Artificial Sea Ice Research Articles

Toward the Detection of Oil Spills in Newly Formed Sea Ice Using C-Band Multipolarization Radar

Oil spills in the Arctic are becoming more likely as shipping traffic increases in response to climate-related sea ice loss. To improve oil spill detection capability, we used a controlled mesocosm to analyze the multipolarized C-band backscatter response of oil in newly formed sea ice (NI). Artificial sea ice was grown in two cylindrical tubs at the Sea-ice Environmental Research Facility, University of Manitoba. The sea ice physical characteristics, including surface roughness, thickness, temperature, and salinity, were measured before and after oil injection below the ice sheet. Time-series C-band radar backscatter measurements detected the differences in the sea ice evolution and oil migration to the sea ice surface in the oil-contaminated tub, which was compared to uncontaminated ice in a control tub. Immediately prior to the presence of oil on the ice surface, the copolarized backscatter is increased by 13-dB local maximum, while the cross-polarized backscatter is decreased by 9-dB. Ice physical properties suggest that the local backscatter maximum and minimum, which occurred immediately before oil migrated onto the surface, were related to a combination of brine and oil upward migration. The findings of this work provide a baseline data interpretation for oil detection in the Arctic Ocean using current and future C-band multipolarization radar satellites.

Low Fe Availability for Photosynthesis of Sea-Ice Algae: Ex situ Incubation of the Ice Diatom Fragilariopsis cylindrus in Low-Fe Sea Ice Using an Ice Tank

Sea-ice algae play a crucial role in the ecology and biogeochemistry of sea-ice zones. They not only comprise the base of sea-ice ecosystems, but also seed populations of extensive ice-edge blooms during ice melt. Ice algae must rapidly acclimate to dynamic light environments, from the low light under sea ice to high light within open waters. Recently, iron (Fe) deficiency has been reported for diatoms in eastern Antarctic pack ice. Low Fe availability reduces photosynthetic plasticity, leading to reduced ice-algal primary production. We developed a low-Fe ice tank to manipulate Fe availability in sea ice. Over 20 days in the ice tank, the Antarctic ice diatomFragilariopsis cylindruswas incubated in artificial low-Fe sea ice ([total Fe] = 20 nM) in high light (HL) and low light (LL) conditions. Melted ice was also exposed to intense light to simulate light conditions typical for melting icein situ. When diatoms were frozen in, the maximum photochemical quantum efficiency of photosystem II (PSII),Fv/Fm, was suppressed by freezing stress. However, the diatoms maintained photosynthetic capability throughout the ice periods with a stableFv/Fmvalue and increased photoprotection through non-photochemical quenching (NPQ) via photoprotective xanthophyll cycling (XC) and increased photoprotective carotenoid levels compared to pre-freeze-up. Photoprotection was more pronounced in the HL treatment due to greater light stress. However, the functional absorption cross section of PSII, σPSII, inF. cylindrusconsistently increased after freezing, especially in the LL treatment (σPSII> 10 nm2PSII–1). Our study is the first to report such a large σPSIIin ice diatoms at low Fe conditions. When the melted sea ice was exposed to high light,Fv/Fmwas suppressed. NPQ and XC were slightly upregulated, but not to values normally observed when Fe is not limiting, which indicates reduced photosynthetic flexibility to adapt to environmental changes during ice melt under low Fe conditions. Although ice algae can optimize their photosynthesis to sea-ice environments, chronic Fe starvation led to less flexibility of photoacclimation, particularly in low light conditions. This may have detrimental consequences for ice algal production and trophic interactions in sea-ice ecosystems if the recent reduction in sea-ice extent continues.

Medium-scale experiment in consolidation of an artificial sea ice ridge in Van Mijenfjorden, Svalbard

This study characterizes a consolidation of undeformed level ice and ice ridges. Field investigations were performed in the Van Mijenfjorden, Svalbard for 66 days between February and May of 2017. The thickness and properties of the level ice that was used to make the ridge were measured, and thermistor-strings were installed in the ridge and the neighboring level ice. The ridge was visited four times for drilling and sampling. During our field experiment, the level ice (LI) grew from 50 to 99 cm, the consolidated layer (CL) grew up to 120 cm, and the ridge initial macroporosity was about 0.36. The experimental results provided enough information for accurate growth prediction and validation of ridge consolidation models.Two analytical resistive models and two-dimensional discretized numerical models are presented. All models need general met-ocean conditions and general ice physical properties. The ridge model includes the effect of the inhomogeneous top and bottom surfaces of the consolidated layer. The models were validated against the field measurements, and the further details of the analytical models were validated against the numerical model.The analytical resistive ridge model with convective atmospheric flux captures the relevant phenomena well and could be used for prediction of the consolidated layer thickness in probabilistic analysis of ice actions on structures. The model including the radiative terms predicted heat fluxes in level ice and ridge better than the convective model but required more input data. Vertical temperature profiles through the consolidated layer and further into respectively a void and an ice block may result in significantly different estimations of the consolidated layer thickness. The difference between fresh and saline ice growth is becoming significant only during the warming phase due to significant change of sea ice microporosity.

