Ash-fall Tuffs Research Articles

Late Carboniferous–Early Permian sedimentary–tectonic evolution in the eastern Qaidam Basin, Western China: Insight into the zircon U–Pb geochronology of ash-fall tuffs and sandstones

The Late Carboniferous–Early Permian period is a significant transitional phase within the late Paleozoic ice age and to investigate the sedimentary–tectonic evolution of the Qaidam Basin in this period is crucial for comprehensively understanding the tectonic history of the northeastern Paleo-Tethys Ocean and the related response to energy and mineral resources. This paper focuses on the Carboniferous–Permian strata of the Wanggaxiu-Dongdagou outcrop that was taken to represent the southern Oulongbruk terrane in the eastern Qaidam Basin. We determined the ages of tuff interbeds within the Zhabusagaxiu Formation originally identified as the upper Carboniferous and obtained the crystallization age spectra of detrital zircon grains from Carboniferous to lower Permian sandstones using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) isotope geochemical techniques. The origin of the volcanic ash and the sedimentary–tectonic evolution in this period were analyzed. The results indicate that the original Zhabusagaxiu Formation can be divided into two chronostratigraphic units: the upper Carboniferous Zhabusagaxiu Formation and the lower Permian. The earliest age obtained from tuffaceous layers within the dark shale interval is 297.8 ± 3.0 Ma (mean square weighted deviation (MSWD) = 0.87), which suggests a stratigraphic boundary between the Carboniferous and Permian periods. Detrital zircons from Carboniferous–Permian samples in the southern Oulongbruk terrane predominantly originated from the Qaidam block-North Qaidam ultrahigh-pressure belt continental island arc to the south. The ultrahigh-pressure belt had a significantly increased contribution to the detrital source supply system from the Late Carboniferous to Early Permian, while the Qaidam block experienced frequent volcanic eruptions from 298 to 293 Ma, dispersing volcanic ash only northward to the Oulongbruk back-arc basin and the Zongwulong Trough. The upper Carboniferous Zhabusagaxiu Formation was marked by siliceous clastic rock–carbonate rock interbedding in an epicontinental sea, while the lower Permian was characterized by shallow to bathyal marine shelf to subaqueous sedimentation. The Early Permian transgression potentially represents the largest transgression during the late Paleozoic ice age, indicating an enriched hydrocarbon-generating interval.

First Report of Tuff in Neoproterozoic Bhima Basin: Field Evidence, Petrography and Geochemical Studies

Abstract We report here the presence of tuffs from the Neoproterozoic Bhima basin unreported hitherto. These are exposed near Hotpet, Hulkal, Kanchankavi, and Ukinal area along two different stratigraphic horizons (1) within carbonates of Shahabad Formation and (2) above shale of Hulkal Formation. Tuffs are of two types: 1. Ash fall tuff and 2. Lapilli tuff, occurring as beds, matrix of a conglomeratic unit and patchy discontinuous layers. Physically ash fall tuff is thinly bedded (2-6 cm) and light-weight, lapilli tuff is hard, compact and individual beds are not discernible in the field. Presence of petrological features like bipyramidal quartz, fiamme structures, embayed quartz grains, blue CL colours of quartz grains, volcanic layering and banding, altered glass, and stretched and elongated volcanic glasses, are clear indications of its volcanic affinity. The tuff is anomalously high in silica content ranging from 71.4-91.2wt% and have low alumina value ranging from 0.75-4.11 wt % compared with that of the normal felsic tuffs, rhyolites and high silica rhyolites. REE in the tuffs can be grouped into two types, 1. Ash fall tuff with enriched LREE and fractionated HREE, 2. Lapilli tuff with flat LREE and HREE pattern. Tuff shows high Hf, overall enrichment of large ion lithophile elements (LILE Rb, Th, K and Pb) and depletion in HFSEs (Nb, Ta, Ti, P). The tuff is probably generated from continental crust source and the depositions are episodic and have more than one eruptive pulses of volcanic activity.

Revised age and regional correlations of Cenozoic strata on Bat Mountain, Death Valley region, California, USA, from zircon U-Pb geochronology of sandstones and ash-fall tuffs

