Preparing Yellow River sediment/fly ash/cement-based alkali-activated cementitious materials for coal mine filling can realize the large-scale consumption of Yellow River sediment and reduce the cost of coal mine filling materials. This paper studied the effects of Ca(OH)2, NaOH, and water glass on the properties of coal mine filling materials. Adding activators Ca(OH)2, NaOH, and water glass can improve the compressive strength and shorten the setting time of the filling materials. NaOH and water glass can also significantly reduce the bleeding rate. The mechanism of activators' influence on the mechanical properties of filling materials was explored based on XRD, TGA, FTIR, MIP, and SEM. The alkaline environment provided by NaOH and Ca(OH)2 accelerated the hydration reaction of cement, and the SiO32- from the hydrolysis of water glass can bind to Ca2+ to form C-S-H gel. The co-mixing of water glass and NaOH can make fly ash and Yellow River sediment's active components react more fully, generating more C-S-H and C-A-S-H gels. This can refine the pore size distribution of the filling materials, reduce the content of harmful pores, make the matrix dense, and improve the filling materials' working and mechanical properties. When the NaOH is 0.5 wt%, and the water glass is 13 wt%, the strength of the filling materials prepared by compound doping was the highest, and the working performance met the requirements. The results had broad application prospects and economic value, contributing to ecological and environmental protection and sustainable development.
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