In this study, we employed the linear combination operation and a modified Lee-Low-Pines unitary transformation method to explore the ground state properties of an interacting electron coupled with piezo-acoustic phonons within a quantum well featuring asymmetric Gaussian confinement potential well under the influence of magnetic and electric fields. We calculated various properties, including the ground state energy, ground state binding energy, magnetic moment, magnetic susceptibility, and polarizability of the weakly coupled piezoelectric polaron. The effects of the magnetic and electric fields, electron-phonon weak coupling strength, Debye cut-off wavenumber, and confinement depth and range on these properties were thoroughly analyzed. Our findings reveal that the ground state energy decreases with increasing the Debye wavenumber, confinement range, and electron-phonon weak coupling strength. In contrast, the ground state binding energy shows the opposite trend, increasing with these parameters. Furthermore, the magnetic and electric fields, confinement depth and range, electron-phonon coupling strength, and Debye wavenumber are critical factors that significantly impact the magnetic and optical properties of the piezoelectric polaron.