Ash Input Research Articles

Effect of abrupt post‐fire ash inputs on water quality and the phytoplankton community in lentic freshwaters

Abstract One of the major threats to biodiversity is changing fire regimes, particularly increasingly frequent fires, especially during the dry season. However, studies on the direct and indirect effects of fire on biotic responses in aquatic ecosystems are still scarce. In this study, we investigated how water quality and phytoplankton community structure were affected by different ash concentrations from burning vegetation of a tropical savanna. We used a microcosm experiment to simulate the aquatic ecosystem with different ash concentration scenarios and evaluated the water quality and the composition, richness and density of phytoplankton over time. We found increased total phosphorus and ammoniacal nitrogen concentrations after ash addition, in addition to changes in electrical conductivity. We identified 242 phytoplankton taxa throughout the experiment and identified changes in species composition among treatments. We identified changes in the taxonomic richness of total phytoplankton, green algae and desmids over time. The density of total phytoplankton, diatoms, green algae, desmids and cyanobacteria also changed over time. Our results suggest that ash from terrestrial fires affects water quality and phytoplankton communities depending on the proportion of ash input. Our results serve as a basis for further investigations of the effects of fire on abiotic conditions in aquatic ecosystems and their communities over long periods of time. Finally, longer‐term experiments are needed to evaluate delayed responses by the phytoplankton community.

Oil shale enrichment mechanisms in the Lower Cretaceous Jiufotang Formation from the Ludong sag, Songliao Basin, Northeast China

In order to investigate the oil shale enrichment mechanisms and the relationship among gravity flows, volcanism, and oil shale deposition, detailed petrological, sedimentological, and organic geochemical research have been carried out on the Lower Cretaceous Jiufotang Formation in the Ludong sag, Songliao Basin, Northeast China. Seven facies were recognized and were grouped into three facies associations, namely hyperpycnites and intrabasinal turbidites, delta, and lacustrine facies associations. During the deposition of the lower Jiufotang Formation, hyperpycnites were developed during catastrophic flooding events that caused an abrupt increase in the discharge of water and sediment into the deep lacustrine environments, and a delta persisted during normal river discharge intervals and prograded into lacustrine environments. During the deposition of the upper Jiufotang Formation, deep lacustrine facies further expanded, and the extent of hyperpycnites decreased. Four types of oil shales were recognized in the Ludong sag of which those in the lower and upper Jiufotang Formation were defined as medium-to good-quality and good-to best-quality source rocks, respectively, exerting an overall thermal maturity of early oil generation. The lacustrine redox conditions show oxic to dysoxic conditions in the lower Jiufotang Formation, and anoxic to dysoxic conditions in the upper Jiufotang Formation. Oil shales were poorly-developed in the lower Jiufotang Formation and were well-developed in the upper Jiufotang Formation. During the active rift stage of the lower Jiufotang Formation, frequent occurrences of gravity flows and water-carried re-sedimentation of tuffaceous materials were unfavorable for oil shale accumulation. During the waning rift phases of the upper Jiufotang Formation, minor wind-transport of volcanic ash input into the deep lacustrine environments fertilized the lake water and supported algae blooms, leading to reduced oxygen concentrations in the bottom lacustrine waters along with high bioproductivity that were favorable for organic matter preservation and oil shale formation.

Uranium Isotope Constraints on the Pre‐Deposition Time of Asian Dust to the North Pacific Ocean: Implications for Provenance and Iron Supply

AbstractAsian dust delivers highly reactive iron (FeHR) to the Pacific Ocean, affecting marine biogeochemical cycles and Earth's climate. Tracing the source of dust deposited in the Pacific is vital for assessing global nutrient cycles but poses challenges. This work applies the (234U/238U) activity ratio to determine the pre‐deposition time and provenance of dust in North Pacific Ocean sediments (Ocean Drilling Program site 1209B). Results indicate a consistent dust pre‐deposition time (134 ± 10 ka) over the past 300,000 years, except during Marine Isotope Stage 7 when volcanic ash input shortened it to 31 ± 19 ka. Comparing the dust pre‐deposition times to those of the potential source deserts, we identify the dust transported to the North Pacific Ocean was primarily from the Taklamakan Desert, which contains higher FeHR content than other deserts. This finding enhances our understanding of soluble Fe supplied to the oceans, especially in dust circulation models.

