Attenuation Of Ultrasonic Waves Research Articles

A novel approach for state-of-charge estimation of lithium-ion batteries by quasi-static component generation of ultrasonic waves

Lithium-ion batteries content complex internal components, such as porous media and electrolytes, which result in strong scattering and high attenuation of ultrasonic waves in these batteries. The low attenuative feature of the quasi-static components (QSCs) of ultrasonic waves offers great potential for nondestructive assessment of highly attenuating and porous materials. This paper presents an innovative approach for estimating the state-of-charge (SOC) of lithium-ion batteries using QSC of ultrasonic waves. Experimental results demonstrate a clear and repeatable linear relationship between the amplitudes of the generated QSC and the SOC of lithium-ion batteries. In addition, the relationships between different SOCs of the battery and the conventional linear ultrasonic parameters, second harmonic generation (SHG), and the QSC were compared to verify the improved sensitivity of the proposed approach. Notably, compared to linear ultrasonic features and the SHG, the generated QSC shows much higher sensitivity to the variations of SOC. We employ the phase-reversal method to further enhance the signal-to-noise ratio of measured QSC signals. The experimental results demonstrate that the proposed method exhibits a heightened sensitivity to changes in the SOC of batteries, resulting in significantly enhanced detection accuracy and resolution. This method effectively addresses the deficiencies observed in the current detection methods such as limited accuracy and sluggish response times. This method provides a new solution to overcome this challenge. Meanwhile, it also confirms that nonlinear ultrasound promises an alternative method for SOC assessment, providing a foundation for efficient and safe battery management practices.

Recent Progress in Ultrasonic Nondestructive Characterization of Material Microstructures: A Review

The scattering and attenuation of high frequency ultrasonic wave in polycrystalline materials such as metal and ceramics have implication of material microstructures. Many studies have recently developed sophisticate forward models that corelate ultrasonic scattering and attenuation with different types of polycrystalline materials. Furthermore, some studies have proposal effective methodologies to nondestructively determine polycrystal microstructures from ultrasonic measurements, namely solving the inversion problems. Its applications cover titanium alloys in aerospace, carbon steels in transportation, additively manufactured components and machineries, to name a few. This paper reviews recent progress in ultrasonic nondestructive characterization of metal microstructures, including voids, grain size, crystallographic texture and grain boundary.

Sideband Peak Count – a new nonlinear ultrasonic technique for monitoring damage progression in engineering materials

Linear ultrasonic (LU) techniques used by majority of the researchers working in material damage monitoring, are reliable for detecting relatively large defects. If the defect dimensions are in the range of the ultrasonic wavelength or larger, then those defects can be detected by analyzing the scattered ultrasonic fields. Material damage affects LU parameters such as ultrasonic wave speed and attenuation and their changes are detectable for relatively large defects. However, for small defects (when defect dimensions are significantly smaller than the wavelength of the propagating signal) the changes in the LU parameters are too small to detect or measure reliably. For detecting small defects engineers often use high frequency ultrasonic signals to make the defect dimensions greater than the wavelength. However, high frequency signals attenuate quickly and therefore, only very small regions near the ultrasonic probe can be inspected in this manner. Inspecting large structures by high frequency ultrasonic signals requires moving the probe mechanically from one point to the next and therefore, can be very time consuming. Nonlinear ultrasonic (NLU) technique on the other hand does not need to satisfy this restricting condition that the wavelength of the signal must be smaller than the defect size. NLU works well when the signal wavelength is much larger than the defect size. Therefore, relatively low frequency signals that can propagate a long distance and monitor a large area of a structure can be used for NLU measurements. Different NLU techniques can be used for detection and monitoring of small damages in a specimen. A relatively new NLU technique called the Sideband Peak Count-Index or SPC-I technique has been developed by the author and his collaborators. SPC-I technique for monitoring different types of materials – composites, metals, concrete, and other cement-based materials has been found to be effective. Along with those success stories of SPC-I the effect of topography and the advantage of topological sensing is also discussed in this presentation.

