Ar Geochronology Research Articles

40 Ar/ 39 Ar geochronology of crustal deformation

<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msup><mml:mrow/> <mml:mn>40</mml:mn> </mml:msup></mml:math>Ar/<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msup><mml:mrow/> <mml:mn>39</mml:mn> </mml:msup></mml:math>Ar geochronology of crustal deformation

Multiscalar 3D temporal structural characterisation of Smøla island, mid-Norwegian passive margin: an analogue for unravelling the tectonic history of offshore basement highs

Abstract. Smøla island, situated within the mid-Norwegian passive margin, contains crystalline-basement-hosted intricate fracture and fault arrays formed during a polyphase brittle tectonic evolution. Its detailed study may strengthen correlation attempts between the well-exposed onshore domain and the inaccessible offshore domain, further the understanding of the passive margin evolution, and provide useful constraints on petrophysical properties of fractured basement blocks. A combination of geophysical and remote sensing lineament analysis, field mapping, high-resolution drill hole logging, 3D modelling, petrographic and microstructural studies, and fault gouge K–Ar geochronology made it possible to define five deformation episodes (D1 to D5). These episodes occurred between the post-Caledonian evolution of the regional-scale Møre–Trøndelag Fault Complex (MTFC) and the Late Cretaceous and younger crustal extension preceding the final stages of Greenland–Norway break-up. Each reconstructed deformation stage is associated with different structural features, fault and fracture geometries, and kinematic patterns. Synkinematic mineralisations evolved progressively from epidote–prehnite, sericite–chlorite–calcite, chlorite–hematite, hematite–zeolite–calcite, to quartz–calcite. K–Ar geochronology constrains brittle deformation to discrete localisation events spanning from the Carboniferous to the Late Cretaceous. Multiscalar geometrical modelling at scales of 100, 10, and 1 m helps constrain the extent and size of the deformation zones of each deformation episode, with D2 structures exhibiting the greatest strike continuity and D1 features the most localised. Overall, the approach highlighted here is of great utility for unravelling complex brittle tectonic histories within basement volumes. It is also a prerequisite to constrain the dynamic evolution of the petrophysical properties of basement blocks.

The Influence of the Closure of the East Paleo‐Tethys Ocean on Southern South China: Evidences from Kinematics and 40Ar/39Ar Geochronology of the Rongxian Ductile Shear Zone in Southeastern Guangxi

AbstractThe Triassic was a crucial period in the tectonic evolution of the South China Block. Research on tectonic deformation during this period provides information on intracontinental orogenic mechanisms in South China. In this study, alongside thermochronological analyses, we examine the macroscopic and microscopic structural features of the Rongxian ductile shear zone, located south of the Darongshan granite in the southeastern part of Guangxi Province, on the southern margin of South China. Sinistral shear is indicated by the characteristics of rotated σ‐type feldspar porphyroclasts, stretching lineations defined by elongated quartz grains and the orientations of quartz c‐axes. LA‐ICP‐MS U‐Pb dating of zircons from two samples of granitic mylonite and one of granite yielded ages of ca. 256 Ma. Furthermore, two samples of granitic mylonite yield muscovite 40Ar/39Ar plateau ages of 249‐246 Ma. These results indicate that the Rongxian ductile shear zone resulted from Early Triassic deformation of the late Permian Darongshan granite. This deformation was likely related to the closure of the eastern Paleo‐Tethys Ocean and the subsequent collision of the South China and Indochina blocks, during the early stage of the Indosinian orogeny.

Detailed 40Ar/39Ar Geochronology of the Loyalty and Three Kings Ridges Clarifies the Extent and Sequential Development of Eocene to Miocene Southwest Pacific Remnant Volcanic Arcs