Milankovitch cycles recorded by the Late Permian volcanic ash layers in southwestern China

The volcanic activity during the Cenozoic is thought to be forced by Earth's orbit, as it exhibits the Milankovitch cycle. However, the pattern of volcanic activity before the Cenozoic is still unclear. In this study, we studied the volcanic ash-bearing layers preserved in Upper Permian in Southwestern China and analyzed the cycle of volcanic activity from Emeishan Large Igneous Province (ELIP) during the waning stage of Emeishan mantle plume activity. Mineralogy, geochemistry, and gamma-ray (GR) data were used for high-resolution identification of volcanic ash-bearing layers. Al2O3/TiO2, aluminum normalized Th and Sn, and positive anomalies GR data can reflect volcanic ash input. The 206Pb/238U weighted age of zircon ranges from 256.00 ± 2.00 Ma to 251.47 ± 1.29 Ma, indicating synsedimentary volcanic ash. We apply cyclostratigraphic analysis to convert data from the depth domain to the time domain, and then utilize the multitaper method to analyze the cycle of volcanic activity of ELIP. Spectral analysis results reveal that the volcanic activity has long eccentricity (405-kyr), obliquity (∼33-kyr), and precession (∼20-kyr) periods. We propose the astronomical orbital forcing in volcanic activity during the Late Permian, and we have discovered volcanic activity cycles on a larger timescale of astronomical orbital periods (405-kyr long eccentricity). Volcanic activity was significantly correlated with sea level and climate change. During periods of low sea levels, the hot climate causes rapid sea level change, leading to rapid changes in crustal stress and strong volcanic activity. The absolute sea level controls volcanic activity, and the high sea levels suppress volcanic activity.

Numerical simulation on the deposition characteristics of MSWI fly ash particles in a cyclone furnace

In melting municipal solid waste incineration (MSWI) fly ash by cyclone furnace, the deposition characteristics of particles affect the slag flow and the secondary MSWI fly ash formation. In this study, the composition mechanism based on critical viscosity is selected as the particle deposition model to predict the deposition and rebound of particles on the furnace wall. The Riboud model with an accurate viscosity prediction performance is selected, then the particle deposition model is integrated into a commercial computational fluid dynamics (CFD) solver through the user-defined function (UDF) to realize the coupling of particle motion and deposition process. The results show that under the same case, the deposition rate decreases obviously with the increase of MSWI fly ash particle size. And the escape rate reaches a maximum at particle size 120 μm. Controlling the particle size of fly ash particles within 60 μm can effectively reduce the generation of secondary MSWI fly ash. During the forward movement of the fly ash inlet position, the escape of MSWI fly ash particles with large particle sizes has been significantly weakened. This measure not only lowers the post-treatment cost but also dramatically reduces the pretreatment step of MSWI fly ash before the melting and solidification process. In addition, the deposition rate and quality will reach the maximum values, respectively, along with gradually increasing MSWI fly ash input flow. Overall, this study has the guiding significance for reducing the pretreatment steps and post-treatment costs of MSWI fly ash by melting in the cyclone furnace.

Independence Effects of Heat and Ash on Forest Soil Nematode-Trapping Fungi Communities

Heat input and ash residues are main components of vegetation fire disturbances. Understanding the distinct impacts of heat and ash on soil microorganisms is crucial to comprehend and predict the induced changes in soil ecosystem composition and dynamics following different types of fire disturbances. This study’s main goal was to track the dynamic shifts in the community of soil nematode-trapping fungi (NTF) following the separate disturbances of heat and ash by means of a specifically designed experiment conducted in the field. Four simulated fire treatments, one treatment reproducing natural burning, and one control treatment were taken into account. Every ten days following the disturbance, soil samples from each treatment were collected, and soil NTF and physicochemical characteristics were measured. The results showed that: (1) Heat drastically decreased the number of strains and heavily altered the NTF community, but it also encouraged the emergence of new NTF species. Instead, no overt changes were observed in the treatment that just experienced the addition of ash on the soil. (2) When compared to treatments that received only heat input, the lower strain count of NTF recovered more quickly in the natural burning treatment which was affected by both heat and ash input. These findings suggest that the disruptive effect of fire heat on soil NTF biomass may be counterbalanced by the emergence of new species and the repairing capabilities of new nutrients introduced by ash residue. In the future, both conventional and cutting-edge techniques should be considered in research designs to better understand the ecological role of fire disturbances occurring at different intensities, as well as the mechanisms that make soil ecosystems resilient to fire, in particular the role of new species.