Abstract Basin analysis and tectonic reconstructions of the Cenozoic history of the Death Valley region, California, USA, are hindered by a lack of volcanic (tuff) age control in many stratigraphic successions exposed in the Grapevine and Funeral Mountains of California, USA. Although maximum depositional ages (MDAs) interpreted from detrital zircon U-Pb data may be a promising alternative to volcanic ages, arguments remain regarding the calculation of MDAs including, but not limited to, the number of “young” grains to consider (i.e., the spectrum of dates used to calculate the MDA); which grains, if any, should be ignored; which approaches yield results that are statistically rigorous; and ultimately, which approaches result in ages that are geologically reasonable. We compare commonly used metrics of detrital zircon MDA for five sandstone samples from the Cenozoic strata exposed on Bat Mountain in the southern Funeral Mountains of California—i.e., the youngest single grain (YSG), the weighted mean of the youngest grain cluster of two or more grains at 1σ uncertainty (YC1σ(2+)) and of three or more grains at 2σ uncertainty (YC2σ(3+)), the youngest graphical peak (YPP), and the maximum likelihood age (MLA). Every sandstone sample yielded abundant Cenozoic zircon U-Pb dates that formed unimodal, near-normal age distributions that were clearly distinguishable from the next-oldest grains in each sample and showed an apparent up-section decrease in peak age. Benchmarked against published K/Ar and 40Ar/39Ar ages and five new zircon U-Pb ages of ash-fall tuffs, our analysis parallels prior studies and demonstrates that many MDA metrics—YSG, YC1σ(2+), YC2σ(3+), and YPP—drift toward unreasonably young or old values. In contrast, the maximum likelihood estimation approach and the resulting MLA metric consistently produce geologically appropriate estimates of MDA without arbitrary omission of any young (or old) zircon dates. Using the MLAs of sandstones and zircon U-Pb ages of interbedded ash-fall tuffs, we develop a new age model for the Oligocene–Miocene Amargosa Valley Formation (deposited ca. 28.5–18.5 Ma) and the Miocene Bat Mountain Formation (deposited ca. 15.5–13.5 Ma) and revise correlations to Cenozoic strata across the eastern Death Valley region.

Pliocene-Pleistocene ash-fall tuff deposits in the intermountain Humahuaca and Casa Grande basins, northwestern Argentina: tracers in chronostratigraphic reconstructions and key to identify their volcanic sources

Ash-fall tuffs of the Pliocene-Pleistocene deposits of Humahuaca and Casa Grande intermountain basins, northwestern Argentina, have been differentiated into two groups based on new geochemical and geochronological data which correspond to the tuffs of the Pliocene-Lower Pleistocene alluvial fan deposits dominated by debris flow, deep sandy gravel braided, and shallow ephemeral lake deposits (Uquia and Mal Paso formations), and those recorded in Pleistocene alluvial fans sheet flood deposits. The two clusters of ages recognized: 4.3 to 2.6 Ma, and 2.2-pre 0.8 Ma, corresponding to these tuff groups, are in agreement with pulses of ignimbrite eruptions in the Altiplano Puna Volcanic Complex (APVC), and Southerm Puna calderas located west of the study region. The ash-fall tuffs of both groups are mainly vitreous to phenocryst-poor of rhyodacite-dacite composition with minor andesites to trachyandesites, characterized by 58-69% SiO2 contents, A/CNK 1-1.4, FeO/MgO (0.8-2.8), which plot in the calc-alkaline range. They can be differentiated based on its immobile trace elements ratios as indicated by a slight enrichment in LREE, higher arc affiliation and somewhat higher Sm/Yb ratios in the case of the younger group, although in both Sm/Yb ratios are indicative of sequestration of HREE in residual hornblende. The new geochemical and geochronological data of those ash fall tuffs point to these as chrono-stratigraphic tracers of the Humahuaca and Casa Grande intermountain basins stratigraphy, during the Pliocene-Pleistocene, also as the key to identify their volcanic sources.

Mineralogická charakteristika sekundárních změn miocenních vulkanoklastických hornin z jižní a střední Moravy (Česká republika)

Bentonite is a significant industrial raw material which deposits deserve protection. The initiative for elaborating this study was the decision from November 2019 of the current owner (the town of Ivančice) to remediate the entire area of the deposit Ivančice-Réna. Lower Miocene volcaniclastic rocks from the Ivančice-Réna (Ivančice) and Middle Miocene sediments in surrounding area of Lipník nad Bečvou are relatively rich in clay minerals (smectites). The mineralogical characteristics of the volcaniclastic rocks were examined using several methods: polarized-light microscopy, X-ray powder diffractometry (XRD), electron microprobe (SEM–WDX), and whole-rocks chemical analysis (ICP-MS). Acid ash-fall tuff and/or very fine-grained tuffite form layers with variable thickness (several cm to m). Grains larger than clay fraction are formed by K-feldspars, plagioclase, biotite, muscovite and quartz crystals accompanied by fragments of pumice and glass shards. The whole-rocks chemical composition of the investigated volcaniclastic rocks indicates similar magmatic sources for both examined samples (Y = 28 and 29 ppm, Yb = 2.8 and 3.2 ppm, Nb = 12 and 14 ppm, Ta = 1.1 and 1.2 ppm, Zr/Ti = 0.16 and 0.17 and Nb/Y = 0.4 and 0.5). The formation of smectite from alteration of rhyolite volcanic glass is accompanied by an increased loss on ignition (LOI: 9.4 and 20.2 wt. %) together with a decrease in K2O (0.7 and 2.1 wt. %) and Na2O (0.6 and 2.1 wt. %). The absence of a negative Ce anomaly suggests that secondary alterations took place under suboxic or anoxic conditions. Smectite and minor opal partially replace volcanic glass and pumice shards. Plagioclase (Ab59–60) and K-feldspar (Or62–78 Ab21–33 An0–1) crystals are relatively fresh (weak sericitic alteration). Biotite is partly to wholly oxidized and chloritized (4.9–6.2 wt. % K2O). Iron oxyhydroxides are present only as minor components. Variation of intensity of secondary alteration (bentonitization) within the studied volcanoclastic layer from the Ivančice-Réna suggests sedimentation in lacustrine environment. In contrast to the case of the sample from Lipník nad Bečvou, the smectite was formed authigenetically from volcanic glass in interaction with seawater or during an early diagenetic process.

