interface contact angle where thin films meet the bulk liquid. Rigorous bubble growth laws have yet to be developed, and the evolution of bulk foam properties is unclear. We present a quasistatic numerical model for coarsening in two-dimensional wet foams, focusing on growth laws and related bubble properties. The deformation of bubble interfaces is modelled using a finite-element approach, and the gas flow through both films and Plateau borders is approximated. We give results for disordered two-dimensional wet foams with $256$ to $1024$ bubbles, at liquid fractions from $2\,\%$ to $25\,\%$ , beyond the zero-contact-angle unjamming transition, and with contact angles up to $10^\circ$ . Simple analytical models for the bubble pressures, film lengths and coarsening growth rates are developed to aid interpretation. If the contact angle is non-zero, we find that a prediction of the coarsening rate approaches a non-zero value as the liquid fraction is increased. We also find that an individual bubble's effective number of neighbours determines whether it grows or shrinks to a good approximation.

Boosting Electrochemical Degradation of Water Pollutants Using Sulfur‐Rich Porous Polyimide‐Derived Laser‐Induced Graphene Catalytic Membrane

Water pollution is an inevitable concern associated with technological advancement. To address this problem, it is necessary to significantly shorten the manufacturing process of porous materials while enabling effective pollutant removal. Herein, a facile, rapid, and scalable approach is reported to obtain sulfur‐doped hierarchically porous laser‐induced graphene (S‐LIG) as a catalytic membrane with three‐dimensional networks by localized laser irradiation, along with possible adsorption and electrochemical degradation mechanisms for pollutant removal. S‐LIG is derived from sulfur‐containing porous polyimide film which is prepared via thermally induced phase separation followed by stepwise thermal imidization. Methylene blue (MB) adsorption behavior on the S‐LIG membrane closely fits the pseudo‐second‐order and Freundlich isotherm models, suggesting a complex sorption mechanism, including both strong chemical interaction and physical adsorption. Furthermore, S‐doping enhances catalytic activity for generating reactive oxygen species (ROS), aiding MB degradation via indirect oxidation, and improves direct oxidation on the anode by accelerating electron transfer at the electrodes. This results in a stable 93% MB degradation at a low 1.5 V after 24 h. Additionally, the impact of solution pH reveals that electrostatic attraction forces under basic conditions and the high generation of ROS under acidic conditions favor adsorption and electrochemical oxidation.

Origin of the intermolecular forces that produce donor–acceptor stacks in π-conjugated charge-transfer complexes

The attraction between π-conjugated planar electron donor and acceptor molecules that form many stable charge-transfer (CT) complexes has been explained by quantum chemical CT interactions, although the fundamental origin remains unclear. Here, we demonstrate the mechanism of CT complex formation by potential energy map analysis for TTF–CA and BTBT–TCNQ, using energy decomposition of intermolecular interaction by symmetry-adapted perturbation theory (SAPT) combined with coupled cluster calculation. We find that the source of attraction between donor and acceptor molecules is ascribed primarily to the dispersion force and also to the electrostatic force. In contrast, the contribution of CT interactions to the attractive forces is minimal. We demonstrate that the highly directional feature of the exchange repulsion force, coupled with the attractive dispersion and electrostatic forces, is crucial in determining the intermolecular arrangements of actual CT crystals. These findings are key for understanding the unique structural and electronic properties of π-conjugated CT complexes.

Dark matter raining on DUNE and other large volume detectors

Direct detection is a powerful means of searching for particle physics evidence of dark matter (DM) heavier than about a GeV with \U0001d4aa(kiloton) volume, low-threshold detectors. In many scenarios, some fraction of the DM may be boosted to large velocities enhancing and generally modifying possible detection signatures. We investigate the scenario where 100% of the DM is boosted at the Earth due to new attractive long-range forces. This leads to two main improvements in detection capabilities: (1) the large boost allows for detectable signatures of DM well below a GeV at large-volume neutrino detectors, such as DUNE, Super-K, Hyper-K, and JUNO, as possible DM detectors, and (2) the flux at the Earth’s surface is enhanced by a focusing effect. In addition, the model leads to a significant anisotropy in the signal with the DM flowing dominantly vertically at the Earth’s surface instead of the typical approximately isotropic DM signal. We develop the theory behind this model and also calculate realistic constraints using a detailed GENIE simulation of the signal inside detectors.