An ultrasound approach to characterize mixtures of vegetable oils with the same type of dominant chemical compositions

The non-destructive characterization of ultrasonic properties in mixtures of vegetable oils with similar dominant chemical compositions is becoming increasingly important for various applications. The combination of ultrasonic wave reflection as an experimental method and the partial least squares statistical method has been employed to establish reference graphs and models for detecting adulterated oils. This experimental study focuses precisely on measuring the attenuation and ultrasonic velocity of mixtures of organic argan oil with volumetric fractions of sesame oil, peanut oil or argan oil extracted from kernels depulped by goats. The measurements exhibit distinct behaviors manifested by electrical signals for the mixture obtained after the addition of each volumetric fraction, reflecting the capability of the adopted method to detect this difference. A notable decrease in ultrasonic velocity is observed in the mixtures as the quantity of added oil increases, with a maximum variation of 11 m/s for the argan/peanut oil mixture. Conversely, The attenuation of ultrasonic waves increases proportionally with the added volumetric fractions, with the argan/peanut oil mixture exhibiting an attenuation variation range of 3.57 Np/m. Prediction models for the added volumetric fractions to organic argan oil based on attenuation and ultrasonic velocity, showed a weak correlation between the predicted quantity of added oil and the actual quantity added to organic argan oil, with determination coefficients (r2) not exceeding 65%. The weak correlation is due to the similar chemical compositions of the oils. These results underscore the value of ultrasonic-statistical analysis for authenticating and ensuring the quality of vegetable oils. However, the limitations highlight the need to refine models for better accuracy. This method can verify oil authenticity in the food industry, ensuring consumer protection and quality standards. Additionally, it offers a quick and simple alternative to traditional methods, reducing costs and improving efficiency in quality control processes.

Characterization of cracking-healing cycle of asphalt mixture based on air-coupled second harmonic measurement using Duffing-van der pol oscillator

Second harmonic generation (SHG) technique using Rayleigh surface wave has been successfully attempted for the non-destruction evaluation of asphalt mixture during the self-healing process. The air-coupled transducer placement is desirable for the convenient implementation of SHG for the large-scale detection. Nevertheless, the pronounced attenuation of ultrasonic wave by air-coupled propagation will cause the second harmonic induced by microcracks to be barely detectable, particularly under the influence of inevitable noise. In this study, a novel approach by combining Duffing oscillator and van der pol equation is developed to identify and quantify the second harmonic in noise-contained signals based on the phase trajectory and periodic trajectory area exponent. The multi-physics finite element model is first established to simulate the air-asphalt propagation of Rayleigh waves, and proof-of-concept numerical simulations are carried out to estimate the second harmonic amplitude of noise-contaminated signals. The air-coupled SHG experiments are conducted, and the approach of the Duffing-van der pol oscillator is applied to extract the second harmonic in experimental data, and the self-healing behavior of asphalt mixture is analyzed through the variation of the nonlinear parameter of SHG measurements. The results indicate that the contactless SHG method combined with the Duffing-van der pol oscillator can effectively realize the convenient and reliable estimation of the nonlinear ultrasonic signal during the cycle of asphalt deterioration and healing, which is important for the property characterization of asphalt mixture considering its high attenuation to the ultrasonic waves.

Dielectric and Ultrasonic Properties of PDMS/TiO2 Nanocomposites.

This work presents the dielectric and ultrasonic properties of polydimethylsiloxane (PDMS) nanocomposites filled with titanium dioxide nanoparticles. The dielectric study was performed over a very broad range of frequencies (20 Hz-3 THz). The dielectric permittivity was almost frequency-independent in all the composites at room temperature over the whole range of measurement frequencies, and the dielectric losses were very low under these conditions (less than 2). The dielectric permittivity strongly increases with the nanoparticle concentration according to the Maxwell-Garnet model. Therefore, the investigated composites are suitable for various flexible electronic applications, particularly in the microwave and terahertz frequency ranges. Dielectric dispersion and increased attenuation of ultrasonic waves were observed at lower temperatures (below 280 K) due to the relaxation of polymer molecules at the PDMS/TiO2 interface and in the polymer matrix. The relaxation time followed the Vogel-Vulcher law, while the freezing temperature increased with the titanium dioxide concentration due to interactions between the polymer molecules and nanoparticles. The significant hysteresis in the ultrasonic properties indicated that titanium dioxide acts as a crystallization center. This is confirmed by the correlation between the hysteresis in the ultrasonic properties and the structure of the composites. The small difference in the activation energy values obtained from the ultrasonic and dielectric investigations is related to the fact that the dielectric dispersion is slightly broader than the Debye-type dielectric dispersion.