Triassic coal measures, Tasmania: new U–Pb CA-TIMS ash bed dates and numerical calibration of palynostratigraphy

Four new high-precision U–Pb ash bed dates constrain the timing and rate of coal measures deposition in Tasmania and, combined with new palynological data, allow improved numerical age calibration of eastern Australian Late Triassic spore-pollen biozones. Felsic ashfall tuff beds are numerous in the middle and upper parts of the 400 m-thick Mount Nicholas Coal Measures of northeast Tasmania. Our four U–Pb CA-TIMS dates on zircon span 99 m of section and range from 222.52 to 217.84 Ma. All four dates are closely associated with palynomorph assemblages belonging to the Craterisporites rotundus Assemblage Zone. Our data indicate an age of at least 223 Ma, and likely several million years older, for our earliest observed C. rotundus Zone assemblages, whereas the base of the Polycingulatisporites crenulatus Zone may be ca 217 Ma (and no older than 217.84 Ma). KEY POINTS Felsic ash beds are common in the middle and upper parts of the Upper Triassic Mount Nicholas Coal Measures. The ash beds have yielded four new U–Pb CA-TIMS dates on zircon that span 99 m of section and range from 222.52 to 217.84 Ma. The new dates all lie within the upper part of the Craterisporites rotundus Assemblage Zone.

Timing of deformation along the Iron Springs thrust, southern Sevier fold-and-thrust belt, Utah: Evidence for an extensive thrusting event in the mid-Cretaceous

ABSTRACT The temporal and spatial distribution of strain associated with the Sevier orogeny in western North America is significantly different in the southern end of the belt, at the latitude of Las Vegas, Nevada, than farther to the north at the latitude of Salt Lake City, Utah. Reasons for these differences have been speculative as a lack of temporal constraints on thrusting in the intervening region hindered along-strike correlation across the belt. We determined a crystallization age of 100.18 ± 0.04 Ma for zircons extracted from a recently recognized dacite lapilli ash-fall tuff near the base of the synorogenic Iron Springs Formation. We propose the name “Three Peaks Tuff Member” for this unit, and identify a type stratigraphic section on the western flank of the “Three Peaks,” a topographic landmark in Iron County, Utah. Field relationships and this age constrain movement on the Iron Springs thrust and the end of the sub-Cretaceous unconformity in the critical intervening area to latest Albian/earliest Cenomanian. Movement on the Iron Springs thrust was synchronous with movement on multiple Sevier thrusts at ~100 Ma, indicating that the mid-Cretaceous was a period of extensive thrust-fault movement. This mid-Cretaceous thrusting event coincided with a period of global plate reorganization and increased convergence, and hence an increased subduction rate for the Farallon Plate beneath North America. The accelerated subduction contributed to a Cordilleran arc flare-up event and steepening of the orogenic wedge, which triggered widespread thrusting across the retroarc Sevier deformation belts. Additionally, based on temporal constraints and the strong spatial connection of mid-Cretaceous thrusts to lineaments interpreted as pre-orogenic transform faults, we suggest that temporal and spatial variations along the strike of the orogenic belt reflect tectonic inheritance of basement structures associated with the edge of the rifted Precambrian craton.

Geology and geochronology of the Jurassic magmatic arc in the Magdalena quadrangle, north-central Sonora, Mexico

This work reports on the geology and U–Pb LA-ICPMS zircon geochronology of a crustal section that is part of the Jurassic magmatic arc in the Magdalena quadrangle of north-central Sonora, Mexico. This rock succession is variably metamorphosed and strained as it was affected by Late Cretaceous shortening, intruded by early Tertiary granitoids, and further exhumed in the lower plate of the early Miocene Magdalena metamorphic core complex. The older and more extensively exposed Jurassic unit is the >3.5 km thick Sierra Guacomea rhyolite that is composed of massive to poorly bedded rhyolite, bedded quartz-phyric rhyolitic ignimbrite and interbedded ash-fall tuffs and quartz-rich sandstone beds. Three rhyolite samples collected at different localities of its outcrops yielded concordia ages of 175.2 ± 0.9, 171.7 ± 0.6, and 171.4 ± 0.7 Ma. The quartz-phyric Rancho La Víbora, Los Vallecitos, and the Agua Caliente rhyolitic domes that are associated with the Sierra Guacomea rhyolite yield concordia ages of 176 ± 0.8, 174.4 ± 0.9 and 173.1 ± 0.8 Ma, respectively. The Rancho Los Pozos unit composed of interbedded rhyolitic ash-fall tuff and flows, sandstone, siltstone and subordinate limestone beds has an estimated thickness of 600 m and yielded a crystallization concordia age of 170.7 ± 0.6 Ma from a rhyolite bed. The porphyritic El Rincón granite that intrudes into the Sierra Guacomea rhyolite yields crystallization ages of 167.43 ± 0.42 and 164.4 ± 0.7 in samples from different localities. The La Jojoba metasandstone that consists of foliated, quartz-rich to arkosic strata of fluvial origin is at least 900 m thick; detrital zircon grains dated from three sandstone samples yielded dominantly Jurassic ages with peaks at 172, 170, and 163.7 Ma, and a combined maximum depositional age of ca. 163 Ma.The younger plutons are the porphyritic El Nopalito granite that has an interpreted crystallization age of 160.8 ± 0.6 Ma, and the leucocratic, two-mica, garnet-bearing La Cebolla granite that yielded a concordia age of 158.1 ± 1 Ma. These granitic intrusions record the waning magmatic pulses of the arc, in the study quadrangle, but their volcanic equivalents were not identified. Inherited zircon grains in the reported volcanic and plutonic units are only of Jurassic age, except by two Proterozoic zircon grains yielded by the El Nopalito granite. The El Salto granite augen gneiss is a xenolith dated at 1071.9 ± 5 Ma that indicates the presence of Grenvillian basement in the study area.Major- and trace-element geochemical data indicate that the volcanic and plutonic units are silica-rich, mostly high K calc-alkaline to shoshonitic rocks associated with a continental margin arc setting. The plutons are mostly peraluminous, and in conjunction with trace element geochemistry data, they suggest crustal assimilation of magmas emplaced in a probably thickened continental crust. Chondrite-normalized REE patterns and primitive mantle-normalized trace element diagrams also suggest partial melting and fractional crystallization processes.The ages obtained indicate that the arc in the study area developed from ca. 176 to 158 Ma, encompassing a 17 m.y. interval of magmatism and associated sedimentation. Regional correlation and geochronologic published data indicate that the arc crustal section of the Magdalena quadrangle is part of the Jurassic magmatic arc that regionally lasted from ca. 190 to 158 Ma.

