Ash-fall Deposits Research Articles

Neutralisation of Acid Rock Drainage by Youngest Toba Tuff Leachate Revealed by Hydrogeochemistry

ABSTRACTThe Youngest Toba Tuff (YTT) supervolcanic eruption occurred 75000 years ago, and resulted in distinctive ash fall deposition in different locations encompassing marine, estuarine, lacustrine, and fluvial sedimentary basins. Of the different sedimentary basins, the YTT crypto‐tephra horizon preserved in the South Kerala Sedimentary Basin (SKSB) of the western coast of India is hosted by a paleo‐estuarine carbonaceous clay layer. Along the eastern margin of SKSB, confined aquifers hosting highly acidic groundwater is associated with this YTT ash and associated organic matter (OM)‐rich carbonaceous clay layer, creating worse acid rock drainage (ARD), which eventually gets neutralised during summer, signalled by the crystallisation of halotrichite. Hydrogeological investigation gave insights on some of the unique geochemical processes, which facilitated the neutralisation of ARD. The main aquifers in the area include laterite and clayey‐sand, which is separated by this impervious layer hosting YTT ash. Wells tapping the clayey‐sand aquifer, beneath this layer, is affected by the ARD condition due to the interaction with pyrite, manifested as low pH of groundwater (3.7). Simultaneously, leaching from YTT ash, which constitutes 11.91% of Al2O3, facilitates Al content to reach groundwater in high concentration (2879.97 ppb). During dry season, when the surface of YTT‐hosting OM‐rich carbonaceous clay layer is exposed, the leached Al interacts with the acid derived from the YTT‐hosting OM‐rich carbonaceous clay layer and results in the precipitation of halotrichite. The two processes, one resulting in ARD condition and the other as formation of halotrichite, occur in succession. Thus, the crystallisation of halotrichite signals the neutralisation of water as well as heralding the potability of water.

Ash deposits link Oceanic Anoxic Event 2 to High Arctic volcanism

Oceanic Anoxic Event 2 (OAE 2) was a major environmental perturbation that occurred ∼94 million years ago. It is associated with profound changes in global climate and carbon cycling, which are commonly attributed to large-scale carbon release from large igneous province (LIP) volcanism. However, the specific LIP(s) involved and the mechanisms of carbon release remain poorly understood, as indicated by discrepancies between carbon release rates suggested by numerical models and LIP degassing estimates. Our study refines the eruptive history of the High Arctic large igneous province (HALIP) by dating ashfall deposits in marine sediments from the Canadian High Arctic using an integrated stratigraphic approach. Our results show that silicic HALIP volcanism began tens of thousands of years before OAE 2, suggesting a strong causal link. Volcanic activity coincides with a marked shift in carbon isotope values, linked to the degassing of HALIP magmas and/or thermogenic gas release. We propose that the concurrent activity of two LIPs—the HALIP and the Kerguelen Plateau—could account for the high rates of carbon release inferred for OAE 2, providing a hypothesis for its pervasive environmental impact.

Metal(loid) bioaccessibility and risk assessment of ashfall deposit from Popocatépetl volcano, Mexico

Ash emission from volcanic eruptions affects the environment, society, and human health. This study shows the total concentration and lung bioaccessible fraction of eight potential toxic metal(loid)s in five Popocatépetl ashfall samples. Mineralogical phases and particle size distribution of the ashfall were analyzed by X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) techniques, respectively. The bioaccessibility test of Gamble solution (GS) and Artificial Lysosomal Fluid (ALF) were conducted to simulate extracellular (pH 7) and intracellular (pH 4.5) conditions, respectively. The studied metal(loid)s showed the following total concentration (mg kg−1): 1.98 (As), 0.17 (Cd), 134.09 (Cr), 8.66 (Cu), 697.33 (Mn), 55.35 (Ni), 8.77 (Pb), and 104.10 (Zn). Geochemical indices suggested that some metal(loid)s are slightly enriched compared to the local soil background concentrations. Several mineralogical phases were identified in the collected ashfall deposits, such as plagioclase, pyroxene, and Fe–Ti oxide, among others. According to the risk assessment results, the non-carcinogenic risk related to ashfall exposure returns an HQ > 1 for children. In contrast, the estimation of carcinogenic risk was found to be within the tolerable limit. Metal(loid)s showed low bioaccessibility (< 30%) in GS and ALF, with the highest values found in ALF solution for As (12.18%) and Cu (7.57%). Despite their metal-bioaccessibility, our findings also showed that dominant ash particle size ranged between fine (< 2.5 μm) and extremely fine (< 1 μm), considered highly inhalable fractions. The results obtained in this work indicate that volcanic ashes are bioinsoluble and biodurable, and exhibit low bioaccessibility when in contact with lung human fluids.

