To investigate the ignition behavior of Mg-Na-Al alloy under impact load and its mechanical properties under different strain rates, the universal testing machine and Separated Hopkinson Pressure Bar (SHPB) experimental system were used to conduct static and dynamic mechanical performance tests of Mg-Na-Al alloy, and the mechanical properties of Mg-Na-Al alloy under different strain rates were discussed. The light gas gun experimental setup was used to launch Mg-Na-Al alloy projectiles and impact rigid target plates to study the energy release behavior of Mg-Na-Al alloy under impact loads. Finally, based on the 12.7 mm ballistic gun experimental platform, the penetration of 12.7 mm armor-piercing projectiles equipped with Mg-Na-Al alloy wind caps into the homogeneous armor steel plates with a thickness of 15 mm, and the ignition test of the oil box behind the steel plates were conducted. The results indicate that the yield strength of Mg-Na-Al alloy under static compression is 265 MPa, while under high strain rates (from 2490 s−1 to 5640 s−1), the yield strength of Mg-Na-Al alloy is 406–423 MPa, which is 53∼60% higher than that under quasi-static compression. When reaching a certain impact velocity, the Mg-Na-Al alloy projectile breaks and induces ignition behavior, releasing energy. The 12.7 mm armor-piercing projectile equipped with an Mg-Na-Al alloy wind cap penetrated the homogeneous armor steel plate with a thickness of 15 mm and ignited. The released energy and the kinetic energy of the fragments ignited the oil box behind the steel plate.
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