Arrangement Of Sheets Research Articles

Synthesis and properties of flexible supercapacitor based on zinc-aluminum layered doubled hydroxide

A flexible, effective supercapacitor using zinc-aluminum-layered double hydroxides (Zn-Al LDHs) as an electrode material is reported. Nanosheets of Zn-Al LDHs were synthesized using a chemical bath deposition method, and they were present in a well-standing shape covering the complete area of the Al foil. The imaging of these nanosheets showed that their average thickness is between 60 and 80 nm, with a width and length average of 1.3 and 0.6 μm, respectively. These dimensions help to create the connection arrangements of sheets with a high specific surface area of 88 m2/g which increased electrochemical active sites for charge storage. The X-ray diffraction further approves the structural properties of the prepared material. The flexibility of the supercapacitor was examined by bending and folding up the device to 180° with little mechanical deformation. The highest capacitance value is found to be ∼597F/g in the case of the flat condition. The capacitance value decreased to ∼387F/g after folding the device 30°, and these values drooped slightly after more increasing the folding angle. The energy density (ED) remains nearly constant at any folding angle (ED=3.39Wh/kg at 30° and ED=3.7Wh/kg at 135°), and similarly, the power density (PD) remains nearly constant (PD=27 kW/kg at 30° and 135°). The aforementioned approves the flexibility of the Zn-Al LHD because it provides lifelong stability (87 % retaining after 2000 charge/discharge cycles) and stable efficiency after different bending and twisting conditions. The impedance measurements along with the obtained equivalent circuits confirm the electrical characteristics of the as-prepared electrodes with low equivalent series resistances, ensuing the promising conductive path in the supercapacitor device.

Ice-marginal volcanic sequence in Iceland found on a nondescript gradual hillslope: An unexpected record of ice thickness late in deglaciation

Volcanism increases when glaciers melt because isostatic rebound during deglaciation decreases the pressure on the mantle, which enhances decompression melting. Anthropogenic climate change is now causing ice sheets and valley glaciers to melt around the world and this deglaciation could stimulate volcanic activity and associated hazards in Iceland, Antarctica, Alaska, and Patagonia. However, current model predictions for volcanic activity associated with anthropogenic deglaciation in Iceland are poorly constrained, in part due to uncertainties in past volcanic output over time compared to ice sheet arrangements. Further work specifically characterizing glaciovolcanic and ice-marginal volcanoes in Iceland is needed to reconstruct volcanic output during time periods with changing ice cover. Here, we describe a previously unrecognized ice-marginal volcanic sequence on a broad, gradual hillslope southeast of Langjökull and the Jarlhettur volcanic chain in Iceland's Western Volcanic Zone. Although previously mapped as interglacial lavas, canyons in this area revealed two southwest-dipping sequences of pillow-bearing tuff-breccias between pāhoehoe lava flows above modern lake Sandvatn. These pillow-bearing tuff-breccias and the quenched meter-scale cavities in coherent lava and cube-jointed facies show lavas came into contact with ice and pockets of trapped meltwater. However, clasts within the tuff-breccias include a mixture of pillow lavas and pāhoehoe fragments, requiring that the subaqueous tuff-breccia facies were derived from subaerial flows. In addition, we observed interfingering of subaerial and transitional subaqueous-subaerial pāhoehoe lava flows with the pillow-bearing tuff-breccias. We propose that during a deglaciation, subaerial lavas sourced upslope from near Skálpanes flowed downslope to the south and came into contact with thin ice north of the modern lake Sandvatn. We constrain the local ice at this time to be ∼30–50 m thick. Importantly, this finding demonstrates that ice-marginal deposits that can provide paleo-environmental constraints may be hidden in terrains without morphologically distinct glaciovolcanic edifices.

Assembled Structures and Electrical Conductivities of Salts Comprised of Cationic Sandwich Complexes and Polyoxometalates.

