Vacuum polarization, nuclear structure and recoil, radiative corrections to the hyperfine structure of S-states in muonic ions of lithium, beryllium and boron are calculated on the basis of quasipotential method in quantum electrodynamics. We consider contributions in first and second orders of perturbation theory which have the order α5 and α6 in the energy spectrum. Total values of hyperfine splittings are obtained which can be used for a comparison with future experimental data.
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