Tracer Measurements in Growing Sea Ice Support Convective Gravity Drainage Parameterizations

AbstractGravity drainage is the dominant process redistributing solutes in growing sea ice. Modeling gravity drainage is therefore necessary to predict physical and biogeochemical variables in sea ice. We evaluate seven gravity drainage parameterizations, spanning the range of approaches in the literature, using tracer measurements in a sea ice growth experiment. Artificial sea ice is grown to around 17 cm thickness in a new experimental facility, the Roland von Glasow air‐sea‐ice chamber. We use NaCl (present in the water initially) and rhodamine (injected into the water after 10 cm of sea ice growth) as independent tracers of brine dynamics. We measure vertical profiles of bulk salinity in situ, as well as bulk salinity and rhodamine in discrete samples taken at the end of the experiment. Convective parameterizations that diagnose gravity drainage using Rayleigh numbers outperform a simpler convective parameterization and diffusive parameterizations when compared to observations. This study is the first to numerically model solutes decoupled from salinity using convective gravity drainage parameterizations. Our results show that (1) convective, Rayleigh number‐based parameterizations are our most accurate and precise tool for predicting sea ice bulk salinity; and (2) these parameterizations can be generalized to brine dynamics parameterizations, and hence can predict the dynamics of any solute in growing sea ice.

Investigations into Frost Flower Physical Characteristics and the C-Band Scattering Response

A dedicated study on the physical characteristics and C-band scattering response of frost-flower-covered sea ice was performed in an artificial sea ice mesocosm over a 36-h period in January 2017. Meteorological conditions were observed and recorded automatically at the facility when the sea ice grew and frost flowers formed while the C-band scattering measurements were conducted continuously over a range of incidence angles. Surface roughness was characterized using a LiDAR. During the experiment, frost flowers did not initially form on the extremely smooth ice surface even though suitable meteorological conditions prevailed during their development (low air temperature, low near-surface wind speed, and high near-surface relative humidity). This provides evidence that both the presence of (i) liquid brine at the surface and (ii) raised nodules as nucleation points are required to enable frost flower initiation. As the ice thickened, we observed that raised nodules gradually appeared, frost flowers formed, and flowers subsequently spread to cover the surface over a six-hour period. In contrast to previous experiments, the frost flower layer did not become visibly saturated with liquid brine. The C-band scattering measurements exhibited increases as high as 14.8 dB (vertical polarization) in response to the frost flower formation with low incidence angles (i.e., 25°) showing the largest dynamic range. Co-polarization ratios responded to the physical and thermodynamic changes associated with the frost flower formation process. Our results indicate that brine expulsion at the sea ice surface and frost flower salination can have substantial temporal variability, which can be detected by scatterometer time-series measurements. This work contributes towards the operational satellite image interpretation for Arctic waters by improving our understanding of the highly variable C-band microwave scattering properties of young sea ice types.

Fractionation of hydrogen and oxygen in artificial sea ice with corrections for salinity for determining meteorological water content in bulk ice samples

Artificial seawater is commonly used to recreate arctic conditions in laboratory and mesocosm studies. Baseline oxygen (O) and hydrogen (H) apparent fractionation factor approaching equilibrium (αapp*) and apparent fractionation coefficient approaching equilibrium (εapp*) were determined between artificial seawater and sea ice in conditions representative of mesocosm studies. Laboratory-based values produced under ideal conditions are desired for comparison with natural observations to determine the contribution of meteorological precipitation to mesocosm studies, as opposed to ice formed from seawater. Equilibrium was approached through the use of a closed cold-laboratory freezing method, high mixing rates, and a salinity-correction equation. Apparent fractionation values approaching equilibrium were compared to published equilibrium fractionation values. Fractionation values observed at the Sea ice Environmental Research Facility (SERF) are also reported. We found the following laboratory αapp* and εapp* values, for the freezing of seawater to form sea ice: α18O=1.0025±0.0002; α2H=1.0212±0.0005; ε18O (‰)=2.5±0.2; ε2H (‰)=21.2±0.5.

