X-rays from outer space are prevented by the atmosphere from reaching the ground. Therefore, X-rays astronomy developed as a new branch of astrophysics only with the advent of spatial technologies. It was born 25 years ago, on the 12 of June 1962, with the first observation of a remote X-ray source (Scorpius X-1). Whereas the pioneering experiments (UHURU, ...) brought to light the very existence of X-ray sources, the most recent ones (such as the EINSTEIN and EXOSAT satellites) were versatile and sophisticated observatories which performed spectroscopic studies as well as imagery. These rocket and satellite experiments have revealed that X-rays are emitted in most astrophysical sites : stars, binary stellar systems, interstellar medium, active galaxies and quasars, galaxy clusters, intercluster medium. Since X-rays originate in highly energetic processes (thermal emission of very hot plasmas, synchrotron emission of relativistic particles, ...) they shed some light on cataclysmic phenomena such as stellar explosions and propagation of the resulting shock wave, huge matter infalls onto the surface of black holes, ... X-ray astronomy may have not yet truly come of age : drastic improvements are expected from a new generation of instruments, such as the high resolution spectrometers which are to be implemented on board the future ESA satellite XMM. The interpretation of the wealth of data they will provide will require an ever increasing collaboration with specialists in spectroscopy and atomic processes.