Newly identified small vulcanian eruptions during the caldera-forming stage of Towada Volcano, Northeast Japan

Understanding the detailed eruptive history and conditions during the buildup to catastrophic caldera-forming eruptions is essential for understanding the evolution of caldera volcanoes and predicting eruptive hazards. Towada Volcano is an active caldera volcano in the northern part of the Northeast Japan Arc. At least two catastrophic caldera-forming eruptions (eruptive episodes N and L) occurred during its caldera-forming stage (61–15.7 ka). A detailed geological survey identified three small vulcanian tephra layers that were erupted during the caldera-forming stage. The tephra layers are blue–gray ash fall deposits that consist mainly of fresh blocky dacite–rhyolite fragments. In ascending order, these deposits are assigned to eruptive episodes O′, N′, and M′. Each eruption had a volume of <0.11 km3, which is much smaller than that of other eruptions during the caldera-forming stage. The eruptive ages of episodes O′, N′, and M′ are estimated to be ca. 40, 23.1, and 17.2 ka, respectively, based on new 14C ages and paleosol thicknesses data. At least three cycles of a medium- to large-scale (3–20 km3) explosive eruption, preceded by a small vulcanian eruption (<0.11 km3), occurred during the latter half of the caldera-forming stage. The small vulcanian eruptions (episodes O′, N′, and M′) occurred after relatively long periods of quiescence (4000–14,000 years) and were followed by medium- to large-scale explosive eruptions (episodes N, M, and L) 1500–4000 years later. This cyclic activity probably reflects changes in overpressure in the magma reservoir. As the overpressure increased, episodes O′, N′, and M′ probably occurred when the overpressure had not increased sufficiently to trigger a medium- to large-scale explosive eruption, and episodes N, M, and L occurred at higher overpressures. These cycles characterize the fermentation phase of Towada Volcano, and terminated with the formation of the Towada Caldera during episode L at 15.7 ka. The magma composition and eruption frequency changed abruptly after episode L, and a small stratovolcano was formed through intermittent eruptions of mafic magma. This change suggests that the caldera collapse during episode L changed the entire shallow magmatic system that existed during the fermentation phase, and the system shifted to a recovery (post-caldera) phase. Based on eruptive volumes and frequencies, the present Towada Volcano has not yet reached the conditions that existed during the late caldera-forming stage and is therefore unlikely to produce a catastrophic caldera-forming eruption in the near future.

Fluorite and Gibbsite Solubility Controls the Vertical Transport of Fluoride and Aluminum during Rainwater Percolation through Ashfall Deposits in La Palma (Canary Islands, Spain)

This study addresses the in situ mobility of fluoride and aluminum in two different ashfall deposits accumulated during the 2021 eruption of the Tajogaite volcano (La Palma, Canary Islands, Spain), which were exposed to contrasting conditions of ambient humidity and precipitation. We selected one site to the east of the volcanic emission center, located near the top of Cumbre Vieja Ridge and exposed to continuous humidity and rain, and another site to the west of the volcano situated in a lowland and characterized by much drier conditions. The mobility of fluoride and aluminum is markedly different at both sites, with the first sequence suggesting a downwards migration of Al and F, and the second sequence showing no sign of mobility. The migration of aluminum and fluorine results from the dissolution of different fluoride salts (mostly AlF3 and CaF2, as suggested by scanning electron microscopy) followed by vertical transport as ionic complexes (AlF3, AlF2+, AlF4−) during the percolation of rainwater through the ashfall deposits. Geochemical calculations suggest that the mobility of fluorine at neutral to alkaline conditions (pH 7.0–9.0) is likely limited by the solubility of fluorite (CaF2), whereas at slightly acidic conditions (pH &lt; 6.5), the aqueous concentration of aluminum seems to be controlled by the solubility of gibbsite (Al(OH)3). This study demonstrates that aluminum and fluoride can be transported from volcanic ash to the underlying soil or groundwater, which is an environmental concern that should be followed in the future.