AbstractThe 2015 VESPA voyage (Volcanic Evolution of South Pacific Arcs) was a seismic and rock dredging expedition to the Loyalty and Three Kings Ridges and South Fiji Basin. In this paper we present 33 40Ar/39Ar, 22 micropaleontological, and two U/Pb ages for igneous and sedimentary rocks from 33 dredge sites in this little‐studied part of the southwest Pacific Ocean. Igneous rocks include basalts, dolerites, basaltic andesites, trachyandesites, and a granite. Successful Ar/Ar dating of altered and/or low‐K basalts was achieved through careful sample selection and processing, detailed petrographic and element mapping of groundmass, and incremental heating experiments on both phenocryst and groundmass separates to interpret the complex spectra produced by samples having multiple K reservoirs. The 40Ar/39Ar ages of most of the sampled lavas, irrespective of composition, are latest Oligocene to earliest Miocene (25–22 Ma); two are Eocene (39–36 Ma). The granite has a U/Pb zircon age of 23.6 ± 0.3 Ma. 40Ar/39Ar lava ages are corroborated by microfossil ages from associated sedimentary rocks. The VESPA lavas are part of a &gt;3,000 km long disrupted belt of Eocene to Miocene subduction‐related volcanic rocks. The belt includes arc rocks in Northland New Zealand, Northland Plateau, Three Kings Ridge, and Loyalty Ridge and, speculatively, D’Entrecasteaux Ridge. This belt is the product of superimposed Eocene and Oligocene‐Miocene remnant volcanic arcs that were stranded along and near the edge of Zealandia while still‐active arc belts migrated east with the Pacific trench.

Diagenesis- and thermal maturity-evolution of the Silurian unconventional hydrocarbon deposits (Tassili n’Ajjer plateau, Algeria): Clay mineralogy, graptolite reflectance, and K–Ar dating

The need for determining the thermal maturity of Lower Paleozoic rocks has increased with the intensified unconventional shale oil/gas resources exploration within North Africa, Arabian Peninsula, and the adjoining regions. Indeed, Lower Paleozoic strata represent an increasingly important resource that is related to the globally widespread occurrence of graptolite-bearing marine sediments in an expansive shelf area of the Gondwana. However, some crucial information for basin analysis remains poorly understood even across the largest hydrocarbon-producing province in Algeria.The present study provides a solid understanding of the diagenesis- and thermal maturity-evolution from the Tassili n’Ajjer plateau while involving multiple and independent approaches, such as clay mineralogy, petrography, graptolite reflectance, source rock maturity, as well as illite K−Ar geochronology. The combined use of X-ray analysis and field emission scanning electron microscope evidenced kaolinite, illite, and iron-rich chlorite as the main authigenic mineral phases. K−Ar data indicate that episodic in situ illite crystallization occurred at different times, the oldest illite at about 335 Ma and the youngest illite between 238 and 179 Ma, under diagenetic-to-hydrothermal conditions. Paleotemperature estimates (∼165–232 °C) derived from illite crystallinity (0.37–1.58 Δ°2θ), and graptolite reflectance (VReqv, 1.09–1.84%) values indicate deep diagenetic-low anchizone boundary conditions. This is broadly suggestive of late oil-to-dry gas zones of hydrocarbon generation and destruction, notably in the western sector of the study area.At least two heating events and diagenetic fluid flow processes are identified mainly in response to various tectonic events. They are largely due to fault reactivations, and migration of hot, potassium-rich, fluids throughout the Phanerozoic. Additionally, these events and processes had a later influence on the hydrocarbon maturation, migration, and/or entrapment, especially along the inherited N–S lineaments and Hoggar Massif mega-shear zones in the westernmost part of the Tassili n’Ajjer plateau.Lastly, it is important to highlight that the promising areas offering the highest potential for future unconventional hydrocarbon resource exploration could be most likely those bordering major lineaments, coupled with subsequent igneous activity, where unrestricted hydrothermal fluids are frequently reported, as well as the maturation, being much more advanced.

Repeated brittle reactivations of a pre-existing plastic shear zone: combined K–Ar and 40Ar–39Ar geochronology of the long-lived (&gt;700 Ma) Himdalen–Ørje Deformation Zone, SE Norway

AbstractBrittle reactivation of plastic shear zones is frequently observed in geologically old terranes. To better understand such deformation zones, we have studied the &gt;700 Ma long structural history of the Himdalen–Ørje Deformation Zone (HØDZ) in SE Norway by K–Ar and 40Ar–39Ar geochronology, and structural characterization. Several generations of mylonites make up the ductile part of HØDZ, the Ørje Shear Zone. A 40Ar–39Ar white mica plateau age of 908.6 ± 7.0 Ma constrains the timing of extensional reactivation of the Ørje mylonite. The mylonite is extensively reworked during brittle deformation events by the Himdalen Fault. 40Ar–39Ar plateau ages of 375.0 ± 22.7 Ma and 351.7 ± 4.4 Ma from pseudotachylite veins and K–Ar ages of authigenic illite in fault gouge at c. 380 Ma are interpreted to date initial brittle deformation, possibly associated with the Variscan orogeny. Major brittle deformation during the Early–Mid Permian Oslo Rift is documented by a 40Ar–39Ar pseudotachylite plateau age of 294.6 ± 5.2 Ma and a K–Ar fault gouge age of c. 270 Ma. The last datable faulting event is constrained by the finest size fraction in three separate gouges at c. 200 Ma. The study demonstrates that multiple geologically significant K–Ar ages can be constrained from fault gouges within the same fault core by combining careful field sampling, structural characterization, detailed mineralogy and illite crystallinity analysis. We suggest that initial localization of brittle strain along plastic shear zones is controlled by mechanical anisotropy of parallel-oriented, throughgoing phyllosilicate-rich foliation planes within the mylonitic fabric.