A volcanic tuff near the Carboniferous–Permian boundary, Taiyuan Formation, North China: Radioisotopic dating and global correlation

A 66 cm thick volcanic ash fall tuff occurring within a thick coal deposit and containing a paleobotanical fossil lagerstätte in the Wuda coal district of North China has been dated as 298.34 ± 0.09 Ma. The fossil flora in the tuff indicates a latest Carboniferous to earliest Permian age and is thus in agreement with the radioisotopic age of earliest Permian, Asselian, age. This bed supplies a well-defined position of the Carboniferous–Permian boundary near the northern edge of the North China Block. The tuff occurs in the top of the Taiyuan Formation and several meters below the base of the Shansi (=Shanxi) Formation. These beds were traditionally considered late Carboniferous to early Permian in age. Our results demonstrate that the Taiyuan Formation is time transgressive and its age has to be revised for the northern part of the North China Block.

Stratigraphy, depositional environments and zircon U-Pb (LA-ICP-MS) ages of the Statherian volcano-sedimentary Beneficente Group: Implications for tectonics and gold mineralization in SW of the Amazon Craton

The Amazon Craton exhibits preserved volcano-sedimentary paleo-basins with age intervals of 2.0–1.96 Ga, 1.90–1.87 Ga and 1.80–1.60 Ga. Recent works in this craton have shown the efficacy of the description and organization of volcanic and sedimentary lithofacies as a tool to postulate stratigraphic frameworks. In the present work we propose the first formal stratigraphy for the Beneficente Group (BG), a Statherian (~1.74 Ga) volcano-sedimentary unit outcropping in the southwestern portion of the Amazon Craton. The BG is divided into three formations: (1) Pedro Sara Formation (PSF), composed of felsic volcanic rocks represented by thick lava-like and densely welded tuffs, normal-graded tuffs, both from pyroclastic density currents, and laminated ash-fall tuffs; (2) Camaiú Formation (CF), comprising sheetfloods, low-energy alluvial channels, non-cohesive sediment-gravity flows, rubbly pahoehoe basaltic flows, stream-channel deposits, and deposits reworked in foreshore/superior shoreface settings, and; (3) Vila do Carmo Formation (VCF), formed by delta front and pro-delta lithofacies associations. The sequence of sedimentary rocks contains clasts exclusively from the related volcanic rocks (PSF), with no clasts from other volcanic sequences nearby. Geochronological analyses evidence a Statherian age for the sequence. A pheno-latite from PSF yielded a crystallization age of 1743.6 ± 7.5 Ma, the youngest zircons of a sandstone from CF have ages between 1746 and 1732 Ma and the youngest zircons of a sandstone from VCF have 1760 Ma to 1601 Ma. The Beneficente paleo-basin is preserved as a NW-SE rift in the margin of the Tapajós-Parima Province. This structure remained as an active depositional locus during the Paleozoic and is the location of the main courses of modern rivers. The development of BG is akin to Statherian taphrogenic systems which were widespread in the Amazon, São Francisco-Congo and North China cratons, and are a key tectonic feature before the Columbia (Nuna) supercontinent break-up.