Polyoxometalates (POMs) are recognized for their diverse structures and catalytic properties, yet their organometallic salts have not been thoroughly investigated. In this study, we synthesized salts of a Keggin-type POM with cationic sandwich complexes featuring various substituents, [X]2[SMo12O40] [X = Ru(C5H5)(C6H5R); R = H (1a), Me (1b), Bu (1c)], [Co(C5H5)2 (2), and Co(C5Me5)2 (3)]. These salts exhibited similar structural characteristics, with each anion surrounded by 10 cations, forming two-dimensional sheet arrangements through O···O anion-anion contacts, except for the salt of 1c, which exhibited one-dimensional contact owing to the larger cation substituent. Additionally, [2](THA)[Mo6O19], [3]2[Mo6O19], and [3](THA)[SMo12O40], containing the Lindqvist-type POM [Mo6O19] and/or tetrahexylammonium (THA) cation, were obtained, with the packing structure of [3]2[Mo6O19] closely resembling that of [X]2[SMo12O40]. Solvate crystals of [1a]3[PMo12O40] were also prepared. [1a]2[SMo12O40] exhibits an electrical conductivity σ of 1.4 × 10-7 S cm-1 at 373 K, which is 2 orders of magnitude higher than those of (THA)2[SMo12O40] and [1a]PF6.

Punching and lateral cyclic behavior of concrete slab-column connections reinforced with steel sheets

During an earthquake, slab-column structures with high gravity-shear ratios often experience increased local shear stress and deformation in the connection area, leading to reduced unbalanced moment capacity and drift capacity of the connections. This study aims to create a new and more efficient method of enhancing the unbalanced moment capacity and deformation capacity of reinforced concrete slab-column structures through using steel sheets as punching reinforcement. Tests were conducted to evaluate the effects of the thickness, extension length, and layout of this new type of punching reinforcement on the unbalanced moment capacity and deformation capacity of the connections when subjected to vertical and horizontal cyclic loads. The results indicated that as the steel sheet thickness increased, the unbalanced moment capacity of SC-2 and SC-3 rose by 24 % and 48 % respectively, while the drift capacity improved by 20 % and 40 % compared to SC-1. Furthermore, the failure mode shifted from stress-induced punching to drift-induced punching. Compared to SC-1, a cruciform layout with an additional diagonal arrangement of sheets increased the unbalanced moment capacity and drift capacity by approximately 17 % and 20 %, respectively. The extension length of the sheets reduced from 600 to 420 had negligible effect on the unbalanced moment capacity and deformation capacity. Utilizing experimental data, this study compared the relationship between the drift capacity and gravity shear ratio of connections reinforced with different shear reinforcements. The underlying causes for the observed lower drift capacity of the specimens are analyzed, and design recommendations for optimizing the steel sheets are subsequently proffered. After thoroughly analyzing the experimental results, a simplified calculation methodology for assessing the shear strength of steel sheets was developed, taking inspiration from the shear strength calculation approach outlined in ACI 318–19. The efficacy of this simplified approach was subsequently validated by comparing the experimental results with those predicted by current design codes. Furthermore, by comparing the experimental results with the predicted values, the relationship between the punching failure mode of connections and their punching strength was discussed.

Harnessing true capacitive activity of nitrogen-doped MXene through hydrogel assembly and theoretical understanding of the role of dopant sites

Heteroatom nitrogen (N) doping in MXene can significantly push its energy storage metric. However, translating the intrinsic improvement of individual sheets into macroscopic electrodes is challenging due to the blockage of dopant sites by restacking. Here, we report the development of restack-controlled N-doped MXene hydrogel through speedy interfacial assembly methods to keep the dopant sites electrochemically accessible. Application of a small voltage between two zinc plates in an aqueous dispersion of N-doped MXene leads to the rapid development of doped hydrogel over the positive zinc plate via electrophoretic drag and linking by interfacial released zinc ions. As-developed hydrogels having continuous porosity and quasi-oriented sheet arrangement preserve ion transporting channels, thus allowing the surface dopant sites to participate in the supercapacitive energy storage actively. N-doped hydrogel displays a high capacitance of 488 F g−1 at 5 mV s−1 much higher as compared to compact film. The N-doped MXene hydrogels display excellent rate performance with retention over 88 % at 1000 mV s−1 and cyclic stability of 87 % over 10000 cycles. The detailed density functional theory (DFT) calculation reveals a major pseudocapacitive contribution from the surface adsorption and functional group substitution type N dopant sites as compared to another dopant site, namely, lattice substitution.