Modeling high-frequency acoustic backscatter for remote sensing of oil under sea ice and oil encapsulated in sea ice

High-frequency acoustic systems provide one of the potentially practical means for remote sensing of oil-in-ice. Sea ice is a complex medium that reflects, refracts, and scatters sound waves in complicated manner. The presence of oil adds additional complexity. A set of high-frequency acoustic data were taken at the Cold Regions Research and Environmental Laboratory (Hannover, NH) where crude oil was injected underneath artificial sea ice. A physics-based model is developed to interpret the data. The model consists of four layers to respectively describe the homogeneous half-space of water, the heterogeneous oil layer under ice, a thin skeletal ice layer, and a thick layer for the body of ice. The skeletal layer is allowed to have very different properties from the body of ice. All the interfaces at the boundaries of the layers are assumed rough. The model predicts scattered sound intensity in the time domain. Model results are discussed when it is applied to the acoustics data taken at both normal and 20-degree oblique incidence angles. The utility and the applicability of the model to actual arctic environments are anticipated.

Under-ice eddy covariance flux measurements of heat, salt, momentum, and dissolved oxygen in an artificial sea ice pool

Turbulent exchanges under sea ice play a controlling role in ice mass balance, ice drift, biogeochemistry, and mixed layer modification. In this study, we examined the potential to measure under-ice turbulent exchanges of heat, salt, momentum, and dissolved oxygen using eddy covariance in an experimental sea ice facility. Over a 15-day period in January 2013, an underwater eddy covariance system was deployed in a large (500m3) in-ground concrete pool, which was filled with artificial seawater and exposed to the ambient (−5 to −30°C) atmosphere. Turbulent exchanges were measured continuously as ice grew from 5 to 25cm thick. Heat, momentum, and dissolved oxygen fluxes were all successfully derived. Quantification of salt fluxes was unsuccessful due to noise in the conductivity sensor, a problem which appears to be resolved in a subsequent version of the instrument. Heat fluxes during initial ice growth were directed upward at 10 to 25Wm−2. Dissolved oxygen fluxes were directed downward at rates of 5 to 50mmolm−2 d−1 throughout the experiment, at times exceeding the expected amount of oxygen rejected with the brine during ice growth. Bubble formation and dissolution was identified as one possible cause of the high fluxes. Momentum fluxes showed interesting correlations with ice growth and melt but were generally higher than expected. We concluded that with the exception of the conductivity sensor, the eddy covariance system worked well, and that useful information about turbulent exchanges under thin ice can be obtained from an experimental sea ice facility of this size.

Parameterization of Centimeter-Scale Sea Ice Surface Roughness Using Terrestrial LiDAR

Microwave scattering from sea ice is partially controlled by the ice surface roughness. In this paper, we propose a technique for calculating 2-D centimeter-scale surface roughness parameters, including the rms height, correlation length, and form of autocorrelation function, from 3-D terrestrial light detection and ranging data. We demonstrate that a single scale of roughness can be extracted from complex sea ice surfaces, incorporating multiple scales of topography, after sophisticated 2-D detrending, and calculate roughness parameters for a wide range of artificial and natural sea ice surface types. The 2-D technique is shown to be considerably more precise than standard 1-D profiling techniques and can therefore characterize surface roughness as a stationary single-scale process, which a 1-D technique typically cannot do. Sea ice surfaces are generally found to have strongly anisotropic correlation lengths, indicating that microwave scattering models for sea ice should include surface spectra that vary as a function of the azimuthal angle of incident radiation. However, our results demonstrate that there is no fundamental relationship between the rms height and correlation length for sea ice surfaces if the sampling area is above a threshold minimum size.