Numerical and experimental study of ultrasonic seismic waves propagation and attenuation on high‐quality factor samples

AbstractWe propose an approach for measuring seismic attenuation at ultrasonic frequencies on laboratory‐scale samples. We use a Gaussian filter to select a bandwidth of frequencies to identify the attenuation in a small window and, by moving the window across the frequency content of the data, we determine the frequency‐dependent attenuation function. We assess the validity of the method with three‐dimensional numerical simulations of seismic wave propagation across different sample geometries, using free surface boundary conditions. We perform the simulations using viscoelastic media under various seismic attenuation models. Our numerical results indicate that we can successfully recover the representative viscoelastic attenuation parameters of the media, regardless of the sample geometry, by processing the seismic signal recorded either within the volume or at the boundaries. Due to the equipartition phenomenon, the energy of S‐waves is consistently higher in seismic records than that of P‐waves. Therefore, we systematically recover the attenuating properties of S‐waves in the medium. We also conduct experiments of seismic wave propagation on samples of aluminum and Fontainebleau sandstone to validate our approach with real data. The quality factor of the S‐wave in the aluminum medium increases from 300 to 7000 between 60 kHz and 1.2 MHz. The Fontainebleau sandstone, which is more attenuating, exhibits a that increases from 200 at 60 kHz to 1000 at 1.2 MHz. With our approach, we are not only able to recover the attenuation property but also identify the frequency‐dependent attenuation model of the samples. Our method allows for seismic attenuation recovery at ultrasonic frequencies in low‐attenuating media.

Low-temperature relaxation of various samarium phosphate glasses

Abstract Glasses constructed, (1 − x) (0.6595P2O5–0.0958ZnO–0.2447PbO) · xSm2O3 with x = 0.00, 0.0045, 0.0089, 0.0132, and 0.0261 mol%, had been created to investigate the attenuation of longitudinal ultrasonic waves at 2, 4, 6, and 14 MHz frequencies between 120 and 300 K. At a variety of temperatures, clear peaks of a large absorption curve have been seen. These peaks are dependent on the structure of the glass as well as the switching frequency. Maximum peaks have been shown to shift to higher temperatures, and the increase in overall frequency points to the presence of some kind of relaxation process. A thermally induced relaxation process is responsible for producing a calm approach, which has been identified as a result of this mechanism. A quiet approach has been defined as a consequence of a thermally triggered relaxation mechanism. The variance of the mean energy of activation of the mechanism counts on primarily the amount of Sm2O3 mol%. Such dependency has been evaluated based on the loss of normal linear solid form, attaining low dispersion, and a large allocation of Arrhenius kind relaxation through temperature-autonomous relaxation power. The measured acoustical energy of activation values have been quantifiably represented based on the number of loss centers (amount of oxygen atoms that now move at a double-well potential).

Parameters evaluation in the process of solid phase pulp sedimentation in technological units of beneficiation plants

The aim of the research is the analysis and modeling of the process of sedimentation of the solid phase of the pulp in the technological units of processing plants to assess the density of particles of crushed ore. The paper analyzes domestic and foreign experience; methods of mathematical modeling were used, as well as methods of mathematical statistics and probability theory for processing the results of experiments. Scientific novelty consists in developing and substantiating a method for estimating the density of crushed ore particles in the process of their sedimentation directly in the process units of beneficiation plants. Practical value consists in developing a methodology for determining the characteristics of the enriched raw materials, which make it possible to form the degree of grinding necessary for the full disclosure of mineral formations. It was proposed to use the density of ore particles as an indicator of changes in the quality characteristics of the ore received for beneficiation, which is determined on the basis of measurements of the attenuation of volumetric ultrasonic waves and Lamb waves propagating in the pulp and the wall of the technological sump that is in contact with it. These measurements must be synchronized with the results of measurements of the pulp level in the sump during its working operation. The proposed method makes it possible to dynamically correct the parameters of the model of a closed ore grinding cycle, depending on the quality characteristics of the feedstock, and thereby form the conditions for the full disclosure of inclusions of the useful component in the product entering the magnetic separation or flotation.