Comparative Retention Analysis of Intercalated Cations Inside the Interlayer Gallery of Lamellar and Nonlamellar Graphene Oxide Membranes in Reverse Osmosis Process: A Molecular Dynamics Study.

Over the past decade, multilayered graphene oxide (GO) membranes have emerged as promising candidates for desalination applications. Despite their potential, a comprehensive understanding of separation mechanisms remains elusive due to the intricate morphology and structural arrangement of interlayer galleries. Moreover, a critical concern of multilayered GO membranes is their susceptibility to swelling within aqueous environments, which hinders their practical implementation. Therefore, this study introduces cation intercalation within GO laminates to elucidate the underlying factors governing swelling behavior and subsequently mitigate it. Moreover, this study performed nonequilibrium molecular dynamics simulations on the cation (Mg2+ or K+)-intercalated lamellar and nonlamellar GO membranes to understand the effect of the arrangement of GO sheets on the retention time of intercalated cations within GO layers, water permeance, and salt rejection mechanism in the reverse osmosis process using cation-intercalated GO membranes. Our results highlight that lamellar GO membranes exhibit higher water permeance, attributed to their well-defined interlayer gallery structure. On the other hand, nonlamellar GO membranes display superior salt rejection due to their complex interlayer gallery structure that impedes salt permeation. Moreover, the structural complexity of nonlamellar GO membranes contributes to greater stability by retention of the more intercalated cations for a longer time within the layers. Furthermore, it is observed that a higher percentage of Mg2+ cations remained inside the GO laminates as compared to K+ cations, hence resulting in the greater stability of the Mg2+-intercalated GO membrane in the aqueous environment.

Nucleate boiling enhancement on hybrid graphene-nanoplatelets/carbon nanotubes coatings for light-emitting diode cooling

This study explores the remarkable enhancement of light-emitting diode (LED) cooling through nucleate boiling using hybrid coatings of graphene-nanoplatelets (GNP) and carbon nanotubes (CNT). The introduction of oxygenated functional groups in the cured GNP and CNT coatings fosters improved hydrophilicity, promoting water intercalation within the nanostructures. The hybrid cured GNP/CNT coating demonstrates superior nucleate boiling performance compared to individual cured GNP and CNT coatings, owing to complementary mechanisms. Cured CNT facilitate efficient water permeation by enabling water molecules to infiltrate through their inner cores and intertwining tube spaces, while cured GNP offer an escape route for trapped water molecules and absorbed latent heat due to their layer-by-layer arrangement of graphene sheets with broadened interlayers. As compared to the bare copper surface, the LED cooled using the hybrid cured GNP/CNT coating exhibits a maximum temperature drop of 20.7 °C and an enhancement up to 1212 % in heat transfer coefficient, surpassing the cured GNP and CNT coatings. Moreover, the hybrid cured GNP/CNT coating improves the LED illuminance by 16.6 %, validating its potency in improving cooling performance. These findings highlight the potential of GNP/CNT hybrid coatings in advancing nucleate boiling cooling technologies and offer valuable insights into optimizing LED performance for high-quality lighting solutions.