Mineralogical and geochemical analysis of sodium bentonites in continental settings: The Uspallata Group (Triassic) of the Cuyana Basin, Mendoza province, Argentina

The Triassic Uspallata Group of the Cuyana rift Basin is characterized by continental deposits including alluvial, fluvial and lacustrine systems, mainly composed of volcaniclastic (reworked) and pyroclastic sediments. The present work focuses on the ash fall tuffs levels (bentonites) in order to understand the origin of their sodium composition since classic worldwide natural sodium bentonites link with marine environments as a source of sodium. The mineralogical attributes and relationship with diagenetic alterations have been explored by petrography, X-ray diffraction, and geochemical analysis. The tuff levels, recorded in the Cerro de las Cabras, Potrerillos and Cacheuta formations, provide the most reliable representation of the composition of the original material and diagenetic alterations due to these levels are devoid of detrital input. Accordingly, they represent key elements to explore the origin of huge bentonite deposits in the basin. In the study units, Na-montmorillonite and analcime, found at concentrations of up to or more than 50 vol%, grew at the expense of vitric components and represent authigenic minerals developed under early diagenesis. Following sedimentological and paleogeographic evidence the alteration of volcanic glass occurred in hydrologically open lacustrine systems that reached saline-alkaline conditions. The changes in the (Na + K)/H+ ratio influenced the formation of Na-montmorillonite and analcime through the succession. In addition, kaolinite is an important alteration mineral that fills cavities, replaces the feldspar grains, and probably the early diagenetic minerals. The origin of kaolinite is due to the combined effects of decomposition of organic matter and incursion of meteoric freshwater during late-stage telogenesis which generated the acidification of pore waters. Based on geochemical proxies, geochronological data and the geodynamic context the input of high volumes of pyroclastic material may thus be the result of explosive volcanism from an arc-subduction complex located to the west at these latitudes. The present work suggests that the composition of Na-rich pyroclastic ashes accumulated in hydrologically-open lake systems which conditioned the formation of sodium bentonites in continental settings.

El Complejo Volcánico Bahía Laura en la zona del distrito minero Manantial Espejo

El levantamiento geológico detallado junto con el análisis petrográfico y geoquímico de las unidades litológicas relevadas en la zona del distrito minero Manantial Espejo, permitió plantear la evolución del volcanismo Jurásico en esa zona del Macizo del Deseado (Provincia de Santa Cruz, Patagonia argentina). Se interpretaron tres ciclos de actividad volcánica, favorecidos por la tectónica distensiva que dominó esta provincia geológica durante el Jurásico Medio a Superior. El primero, el Ciclo Volcánico Inferior, corresponde a la efusión de lavas de composición andesítica (Formación Bajo Pobre) con una intercalación de areniscas tufíticas y niveles de aglomerados volcánicos producto de remoción en masa. La efusión de estas lavas se produjo sobre un basamento conformado por esquistos y granitos. El segundo, Ciclo Volcánico Medio, se inicia con una ignimbrita de composición dacítica a la que le siguen dos unidades ignimbríticas riolíticas, denominadas 1 y 2. La Ignimbrita dacítica y la Ignimbrita riolítica 2, son rocas con fuerte soldamiento, texturas reomórficas y muy alta participación de cristaloclastos, características que indican una elevada temperatura de depositación a partir del colapso de columnas eruptivas de baja altura, de relativa baja energía, elevada densidad y un bajo contenido de gases, originadas a partir de fontanas tipo ?boiling-over?. La Ignimbrita riolítica 1, intercalada entre las anteriores, se caracteriza por incluir grandes fragmentos líticos de naturaleza polimíctica, se correlaciona con las ignimbritas de extra-caldera formadas durante el colapso y erupción de la Caldera Cerro Primero de Abril, ubicada al norte del distrito Manantial Espejo, en las inmediaciones de Mina Martha. Continúa un período inter-eruptivo, durante el cual se depositan tufitas y travertinos que evidencian una actividad hidrotermal del tipo ?hot spring? controlada por estructuras de rumbo NNE y NNO a NO. El aporte de calor y la fuente de CO2 del sistema geotermal habrían estado vinculados a la desgasificación de un nuevo pulso de magma riolítico que marca el inicio del Ciclo Volcánico Superior, y que habría ascendido a través del mismo sistema extensional, evidenciado por diques riolíticos de rumbo NNO. El ascenso de lavas riolíticas dio lugar a la formación de dos centros volcánicos, el Centro Volcánico Norte, compuesto por un complejo extrusivo de domos riolíticos con depósitos de colapso tipo block and ash, y el Centro Volcánico Sur con el desarrollo de una compleja asociación de facies que sugieren que se trató de una erupción de tipo hidromagmática, con la formación de un aparato volcánico de tipo maar-diatrema al que se asocia un depósito de brecha constituida por fragmentos de lava acompañados por cantidades subordinadas de litoclastos de ignimbritas, tufitas y rocas laminadas silicificadas. Asociado a este evento explosivo se reconoció un depósito de tobas de caída con lapilli acrecionales que apuntan también a un probable origen hidromagmático. La interacción entre el magma y agua líquida sobrecalentada habría sido el responsable para la generación de esta erupción. Luego de un corto periodo de calma volcánica, la continuidad en el régimen deformacional distensivo permite nuevos asensos de magmas con la generación de nuevas unidades ignimbríticas riolíticas de similares características a las del segundo ciclo. El volcanismo andesítico a riolítico de la zona pertenece a una serie calcoalcalina de moderado a alto potasio, con afinidades de arco, mayoritariamente peraluminosas y subalcalinas. Dentro de este esquema, el Ciclo Volcánico Inferior es de composición netamente andesítica, el Ciclo Volcánico Medio registra la evolución de los magmas desde dacitas a riolitas y, por último, el Ciclo Volcánico Superior es típicamente riolítico en composición.