Ultrasonic in situ measurements for hybrid metal additive manufacturing

Hybrid additive manufacturing (AM) of metals includes synergistic secondary processes such as milling or peening that impart changes to the component for improved performance. Although a valuable concept, implementation is difficult to verify due to a current lack of in situ inspection methods. In this presentation, two different strategies are described with respect to ultrasonic inspections for hybrid metal AM. Both are used for inspections during laser-based directed energy deposition with milling as the hybrid process. The first uses a transducer mounted below the build plate. This configuration allows waves to interrogate the entire sample during all additive and subtractive manufacturing steps. Experiments with Ti6Al4V show the changes in ultrasonic wave speed and attenuation that track the manufacturing temporally. The second inspection approach uses ultrasonic surface waves at the top surface of the sample. These measurements are used on samples of 316L stainless steel at the end of additive steps as well as before and after milling to quantify localized information regarding the most recent layers. Wave speed and diffuse scattering information show the variability with respect to sample geometry, build height, and process parameters. Finally, advantages and limitations of both approaches and prospects for validated parts are discussed.

Modelling of ultrasonic vibration-assisted forming considering the distribution of ultrasonic field with structure deformation

Ultrasonic vibration-assisted (UVA) forming is typically used to promote the forming quality of complex structures due to the acoustic-plastic effect. Ultrasonic vibration (UV) is always applied via the contact of tools with the structure surface; thus a distribution of ultrasonic field exists owing to the propagation and attenuation of ultrasonic waves, which may vary with structural deformation. This makes the prediction and control of ultrasonic effect extremely difficult in achieving high forming quality. To develop a new coupling model considering the interaction between ultrasonic field and deformation field, UVA tensile experiments of superalloy sheet were performed first. The experimental results demonstrated that UV had a local effect on the tensile specimen, resulting in non-uniform distribution of temperature, strain and dislocation density. During the modelling, the intensity of ultrasonic field was quantified by acoustic energy density, which can be calculated using vibration velocity. A dislocation-based constitutive relation was also established, in which ultrasonic-related functions were introduced to reflect the effect of ultrasonic field on structural deformation. Then, a sequential coupling modelling method was proposed. Through the cyclic calculation of ultrasonic field and deformation field, the simulation of UVA forming considering the distribution of ultrasonic field with structure deformation was realised. With the coupling model, the non-uniform distribution of deformation accompanied by a non-uniform ultrasonic field during UVA forming was revealed. When applied to a complex W-bending process, the targeted softening effect on the W-bending specimen was precisely predicted. The coupling model is expected to lay a foundation for the optimisation and control of the UVA forming process.

Study of the attenuation of ultrasonic oscilliations in 3D-orthogonal woven composite

The particularities of 3D-woven composite’s defects are observed. Automated ultrasonic immersion through-transmission technique for their non-destructive testing is offered. X-ray computed tomography (X-ray CT) application for the definition of the reasons of ultrasonic waves high attenuation in 3D-orthogonal woven composite sample is described. The analysis of defects detected with X-ray CT is shown. The suggestion about connection between quantity of projection of defects total area at the plane which is perpendicular to ultrasonic wave propagation and ultrasonic wave attenuation has been made.

Axial stress measurement for tightened bolt based on the effect of stress on ultrasonic wave attenuation

ABSTRACT Accurate assessment and monitoring of axial stress during the service life of the bolt connection is of great significance in ensuring the stability and reliability of the aerospace structure. The current acoustoelastic method requires both transverse and longitudinal mode waves and is less sensitive to small-size bolts, resulting in relatively larger errors in the evaluation of axial stress. In this paper, an axial stress measurement method with only a single longitudinal/transverse transducer for tightened bolts based on a novel attenuation-based model is introduced. The ultrasonic responses under axial preload in different frequency bands are comprehensively reflected through the energy attenuation coefficient matrix. In addition, an experimental method for selecting the optimal frequency band is given. Furthermore, the semi-permanent coupling method is proposed to provide a stable coupling condition to verify the feasibility of the attenuation-based model. Loading tests and ultrasonic tests were conducted on two kinds of strength-grade materials to obtain the calibration curves of both the longitudinal and transverse attenuation models. The experimental results show that the energy attenuation coefficient is positively correlated with the axial stress in a specific frequency range and the calibrated curve has a high fitting rate with a quadratic fitting function. The average relative error of the prediction results is less than 7.5%, which is better than the conventional acoustoelastic effect model.