40Ar–39Ar geochronology and palaeostress analysis using lamprophyre dikes and quartz veins in the Sizhuang gold deposit: new implications for Early Cretaceous stress regime in the Jiaodong Peninsula, North China Craton

AbstractLamprophyre dikes and quartz veins in the Sizhuang gold deposit are used to date and unravel the Early Cretaceous stress regime in the Jiaodong Peninsula, North China Craton. The lamprophyre dikes are grouped into two major sets, trending NNW–SSE and NNE–SSW, respectively, and a subsidiary one, trending WNW–ESE, whereas the quartz veins trend mainly NNE–SSW. The age of lamprophyre dikes’ intrusion was robustly calculated at c. 119 Ma by phlogopite 40Ar–39Ar dating. The fuzzy clustering technique defined four stress states, which were grouped into three stress regimes in Sizhuang. Furthermore, these stress regimes were interrelated with two regional far-field stress regimes, ST1 and ST2, defined by the available published fault-slip data near Sizhuang by applying the separation and stress inversion TR method (TRM). The palaeostress reconstruction indicates that extension and strike-slip tectonics (i.e. transtension) affect the emplacement of the lamprophyre dikes and quartz veins. More precisely, the dike emplacement occurred under unstable stress conditions related to the shift from E–W pure extension–transtension to WNW–ESE transtension, whereas the quartz veins formed under relatively stable WNW–ESE transtension with the variant and increasing fluid pressure ( ${P_{\rm{f}}})$ giving rise to the strike-slip against dip-slip kinematics along the faults. The change from the ST1 to ST2 stress regimes reflects the significant clockwise rotation in the palaeo-Pacific plate subduction direction and defines the switching time at c. 119 Ma as precisely obtained by the lamprophyre dating.

Mid-Devonian basaltic magmatism and associated sedimentation: the Ooloo Hill Formation, central-eastern South Australia

We report composition and age data from a restricted <370 km2, volcano-sedimentary basin beneath Mesozoic cover to the northwest of the Flinders Ranges, South Australia. This volcano-sedimentary basin comprises two components: a sedimentary sequence that includes shales, siltstones and sandstones, and a basalt–sedimentary member. Together, these components are defined as the Ooloo Hill Formation. Whole-rock K–Ar geochronology for five basalt samples yields a preferred mean K–Ar age of 392 ± 8 Ma. Two samples of detrital zircons from the sedimentary rock yield SHRIMP U–Pb maximum depositional ages of ca 527 and 510 Ma. These ages are significant, as they rule out a Neoproterozoic age for the sedimentary basin and demonstrate that this basin is not part of the Adelaide Superbasin. Lower eruptive sequences are calc-alkaline and mafic in composition (SiO2 = 46.1–47.8 wt%, Na2O + K2O = 3.7–6.1 wt%, MgO = 6.85–8.37 wt%, Mg# = 57–65 and εNd(390 Ma) = 3.4–4.0) and may represent two small-scale melting events from compositionally distinct mantle reservoirs. The uppermost eruptive sequence is tholeiitic andesite (SiO2 = 51.6 wt%, Na2O + K2O = 8.1 wt%, MgO = 2.2 wt%, Mg# = 27 and εNd(390 Ma) = 3.0) and displays geochemical affinity to the first two eruptive sequences, possibly representing a differentiated magma from a similar source region. Incompatible trace-element ratios and isotopic compositions suggest the source was a heterogeneous oceanic island basalt-like parent magma derived from partial melting of the asthenospheric mantle. We envisage decompressional melting was linked to large-scale tectonic processes inboard of the Tasman Orogen, with magma ascent facilitated by crustal faulting. KEY POINTS First record of a mid-Devonian intracontinental volcano-sedimentary basin in South Australia. Basalts have an oceanic island basalt-like mantle source that represents at least two small-scale melting events from compositionally distinct mantle reservoirs. A localised mid-Devonian backarc basin or transpressional/transtensional basin linked to intracontinental faulting formed inboard of the Tasman Orogen.