Heat and smoke from wildfires influence water temperature and dissolved oxygen levels in headwater streams

Wildfire has become increasingly common and severe in forested landscapes across the western United States. Stream and air temperatures within these landscapes are influenced not only by direct heating during the fire but by shading from heavy smoke. In addition, dissolved oxygen (DO) can be affected by increased ash inputs from fire or reduced primary production under lower light conditions. Because collecting data as the event occurs is challenging, most research exploring fire effects on streams has focused on responses months to years after the event as opposed to during and immediately after the fire. We sought to understand how physical stream parameters change as wildfire burns near streams, how stream temperature responses vary through a stream reach, how parameters respond to shading from pervasive smoke during and shortly after the fire, and how fire severity correlates with observed changes. In this study, we report measurements of light, air temperature, stream temperature, and DO across eleven 2nd- to 4th-order streams in the western Cascade Mountains of Oregon, USA, 1 wk before, during, and 1 wk after an extensive wildfire in 2020. Burning near streams resulted in a brief increase in daily maximum stream temperature of 4.5°C at the most severely burned site but small increases or decreases at less affected sites. Longitudinal replication revealed that temperature responses can be patchy at relatively small scales (∼50 m). DO daily minima decreased by 1.3 to 16.9% saturation on the day of the fire, with the magnitude of effect corresponding to burn severity. Across all 11 sites, riparian and watershed estimates of Rapid Assessment of Vegetation Condition after Wildfire and soil burn severity were better correlated with stream temperature responses to fire than percentage of watershed burned. Smoke effects were pervasive, both spatially and temporally, resulting in decreased light, stream temperature maxima, and diurnal variation in DO. Our results suggest that acute changes to physical stream parameters caused minimal harm to aquatic biota at our sites, and the effects of smoke on physical stream parameters will likely impose larger immediate effects on headwater streams than heating from the fire itself.

Terrigenous and volcanogenic contribution to the deep basin of the South China Sea: Evidence from trace elements and Sr-Nd isotopes

The deep basin of the South China Sea (SCS) receives terrigenous materials from the surrounding continents and islands, making it an ideal region for studies on source-to-sink transport. The analysis of grain size, major and trace elements, and Sr-Nd isotopes of 130 surface sediment samples throughout the SCS deep basin has been performed for identifying the contribution of terrigenous and volcanic materials. Based on the analysis results, the SCS deep basin can be divided into three geographic areas with different provenances: the northern area of the East Subbasin (NES), the southern region of the East Subbasin (SES), and the Southwest Subbasin (SWS). The predominant provenances of sediments in the NES and SWS are Taiwan rivers and Mekong River, respectively. Sediments from the SES exhibit higher mean grain size, less radiogenic 87Sr/86Sr, and more radiogenic 143Nd/144Nd than those from the NES and SWS. Pinatubo ash input from the Luzon Island may be a predominant source in the SES. The contribution of Pinatubo ash decreased westward from 80% to 20% in the SES. The supply of Pinatubo ash could be considered insignificant to the NES and SWS. Sediments from Taiwan rivers or Mekong River were the subordinate source in the SES. The deep-water current and mesoscale eddies may play a role in transporting terrigenous materials into the SCS deep basin as well as the turbidity current.

Can ash from smoldering fires increase peatland soil pH?

Peatland wildfire frequency and severity are increasing globally owing to climate change. The direct risk of elevated greenhouse gas emissions from peat burning receives much attention, yet the risks to vegetation composition or peat decomposition from alkaline ash inputs are poorly understood. We explored whether ash produced during smoldering increases peatland topsoil (∼0–25 cm) pH through field observations and laboratory experiments. We assessed spatial patterns of smoldering and ash presence, and measured soil and ash pH after a peatland wildfire in the Netherlands. Additionally, a peat smoldering experiment was conducted to compare freshly produced ash pH with aged ash pH collected 2 months following the wildfire. Additionally, we assessed the amount of ash needed to increase soil pH. Results showed that ash inputs at the field site were insufficient to increase pH of the acidic peatland after the wildfire. Incubation experiments showed that a ≥3 cm ash layer (ash load 163 t ha–1) would be required to increase soil pH by at least 1 unit. Given that aged ash was slightly acidic and fresh ash was alkaline, leaching and neutralisation of ash after wildfire is likely, suggesting that elevated soil pH from ash input may be transient rather than long term.