A history of explosive eruptions at Young Damavand volcano, Iran

Young Damavand volcano is a steep isolated volcano in the Central Alborz Mountains, Iran, that is characterized by extensive lava flows and pyroclastic successions and is placed on the eroded remains of Old Damavand. Pyroclastic fall and density current deposits on all flanks of the volcano were sampled and studied. From a tephrostratigraphic and geochemical study of the proximal-medial sequences, 14 phases of explosive volcanic activity are identified, characterized by a combination of ash and pumice fall deposits, and/or dense and dilute pyroclastic density current deposits. Some explosive phases of Damavand are thought to have happened one after the other with only short time intervals, since almost no traces of paleosol can be identified between them. We also show that the intensity of the eruptions varied between different phases, confirmed by relative thickness and grain size of the different fall deposits and their distance from the crater. The evidence of numerous explosive eruptions, five of which with Volcanic Explosivity Index 4 in the history of the activity of Young Damavand volcano, shows the importance of assessing its potential volcanic hazards.

Vapor-phase crystallization from a hydrous silicate melt: an experimental simulation of diktytaxitic texture

Groundmass textures of volcanic rocks provide valuable insights into the processes of magma ascent, crystallization, and eruption. The diktytaxitic texture, characterized by a lath-shaped arrangement of feldspar microlites forming glass-free and angular pores, is commonly observed in silicic dome-forming rocks and Vulcanian ashfall deposits. This texture has the potential to control the explosivity of volcanic eruptions because its micropore network allows pervasive degassing during the final stages of magma ascent and eruption. However, the exact conditions and kinetics of the formation of diktytaxitic textures, which are often accompanied by vapor-phase cristobalite, remain largely unknown. Here, we show that the diktytaxitic texture and vapor-phase minerals, cristobalite and alkali feldspar, can be produced from bulk-andesitic magma with rhyolitic glass under water-saturated, near-solidus conditions (± ~10 MPa and ± ~20 °C within the solidus; 10–20 MPa and 850 °C for our starting pumices). Such crystallization proceeds through the partial evaporation of the supercooled melt, followed by the deposition of cristobalite and alkali feldspar as a result of the system selecting the fastest crystallization pathway with the lowest activation energy. The previously proposed mechanisms of halogen-induced corrosion or melt segregation by gas-driven filter pressing are not particularly necessary, although they may occur concurrently. Diktytaxitic groundmass formation is completed within 4–8 days, irrespective of the presence or composition of the halogen. These findings constrain the outgassing of lava domes and shallow magma intrusions and provide new insights into the final stages of hydrous magma crystallization on Earth.

Reconciling complex stratigraphic frameworks reveals temporally and geographically variable depositional patterns of the Campanian Ignimbrite

Abstract The 39.8-ka Campanian Ignimbrite was emplaced during a large caldera-forming eruption of Campi Flegrei near Naples, Italy. The ignimbrite is found up to 80 km from the caldera, and co-ignimbrite ash-fall deposits occur 3200 km away. The proximal and distal stratigraphy of the Campanian Ignimbrite has not been definitively correlated due to the dissimilar appearance of the proximal and distal deposits, a lack of medial exposures, and the inconsistency and heterogeneity of the proximal stratigraphy. Here, we document the major-element glass-shard chemistry, matrix componentry, and lithic componentry of the proximal and distal stratigraphic sequences of the ignimbrite to attempt to correlate the units. The results of these disparate observations taken together suggest that the established stratigraphic units cannot be directly and uniquely correlated between the proximal and distal regions and that neither the proximal nor distal stratigraphy provides a record of the entire eruptive sequence. However, the characteristics studied can be used to demarcate eruptive phases that are connected to some of the defined units in the proximal and distal stratigraphy.