Bidirectionally promoting assembly order for ultrastiff and highly thermally conductive graphene fibres

Macroscopic fibres assembled from two-dimensional (2D) nanosheets are new and impressing type of fibre materials besides those from one-dimensional (1D) polymers, such as graphene fibres. However, the preparation and property-enhancing technologies of these fibres follow those from 1D polymers by improving the orientation along the fibre axis, leading to non-optimized microstructures and low integrated performances. Here, we show a concept of bidirectionally promoting the assembly order, making graphene fibres achieve synergistically improved mechanical and thermal properties. Concentric arrangement of graphene oxide sheets in the cross-section and alignment along fibre axis are realized by multiple shear-flow fields, which bidirectionally promotes the sheet-order of graphene sheets in solid fibres, generates densified and crystalline graphitic structures, and produces graphene fibres with ultrahigh modulus (901 GPa) and thermal conductivity (1660 W m−1 K−1). We believe that the concept would enhance both scientific and technological cognition of the assembly process of 2D nanosheets.

Electrochemically enhanced battery-type Ni substituted CaMo-MOF electrodes: Towards futuristic energy storage system

Constructing a physiochemically proficient electrode for energy application is of pioneer in commercializing electronic devices. In that view, we engineered the nickel-incorporated calcium molybdate (NCMF) metal-organic framework (MOFs) with nanosheets in 3D floral morphology using the facile hydrothermal method. The floral structured NCMF0.5 MOFs when employed as the electrode in supercapacitor (SC) application exhibit impressive electrocatalytic performance. The advantage of a well-defined arrangement of petal-like sheets hierarchically, makes the KOH electrolyte access the inner area of the electrode resulting in a distinguished specific capacitance value of 822 F/g at 1 A/g current density. The fabricated NCMF0.5||AC asymmetric supercapacitor device (ASC) on account of the high specific surface area with more metal active sites contributes to achieving excellent energy and power density of 45 Wh/kg and 750 W/kg at the current density of 1 A/g. The stability and reproducibility of the constructed ASC device were 84 % and 99.4 %, respectively. Hereby, our findings clearly elucidate the substantial prospects attained by the synergistic effect in NCMF0.5 MOFs, which could be beneficial for developing sophisticated energy storage devices.

Structural Characterization of Boron Sheets beyond the Monolayer and Implication for Experimental Synthesis and Identification.

The successful synthesis of quasi-freestanding bilayer borophene has aroused much attention for its superior physical properties and holds great promise for future electronic devices. Herein, we comprehensively explore six boron sheets beyond the monolayer and structurally characterize them via various methods using first-principles calculations for experimental references. On the basis of atomic models of borophenes, simulated scanning tunneling microscope (STM) images show different morphologies at different bias voltages and are explained by the partial densities of states and the height differences in the vertical direction. Simulated transmission electron microscope images further probe the internal atomic arrangement of boron sheets and compensate for the shortcomings of STM images to better distinguish different phases of boron sheets. The interlayer coupling strength is stronger in bilayer borophenes than in the three-layer system via the electron localization function and Mulliken bond population. In addition, simulated X-ray diffraction and infrared spectra show different characteristic peaks and corresponding vibrational modes to further characterize these boron sheets. These theoretical results can decrease the prime cost and provide vital guidance for the experimental synthesis and identification of boron sheets beyond the monolayer.

The effects of formation and functionalization of graphene-based membranes on their gas and water vapor permeation properties

The gas and water vapor permeabilities of graphene-based membranes can be affected by the presence of different functional groups directly bound to the graphene network. In this work, one type of carboxylated graphene oxide (GO-COOH) and two types of graphene oxide synthesized i) under strong oxidative conditions directly from graphite (GO-1) and ii) under mild oxidative conditions from exfoliated graphene (GO-2) were used as precursors of self-standing membranes prepared with thicknesses in the range of 12–55 μm via slow-vacuum filtration preparation method. It was observed that the permeabilities for all tested gases decreased in order GO-2 > GO-1 > GO-COOH and depended on both the arrangement of graphene sheets and their functionalization. The GO-1 membrane with a high content of oxygen-containing groups showed the best performance for water vapor permeability. The GO-2 membrane with a thickness of 43 μm exhibited a disordered GO sheet morphology and, therefore, unique gas-separation performance towards H2/CO2 gas pair, showing high hydrogen permeability while keeping extremely high H2/CO2 ideal selectivity that exceeds the Robeson 2008 upper bound of polymer membranes.