Mineralogy and K–Ar geochronology of clay alteration associated with uranium mineralization in the Patterson Lake Corridor, Saskatchewan

The Patterson Lake Corridor (PLC) along the southwestern margin of the Athabasca Basin contains high-grade uranium deposits entirely within crystalline basement rocks. Visible–near infrared–shortwave infrared (VNIR–SWIR) spectroscopy measurements were collected on drill core samples from several locations in the PLC. The Triple R and Arrow deposits exhibit downhole spectral trends related to the crystallinity and thermal maturity of clays (illite and kaolinite) and mineralization. The K–Ar dates of silt-and-clay size fractions (10–6 μ m; 6–2 μ m; 2–0.6 μ m; 0.6–0.2 μ m; &lt;0.2 μ m) from five clay-altered samples decrease with grain size, and span 1608 ± 17 Ma to 1060 ± 14 Ma for the Spitfire discovery ( n = 14) and 1342 ± 17 Ma to 289 ± 4.3 Ma for the Arrow deposit ( n = 4). Alteration assemblages are broadly similar to Athabasca Basin basement-hosted deposits, and K–Ar dates indicate that high-grade uranium mineralization in the PLC reflects remobilization and concentration of primary ores. Integration of geochronology, clay mineralogy and VNIR–SWIR spectral parameters identify fertile fluid conduits when expanded to property or corridor scales, and provide additional evidence that ore grades of the Athabasca Basin deposits reflect several stages of hydrothermal mineralization spanning c. 1000 Ma. Supplementary material: Supporting information document and datasets are available at https://doi.org/10.6084/m9.figshare.c.6033890 Thematic collection: This article is part of the Uranium Fluid Pathways collection available at: https://www.lyellcollection.org/cc/uranium-fluid-pathways

Petrology of the Paleogene shoshonitic volcanism in north Sarab area, NW Iran: Geochemical, Ar-Ar dating and Sr-Nd-Pb isotopic constraints

This study reports the earliest presumably known collisional magmatism of the NW Iran–eastern Turkey–Caucasus region from the north of Sarab city in East Azarbaijan province, NW Iran. Volcanic rocks of the area comprise alternating lava flows of mainly alkalibasalt, andesite, trachyandesite, dacite and pyroclastics (tuff and ignimbrite) affiliated with high-K calk-alkaline to shoshonitic magmatic series. Ar–Ar geochronology of the glass, matrix and plagioclase laths revealed crystallization time restricted to Late Eocene to Early Oligocene (34.90–30.69 Ma) which is coincident with the onset of the Arabian-Eurasian continental collision. Geochemical data show LREE enrichment compared with HREE and Nb and Ti depletion, indicating that they are subduction related. The Sr-Nd-Pb isotopic data reflect the incorporation of oceanic sediment into the magma source. We suggest that the volcanic rocks were generated from a metasomatised subcontinental lithospheric mantle source through 5 to 10 vol% partial melting in an extensional back arc basin by the Neotethys slab roll-back under the Iranian plateau.

Zircon U–Pb and sericite Ar–Ar geochronology, geochemistry and S–Pb–Hf isotopes of the Zebuxia Pb–Zn deposit, Tibet, southwestern China

The Zebuxia Pb–Zn deposit is located in southern Tibet and belongs to the western segment of the Northern Gangdese Metallogenic Belt. Based on the characters of deposit geology, geochronology, geochemistry, and S–Pb-Hf isotopes, the genesis and spatial–temporal evolution of the Pb–Zn mineralization in the Northern Gangdese Metallogenic Belt were elucidated. The results of sericite Ar-Ar dating yields an isochron age of 55.2 ± 0.8 Ma, accordant with the zircon U-Pb 54.9 ± 0.4 Ma age obtained from the biotite granite. The biotite granite is of high-K calc–alkaline and metaluminous with I-type affinity. The δ34S values of galena and pyrite range from + 1.3‰ to + 3.5‰ (mean = +2.4‰) and show magmatic origin. Pb isotopic results of galena and pyrite show the 206Pb/204Pb values are 18.611–18.666 (mean = 18.631), 207 Pb/ 204Pb values are 15.654–15.718 (mean = 15.678), 208Pb/204Pb values are 38.982–39.195 (mean = 39.064), representing the orogenic feature with upper crustal source mixed by mantle-derived materials. Based on the comprehensive analyses above, the Zebuxia Pb–Zn deposit belongs to structure–hydrothermal–filling type deposit. Combined with previous studies, we propose that the magmatic intensity determine the mineralization scale of the Pb–Zn deposits, while the nature of ore–related plutons constrain the source of mineralized fluids in the Northern Gangdese Metallogenic Belt. The investigation of the Zebuxia Pb–Zn deposit reveals the western section of the Northern Gangdese Metallogenic Belt has great prospecting potential as well.

