In the following study, we examine the performance of a new design of the classic gliding arc discharge (GAD) with diverging electrodes between dielectric walls at atmospheric pressure. In the present design, a tungsten pin-to-pin electrode pair ladder replaces the standard curved diverging electrodes. A major problem with the classic GAD design is the surface erosion of the electrodes, which leads to bad repeatability and issues with long-term usage. The new construction provides controlled electrode wear at well-defined points of arc attachment. This ensures stable operation while retaining the arc expansion effect. This new configuration of the discharge is being developed for gas treatment. In the current work, the device was applied for CO2 dissociation. The most significant quantities for this application of the GAD, the CO2 conversion rate and energy efficiency, are measured at different gas flow rates (2–12 Ln/min) and arc currents (50–210 mA). The results are analyzed and compared with previous measurements using the classic GAD at the same conditions.