Exploring Interatomic Electron Transfer and Metal-Ligand Binding Mechanism in Trimethylenemethane Iron Tricarbonyl: Insights from Potentials per Electron and Corresponding Force Density Fields.

This study employs an analysis of the per-electron potentials and the superposition of the electrostatic and kinetic force fields, Fes(r) and Fk(r), and the gradients of the potential energy and one-electron densities to investigate the binding mechanism in trimethylenemethane iron tricarbonyl complex (TMM)Fe(CO)3. Our approach permits the delineation of the "ligand-binding" force field generated by the metal nucleus but partially operating within the ligand atoms. A mechanical rationale for metal-ligand interactions is thus presented: In the corresponding area, the attractive force Fes(r) provides the backdrop against which the homotropic static force (r) and the heterotropic kinetic force Fk(r) exert attractive and repulsive influences, respectively, toward the metal nucleus on a portion of the electrons belonging to the ligand atoms. This area thus represents electron sharing, which emerges as a quantum chemical response against the metal-to-ligand electron transfer. It has been demonstrated that the response is facilitated by the decreased potential energy density in the vicinity of the interatomic surface. Our findings indicate that the polar coordination bonds in (TMM)Fe(CO)3 exhibit notable quantum chemical responses. However, the previously described nonbonded contact also features an unexpectedly pronounced response, despite the absence of a bond path. It can be proposed that the unforeseen response is a consequence of the formation of the 18-electron, closed valence shell, rather than an indication of the establishment of an organometallic chemical bond.

Enhanced Attractive Force via Torsion Spring as Rotatable Tip Structure in Beam-Structure Electrostatic Chucks

This research aims to replace ball joints of beam-structure electrostatic chucks (BSESC), which are limited by issues such as structural friction and inconsistent operation, thus enhancing the applicability in industrial settings. Torsion springs are used as rotational degree-of-freedom (RDOF) mechanisms at the tip of BSESCs to reduce friction and improve repeatability, while also highlighting the positive relationship between tip rotatability and the attractive force generated. Following the law of conservation of energy, an analytical calculation was performed using a beam-spring-capacitor model to establish the correlation between tip rotatability and the maximum attractive force generated through energy system analysis. An analytical solution was derived, explicitly defining the relationship between tip rotatability and the achievable attractive force. The results were plotted using MATLAB. Experimental validations were carried out by fabricating devices that differed only in tip rotatability, and measurements of the attractive force were taken. Both analytical and experimental results clearly demonstrate a positive relationship between tip rotatability and attractive force generation in BSESCs. The use of torsion springs effectively reduces the energy concentration at the tip, delaying detachment while simultaneously increasing the attractive force, significantly improving the overall performance of BSESCs. These findings provide a foundation for future industrial applications, particularly for automated large-area manipulation of irregularly shaped targets in industries such as screen production and semiconductors.

Radiative Back-Reaction on Charged Particle Motion in the Dipole Magnetosphere of Neutron Stars

The motion of charged particles under the Lorentz force in the magnetosphere of neutron stars, represented by a dipole field in the Schwarzschild spacetime, can be determined by an effective potential, whose local extrema govern circular orbits both in and off the equatorial plane, which coincides with the symmetry plane of the dipole field. In this work, we provide a detailed description of the properties of these “conservative” circular orbits and, using the approximation represented by the Landau-Lifshitz equation, examine the role of the radiative back-reaction force that influences the motion of charged particles following both the in and off equatorial circular orbits, as well as the chaotic orbits confined to belts centered around the circular orbits. To provide clear insight into these dynamics, we compare particle motion with and without the back-reaction force. We demonstrate that, in the case of an attractive Lorentz force, the back-reaction leads to the charged particles falling onto the neutron star's surface in all scenarios considered. For the repulsive Lorentz force, in combination with the back-reaction force, we observe a widening of stable equatorial circular orbits; the off-equatorial orbits shift toward the equatorial plane and subsequently widen if they are sufficiently close to the plane. Otherwise, the off-equatorial orbits evolve toward the neutron star surface. The critical latitude, which separates orbital widening from falling onto the surface, is determined numerically as a function of the electromagnetic interaction's intensity.