Mineral assemblages and low energy sedimentary processes in the FLK-Zinj, DS, PTK and AMK complex palaeolandscape (Olduvai Gorge, Tanzania)

The mineralogical composition of the clay stratum (level 22) that contains the FLK Zinj-DS-PTK-AMK complex, the only example of pene-contemporaneous early Pleistocene sites occurring on the same palaeolandscape and simultaneously covered by the same ash fall tuff, shows significant intra-site and inter-site differences. Overall, level 22A is related to a more hydrologically closed system, with higher salinity and alkalinity than level 22B. Both levels show fresher water was entering the system from the DS area during deposition. Textural analysis of the studied samples shows great microporosity and abundant edge-to-edge and edge-to-face contacts between crystals. These results have major repercussions for the interpretation of the archaeological assemblages in the FLK Zinj-DS-PTK-AMK palaeolandscape. First, this implies that two distinct archaeological levels formed at different times with different environmental conditions in most of these localities. Second, textural analyses provide evidence that no important sedimentary compaction took place after the deposition of this layer. This affects interpretations of palaeolandscape geomorphology. Third, it shows that the sedimentary processes during all the clay sequence occurred in very low-energy conditions. This reinforces that no significant physical forces disturbed the original configurations of materials contained within these assemblages and reinforces their autochthony. Behavioural interpretations can, thus, be more solidly built upon the conception that those sites preserve most of their original in situ properties.

An extensive K-bentonite as an indicator of a super-eruption in northern Iberia 477 My ago

Zircon and monazite ID-TIMS U-Pb dating of four Lower Ordovician altered ash-fall tuff beds (K-Bentonites) in NW Iberia provided coetaneous ages of 477.5±1, 477±1.3 Ma, 477.2±1.1 Ma and 477.3±1 Ma, with a pooled concordia age of 477.2±0.74 Ma. A conservative estimation of the volume and mass of the studied K-bentonite beds (using data from the Cantabrian Zone) returns a minimum volume for the preserved deposits of ca. 37.5 km3 (Volcanic Explosivity Index - VEI = 6, Colossal). When considering other putative equivalent beds in other parts of Iberia and neighbouring realms the volume of ejecta associated to this event would make it reach the Supervolcanic-Apocalyptic status (VEI=8, >1000 km3). Contrary to most cases of this kind of gargantuan eruption events, the studied magmatic event took place in relation to continental margin extension and thinning and not to plate convergence. We speculate that a geochronologically coincident large caldera event observed in the geological record of NW Iberia could be ground zero of this super-eruption.

Late Jurassic intraplate faulting in eastern Australia: A link to subduction in eastern Gondwana and plate tectonic reorganisation

Eastern Gondwana was subjected to subduction processes during the Middle-Late Jurassic, but how these processes affected intraplate deformation in eastern Australia is poorly understood. Here we present 40Ar/39Ar, K-Ar, and Rb-Sr geochronological data from illitic clay-bearing fault gouges associated with the northern part of the 200km long, N-striking, dextral strike-slip, Demon Fault in eastern Australia. We show a major range of geochronological ages at 162.99±0.74–152.1±4.8Ma, indicating that the Demon Fault was active during the Late Jurassic. This period partially coincides with the Middle-Late Jurassic deposition of widespread ash-fall tuffs in the Clarence-Moreton, Surat, and Eromanga basins. We propose that Middle-Late Jurassic intraplate tectonism in eastern Australia was influenced by subduction processes farther east, which produced extensive calc-alkaline magmatism in New Zealand from ~170Ma. A global plate reorganisation event, related to the development of Early-Middle Jurassic sea-floor spreading of the Pacific Plate, possibly acted as the driving mechanism responsible for the intensification of magmatism and intraplate faulting in eastern Gondwana.

Facies analysis of tuffaceous volcaniclastics and felsic volcanics of Tadpatri Formation, Cuddapah basin, Andhra Pradesh, India

The felsic volcanics, tuff and volcaniclastic rocks within the Tadpatri Formation of Proterozoic Cuddapah basin are not extensively studied so far. It is necessary to evaluate the extrusive environment of felsic lavas with associated ash fall tuffs and define the resedimented volcaniclastic components. The spatial and temporal bimodal association were addressed, but geochemical and petrographic studies of mafic volcanics are paid more attention so far. The limited exposures of eroded felsic volcanics and tuffaceous volcaniclastic components in this terrain are highly altered and that is the challenge of the present facies analysis. Based on field observation and mapping of different lithounits a number of facies are categorized. Unbiased lithogeochemical sampling have provided major and selective trace element data to characterize facies types. Thin-section studies are also carried out to interpret different syn- and post- volcanic features. The facies analysis are used to prepare a representative facies model to visualize the entire phenomenon with reference to the basin evolution. Different devitrification features and other textural as well as structural attributes typical of flow, surge and ash fall deposits are manifested in the middle, lower and upper stratigraphic levels. Spatial and temporal correlation of lithologs are also supportive of bimodal volcanism. Felsic and mafic lavas are interpreted to have erupted through the ~ N-S trending rift-associated fissures due to lithospheric stretching during late Palaeoproterozoic. It is also established from the facies model that the volcaniclastics were deposited in the deeper part of the basin in the east. The rifting and associated pressure release must have provided suitable condition of decompression melting at shallow depth with high geothermal gradient and this partial melting of mantle derived material at lower crust must have produced mafic magmas. Such upwelling into cold crust also caused partial heat transfer and associated melting of the surrounding shallow crustal rocks to generate felsic magmas.