Ultrasonic diagnostics in the study of coatings applied by gas-flame spraying

The quality control of coatings when selecting a powder material for the restoration of worn surfaces by gas-flame spraying is hampered by the lack of an operational method of non-destructive diagnostics. We present the results of studying coatings applied by gas-flame spraying using ultrasonic diagnostics. The powder coatings obtained using different technologies of gas-flame spraying were studied. Features of the structural state of coatings were evaluated using a model based on the effect of the structural inhomogeneities of the coating on the velocity and attenuation of ultrasonic waves. It is shown that the amplitude-time characteristics of the pulse of surface elastic waves when they pass along the coating are consistent with the data obtained from friction and hardness tests, the characteristics of the pulse being dependent on the quality of the coating material. The obtained results can be used to improve the quality control of coatings formed by gas-flame spraying.

Evidence of Self-Association and Conformational Change in Nisin Antimicrobial Polypeptide Solutions: A Combined Raman and Ultrasonic Relaxation Spectroscopic and Theoretical Study

The polypeptide Nisin is characterized by antibacterial properties, making it a compound with many applications, mainly in the food industry. As a result, a deeper understanding of its behaviour, especially after its dissolution in water, is of the utmost importance. This could be possible through the study of aqueous solutions of Nisin by combining vibrational and acoustic spectroscopic techniques. The velocity and attenuation of ultrasonic waves propagating in aqueous solutions of the polypeptide Nisin were measured as a function of concentration and temperature. The computational investigation of the molecular docking between Nisin monomeric units revealed the formation of dimeric units. The main chemical changes occurring in Nisin structure in the aqueous environment were tracked using Raman spectroscopy, and special spectral markers were used to establish the underlying structural mechanism. Spectral changes evidenced the presence of the dimerization reaction between Nisin monomeric species. The UV/Vis absorption spectra were dominated by the presence of π → π* transitions in the peptide bonds attributed to secondary structural elements such as α-helix, β-sheets and random coils. The analysis of the acoustic spectra revealed that the processes primarily responsible for the observed chemical relaxations are probably the conformational change between possible conformers of Nisin and its self-aggregation mechanism, namely, the dimerization reaction. The activation enthalpy and the enthalpy difference between the two isomeric forms were estimated to be equal to ΔH1* = 0.354 ± 0.028 kcal/mol and ΔH10 = 3.008 ± 0.367 kcal/mol, respectively. The corresponding thermodynamic parameters of the self-aggregation mechanism were found to be ΔH2* = 0.261 ± 0.004 kcal/mol and ΔH20 = 3.340 ± 0.364 kcal/mol. The effect of frequency on the excess sound absorption of Nisin solutions enabled us to estimate the rate constants of the self-aggregation mechanism and evaluate the isentropic and isothermal volume changes associated with the relaxation processes occurring in this system. The results are discussed in relation to theoretical and experimental findings.

Estimation of Grain Size and Composition in Steel Using Laser UltraSonics Simulations at Different Temperatures

The applicability of laser ultrasonics for the determination of grain size and phase composition in steels under different temperatures was investigated. This was done by obtaining the velocity and attenuation of propagating ultrasonic waves in a simulated steel medium. Samples of ferrite and austenite with varying microstructures were modelled and simulated with the finite difference method, as were samples with varying ratios of austenite and martensite. The temperature of the medium was taken into account as an essential parameter, since both velocity and attenuation are temperature dependent. Results of the velocity and attenuation analysis showed that the use of the wave propagation velocity is not feasible for determination of grain size or phase composition due to a high sensitivity to temperature and sample thickness. The frequency-dependent ultrasonic wave attenuation was less sensitive to the variation of temperature and sample thickness. It can be concluded that accurate knowledge of the temperature is essential for obtaining a correct grain size or phase ratio estimation: a temperature accuracy of 100 °C yields a grain size accuracy in the order of a micrometer using the attenuation. Similarly, a temperature accuracy of 70 °C leads to a phase ratio estimation accuracy of 10%.