The Geological and Tectonic Evolution of Feni, Papua New Guinea

Feni is located at the southeastern end of the NW-trending Tabar–Lihir–Tanga–Feni (TLTF) volcanic island chain, in northeastern Papua New Guinea. This island chain is renowned for hosting alkaline volcanics, geothermal activity, copper–gold mineralization, and mining. There is no agreed consensus on the tectonic and petrogenetic evolution of Feni. Thus, the purpose of our paper is to present the geology of Feni within the context of the regional tectonic evolution of the TLTF chain and offer a succinct and generic geodynamic model that sets the stage for our next paper. The methodologies used in this study include a critical review of published and unpublished literature in conjunction with our geological observations on Feni. The Pliocene-to-Holocene TLTF chain is a younger arc situated within the greater Eocene-to-Oligocene Melanesian Arc bounded by New Ireland to the west, the Kilinailau Trench and Ontong Java Plateau in the east, and the New Britain Trench to the south. The geological units mapped on Feni include a large volume of basaltic lava flow and trachyandesite stocks intruding a limestone and siltstone basement. Younger units include the trachyte domes, pyroclastic flow, and ash fall deposits. The major structures on Feni are normal or extensional faults such as the Niffin Graben. Feni magmatism is attributed to the petrogenetic processes of polybaric or decompression melting and crystal fractionation of magmas previously influenced by sediment assimilation, mantle wedge metasomatism, slab tears, slab melts, and subduction. Deep lithospheric normal faults provide the fluid pathways for the Feni alkaline magmas.

U-Pb Zircon Geochronology of Detrital and Ash Fall Deposits of the Southern Paraná Basin: A Contribution for Provenance, Tectonic Evolution, and the Paleogeography of the SW Gondwana

Zircon U-Pb geochronology was applied to investigate the provenance, depositional ages, and paleogeography of the southwestern Gondwana in detrital and ash fall sediments from Carboniferous to Jurassic succession of the southern Paraná Basin. Four detrital age populations suggest provenance from local and distal sources located to the south, southeast, and southwest: (i) Archean to Paleoproterozoic zircons from the Rio de La Plata Craton, Nico Peres and Taquarembó terranes; (ii) Grenvillian zircons from the basement of the Gondwanides and Namaqua–Natal belts; (iii) Neoproterozoic grains from the Don Feliciano Belt; and (iv) Phanerozoic populations from Paleozoic orogenic belts and related foreland systems in Argentina, as well as eroded units of the Paraná Basin. The paleogeographic reconstruction indicates an evolution in three distinct stages: (1) a gulf open to the Panthalassa Ocean during the Carboniferous; (2) an epicontinental sea with the rise of the Gondwanides Orogeny during the Permian; and (3) continental deposits controlled by an intra-plate graben system during the Triassic. Permian–Triassic volcanogenic zircons provide constrained maximum depositional ages and attested persistent volcanism, related to the Choiyoi magmatism and effects of the climate change episodes. During the Triassic, the extensional graben system recorded the uplift of the basement through regional northwest and northeast fault systems, and the recycling of Permian zircons, modifying source-to-sink relationships.