Petrological features of the first Cenozoic alkaline magmatic event recorded in northwestern Uruguay, southern extreme of the Paraná basin

The Cenozoic mafic alkaline rocks found in northwestern Uruguay, in the southernmost portion of the Paraná Basin, comprise three subvolcanic plugs composed of Ne-tephrites. They cut through basalts that make up the Paraná Magmatic Province as well as part of the sandstones of the Late Jurassic–Early Cretaceous age. These mafic rocks are characterized by an aphanitic hypocrystalline texture that is occasionally porphyritic with pyroxene and olivine macrocrysts/xenocrysts. We present the first lithogeochemical results that also include the Sr–Nd–Pb isotopes to determine the petrogenetic processes. These mafic rocks are enriched in light rare earth elements (La/LuN = 23.12–28.81) with respect to chondrite, in large-ion lithophile elements (Ba, U, and La), and in high-field-strength elements, such as Ta, Nb, and Zr, with respect to primitive mantle, and have a Mg# of 0.53–0.56. The trace element geochemistry and isotopic data (low radiogenic 206Pb/204Pb and low 87Sr/86Sri between 18.315 and 18.733, 0.70397 and 0.70443, respectively) indicate that the primary magma could be the product of the melting of an enriched mantle source with the possible involvement of metasomatic processes, lacking significant contamination by the continental crust. The K–Ar (whole rock) geochronology conducted on two samples yielded ages of 63.7 ± 2.5 and 51.5 ± 1.7 Ma for this magmatic event.

New mammals from the Naskal intertrappean site and the age of India’s earliest eutherians

The first Cretaceous mammals described from India were recovered from the Naskal locality, on the southeastern edge of the Deccan Traps Volcanic Province (DTVP), where it is preserved between two basalt flows. Because the DTVP eruptions spanned the Cretaceous-Paleogene boundary (KPB), it is often unknown whether trap-associated fossil sites are latest Cretaceous (Maastrichtian) or early Paleocene in age. The Naskal locality accounts for nearly half of published mammal records from DTVP-associated sediments as well as a host of other vertebrate microfossils. Its age takes on singular importance in the context of mammalian evolution in India and the effects of the end-Cretaceous mass extinction and subsequent evolutionary radiation of placentals. Here we describe two new mammal species, Indoclemensia naskalensis gen. et sp. nov. and I. magnus sp. nov., from Naskal and present evidence from 40 Ar/ 39 Ar geochronology, magnetostratigraphy, and chemostratigraphy of the over- and underlying basalt flows to refine the age of the Naskal locality and nearby Rangapur locality. In conjunction with palynostratigraphy and vertebrate biostratigraphy, these sites can be confidently restricted to a <100 kyr interval spanning the KPB. The most probable 40 Ar/ 39 Ar age is latest Cretaceous (66.136–66.056 Ma), but an earliest Paleogene age cannot be ruled out. We explore the implications of this age assignment for Deccan chemostratigraphy and Deccan volcanism, Cretaceous-Paleogene (K/Pg) mass extinction, Indian mammalian faunal evolution, and the timing of the origin of placental mammals. • New 40 Ar/ 39 Ar geochronology, magnetostratigraphy, chemostratigraphy, and palynofloras from the Naskal and Rangapur sites. • Age of Naskal and Rangapur are likely Maastrichtian, constrained to within 100 kyr of the Cretaceous-Paleogene boundary. • Two new eutherian mammal species from the Naskal site of India are described. • These sites are ‘transitional’ distinctive in biotic composition from older and younger infra - and intertrappean localities.