Physical and bacterial controls on inorganic nutrients and dissolved organic carbon during a sea ice growth and decay experiment

We investigated how physical incorporation, brine dynamics and bacterial activity regulate the distribution of inorganic nutrients and dissolved organic carbon (DOC) in artificial sea ice during a 19-day experiment that included periods of both ice growth and decay. The experiment was performed using two series of mesocosms: the first consisted of seawater and the second consisted of seawater enriched with humic-rich river water. We grew ice by freezing the water at an air temperature of −14°C for 14days after which ice decay was induced by increasing the air temperature to −1°C. Using the ice temperatures and bulk ice salinities, we derived the brine volume fractions, brine salinities and Rayleigh numbers. The temporal evolution of these physical parameters indicates that there was two main stages in the brine dynamics: bottom convection during ice growth, and brine stratification during ice decay. The major findings are: (1) the incorporation of dissolved compounds (nitrate, nitrite, ammonium, phosphate, silicate, and DOC) into the sea ice was not conservative (relative to salinity) during ice growth. Brine convection clearly influenced the incorporation of the dissolved compounds, since the non-conservative behavior of the dissolved compounds was particularly pronounced in the absence of brine convection. (2) Bacterial activity further regulated nutrient availability in the ice: ammonium and nitrite accumulated as a result of remineralization processes, although bacterial production was too low to induce major changes in DOC concentrations. (3) Different forms of DOC have different properties and hence incorporation efficiencies. In particular, the terrestrially-derived DOC from the river water was less efficiently incorporated into sea ice than the DOC in the seawater. Therefore the main factors regulating the distribution of the dissolved compounds within sea ice are clearly a complex interaction of brine dynamics, biological activity and in the case of dissolved organic matter, the physico-chemical properties of the dissolved constituents themselves.

Laboratory study on coprecipitation of phosphate with ikaite in sea ice

AbstractIkaite (CaCO3·6H2O) has recently been discovered in sea ice, providing first direct evidence of CaCO3 precipitation in sea ice. However, the impact of ikaite precipitation on phosphate (PO4) concentration has not been considered so far. Experiments were set up at pH from 8.5 to 10.0, salinities from 0 to 105, temperatures from −4°C to 0°C, and PO4 concentrations from 5 to 50 µmol kg−1 in artificial sea ice brine so as to understand how ikaite precipitation affects the PO4 concentration in sea ice under different conditions. Our results show that PO4 is coprecipitated with ikaite under all experimental conditions. The amount of PO4 removed by ikaite precipitation increases with increasing pH. Changes in salinity (S ≥ 35) as well as temperature have little impact on PO4 removal by ikaite precipitation. The initial PO4 concentration affects the PO4 coprecipitation. These findings may shed some light on the observed variability of PO4 concentration in sea ice.

Amplified Inception of European Little Ice Age by Sea Ice–Ocean–Atmosphere Feedbacks

Abstract The inception of the Little Ice Age (~1400–1700 AD) is believed to have been driven by an interplay of external forcing and climate system internal variability. While the hemispheric signal seems to have been dominated by solar irradiance and volcanic eruptions, the understanding of mechanisms shaping the climate on a continental scale is less robust. In an ensemble of transient model simulations and a new type of sensitivity experiments with artificial sea ice growth, the authors identify a sea ice–ocean–atmosphere feedback mechanism that amplifies the Little Ice Age cooling in the North Atlantic–European region and produces the temperature pattern suggested by paleoclimatic reconstructions. Initiated by increasing negative forcing, the Arctic sea ice substantially expands at the beginning of the Little Ice Age. The excess of sea ice is exported to the subpolar North Atlantic, where it melts, thereby weakening convection of the ocean. Consequently, northward ocean heat transport is reduced, reinforcing the expansion of the sea ice and the cooling of the Northern Hemisphere. In the Nordic Seas, sea surface height anomalies cause the oceanic recirculation to strengthen at the expense of the warm Barents Sea inflow, thereby further reinforcing sea ice growth. The absent ocean–atmosphere heat flux in the Barents Sea results in an amplified cooling over Northern Europe. The positive nature of this feedback mechanism enables sea ice to remain in an expanded state for decades up to a century, favoring sustained cold periods over Europe such as the Little Ice Age. Support for the feedback mechanism comes from recent proxy reconstructions around the Nordic Seas.

In-situ measurements of the low frequency dielectric permittivity of first-year Antarctic sea ice

Abstract Measurement of the low frequency dielectric permittivity of sea ice is an important step in developing microstructural models that will permit the calculation of other physical properties of sea ice. We report the adaptation of the technique of cross-borehole resistivity tomography to obtain in-situ measurements of the horizontal component of the permittivity of first year Antarctic sea ice. Results show features of the permittivity previously identified from measurements on laboratory grown artificial sea ice. Modeling of the measured permittivity curves allows estimates of physical parameters related to the conduction mechanisms in the ice to be made. Both e ∞ , the high frequency relative permittivity, and χ , the susceptibility of the Debye relaxation, appear to depend upon brine volume fraction, while the time constant of relaxation is consistent with values determined from previous studies. Empirical parameters representing the effect of space charge polarization show complicated relationships with temperature, salinity and brine volume fraction. There are also indications that differences in some of these parameters occur between columnar ice, observed to exist to a depth of about 1.1 m, and incorporated platelet ice below this depth.

