In the calculation of the electrostatic force between two charged dielectric spheres, it is not easy to include the contribution of higher-order polarization which becomes very important when the spheres are closely located. We found that the re-expansion technique proposed by Washizu for the precise calculation of the dielectrophoretic force on a single sphere in an arbitrary external electrostatic field can be applied directly to a two-particle system. In this paper, the mathematical procedure for the application and some examples of the numerical calculation are presented. Comparison with existing methods, i.e., the method of successive images for conducting spheres and the bispherical coordinate method, shows the validity of the present approach. Convergence of the re-expansion method is poor if the ratio of the radii of the spheres is large and if the particles are closely spaced. Therefore, calculation of the force between a sphere and a dielectric plane wall is the hardest problem for the re-expansion method. Hence the electrostatic force on a small sphere resting on a large sphere is calculated to show that we can use the re-expansion method even for this case by substituting a large sphere for a plane wall in the force calculation.
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