K–Ar Geochronology of the Andesite Lavas of the Lower Pleistocene Enrei Formation on the Southwestern Slope of the Suwa Basin, Central Japan

K–Ar Geochronology of the Andesite Lavas of the Lower Pleistocene Enrei Formation on the Southwestern Slope of the Suwa Basin, Central Japan

Short-lived alkaline magmatism related to the Réunion plume in the Deccan Large Igneous Province: inferences from petrology, 40 Ar/ 39 Ar geochronology and palaeomagnetism of lamprophyre from the Sarnu-Dandali Alkaline Igneous Complex

Abstract Available geochronological information on Deccan indicates prolonged (started at 68.5 Ma) alkaline magmatism related to the Réunion mantle plume based on the 40 Ar/ 39 Ar ages from Sarnu-Dandali and Mundwara alkaline complexes. We studied in detail an alkaline lamprophyre, from the Sarnu-Dandali Complex, rich in groundmass (magmatic) as well as xenocrystic phlogopites and clinopyroxenes. 40 Ar/ 39 Ar age determinations of the phlogopites from this lamprophyre reveal two distinct ages of 65.44 ± 1.5 Ma and 68.17 ± 1 Ma. However, palaeomagnetic results show a VGP at 32.31° N and 298.52° E concordant with that of the Deccan Super Pole at 65.5 Ma and support the younger eruption age at c. 65.44 ± 1.5 Ma. Analysed phlogopites lack any signs of retention of excess radiogenic Ar and yield similar inverse isochron ages, which suggests that the older age of c. 68.17 ± 1 Ma belongs to the crystallization of xenocrystic phlogopite during mantle metasomatism. Trace element compositions support derivation of lamprophyre magma from an OIB-type enriched (metasomatized) mantle source with an involvement of phlogopite. This finding suggests that the pre-Deccan ages of c. 68–69 Ma reported previously may reflect the timing of metasomatism of the subcratonic lithospheric mantle during the separation of Greater-Seychelles from India at c. 68.5 Ma. The absence of pre-Deccan alkaline rocks therefore indicates the short duration (between 67–65 Ma) of alkaline as well as small-volume, volatile-rich magmatism directly related to the Réunion (Deccan) plume.

Cretaceous to Miocene NW Pacific Plate Kinematic Constraints: Paleomagnetism and Ar–Ar Geochronology in the Mineoka Ophiolite Mélange (Japan)

AbstractThe Mineoka Ophiolite Mélange is located at the intersection of the Pacific, Philippine Sea, Eurasian, and North American plates. The Mineoka ophiolite origin is disputed, and it has been ascribed to a fully subducted plate or part of the Pacific and Philippine Sea plates. In this paper, we present a kinematic reconstruction of the Mineoka Ophiolite Mélange and its relation with the Pacific Plate, based on new paleomagnetic data and bulk‐rock 40Ar/39Ar ages of basaltic rocks. In addition to standard analyses for paleolatitudes, we performed a Net tectonic rotation analysis on sheeted dolerite dikes to infer the paleospreading direction that formed the ophiolite. The analysis shows that 85–80 Ma MOR pillow basalts erupted at a paleolatitude of N ∼16°, whereas ∼50 Ma basalts formed at N ∼34°. Net Tectonic Rotation analysis suggests that the spreading direction was NE 60°. Ar–Ar ages yielded 53–49 Ma for MORBs and 41–35 Ma for island‐arc basalts. The formation of this ophiolite occurred in the back‐arc spreading of the Nemuro–Olyutorsky arcs of the NW Pacific. It infers that the final consumption of Izanagi below Japan instigated a subduction jump and flipped its polarity. Subduction initiated parallel to the ridge, and a piece of the original back‐arc crust got trapped near the Japan trench during the northwards motion of the Philippine Sea Plate. The contrasting motion between the Pacific and the Philippine Sea plates generated a highly unstable setting followed by a subduction zone that left a small‐sized and short‐lived plate (“Mineoka”), surrounded by subduction zones.