Analysis of the Vibration Characteristics and Vibration Reduction Methods of Iron Core Reactor

Series iron core reactors are one of the most commonly used electrical equipments in power systems, which can limit short-circuit currents and suppress harmonic waves from capacitor banks. However, the vibration of the reactor will not only generate noise pollution but also diminish the service life of the reactor and jeopardize power system safety. In order to reduce the vibration noise in the core disc region of the reactor, the vibration characteristics of a core reactor are calculated by modifying the anisotropy parameters of the Young’s modulus of the core disc lamellar structure and introducing the core magnetostriction effect based on the simulation analysis method of electromagnetic and mechanical coupling. A detachable single-phase series core reactor model is established, and the validity of the simulation calculation is measured and verified. At the same time, from the perspective of improving the air gap size of the series core reactor and the arrangement of electrical steel sheets, the corresponding iron core vibration reduction scheme is given. The average vibration reduction in the reactor is about 11.6% after comprehensive improvement according to the vibration reduction scheme, which provides an effective method for realizing the vibration and noise reduction in the reactor.

A Novel Elastic Sensor Sheet for Pressure Injury Monitoring: Design, Integration, and Performance Analysis

This study presents the SENSOMATT sensor sheet, a novel, non-invasive pressure monitoring technology intended for placement beneath a mattress. The development and design process of the sheet, which includes a novel sensor arrangement, material selection, and incorporation of an elastic rubber sheet, is investigated in depth. Highlighted features include the ability to adjust to varied mattress sizes and the incorporation of AI technology for pressure mapping. A comparison with conventional piezoelectric contact sensor sheets demonstrates the better accuracy of the SENSOMATT sensor for monitoring pressures beneath a mattress. The report highlights the sensor network’s cost-effectiveness, durability, and enhanced data measurement, alongside the problems experienced in its design. Evaluations of performance under diverse settings contribute to a full understanding of its potential pressure injury prediction and patient care applications. Proposed future paths for the SENSOMATT sensor sheet include clinical validation, more cost and performance improvement, wireless connection possibilities, and improved long-term monitoring data analysis. The study concludes that the SENSOMATT sensor sheet has the potential to transform pressure injury prevention techniques in healthcare.

Minerals with a palmierite-type structure. Part II. Nomenclature and classification of the palmierite supergroup.

AbstractThe palmierite supergroup, approved by the IMA-CNMNC, includes five mineral species characterised by the general crystal-chemical formula XIIM1XM22(IVTO4)2 (Z = 3). On the basis of the crystal-chemical arguments and heterovalent isomorphic substitution scheme M++T6+ ↔ M2++T5+, the palmierite supergroup can be formally divided into two groups: the palmierite group M12+M22+(T6+O4)2, and the tuite group M12+M222+(T5+O4)2. Currently, the palmierite group includes palmierite K2Pb(SO4)2, and kalistrontite K2Sr(SO4)2, whereas the tuite group combines tuite Ca3(PO4)2, mazorite Ba3(PO4)2, and gurimite Ba3(VO4)2. The isostructural supergroup members crystallise in space group R$\bar{3}$m (no. 166). The palmierite-type crystal structure is characterised by a sheet arrangement composed of layers formed by M1O12 and M2O10 polyhedra separated by TO4 tetrahedra perpendicular to the c axis. The abundance of distinct ions, which may be hosted at the M and T sites (M = K, Na, Ca, Sr, Ba, Sr, Pb, Rb, Zn, Tl, Cs, Bi, NH4 and REE; T = Si, P, V, As, S, Se, Mo, Cr and W) implies many possible combinations, resulting in potentially new mineral species. Minerals belonging to the palmierite supergroup are relatively rare and usually form under specific conditions, and their synthetic counterparts play a significant role in various industrial applications.