Coal fly ash is a major carbon flux in the Chang Jiang (Yangtze River) basin

Fly ash-the residuum of coal burning-contains a considerable amount of fossilized particulate organic carbon (FOCash) that remains after high-temperature combustion. Fly ash leaks into natural environments and participates in the contemporary carbon cycle, but its reactivity and flux remained poorly understood. We characterized FOCash in the Chang Jiang (Yangtze River) basin, China, and quantified the riverine FOCash fluxes. Using Raman spectral analysis, ramped pyrolysis oxidation, and chemical oxidation, we found that FOCash is highly recalcitrant and unreactive, whereas shale-derived FOC (FOCrock) was much more labile and easily oxidized. By combining mass balance calculations and other estimates of fly ash input to rivers, we estimated that the flux of FOCash carried by the Chang Jiang was 0.21 to 0.42 Mt C⋅y-1 in 2007 to 2008-an amount equivalent to 37 to 72% of the total riverine FOC export. We attributed such high flux to the combination of increasing coal combustion that enhances FOCash production and the massive construction of dams in the basin that reduces the flux of FOCrock eroded from upstream mountainous areas. Using global ash data, a first-order estimate suggests that FOCash makes up to 16% of the present-day global riverine FOC flux to the oceans. This reflects a substantial impact of anthropogenic activities on the fluxes and burial of fossil organic carbon that has been made less reactive than the rocks from which it was derived.

Intra-oceanic submarine arc evolution recorded in an ~1-km-thick rear-arc succession of distal volcaniclastic lobe deposits

Abstract International Ocean Discovery Program (IODP) Expedition 351 drilled a rear-arc sedimentary succession ~50 km west of the Kyushu-Palau Ridge, an arc remnant formed by rifting during formation of the Shikoku Basin and the Izu-Bonin-Mariana arc. The ~1-km-thick Eocene to Oligocene deep-marine volcaniclastic succession recovered at Site U1438 provides a unique opportunity to study a nearly complete record of intra-oceanic arc development, from a rear-arc perspective on crust created during subduction initiation rather than supra-subduction seafloor spreading. Detailed facies analysis and definition of depositional units allow for broader stratigraphic analysis and definition of lobe elements. Patterns in gravity-flow deposit types and subunits appear to define a series of stacked lobe systems that accumulated in a rear-arc basin. The lobe subdivisions, in many cases, are a combination of a turbidite-dominated subunit and an overlying debris-flow subunit. Debris flow–rich lobe-channel sequences are grouped into four, 1.6–2 m.y. episodes, each roughly the age range of an arc volcano. Three of the episodes contain overlapping lobe facies that may have resulted from minor channel switching or input from a different source. The progressive up-section coarsening of episodes and the increasing channel-facies thicknesses within each episode suggest progressively prograding facies from a maturing magmatic arc. Submarine geomorphology of the modern Mariana arc and West Mariana Ridge provide present-day examples that can be used to interpret the morphology and evolution of the channel (or channels) that fed sediment to Site U1438, forming the sequences interpreted as depositional lobes. The abrupt change from very thick and massive debris flows to fine-grained turbidites at the unit III to unit II boundary reflects arc rifting and progressive waning of turbidity current and ash inputs. This interpretation is consistent with the geochemical record from melt inclusions and detrital zircons. Thus, Site U1438 provides a unique record of the life span of an intra-oceanic arc, from inception through maturation to its demise by intra-arc rifting and stranding of the remnant arc ridge.

Bacterial response to soil property changes caused by wood ash from wildfire in forest soils around mining areas: Relevance of bacterial community composition, carbon and nitrogen cycling

The different physical-chemical properties of the black ash (200–500 °C) and white ash (>510 °C) generated by wildfire may result in varied impacts on soil biological and abiotic indicators. Many studies have highlighted the environmental impacts of wood ash application due to its complex mixture of beneficial and detrimental compounds. However, few studies have compared the effect of black ash and white ash on soil, especially for the heavy metal polluted soil. In this study, we used the comparative analysis of parallel microcosm experiments to study the impacts of white ash and black ash on bioavailable heavy metals and metabolic potentials of microbial community. The results indicated that both white ash and black ash increased the concentration of soil bioavailable As and Cr, while the increasing trend of bioavailable As could be limited by Ca in the treatment of white ash. The addition of black ash could enhance the abundance of genes related to the Calvin cycle (CBB). Different kinds of wood ash inputs into soils could cause the differences in the microbial taxa for carbon fixation, as indicated by the dominance of different taxa for carbon fixation in white ash versus black ash treatments. Additionally, both white ash and black ash impaired dissimilatory nitrate reduction to ammonium (DNRA), nitrate assimilation and nitrification, while white ash enhanced denitrification.