Mechanisms and kinetics of argon diffusion in hypogene and supergene jarosites: Implications for geochronology and surficial geochemistry on Earth and Mars

Jarosite [KFe3(SO4)2(OH)6] occurs both as a hydrothermal mineral and as the product of weathering and chemical sedimentation. It has been used in 40Ar/39Ar geochronology to date water–rock interaction and weathering processes on the surfaces of Earth and Mars, but the lack of information about Ar diffusivity parameters relevant to specific types of jarosites makes the interpretation of geochronological results tentative. We have filled this gap by investigating Ar diffusion parameters in representative supergene and hypogene jarosites. Detailed diffusion studies were carried out on a hypogene jarosite sample from Gilbert, Nevada, and two supergene jarosite samples from Baiyin, China. The diffusion studies were accompanied by in-situ heating investigations in a transmission electron microscope to directly determine the thermal stability and the phase transformations that jarosite undergoes under progressive heating under ultra-high vacuum. The TEM results suggest that jarosite is stable under vacuum up to ∼400 °C, when it undergoes phase transition to yavapaiite [KFe(SO4)2] and hematite (Fe2O3). Incremental-heating experiments reveal average diffusion parameters of Ea = 138.6 ± 4.2 kJ/mol and ln(Do/a2) = 9.9 ± 0.9 ln(s−1) for hypogene jarosite; Ea = 110.3 ± 3.2 kJ/mol and ln(Do/a2) = 5.7 ± 0.7 ln(s−1) for one supergene jarosites; and Ea = 141.2 ± 7.9 kJ/mol and ln(Do/a2) = 11.3 ± 1.7 ln(s−1) for the other supergene jarosite sample from the same weathering profile. Jarosite closure temperatures depend strongly on sieve size. For samples between 500–200 µm (grain size usually used for samples in Ar geochronology), at a cooling rate 100 °C·Ma−1, the closure temperatures are 143 ± 18 °C for the hypogene jarosite, and 105 ± 8 and 113 ± 14 °C, respectively, for the two supergene jarosites. Forward modelling of incremental-heating results predicts that coarse-grained hypogene jarosite is retentive of Ar below 50 °C for 100 Ma and below 25 °C for 4 Ga. Densely packed supergene jarosite grains larger than 200 µm are suitable for 40Ar/39Ar geochronology at the timescales suitable for investigating water–rock interaction at the surface of Earth and Mars. Fine-grained, porous jarosites require detailed diffusion analyses prior to geochronology due to possible high Ar losses over Ma timescales. The absence of jarosites older than ∼40 Ma on Earth suggests that jarosite may require continuous exposure to acid oxidizing conditions, and that it does not survive burial and exhumation. Therefore, the occurrence of jarosite on Earth and Mars may identify segments of the planets’ surfaces continuously exposed to acid-oxidizing conditions since jarosite precipitation.

Alkalic to tholeiitic magmatism near a mid-ocean ridge: petrogenesis of the KR1 Seamount Trail adjacent to the Australian-Antarctic Ridge

ABSTRACT Coexisting alkalic and tholeiitic basalt lavas has been identified in a seamount chain located near the Australian–Antarctic spreading ridge. The KR1 Seamount Trail (KR1 ST) is a series of volcanic seamounts extending to the southeast in the spreading direction of the Australian–Antarctic Ridge (AAR). We herein report Sr, Nd and Pb isotopic compositions and (U–Th)/He and K–Ar geochronology for dredge samples from the KR1 ST in order to evaluate mantle processes and the role of enriched components for alkalic to tholeiitic magma generation in this region. The KR1 ST is a medium-sized seamount chain that extends for ~60 km, has a maximum height of ~1600 m above the seafloor, and consists of alkaline basalts and tholeiites with formation ages of ~0.4 Ma to ≤1.3 Ma. The isotopic characteristics of the alkaline basalts (206Pb/204Pb = 19.52–19.91; 87Sr/86Sr = 0.7030–0.7033; 143Nd/144Nd = 0.5128–0.5130) from the KR1 ST reflect a dominant ‘PREMA (or FOZO)’ mantle component represented by radiogenic Pb and mildly enriched Sr and Nd isotopic compositions. On the other hand, the weak PREMA (FOZO)-affinity (206Pb/204Pb = 18.89–18.93; 87Sr/86Sr = 0.7028–0.7029; 143Nd/144Nd = ~0.5130; 3He/4He = 7.64 ± 0.13 (R/RA)) coupled with their enriched mid-ocean ridge basalt (E-MORB) characteristics of tholeiites from the KR1 ST largely overlap with the KR1 MORB composition. The potential source materials for the alkaline basalts are considered to be ancient, recycled oceanic crust (i.e. eclogite) as well as sub-KR1 depleted MORB mantle (DMM). Whereas the main source materials for the KR1 ST tholeiites are presumed to be the DMM-dominant lithology with minor recycled material. We interpret the KR1 ST as a submarine hotspot chain that was formed by asthenospheric upwelling and spreading processes that delivered fertile blobs of recycled oceanic crust to the sub-KR1 region. The fundamental reason for sub-KR1 upper mantle enrichment might be attributed to a mantle plume event that possibly occurred prior to the formation of the KR1 ST.