Translation, a measure of force of attraction? States, international organizations and the consecrating power of translation

ABSTRACT Based on the premise that both translations and collective bodies have historically been used to build collective identities, shape their images, and defend their interests, this article examines several projects constituting the translation policy of the Intellectual Cooperation Organization (1925–1945) and the United Nations Educational, Scientific and Cultural Organization (1945–) from a soft-power perspective. In the first section, I identify several contemporary trends in translation studies that share an interest in the state, though I also delve into parallel critiques against methodological nationalism. The second section addresses states and international organizations as agents of translation that maximize the potential of translation as a soft-power resource. The third and the fourth section examine two specific translation projects as soft-power resources from the perspective of the producing end. The fifth section examines the way the press of the time covered said projects and discusses their reception in different social spaces. This case study is used as a heuristic tool to discuss states as relevant objects of study in translation studies, the multiple receptions of translations, and the consecrating power of translation.

Atmospheric implications of hydrogen bonding between methanesulfonic acid and 12 kinds of N-containing compounds

The hydrogen bonding interactions between methanesulfonic acid (MSA) and NHx compounds, such as ammonia (A), alkylamines (aNHx), and cyclic amino compounds (cNHx), were investigated using density functional theory, atoms in molecules, localized molecular orbitals-based energy decomposition analysis, and atmospheric clusters dynamic code methods. The results revealed that these dimers exhibit hydrogen bonds by SOH⋯N interactions. MSA–cNHx dimers showed higher binding energies compared to MSA–aNHx/A dimers. Topological analysis using AIM confirmed the presence of hydrogen bonding in these dimers by ρ(r) and ∇2ρ(r). The results of IRI indicate that there are different strength types of hydrogen bonding interactions in these dimers. LMO–EDA highlighted electrostatic interactions as the main attractive force, particularly in MSA–cNHx dimers. ACDC results showed a low evaporation rate for MSA–cNHx dimers compared to others. These findings suggest that MSA plays a crucial role in NPF events, and MSA–cNHx clusters could potentially act as nucleation nuclei in the atmosphere.

Coarse-Grained MD Simulations of the Capillary Interaction between a Sphere and a Binary Fluid with Truncated Lennard-Jones Potentials.

In atomic force microscopy experiments on fluid samples, a capillary bridge forms between the tip and the fluid, causing an attractive capillary force. Here, we present a computational model of the capillary interaction between a solid sphere and a coarse-grained Lennard-Jones fluid containing 10% antifreeze particles with an enlarged van der Waals radius. The capillary force acting on the sphere is obtained from the displacement of the sphere in a trap potential as the sphere is incrementally approached and then retracted from the fluid. This yields force-distance data similar to that obtained in atomic force microscopy experiments. We use this methodology to study the influence of the cutoff radius of the truncated Lennard-Jones potentials on the capillary force and its temperature dependence. The latter is found to scale with the critical temperature of the system. With the presented approach, the tip-sample interaction can be studied for a wide range of complex fluids, particle shapes, and force-probing schemes.

A two-dimensional numerical characterization on the droplet dynamics in the electric field by VOSET method

A coupled volume-of-fluid and level set (VOSET) model is extended to the simulation of electro-hydrodynamic (EHD) flow. The good accuracy of proposed model is validated by comparing with previous results. Although the electrostrictive force might be greater than the Coulomb and dielectric forces under certain conditions, it has no influence on droplet dynamic behaviors except the pressure distribution. The electro-coalescence of droplet pair is systematically investigated. In addition to the coalescence and repulsion, two droplets might neither coalesce nor repulse with the repulsive hydrodynamic force and attractive electric force strike a balance. The electro-coalescence of two droplets always happens as long as the electric conductivity ratio is smaller than the permittivity ratio. The critical permittivity ratio separating the coalescence and repulsion of droplets increases as the increase of electric conductivity ratio. The electro-coalescence time of two droplets decreases as the permittivity ratio and electric capillary number increase. Nevertheless, the electro-coalescence time shows different variation tendency as the increase of electric conductivity ratio with different permittivity ratios and electric capillary numbers.

Effect of surface charge on mechano-bactericidal activity of cellulose nanocrystals constructed chevaux-de-frise and meat preservation