The Ordovician magmatic arc in the northern Chile-Argentina Andes between 21° and 26° south latitude

A continental magmatic arc (the Famatinian magmatic arc) was developed on the western margin of Gondwana during the Early to Middle Ordovician. This has a northwestern orientation in the northern Chile-Argentina Andes between 21° and 26° south latitude with a northeastern directed subduction zone and developed on a continental crust represented by a metamorphic basement. A paleogeographical scheme for the Ordovician magmatic arc is proposed and two tectonic environments can be recognized from our own data and data from the literature: forearc and arc. The Cordón de Lila Complex can be assigned to a forearc position. Here the turbiditic flows become paralell to the northwestern elongation of the magmatic arc. The sedimentation in the frontal-arc high platform of the forearc is represented by stromatolitic limestones and a zone of phosphate production. The internal structure of the arc can be inferred from the petrographic composition of the turbidites: basaltic and andesitic lavas, dacitic and/or rhyolitic lavas and ash fall tuffs. Also the Quebrada Grande Formation was developed on the forearc. Plutonic Ordovician rocks testify the continuity of the magmatic arc. The data about the basement exposed in the present paper do not support the existence of the Arequipa-Antofalla Terrane.

Stratigraphy, geochronology and regional tectonic setting of the Late Cretaceous (ca. 82-70 Ma) Cabullona basin, Sonora, Mexico

The Cabullona basin in northeastern Sonora is a continental depocenter whose origin is related to the adjacent Sierra Anibacachi uplift that bounds its tectonic eastern flank. Its exposed, mostly fluvial and lacustrine sedimentary fill, the Cabullona Group, was deposited between 81.9 ± 0.7 and 69.8 ± 0.7 Ma and its outcrops extends for 70 km from north to south. The oldest measured stratigraphic column of the Cabullona Group is the Los Atolillos column of the southern part of the basin, but its base is not exposed. A basal conglomerate in the younger El Malacate (ca. 80 Ma), Cuauhtémoc (ca. 75 Ma) and San Joaquín (ca. 70 Ma) columns onlaps deformed basement rocks. The type section in which the Cabullona Group was previously named is herein referred as the Naco section and is dated ∼73-72 Ma. The younger strata of the Cabullona Group correspond to the fluvial San Joaquín column that onlaps the eastern tectonic boundary of the basin and to the lacustrine Esqueda column. These columns are dated at ca. 70 Ma and may represent the late evolution of the Cabullona basin.Sandstone petrography and detrital zircon geochronology are used to infer provenance of sediments of the Cabullona Group. Sandstones consist of lithic arkose to feldespathic litharenite, indicating provenance from dissected to transitional volcanic arc, but samples of the El Malacate column classify as arkose and lithic arkose with possible provenance from basement uplift of Sierra Los Ajos; litharenite from the Esqueda column indicate arc provenance. Detrital zircons yielded mostly Proterozoic and Mesozoic ages with age peaks at ca. 1568, 167, 100, 80 and 73 Ma indicating possible provenance from the Precambrian basement rocks and the Jurassic continental magmatic arc that underlie the region, the Alisitos arc and La Posta plutons in Baja California, and from the Laramide magmatic arc of Sonora.The Cabullona basin developed nearly contemporaneous to the early, eastwards migrating Laramide magmatic arc that located to the west of the basin, and to a tectonic shortening that occurred in northern Sonora during Late Cretaceous time. In the older columns of the Cabullona Group and in columns of the northern part, the early arc had a distal influence during sedimentation as shown by interbedded ash fall tuffs and minor rhyolitic flows, but sections in the southern part of the basin record more abundant rhyolitic ash-fall tuffs and flows indicating the arc proximity. An important regional flare-up of the arc at ca. 74 Ma is recorded by the Ejido Ruiz Cortines column, while the upper part of the Cabullona Group was interdigitating with rhyolitic rocks by 70 Ma. The Cabullona basin started to form during the shortening event whose age is constrained between ca. 93 and 76 Ma according to U-Pb ages of the syntectonic Cocóspera Formation of northern Sonora and from Laramide arc rocks that overlie it. Ages and correlation of the Cocóspera and the Altar formations may indicate that a Laramide tectonic front extended from north-central Sonora to the Caborca region and whose trace may correspond to a westward extension of the San Antonio fault.

Hinterland drainage closure and lake formation in response to middle Eocene Farallon slab removal, Nevada, U.S.A.