Towards a method for high vertical resolution measurements of the partial pressure of CO2 within bulk sea ice

AbstractFluxes of atmospheric CO2 have been reported over sea ice during winter and spring. These fluxes are partly driven by the gradient of the CO2 concentration between sea ice and the atmosphere. We present a new non-destructive method to measure the pCO2 of bulk sea ice at its in situ temperature. This method is based on an equilibration procedure between sea ice and a standard gas of known CO2 concentration. The concentration is measured by gas chromatography with a precision of 5%. Tests were performed on artificial standard sea ice and confirmed the reproducibility of the technique in the range of precision of the gas chromatograph. To test the accuracy of this method, the first profiles of pCO2 measured in bulk sea ice are reported and compared with direct in situ measurements of brine pCO2 over depth-integrated intervals.

Thermal evolution of diffusive transport of atmospheric halocarbons through artificial sea–ice

Diffusion through brine channels in sea–ice is a potential pathway for trace gases produced under and within sea–ice to exchange with the overlying atmosphere. The effectiveness of this transport pathway is highly dependent on temperature and sea–ice thickness, both of which are changing in favour of increased gas diffusion through porous sea–ice. We conducted several experiments with artificial sea–ice in a cold chamber to assess the potential for dissolved gaseous halocarbons to percolate through brine channels within sea–ice to the overlying air. Physico-chemical properties of the hyper-saline brine, sea–ice and the under-lying seawater were measured to quantify the vertical transport of a comprehensive range of volatile organic iodinated compounds (VOICs), including CH3I, C2H5I, 2-C3H7I and 1-C3H7I, at air temperatures of −3 and −14 °C. We find that the vertical transport of VOICs through sea–ice provides a very small flux pathway for gas transport during periods of consolidated ice cover. The results suggest that VOIC gas transfer velocities from diffusion through the sea–ice alone are at least ∼60 times lower at −3 °C than gas exchange from leads and polynas during the winter (assuming a sea–ice fractional coverage of 0.1). Assuming 100% brine channel fractional connectivity and a diffusion coefficient (D) of 5 × 10−5 cm2 s−1 at −3 °C, the timescale of diffusion through 500 mm of first year sea–ice is ∼145 days. This has significant implications for in-situ VOIC losses within the brine from chlorination, hydrolysis and photolysis processes and it is unlikely that measurable concentrations of VOICs would survive vertical transport from the under-lying seawater to the surface sea–ice quasi-liquid layer.

Calcium carbonate as ikaite crystals in Antarctic sea ice

We report on the discovery of the mineral ikaite (CaCO3·6H2O) in sea‐ice from the Southern Ocean. The precipitation of CaCO3 during the freezing of seawater has previously been predicted from thermodynamic modelling, indirect measurements, and has been documented in artificial sea ice during laboratory experiments but has not been reported for natural sea‐ice. It is assumed that CaCO3 formation in sea ice may be important for a sea ice‐driven carbon pump in ice‐covered oceanic waters. Without direct evidence of CaCO3 precipitation in sea ice, its role in this and other processes has remained speculative. The discovery of CaCO3·6H2O crystals in natural sea ice provides the necessary evidence for the evaluation of previous assumptions and lays the foundation for further studies to help elucidate the role of ikaite in the carbon cycle of the seasonally sea ice‐covered regions

Ice And The Origin Of Life

Sea ice occurs abundantly at the polar caps of the Earth and, probably, of many other planets. Its static and dynamic properties that may be important for prebiotic and early biotic reactions are described. It concentrates substrates and has many features that are important for catalytical actions. We propose that it provided optimal conditions for the early replication of nucleic acids and the RNA world. We repeated a famous prebiotic experiment, the poly-uridylic acid-instructed synthesis of polyadenylic acid from adenylic acid imidazolides in artificial sea ice, simulating the dynamic variability of real sea ice by cyclic temperature variation. Poly(A) was obtained in high yield and reached nucleotide chain lengths up to 400 containing predominantly 3'--> 5' linkages.