Science results from sixteen years of MRO SHARAD operations

In operation for >16 years to date, the Mars Reconnaissance Orbiter (MRO) Shallow Radar (SHARAD) sounder has acquired data at its nominal 300–450 m along-track and 3-km cross-track resolution covering >55% of the Martian surface, with nearly 100% overlap in coverage at that scale in the polar regions and in a number of smaller mid-latitude areas. While SHARAD data have opened a new window into understanding the interior structures and properties of Martian ices, volcanics, and sedimentary deposits up to a few kilometers in depth, they have also led to new revelations about the deeper interior and the behavior of the planet's ionosphere. Here we summarize the data collected by SHARAD over this time period, the methods used in the analysis of that data, and the resulting scientific findings. The polar data are especially rich, revealing complex structures that comprise up to several dozen reflecting interfaces that extend to depths of 3 km, which inform the evolution of Martian climate in the late Amazonian period. SHARAD observations of mid-latitude lobate debris aprons and other glacier-like landforms detect strong basal reflections and low dielectric loss, confirming that they are ice-rich debris-covered glaciers. In other mid-latitude terrains, SHARAD data demonstrate the presence of widespread ground ices, likely at lower concentrations. SHARAD signals also probe non-icy materials, mapping out stacked lava flows, probing low-density materials thought to be ash-fall deposits, and occasionally penetrating sedimentary deposits, all of which reveal the structures and interior properties diagnostic of emplacement processes. SHARAD signals are impacted by their passage through the Martian ionosphere, revealing variations in time and space of the total electron content linked with the remanent magnetic field. Advanced techniques developed over the course of the mission, which include subband and super-resolution processing, coherent and incoherent summing, and three-dimensional (3D) radar imaging, are enabling new discoveries and extending the utility of the data. For 3D imaging, a cross-track spacing at the nominal 3-km resolution is more than sufficient to achieve good results, but finer spacing of 0.5 km or less significantly improves the spatially interpolated radar images. Recent electromagnetic modeling and a flight test show that SHARAD's signal-to-noise ratio can be greatly improved with a large (∼120°) roll of the spacecraft to reduce interference with the spacecraft body. Both MRO and SHARAD are in remarkably fine working order, and the teams look forward to many more years in which to pursue improvements in coverage density, temporal variability in the ionosphere, and data quality that promise exciting new discoveries at Mars.

Early Cretaceous lepidosaur (sphenodontian?) burrows

Scarce fossil tetrapod burrows have been recorded in Cretaceous rocks, which is probably linked to the dominant equable climates that existed for most of this period. The occurrence of Cretaceous tetrapod burrows from Patagonia (Chubut Province, Argentina) dated between 118 and 115 million years ago, gives insights into their paleoecology and paleoenvironment. The rocks containing the tetrapod burrows are of pyroclastic origin and represent eolian dunes and ash-fall deposits, some reworked by fluvial currents and others showing soil development. Fossil burrow casts preserved in a paleosol are composed by a ramp with a slightly curved or straight path in plan-view and lacking bifurcation, a rounded termination with no enlargement, showing a reniform cross-section, and are assigned to the ichnospecies Reniformichnus katikatii. The strongly flattened cross-sectional shape of the burrow casts and comparison with modern lizard burrows suggest that the producers were lepidosaurs (body mass = 50–323 g). Among Cretaceous fossorial lepidosaurs from Patagonia, the best candidate is an eilenodontine sphenodontian. Sphenodontians burrowed in the fossil soils where also arthropods, earthworms and shrubby plants thrived. The rare occurrence of tetrapod burrows in Cretaceous rocks is linked to stressing conditions related to frequent arrival of volcanic ash and a semiarid seasonal climate.

Ash aggregate-rich pyroclastic density currents of the 431 CE Tierra Blanca Joven eruption, Ilopango caldera, El Salvador

The VEI 6, Tierra Blanca Joven pyroclastic sequence (30–90 km3 DRE volume), erupted from Ilopango caldera, El Salvador, in 431 CE, is the product of one of the largest eruptions of the last two millennia. The eruption devastated Central America's Mayan civilization. The eruption began with a short-lived phase of ash and pumice fall deposition and transitioned to a ‘wet’ explosive phase during which pyroclastic density currents flowed >40 km from the caldera. Detailed field and sedimentological analyses are provided for the deposits of ash-aggregate-rich pyroclastic density currents generated during early phases of the eruption. The first phase of pyroclastic density current inundation incinerated forests and deposited up to 30 m of, non-welded, ash-rich ignimbrite in proximal regions, along with ash fall layers of co-ignimbrite origin. Following fallout of a thin layer of pumice and lithic lapilli, a second phase of pyroclastic density current inundation and co-ignimbrite ash fall commenced. A range of ash aggregate types is present in the pyroclastic density current deposits and interbedded co-ignimbrite ash fall layers. Whole and broken concentrically layered ash aggregates (accretionary lapilli) reach >50 vol% in some horizons within some beds in the pyroclastic density current deposits. The evidence indicates that the ash aggregates grew within overriding co-ignimbrite ash plumes and subsequently fell into ground-hugging currents. Our findings suggest that the aggregate-rich nature of the pyroclastic density current deposits originated through incorporation of lake water into eruptive plumes, which in turn triggered rapid, pervasive aggregation within ash clouds and co-ignimbrite plumes.