Organic petrology and geochemistry of Lower Cretaceous lacustrine sediments in the Chaoyang Basin (Liaoning Province, northeast China): Influence of volcanic ash on algal productivity and oil shale formation

Airfall volcanic ash deposited in the form of tuff layers is widely distributed in oil-shale bearing basins in western Liaoning Province, northeast China. In order to investigate the impacts of volcanic ash on algal productivity and the formation of organic-rich oil shales, the organic petrology and organic geochemistry of lacustrine sediments of the Lower Cretaceous Jiufotang Formation were investigated. Molecular geochemical data (the pristane/phytane ratio, the gammacerane index and the relative amount of β-carotane) indicate that they were formed in suboxic/anoxic depositional environments, with salinity fluctuations from freshwater to saline. Oil shales in the semi-deep to deepwater lake facies were mainly deposited under still and anoxic bottom water conditions, concomitant with water column salinity stratification. The relative abundances of diterpenoids and regular steranes indicate a limited terrigenous conifer plant contribution and a predominantly algal contribution to the organic matter. Blooms of algae contributing to high primary productivity, and anoxic depositional environments contributing to organic matter preservation, were key to organic-rich oil shale formation. Fish bones, ostracod shells, and alginite are present below the thick tuff layer. Alginite richness gradually increased from very low just above the tuff layer, to a higher concentration further above the tuff layer, indicating that during major volcanic eruptions, large quantities of volcanic ash led to water column poisoning, causing the sudden mass mortality of some aquatic organisms that were sensitive to turbid, acidified and toxic water. The increased proportion of brackish/saline-water dinoflagellates, which is corroborated by the high concentration of telalginite, abundant dinoflagellate-specific biomarkers (C31 4,22,23,24-tetramethylcholestanes), high values of the C27/C29 ααα-20R and C28/C29 ααα-20R sterane ratios, 4-methylsterane index, dinosterane index, and tetramethylsterane index, suggest that brackish/saline-water dinoflagellates show a positive response to volcanic ash input. Some specific brackish/saline-water dinoflagellates are present in organic-rich tuff laminae, indicating that during periods of minor volcanic eruptions or in intermissions between major eruptions, a minor volcanic ash input was more likely to result in rapid and efficient volcanic fertilisation effects and high-quality oil shale formation. Although the lacustrine oil shale system of the Jiufotang Formation shares some similar petrological and geochemical characteristics with the classical saline lacustrine oil shale system of the Green River Formation in the United States of America, the significant influence of airfall volcanic ash on algal productivity makes the formation mechanism of oil shales within the Jiufotang Formation strata quite different from that of oil shales within the Green River Formation.

A test of the relative importance of iron fertilization from aeolian dust and volcanic ash in the stratified high-nitrate low-chlorophyll subarctic Pacific Ocean

To test the biological effectiveness of iron fertilization by Asian aeolian dust and volcanic ash in the stratified high-nitrate, low-chlorophyll subarctic Pacific Ocean over long-time scales, we analysed sediments with ages between 2.8 and 0.9 Ma at ODP Site 885/886. This site lies far from the influence of other iron sources (e.g. icebergs or lateral iron transportation) and the water column has been stratified since intensification of northern hemisphere glaciation (iNHG) at ∼2.7 Ma, which limits nutrient upwelling and makes it an ideal location for testing iron bioavailability of different atmospheric sources that fell onto the surface ocean. We investigate diatom assemblages and opal export changes, and compare them with the properties of iron minerals in Asian aeolian dust and volcanic ash. Our results reveal that Asian aeolian dust contains mostly unreactive iron-bearing minerals that supplied limited bioavailable iron for diatom growth at Site 885/886. Diatom productivity changes were dominated by upwelling/stratification changes over long timescales, and by sporadic iron fertilization from volcanic ash inputs. Iron from volcanic ash particles is likely to have become bioavailable because such particles dissolved more readily due to their high porosity and ultra-fine size.