Practical Investigation on the Strengthening of the Built-Up Steel Main Girder of a Metro Station with Carbon-Fiber-Reinforced Polymer on the Inside Part of the Tensioned Flange

This study investigates the effectiveness of a carbon-fiber-reinforced polymer (CFRP) in enhancing the load-carrying capacity of a steel main girder in a metro station. The objective is to evaluate the applicability of CFRPs in sustaining increases in applied loads and assessing their effectiveness on curved surfaces. Finite element analysis (FEA) identified the most stressed areas of the girder under design loads. Based on the FEA results, a targeted strengthening procedure using CFRP sheets was proposed. Various arrangements of CFRP sheets were tested, including different orientations and thicknesses up to 60% of the girder’s flange thickness. To validate the FEA accuracy, two small-scale specimen beams were prepared and tested in the laboratory. One beam was strengthened with CFRP sheets on the tension part of the inner flange side, similar to the suggested strengthening method for the girder. The FEA results show that the CFRP increases stresses by an average of 8% to 10% for the steel main girder, with strengthening effects up to 19% at the center of the CFRP strengthening positions, differing from a regular straight flange shape. Significantly reducing stresses required a total CFRP layer thickness of at least 50% of the flange’s total thickness. Applying a CFRP on the inner face of the girder preserves its usability without the need for openings in finishes or the metal deck surface. The findings highlight CFRP’s potential to enhance load-carrying capacity on curved surfaces and sustain increased applied loads, offering a promising solution for strengthening infrastructure and similar applications.

Scalable Production of Catecholamine-Densified MXene Coatings for Electromagnetic Shielding and Infrared Stealth.

Processing transition metal carbides/nitrides (MXenes) inks into large-area functional coatings expects promising potential for electromagnetic interference (EMI) shielding and infrared stealth. However, the coating performances, especially for scalable fabrication techniques, are greatly constrained by the flake size and stacking manner of MXene. Herein, the large-area production of highly densified and oriented MXene coatings is demonstrated by engineering interfacial interactions of small MXene flakes with catecholamine molecules. The catecholamine molecules can micro-crosslink MXene nanosheets, significantly improving the ink's rheological properties. It favors the shear-induced sheet arrangement and inhibition of structural defects in the blade coating process, making it possible to achieve high orientation and densification of MXene assembly by either large-area coating or patterned printing. Interestingly, the MXene/catecholamine coating exhibits high conductivity of up to 12 247 S cm-1 and ultrahigh specific EMI shielding effectiveness of 2.0 ×10 5 dB cm2 g-1 , obviouslysuperior to most of the reported MXene materials. Furthermore, the regularly assembled structure also endows the MXene coatings with low infrared emissivities for infrared stealth applications. Therefore, MXene/catecholamine coatings with ultraefficient EMI shielding and low infrared emissivity prove the feasibility of applications in aerospace, military, and wearable devices.

Progress in the Graphene Oxide-Based Composite Coatings for Anticorrosion of Metal Materials

Graphene oxide (GO), derived from the two-dimensional nanosheet graphene, has received unprecedented attention in the field of metal corrosion protection owing to its excellent barrier performance and various active functional groups. In this review, the protection mechanism “labyrinth effect” of composite coatings against metal corrosion was demonstrated systematically. The origination, structure and properties of GO were also analyzed. Their poor dispersion in polymer and tendency to aggregate as nanofillers in composite coatings are the main limitations during application of the coating fillers. In addition, a comprehensive overview on the perspectives of the surface modification of GO and the multi-functionalization of the composite coatings based on GO were given in particular. Green modification methods, reasonable arrangement of GO sheets in composites and development of multi-functional coatings remain challenges in current studies and should be a focus in the future development of GO-based anticorrosive coatings. This review is of value to researchers interested in the design and application of GO in corrosion protection coatings.