An Eocene leaf flora from the northern Peruvian Andes

The fossil forest known as El Bosque Petrificado Piedra Chamana lies in close proximity to the village of Sexi in the Department of Cajamarca in northern Peru. The forest was deposited in either a lahar or pyroclastic flow, and ashfall deposits, as mineralized wood and leaf impressions 39 million years ago (late Middle Eocene). More than 30 types of non-monocot angiosperms have been described from the fossil wood, which is densely embedded in rock outcrops, scattered across the ground, and occasionally found in situ. Anatomical characteristics and identifications of the woods suggest a seasonally flooded lowland tropical forest with a dry period. This site also preserves a small leaf flora which has not received a full treatment in earlier works and is the focus of the present study. The leaves are described in detail using standard leaf architecture terminology. The flora has 31 non-monocot leaf morphotypes. The presence of more than 30 morphotypes suggests high diversity based on having only ∼210 non-monocot leaf specimens. The leaf collection also includes ∼10 monocot specimens. One of the leaf morphotypes shows similarities to the extant mangrove genus Avicennia, possibly confirming one of the fossil wood identifications. Most of the leaves are incomplete, but when the margin is preserved, it is untoothed. The lack of teeth indicates a warm, tropical climate (estimated mean annual temperature of >25 °C based on leaf margin analysis). Leaves in the collection are small with 28 of 31 morphotypes inferred as microphyll or notophyll in laminar size, providing support for the seasonal dryness indicated by the fossil woods. Despite the small size of the collection, this leaf flora is important to document as there are few Eocene plant macrofossil localities in Peru; it provides some insight into the Cenozoic forests in this understudied region.

Estimates of volcanic mercury emissions from Redoubt Volcano, Augustine Volcano, and Mount Spurr eruption ash

Ash is a potential sink of volcanically sourced atmospheric mercury (Hg), and the concentration of particle-bound Hg may provide constraints on Hg emissions during eruptions. We analyze Hg concentrations in 227 bulk ash samples from the Mount Spurr (1992), Redoubt Volcano (2009), and Augustine Volcano (2006) volcanic eruptions to investigate large-scale spatial, temporal, and volcanic-source trends. We find no significant difference in Hg concentrations in bulk ash by distance or discrete eruptive events at each volcano, suggesting that in-plume reactions converting gaseous Hg0 to adsorbed Hg2+ are happening on shorter timescales than considered in this study (minutes) and any additional in-plume controls are not discernable within intra-volcanic sample variability. However, we do find a significant difference in Hg concentration of ash among volcanic sources, which indicates that volcanoes may emit comparatively high or low quantities of Hg. We combine our Hg findings with total mass estimates of ashfall deposits to calculate minimum, first-order Hg emissions of 8.23 t Hg for Mount Spurr (1992), 1.25 t Hg for Redoubt Volcano (2009), and 0.16 t Hg for Augustine Volcano (2006). In particular, we find that Mount Spurr is a high Hg emitting volcano, and that its 1992 particulate Hg emissions likely contributed substantially to the global eruptive volcanic Hg budget for that year. Based on our findings, previous approaches that use long-term Hg/SO2 mass ratios to estimate eruptive total Hg under-account for Hg emitted in explosive events, and global volcanogenic Total Hg estimates need revisiting.