Volcanic ash inputs enhance the deep-sea seabed metal-biogeochemical cycle: A case study in the Yap Trench, western Pacific Ocean

Although volcanic ash deposition into oceans has been a frequent phenomenon for much of geologic history, the potential effects on deep-sea seabed metal-biogeochemical cycles remain enigmatic. In this study, we analyzed mineral compositions, microbial communities, and metal-related functional genes in a sediment core with volcanic ash layers from the Yap Trench in the western Pacific Ocean. The mineralogical analysis showed that volcanic activity introduced large amounts of Fe-rich igneous minerals, such as olivine, pyroxene, hornblende, grossularite, and biotite, into the trench seabed sedimentary environments. Furthermore, some differentiation in microbial communities was observed and potential Fe-metabolizing bacteria (such as Pseudomonas, Alteromonas, Marinobacter, Halomonas, Pseudoalteromonas, and Erythrobacter) were dominant in the volcanic ash layers. Moreover, compared with the background sediment metagenome, the volcanic ash metagenomes were enriched in pathways for siderophore synthesis and uptake, and metal resistant functional genes. These results suggest that volcanic ash can lead to changes in trench-sediment-based microbial communities and stimulate microbial Fe acquisition and other metal-related metabolism. In response, microorganisms could promote decomposition of the metal-rich volcanic minerals and metal release rates from them, subsequently enhancing the deep-sea metal-biogeochemical cycle.

Sedimentary basin evolution, gravity flows, volcanism, and their impacts on the formation of the Lower Cretaceous oil shales in the Chaoyang Basin, northeastern China

No detailed research has been carried out on the oil shales that are interbedded with gravity flow deposits and volcaniclastic rocks in the third Member of the Jiufotang Formation. In order to study the impact of basin evolution, gravity flows, and volcanism on oil shale formation, petrology, sedimentology, sequence stratigraphy, organic geochemistry, and elemental geochemistry were used to characterise the oil shales. Extensional tectonic subsidence is suggested as the controlling factor for basin evolution. The predominant maceral in the oil shales is sapropelinite, suggesting organic matter was derived from mainly aquatic organism (especially algae). Element indices (δU, (Cu + Mo)/Zn, Sr/Ba, Th (μg/g), Zr (μg/g), and the chemical index of alteration (CIA) show that the water conditions during deposition of the oil shales were anoxic and brackish, with little terrigenous detrital input and a cold and dry palaeoclimate. Gravity flows were accompanied by the input of terrestrial detritus and a degree of oxygenation of the bottom waters, reducing oil shale formation. Volcanic eruptions ejected intermediate-acidic ashes, not only leading to climate cooling, but also either enhancing algal blooms (by a fertilisation effect due to minor volcanic ash input) or inhibiting algal blooms (by a poisoning effect due to major volcanic ash input). There is synchronicity between the occurrence of rifting, gravity flows, volcanism, and earthquakes. The best periods for oil shale formation were during intermissions between tectonic movement, when there were few gravity flows, volcanic eruptions, or earthquakes. High bioproductivity and lake expansion along with an anoxic environment were the main controlling factors for high-quality oil shale formation. There is a series of oil shale-bearing rift basins formed in northeastern China that share a similar geological setting, so this research provides a useful example for future resource exploration of coeval oil shales in northeastern China.

Detrital Zircon Provenance and Lithofacies Associations of Montmorillonitic Sands in the Maastrichtian Ripley Formation: Implications for Mississippi Embayment Paleodrainage Patterns and Paleogeography

We provide new detrital zircon evidence to support a Maastrichtian age for the establishment of the present-day Mississippi River drainage system. Fieldwork conducted in Pontotoc County, Mississippi, targeted two sites containing montmorillonitic sand in the Maastrichtian Ripley Formation. U-Pb detrital zircon (DZ) ages from these sands (n = 649) ranged from Mesoarchean (~2870 Ma) to Pennsylvanian (~305 Ma) and contained ~91% Appalachian-derived grains, including Appalachian–Ouachita, Gondwanan Terranes, and Grenville source terranes. Other minor source regions include the Mid-Continent Granite–Rhyolite Province, Yavapai–Mazatzal, Trans-Hudson/Penokean, and Superior. This indicates that sediment sourced from the Appalachian Foreland Basin (with very minor input from a northern or northwestern source) was being routed through the Mississippi Embayment (MSE) in the Maastrichtian. We recognize six lithofacies in the field areas interpreted as barrier island to shelf environments. Statistically significant differences between DZ populations and clay mineralogy from both sites indicate that two distinct fluvial systems emptied into a shared back-barrier setting, which experienced volcanic ash input. The stratigraphic positions of the montmorillonitic sands suggest that these deposits represent some of the youngest Late Cretaceous volcanism in the MSE.