Hinterland basins can accumulate high resolution archives of orogenic processes and continental climate, but are challenging to reconstruct due to tectonic overprinting and the inherent complexity of their lithofacies assemblages. The Cordilleran hinterland of northeast Nevada has been interpreted to have overlain a flattened Farallon slab from the Late Cretaceous to Eocene. Slab removal and advection of asthenospheric mantle beneath Nevada have been invoked to explain a southwestward migrating wave of Eocene to Oligocene volcanism and proposed as a driver for topographic uplift. However, the timing of slab removal and possible subsequent delamination of North American lithospheric mantle can only ambiguously be related to the surface record. Subsequent Neogene extension and basin filling has complicated the correlation and interpretation of strata that record these events. Here we apply single crystal sanidine 40Ar/39Ar geochronology to 26 ash beds in northeast Nevada to reconstruct Paleogene geographic and hydrologic evolution. We use these ages and legacy geochronology to compare lithofacies and isotope proxy records of meteoric waters to regional tectonics and global climate, and assess competing tectonic interpretations for lake basin formation. Lakes formed locally prior to ca. 48.7 Ma in northeast Nevada, coeval with foreland lakes of the Green River Formation. The most expansive phase of lacustrine deposition resulted in onlap onto locally derived fluvial deposits and folded Paleozoic bedrock, and occurred between ca. 43.4 and ca. 40.8 Ma. Elko Formation strata exhibit a basin-wide transition from fluvial-lacustrine to fluctuating profundal lithofacies at ca. 42.7 Ma, suggesting a shift towards regional hydrologic closure. The stromatolitic upper Elko Formation is intercalated with ash fall tuffs and several partially welded to unwelded ignimbrites from increasingly proximal volcanism. Elko Formation deposition ended by ca. 40.4 Ma. 40Ar/39Ar ages for seven ash beds in the Dead Horse Formation at Copper Basin in northern Elko County indicate intermittent ash bed deposition between 45.2 Ma and 38.6 Ma, and an episode of lacustrine deposition between 39.8 Ma and 38.6 Ma that post-dates the main phase of Lake Elko. δD values of volcanic glass sampled from dated ash beds reflect changes in the hydrogen isotope compositions of local Eocene waters, and systematically vary by 80–102‰ according to their depositional environment. The Elko Formation and overlying volcanic strata are overlain regionally by a pronounced unconformity of ∼20 m.y. In the Copper Basin area, deposition continued locally into the Oligocene in the hanging wall of a ductile detachment. The geochronologic and isotopic framework presented here permits reanalysis of the Piñon Range carbonate proxy record that was previously interpreted to record both regional uplift and the middle Eocene climatic optimum. New data suggest instead that isotope values of hydration waters within the Elko Formation were strongly influenced by evaporation, and a change from lacustrine to non-lacustrine conditions can account for the δ18O shift that was interpreted to reflect regional uplift. Moreover, the end of Elko Formation deposition predated the middle Eocene climatic optimum. We interpret the overall record of drainage ponding and paleovalley inundation, progressively more evaporative lacustrine conditions, increasingly proximal volcanism, and subsequent prolonged unconformity to reflect the surface effects of progressive NE to SW removal of the Farallon slab.

Onset of the Laramide orogeny and associated magmatism in southern New Mexico based on U-Pb geochronology

The Laramide orogeny is a classic yet controversial mountain-building event that resulted, in the southwest United States, in uplifts, sedimentation, and magmatism that can be used to constrain the onset of this event in the region and expand our knowledge of Late Cretaceous to Paleogene tectonism. The McRae Formation marks the onset of deposition in the Laramide Love Ranch Basin, which was located to the northeast of the west-northwest-trending coeval Rio Grande uplift in south-central New Mexico, but its age is not well constrained. A previously published late Maastrichtian age for the McRae Formation was based on the presence of dinosaur bones in the upper of two members of the formation. We obtained new U-Pb dates from one dacite clast and three ash-fall tuffs from the lower Jose Creek Member and from one ash-fall tuff from the lower part of the overlying Hall Lake Member of the McRae Formation. The clast yielded a date of 75.0 ± 1.1 Ma, whereas the ages of the tuffs, in ascending stratigraphic order, are 74.9 ± 0.7 Ma, 74.7 ± 0.6 Ma, 75.2 ± 1.3 Ma, and 73.2 ± 0.7 Ma. These dates indicate that the onset of Laramide deposition in the Love Ranch Basin must have occurred earlier, in late Campanian time, similar to deposition in the Laramide Ringbone Basin in southwestern New Mexico. In addition, U-Pb zircon dates of 75.7 ± 1.3 Ma and 75.0 ± 2.8 Ma were obtained on the Twin Peaks stock and on a dacite sill, respectively, in the Burro Mountains of southwestern New Mexico. These dates are similar to those of other Laramide arc magmatic centers in southern New Mexico, which have a limited range of ages from 75 to 70 Ma, including the Hidalgo Formation in the Little Hatchet Mountains, the Silver City-Pinos Altos region, and the Copper Flat porphyry system. These new and previously published dates indicate that during the onset of Laramide deformation in southwestern and south-central New Mexico, the angle of subduction of the Farallon plate may have been steep enough to allow partial melting of an asthenospheric wedge, resulting in arc magmatism far inboard of the trench.