Long-term ash dispersal dataset of the Sakurajima Taisho eruption for ashfall disaster countermeasure

Abstract. A large volcanic eruption can generate large amounts of ash which affect the socio-economic activities of surrounding areas, affecting airline transportation, socio-economics activities, and human health. Accumulated ashfall has devastating impacts on areas surrounding the volcano and in other regions, and eruption scale and weather conditions may escalate ashfall hazards to wider areas. It is crucial to discover places with a high probability of exposure to ashfall deposition. Here, as a reference for ashfall disaster countermeasures, we present a dataset containing the estimated distributions of the ashfall deposit and airborne ash concentration, obtained from a simulation of ash dispersal following a large-scale explosive volcanic eruption. We selected the Taisho (1914) eruption of the Sakurajima volcano, as our case study. This was the strongest eruption in Japan in the last century, and our study provides a baseline for a worst-case scenario. We employed one eruption scenario (OES) approach by replicating the actual event under various extended weather conditions to show how it would affect contemporary Japan. We generated an ash dispersal dataset by simulating the ash transport of the Taisho eruption scenario using a volcanic ash dispersal model and meteorological reanalysis data for 64 years (1958–2021). We explain the dataset production and provide the dataset in multiple formats for broader audiences. We examine the validity of the dataset, its limitations, and its uncertainties. Countermeasure strategies can be derived from this dataset to reduce ashfall risk. The dataset is available at the DesignSafe-CI Data Depot: https://www.designsafe-ci.org/data/browser/public/designsafe.storage.published/PRJ-2848v2 or through the following DOI: https://doi.org/10.17603/ds2-vw5f-t920 by selecting Version 2 (Rahadianto and Tatano, 2020).

Re-investigation of the sector collapse timing of Usu volcano, Japan, inferred from reworked ash deposits caused by debris avalanche

It is essential to establish the timing of past sector collapse events at a volcanic edifice to evaluate not only the evolution of the volcanic system but also potential volcanic hazards. This can be done by determining the age of the collapse-generated debris avalanche deposits. However, without evidence of an associated magmatic eruption, it is impossible to recognize juvenile materials in these deposits. Thus, it is usually difficult to determine the precise age of sector collapse. Usu is a post-caldera volcano of the Toya Caldera (Hokkaido, Japan) and has been constructed since ca. 19–18 ka on top of the caldera-forming Toya pyroclastic flow deposits (Tpfl deposit: 106 ka). A sector collapse occurred after the formation of a stratovolcano edifice and produced the Zenkoji debris avalanche (ZDA) deposit with reported ages ranging from &amp;gt;20 to 6 ka. We investigated the tephrostratigraphy preserved in the soil above the ZDA deposit and in the surrounding area and recognized fine ash fall deposits at two locations, above and east of the ZDA deposit. The glass shards within these deposits were correlated with several tephra layers with the majority being derived from Tpfl deposits. Thus, these ash deposits should be considered reworked tephra. A considerable number of hummocks in the ZDA deposit were also composed of deformed and fragmented Tpfl deposits, which suggests that the ZDA bulldozed and partially incorporated the Tpfl deposit on the flank of the volcano. Deformation and fragmentation of the non-welded soft silicic Tpfl deposit during the transport and emplacement of the ZDA produced an accompanying ash cloud, which deposited the observed glassy, fine, ash fall units. Radiocarbon dating of soil samples directly below and above the reworked ash deposits allowed dating the sector collapse to ca. 8 ka. This age is much younger than previously proposed results. Based on our findings, the transport and emplacement mechanism of the sector collapse should be revised. Our study shows that reworked ash layers caused by the flow of a debris avalanche can be used as an indicator of the timing of a sector collapse of the volcano.