Clay mineralogy of Miocene mudstones from the Lower Austrian Molasse Basin

Abstract Recent studies established the lithological and chemical sediment evolution in the Lower Austrian Molasse Basin (LAMB), a part of the North Alpine foreland basin, during the Early Miocene. In this study, we aim to integrate the clay mineralogy of seven wells across the LAMB with a newly proposed lithostratigraphy, and to infer implications for provenance, palaeo-geography and palaeoclimate. The results of our qualitative and quantitative evaluation of the clay-sized fraction with x-ray diffractometry largely support the stratigraphic model. The early stage of foreland basin formation (Egerian/Eggenburgian?) is represented by kaolinite contents up to 93 % in the clay sized fraction. This indicates an orogen-external source, i.e. the Bohemian Massif, and erosion of intensively chemical weathered products during this early Molasse basin stage. The over-lying marine Robulus Schlier (lower/middle Ottnangian) is characterized by a distinctly reduced kaolinite content and overall increased illite content compared to the other formations. Illite was predominantly provided from denudation of the rising Eastern Alps, i.e. characterizing the orogen-internal provenance. The pelites of the overlying carbonate poor Traisen Formation (upper Ottnangian) show again a higher kaolinite and smectite content. In the largely coeval basinal Wildendürnbach Formation, smectite reaches up to 70 % in the clay sized fraction. Peak smectite values may be linked to volcanic ash input from the nearby Carpathian volcanic arc. Generally rising smectite versus illite ratios during the Ottnangian-Karpatian could point to a warming and intensified chemical weathering of the rising Alpine orogen.

The petrological characteristics and significance of organic-rich shale in the Chang 7 member of the Yanchang Formation, south margin of the Ordos basin, central China

The organic-rich shale of the Chang 7 member is the most important source rock in the Ordos basin. The sedimentary environment and the controlling factors of organic matter enrichment, however, are still in contention. In this investigation, the Yishicun outcrop, located on the south margin of the Ordos basin, has been considered for the study. X-ray diffraction, polarizing microscopy, field emission scanning electron microscopy and cathodoluminescence (CL) were used to investigate the petrological features of the organic-rich shale. The content of volcanic ash and the diameter of pyrite framboid pseudocrystals were measured to illustrate the relationship between oxygen level, ash content and the enrichment of organic matter. It has been found that the diameter of pyrite framboid pseudocrystals has a strong correlation with the total organic carbon, demonstrating that the redox status degree of the water column has a positive impact on the enrichment of organic matter. Additionally, with an increase in the ash content, the content of organic matter increased at first and then decreased, and reached a maximum when the ash content was about 6%, illustrating that the ash input has a double effect on the enrichment of organic matter.

Biological Nitrogen Fixation Does Not Replace Nitrogen Losses After Forest Fires in the Southeastern Amazon

Tropical forest fires have become more common due to interactions between deforestation, land clearing, and drought. Forest recovery following fires may be limited by nitrogen. Biological nitrogen fixation (BNF) is the main pathway for new nitrogen (N) to enter most ecosystems, but BNF may be constrained by other nutrients, such as molybdenum and phosphorus, which are required for the process. We studied the role of BNF 7 years into the recovery of southeastern Amazon tropical forests that were burned experimentally either annually or every 3 years between 2004 and 2010. We hypothesized that, compared with unburned primary forests, BNF in burned forests would increase due to the depletion of N in the aboveground biomass pool and that soil concentrations of molybdenum and phosphorus from ash inputs would increase, reducing their potential constraints on BNF. Despite the fires depleting about half the aboveground N pool and rapid rates of recovery in leaf biomass and litterfall production, we found low rates of both free-living and symbiotic BNF. Higher concentrations of molybdenum and phosphorus in the mineral soils of the burned forests indicated that these elements were likely not limiting BNF. Our results suggest that despite the N demand for regrowth post-fire, substantial N stored in soils likely downregulates BNF. Overall, we found surprisingly low BNF rates (< 1.2 kg N ha−1 y−1) in this region of the Amazon, which contrasts with the traditional paradigm that (1) tropical forests fix large quantities of N and (2) that BNF increases after forest disturbance.