The nanostructured insect wings have inspired the development of antimicrobial surfaces with mechano-bactericidal activity. For the first time, a chevaux-de-frise-like nanostructure was fabricated through the coating of cellulose nanocrystals (CNC) onto regenerated cellulose (RC) films via vacuum filtration and the impact of contact time, temperature, and surface topography on eliminating foodborne bacteria was examined. Herein, our focus is to explore in more detail how the surface charge of CNC affects the mechano-bactericidal activity and the performance of chevaux-de-frise-like nanostructure in meat preservation. CNC with neutral (weak), negative, and positive charges were prepared by hydrochloric acid hydrolysis (HCNC), TEMPO oxidation (TCNC), and amination (ACNC), respectively, and showed similar reinforcing effects on the tensile strength (increased from 74.23 ± 1.20 to about 100 MPa) and water vapor barrier property (reduced from 1.83 ± 0.08 to about 1.20 × 10−7 g m−1 h−1 Pa−1). Among them, RC-ACNC showed the highest log reduction against Escherichia coli (0.83 ± 0.06) and Staphylococcus aureus (0.69 ± 0.04) after 5 min contact, respectively, indicating the important role of attractive force in fast eliminating bacteria upon contact. It was worth noting that, during the meat preservation test, all three CNC-coated RC films exhibited a similar 0.4 log reduction of bacteria after day 4, likely due to the same physical attachment with an extended contact time. Therefore, the construction of chevaux-de-frise nanostructure from CNC on food packaging provides a sustainable strategy to contribute to preventing bacterial growth.

A Topological Investigation of the Cosmic Web Formation

N-body simulations of the evolution of the large-scale structure of the universe (the Cosmic Web) were run while altering attractive gravity laws and initial conditions, in order to infer which properties of the universe are revealed by its current large-scale topology. The Cosmic Web was found to develop regardless of the gravitational alteration made. Significantly altering the initial conditions from Gaussian distribution ones was found to eliminate the Cosmic Web. Thus, we require small random perturbations in otherwise uniform initial conditions in the early universe, under an attractive gravitational force, for the Cosmic Web to develop.

Cnicus Benedictus roots as a low-cost adsorbent for methylene blue dye removal from aqueous solution: kinetic and equilibrium studies

In this research, Cnicus Benedictus roots powder (CBRP) was utilized as a low-cost adsorbent for removing methylene blue (MB) as a cationic dye from aqueous solution. Characterization of CBRP by Boehm titration method, Fourier transform infrared (FT-IR) and environmental scanning electron microscope (ESEM) indicates the presence of different types of functional groups and a very rough surface filled with cavities, suitable for MB adsorption. The effect of various parameters such as CBRP dose (0.2–2 g/1L), contact time (0–180 min), initial pH (1–10), coexisting anions/cations and the initial MB concentration (100–500 mg L−1) on MB adsorption were examined, the results showed that MB uptake depends on the pH of solution, the electrostatic attraction forces, the formation of H-bonds and π–π interactions are the possible CBRP–MB interaction mechanisms. Adsorption kinetic of MB on CBRP was best represented by linear and non-linear form of the pseudo-second order model. The experimental equilibrium data were best described by linear and non-linear forms of Langmuir and Redlich–Peterson isotherm models (R 2> 0.98) with a maximum MB adsorption capacity of 85.47 mg g−1 at 25 °C, the adsorption efficiency R (%) was greater than 90 (%). MB adsorption-desorption experiments showed the reusability of CBRP for five consecutive cycles. According to the obtained results, CBRP can be used as a natural adsorbent material for cationic dyes removal from aqueous solution.

A critical state μ(I)-rheology model for cohesive granular flows

The dynamic behaviour of granular media can be observed widely in nature and in many industrial processes. Yet, the modelling of such media remains challenging as they may act with solid-like and fluid-like properties depending on the rate of the flow and can display a varying apparent friction, cohesion and compressibility. Over the last two decades, the $\mu (I)$ -rheology has become well established for modelling granular liquids in a fluid mechanics framework where the apparent friction $\mu$ depends on the inertial number $I$ . In the geo-mechanics community, modelling the deformation of granular solids typically relies on concepts from critical state soil mechanics. Along the lines of recent attempts to combine critical state and the $\mu (I)$ -rheology, we develop a continuum model based on modified cam-clay in an elastoplastic framework which recovers the $\mu (I)$ -rheology under flow. This model permits a treatment of plastic compressibility in systems with or without cohesion, where the cohesion is assumed to be the result of persistent inter-granular attractive forces. Implemented in a two- and three-dimensional material point method, it allows for the trivial treatment of the free surface. The proposed model approximately reproduces analytical solutions of steady-state cohesionless flow and is further compared with previous cohesive and cohesionless experiments. In particular, satisfactory agreements with several experiments of granular collapse are demonstrated, albeit with shear bands which can affect the smoothness of the surface. Finally, the model is able to qualitatively reproduce the multiple steady-state solutions of granular flow recently observed in experiments of flow over obstacles.