The Abra del Toro rock shelter, northwestern Argentina, a space occupied by hunter-gatherers that was hit by the large 4.2 ka Cerro Blanco eruption

Occupation sites have been rarely found during research on the prehistorical hunter-gatherer populations in the Andean intermontane valleys. Some reasons are the intense anthropization of the landscape and the scarce research efforts. Recent work opens new perspectives at the Abra del Toro rock shelter in the Yocavil valley (province of Catamarca, Argentina). Stratigraphy of rock shelter shows a 1 m thick volcanic ash deposit formed by wind transportation from primary ash-fall deposits. Geomorphological, sedimentological, textural, glass and mineral content, bulk chemical composition, and radiocarbon dating prove the tephra derived from the 4.2 ka BP eruption of the Cerro Blanco Volcanic Complex in the southern Puna. This is the world's largest documented volcanic eruption in the past five thousand years, and it covered the archeological site surroundings with an approximately 1-meter-thick ash-fall layer. Throughout the stratigraphic sequence of the Abra del Toro rock shelter, we can hypothesize that there were three main occupational moments: two hunter-gatherer moments, separated by the record of the large volcanic eruption, and a latern agro-pottery period. The evidence of the catastrophic volcanic event in the Abra del Toro rock shelter makes it possible to predict future impact on the contemporaneous communities.

Continuously Operable Simulator and Forecasting the Deposition of Volcanic Ash from Prolonged Eruptions at Sakurajima Volcano, Japan

At Sakurajima volcano, frequent Vulcanian eruptions have been seen at the summit crater of Minamidake since 1955. In addition to this eruption style, the eruptive activities of Strombolian type and prolonged ash emission also occur frequently. We studied the design of a simulator of advection-diffusion-fallout of volcanic ash emitted continuously. The time function of volcanic ash eruption rate is given by a linear combination of the volcanic tremor amplitude and the volume change of the pressure source obtained from the ground motion. The simulation is repeated using discretized values of the eruption rate time function at an iteration time interval of the simulation. The integrated value of the volcanic ash deposition on the ground obtained from each individual simulation is used to estimate the value of the ash fallout. The plume height is given by an empirical equation proportional to a quarter of the power of the eruption rate. Since the wind velocity field near the volcano is complicated by the influence of the volcanic topography, the predicted values published by meteorological organizations are made in high resolution by Weather Research and Forecasting (WRF) for the simulation. We confirmed that an individual simulation can be completed within a few minutes of iteration interval time, using the PUFF model as the Lagrangian method and FALL3D-8.0 as the Eulerian method on a general-purpose PC. Except during rainfall, the radar reflectivity, the count of particles per particle size, and fall velocity obtained by the disdrometers can be used for the quasi-real time matching of the plume height calculated from the eruption rate and the ash fall deposition rate obtained from the simulation.

Pliocene-Pleistocene ash-fall tuff deposits in the intermountain Humahuaca and Casa Grande basins, northwestern Argentina: tracers in chronostratigraphic reconstructions and key to identify their volcanic sources

Ash-fall tuffs of the Pliocene-Pleistocene deposits of Humahuaca and Casa Grande intermountain basins, northwestern Argentina, have been differentiated into two groups based on new geochemical and geochronological data which correspond to the tuffs of the Pliocene-Lower Pleistocene alluvial fan deposits dominated by debris flow, deep sandy gravel braided, and shallow ephemeral lake deposits (Uquia and Mal Paso formations), and those recorded in Pleistocene alluvial fans sheet flood deposits. The two clusters of ages recognized: 4.3 to 2.6 Ma, and 2.2-pre 0.8 Ma, corresponding to these tuff groups, are in agreement with pulses of ignimbrite eruptions in the Altiplano Puna Volcanic Complex (APVC), and Southerm Puna calderas located west of the study region. The ash-fall tuffs of both groups are mainly vitreous to phenocryst-poor of rhyodacite-dacite composition with minor andesites to trachyandesites, characterized by 58-69% SiO2 contents, A/CNK 1-1.4, FeO/MgO (0.8-2.8), which plot in the calc-alkaline range. They can be differentiated based on its immobile trace elements ratios as indicated by a slight enrichment in LREE, higher arc affiliation and somewhat higher Sm/Yb ratios in the case of the younger group, although in both Sm/Yb ratios are indicative of sequestration of HREE in residual hornblende. The new geochemical and geochronological data of those ash fall tuffs point to these as chrono-stratigraphic tracers of the Humahuaca and Casa Grande intermountain basins stratigraphy, during the Pliocene-Pleistocene, also as the key to identify their volcanic sources.