Timing and Processes of Ore Formation in the Qingchengzi Polymetallic Orefield, Northeast China: Evidence from 40Ar/39Ar Geochronology

AbstractThe Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula, northeastern China, that includes twelve Pb‐Zn deposits and five Au‐Ag deposits along its periphery. The ore‐forming age remains much disputed, which prevents the identification of the relationship between the mineralization and the associated magmatism. In this paper, we quantitatively present the feasibility of making ore mineral 40Ar/39Ar dating and report reliable 40Ar/39Ar ages of lamprophyre groundmass, K‐feldspar and sphalerite from the Zhenzigou deposit. Direct and indirect methods are applied to constrain the timing of mineralization, which plays a vital role in discussing the contribution of multistage magmatism to ore formation. The low‐potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma, which features a relatively large uncertainty. Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma, respectively. K‐feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma. These four ages indicate that the mineralization is closely associated with Mesozoic magmatism. Consequently, regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion (224.2±1.2 Ma) as the initial time of mineralization, we can further constrain the age of the sphalerite to 224–191 Ma. These new and existing geochronological data, combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins, suggest that the Pb‐Zn‐Au‐Ag mineralization in the Qingchengzi orefield mainly occurred during three periods: the late Triassic (ca. 224–193 Ma), the late Jurassic (ca. 167–152 Ma) and the early Cretaceous (ca. 138–134 Ma). This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity. In contrast, the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore‐forming substances at the Liaohe Group with no associated Pb‐Zn‐Au‐Ag mineralization.

Syn-accretionary multistage assembly of an Early Jurassic Alaskan-type intrusion in the Canadian Cordillera: U–Pb and 40Ar/39Ar geochronology of the Turnagain ultramafic–mafic intrusive complex, Yukon–Tanana terrane

The magmatic evolution of the Early Jurassic Turnagain Alaskan-type intrusion is inextricably linked to terrane accretionary events at the North American continental margin. We have calibrated the multistage assembly of the Turnagain ultramafic–mafic complex using high-precision air and chemical abrasion ID-TIMS U–Pb and 40Ar/39Ar geochronology. Our results are the first published geochronological calibration of zoning in an Alaskan-type intrusion. Three of four intrusive phases (Stages 1–4, oldest to youngest) were successfully dated. Cooling ages obtained on Stage 2 dunite–wehrlite include statistically identical 40Ar/39Ar plateau dates of 187.4 ± 1.5 (2σ) Ma on hornblende and 188.6 ± 1.2 Ma on phlogopite, and a concordant 206Pb/238U date of 190.3 ± 4.6 Ma on titanite. Stage 3 diorite has a 206Pb/238U zircon crystallization age of 188.11 ± 0.13 Ma. Stage 4 wehrlite and leucodiorite yield 206Pb/238U zircon crystallization ages of 185.68 ± 0.19 and 185.30 ± 0.12 Ma, respectively. The ca. 189 Ma phlogopite date represents a minimum crystallization age for Stage 2, indicating that assembly of the Turnagain intrusion spanned at least ∼4 million years from ca. 189 Ma to 185 Ma. Regional progressive contractional deformation in the Early Jurassic is constrained by the geochronological results (&gt;189 to &lt;185 Ma) and initially generated northeast-vergent folds in the country rocks (&gt;189 Ma), deformed Stage 1 wehrlite–clinopyroxenite prior to emplacement of Stages 2–4, and subsequently thrust the intrusion and its host rocks onto the ancient North American continental margin (&lt;185 Ma). Contrary to previous interpretations, new geophysical data support an allochthonous origin for the host rocks of the Turnagain intrusion. The Turnagain host succession is correlated with late Paleozoic arc-related and basinal lithostratigraphic units developed at the inboard margin of the accreted Yukon–Tanana terrane and peripheral to the Slide Mountain marginal ocean basin. The geochronological results rigorously constrain the timing and style of Early Jurassic deformation attending the initial accretion of allochthonous arc terranes in the northern Cordillera.