EFFECT OF PRESSURE ON ELASTIC CONSTANTS AND RELATED PROPERTIES OF RARE-EARTH INTERMETALLIC COMPOUND TBNIAL

The Lennard-Jones potential approach is used to investigate the effect of pressure on the ultrasonic and elastic properties of the rare-earth ternary TbNiAl intermetallic compound. The second- and third-order elastic constants of TbNiAl are considered using the potential model. The pressure-dependent higher-order elastic constants are studied, and it is observed that the elastic constants of the TbNiAl compound increased monotonously with pressure. The hexagonal TbNiAl compound is mechanically stable up to the pressure 20 GPa according to the Born elastic stability criteria. The Voigt-Reuss-Hill approach is used to compute such elastic parameters as Young’s modulus, bulk modulus, Poisson’s ratio, and shear modulus in the pressure range 0-45 GPa. Hardness, melting temperature, and anisotropy are also determined for the intermetallic TbNiAl compound. The pressure-dependent velocities and attenuation of ultrasonic waves in this ternary compound are evaluated. The computation results are also satisfactory in estimating the Debye temperature and thermal conductivity Kmin under different pressure. It is observed that TbNiAl has a significant anisotropy at zero pressure, which becomes stronger as the pressure increased. This ternary compound behaves as its purest form at higher pressure and is more ductile, which is demonstrated by the minimum attenuation.

Fractal wave velocity evolution model of ultrasonic propagation and attenuation in water-bearing coal

A fractal wave velocity evolution model of the water-bearing coal is constructed to explore the relationship between the complex pore and fissure structure parameters of the water-bearing coal mass and the ultrasonic P-wave velocity, based on the fractal theory and with consideration of the attenuation of ultrasonic waves propagating in the porous media of coal. In addition, experimental study and numerical analysis of the model are carried out, the following conclusions are reached. (1) The P-wave velocity increases with the increase of the coal sample length, the water content, the wave velocity in the coal matrix and the maximum pore radius, and decreases with the increase of the minimum pore radius. (2) The experimental results also show that the P-wave velocity increases with the increase of the water content and fractal dimension of the coal sample, indicating that the wave velocity prediction model has high accuracy. (3) The fractal dimension, water content, wave velocity in the coal matrix and coal sample length have great effects on the P-wave velocity of coal samples, while the minimum pore radius and the maximum pore radius have relatively little influences on the P-wave velocity.

Assessment of flaws in cold sintered ZnO via longitudinal ultrasonic wave speed and attenuation measurements

The cold sintering process (CSP) is a low temperature processing technique that utilizes a transient phase to synthesize dense ceramics. However, some CSP parts contain microflaws that arise due to pressure gradients and inhomogeneities in temperature and distribution of the transient phase. This work uses high frequency ultrasound (20 MHz) to verify the presence of defects larger than 15 μm in effective radius in CSP ZnO samples of varying densities (84–97%). The acoustic data were compared to X-ray Computed Tomography (XCT) images to validate the findings. Acoustic metrics used in this work include wave speed, which is affected by differences in the effective elastic properties of the medium, and attenuation, which is wave energy loss due to scattering from defects, including those smaller than the wavelength. Wave speed maps were inhomogeneous suggesting density gradients which were verified with SEM. Areas of high attenuation (> 300 Np/m) are present in all samples independent of relative density and correspond to defects identified in XCT ranging from 15 μm to 50 μm in effective radius. This suggests the presence of microflaws possibly due to the inhomogeneous removal of the transient phase. However, some high attenuation spots do not correspond to visible defects in XCT which suggests the presence of features such as texturing which are undetectable with XCT. These results show the viability of high frequency ultrasound for defect detection in cold sintered ZnO.

Theory of ultrasound propagation in LuCo3 near the low-spin–high-spin crossover

The possibility of experimental observation of the ultrasonic attenuation in the ferromagnet $\mathrm{LuCo}{}_{3}$ near the low-spin-high-spin crossover is discussed. We show that ultrasound propagation gives rise to transitions between states of the magnon band due to absorption of phonons, and this process is highly sensitive to the value of magnetization. The high magnetic field, which governs the crossover, alters the ultrasound propagation regime from off-resonant to resonant and we formulate a criterion of the change. Calculated temperature and field dependences of the ultrasonic wave number and attenuation clearly demonstrate anomalies in these characteristics in the vicinity of the crossover at intermediate temperatures far below the Curie temperature.