Synthesis, crystal structure and Hirshfeld surface analysis of the hybrid salt bis-(2-methyl-imidazo[1,5-a]pyridin-2-ium) tetra-chlorido-manganate(II).

The 0-D hybrid salt bis-(2-methyl-imidazo[1,5-a]pyridin-2-ium) tetra-chlorido-manganate(II), (C8H9N2)2[MnCl4] or [L]2[MnCl4], consists of discrete L + cations and tetra-chlorido-manganate(II) anions. The fused heterocyclic rings in the two crystallographically non-equivalent monovalent organic cations are almost coplanar; the bond lengths are as expected. The tetra-hedral MnCl4 2- dianion is slightly distorted with the Mn-Cl bond lengths varying from 2.3577 (7) to 2.3777 (7) Å and the Cl-Mn-Cl angles falling in the range 105.81 (3)-115.23 (3)°. In the crystal, the compound demonstrates a pseudo-layered arrangement of separate organic and inorganic sheets alternating parallel to the bc plane. In the organic layer, pairs of centrosymmetrically related trans-oriented L + cations are π-stacked. Neighboring MnCl4 2- dianions in the inorganic sheet show no connectivity, with the minimal Mn⋯Mn distance exceeding 7 Å. The Hirshfeld surface analysis revealed the prevalence of the non-conventional C-H⋯Cl-Mn hydrogen bonding in the crystal packing.

Vertical-MXene based micro-supercapacitors with thickness-independent capacitance.

MXenes have shown great potential as an emerging two-dimensional (2D) material for micro-supercapacitors (MSCs) due to their high conductivity, rich surface chemistry, and high capacity. However, MXene sheets inherently tend to lay flat on the substrate during film formation to assemble into compact stacked structures, which hinders ion accessibility and prolongs ion transport paths, leading to highly dependent electrochemical properties on the thickness of the film. Here, we demonstrate a vertically aligned Ti3C2Tx MXene based micro-supercapacitor with an excellent electrochemical performance by a liquid nitrogen-assisted freeze-drying method. The vertical arrangement of the 2D MXene sheets allows for directional ion transport, enabling the vertical-MXene based MSCs to exhibit thickness-independent electrochemical properties even in thick films. In addition, the MSCs displayed a high areal capacitance of 87 mF cm-2 at 10 mV s-1 along with an excellent stability of ∼87.4% after 10 000 charge-discharge cycles. Furthermore, the vertical-MXene approach proposed here is scalable and can be extended to other systems involving directional transport.

High Gain Passive UHF RFID Reader Antenna Using Novel FSS for Longer Read Range

Frequency Selective Surface (FSS) is widely used to enhance the gain of antenna & reduces Electromagnetic Interference (EMI). In this work, a novel Frequency Selective Surface (FSS) is designed, analyzed, and fabricated along with passive Radio Frequency Identification (RFID) reader antenna operating at global Ultra-High Frequency (UHF) for wireless RFID applications. The antenna & FSS sheet is fabricated on less costly FR4 substrate with resonant bandwidth of 860–960 MHz. The Fabry–Perot arrangement of FSS sheet with antenna increases the gain & directivity without modifying the antenna profile or increasing radiation patch size. The maximum measured gain is 9.8 dB & 7.2 dB with the Reflection coefficient (S11) of −35 dB & −15 dB at 910 MHz & 950 MHz respectively. The proposed antenna of dimension 40 mm by 40 mm is fabricated & tested for further experimental validation with measured read range longer than 8 m. The novelty in proposed work is integration of FSS with passive UHF RFID technology which can be effectively used in wireless RFID applications for improved read range, higher gain, lower power consumption & better immunity within the resonating band. The proposed antenna effectively isolates out-of-band frequencies from in-band frequencies over a required bandwidth reducing Electromagnetic Interference (EMI) for UHF RFID applications.