A mesocosm study of physical-biological interactions in artificial sea ice: effects of brine channel surface evolution and brine movement on algal biomass

The impact of changing physico-chemical boundary conditions in sea ice on biological processes was investigated during a 20-day-long simulated freeze-melt cycle in an 180-m3 mesocosm filled with artificial seawater and addition of a mixed Arctic sea-ice community. Ice formation started at Tair of –15°C with a growth rate of 0.7–1.2 mm h–1 for 10 days. The last 10 days (Tair of=–5°C), ice thickness remained around 20 cm. Ice temperature gradients inside the ice were linear and determined brine salinities. Brine was collected by means of centrifugation and its volume ranged from 5 to 30% of total ice volume. Surface areas of interconnected brine channels were determined with two similar techniques and maximum values ranged between 1.5 and 4.8 m2 kg–1ice. Measurements determined with a modified method varied considerably and differed by a maximal factor of 2.0–6.5. Brine channel surfaces increased during the experiment as a result of the warming of the ice. The inoculated algal community was dominated by flagellates <10 µm. The low diatom biomass increased in the ice after the air temperature rise with rates comparable to field data (µ=0.2–0.3 day–1). Comparison with brine salinities points towards the hypothesis of vertical brine stability being a controlling factor for ice algal growth. We infer from brine channel surface measurements that persistence of brine channel surfaces during spring might be an important prerequisite for the commencement of net diatom biomass accumulation. Advantages and limitations of mesoscale mesocosms as alternatives in ice biological work are discussed.

The bearing capacity of saline ice sheets: centrifugal modelling

Artificial sea ice sheets have been frozen in a centrifuge using novel techniques which yield reproducible ice growth rates and result in ice sheets of uniform thickness. The upper surface of these ice sheets has been subjected to an increasing load applied over a limited area, the maximum sustained load giving the bearing capacity at high inertial acceleration. Such centrifugal modelling techniques produce ice sheets with bearing capacities in agreement with existing field and laboratory data. In particular, the influence of indentor diameter and loading rate is examined and the centrifuge data are found to behave in the same manner as existing data with respect to both of these variables. All data are compared with a number of theoretical descriptions of bearing capacity, and these comparisons are discussed with regard to their impact on the applicability of the centrifuge modelling technique on ice penetration problems.Key words: centrifugal modelling, sea ice, bearing capacity.

Sea‐salt aerosol in coastal Antarctic regions

Continuous year round records of atmospheric sea‐salt concentrations have been recovered at three coastal Antarctic stations (Halley, Dumont D'Urville, and Neumayer) at temporal resolutions typically between 1 day and 2 weeks. The records were evaluated in terms of their spatial and seasonal variability as well as with respect to changes in the relative ion composition of airborn sea‐salt particles. Annual mean sea‐salt concentrations vary between 1400 ng m−3 at Dumont D'Urville, 850 ng m−3 at Neumayer, and 200 ng m−3 at Halley, respectively. They are thus considerably lower than the mean levels previously observed at the north tip of the Antarctic Peninsula but are, at their lower end, comparable to the level previously reported from Mawson. The representativeness of the atmospheric sea‐salt data appears to be weak due to their high temporal variability, strong impacts of site specific aspects (such as site topography) but also due to the nonuniform sampling techniques applied so far. In accordance with the ice core evidence, the seasonal change in the atmospheric sea‐salt load is found to be clearly out of phase with the seasonal cycle of the open water fraction offshore from the station as (with the exception of Dumont D'Urville) the lowest concentrations are generally observed during the local summer months. Major ion analyses of bulk aerosol and concurrently sampled fresh snow show a strong, systematic depletion of the SO42− to Na+ (Cl−) ratios with respect to bulk sea water, which appeared to be confined to the local winter half year. During that time, sea‐salt SO42− was found to be depleted typically by 60–80% along with a concurrent Na+ deficit, which is in accordance with the precipitation of mirabilite. No significant fractionation of Mg2+, K+, and Ca2+ between seawater and sea‐salt particles is observed. Laboratory experiments failed to simulate the SO42− fractionation in airborne seawater droplets or in the skin of seawater bubbles at low air temperatures. They gave, however, SO42− depletion factors, similar to the field observation in air and snow, in the remaining brine of seawater which was partly frozen below −8°C to an artificial sea ice surface. It is suggested therefore that the mobilization of brine from the sea ice surface constitutes an important sea‐salt source in winter which may dominate the atmospheric sea‐salt load at high latitudes of coastal Antarctica.