Aquifer Storage And Recovery System Research Articles

Comprehensive assessment for the seasonal variations of organic compounds and core soil microbiome in the simulated pilot-scale aquifer storage and recovery (ASR) system

Soil microbiome is responsible for crucial biochemical reactions by interacting with organic compounds in the injection wells in aquifer storage and recovery (ASR) processes. This study investigated seasonal variations in organic compounds and microbial communities in a simulated ASR system. For this purpose, eleven pilot-scale soil columns were operated in ASR mode over 13 months. River water was intermittently fed into the simulated ASR system after sedimentation pretreatment. As a result, the sand ratios in soil texture were slightly increased from 93.2-93.4 % to 96.6–98.1 % while the total organic carbon content in the soil was accumulated and maintained at < 0.2 % during the ASR operation. During the sedimentation process, 9–31 % of dissolved organic carbon (DOC) was removed in the water, while during the storage in the soil column, the DOC in water was fluctuated. However, the DOC concentration (less than 4 mg/L) in the effluent was stably maintained until the end of operational periods. High-throughput sequencing results showed that the predominant phylum was Proteobacteria. Interestingly, at the species level, the microbial community structure clearly shifted with elapsed time and column location; various organic degrading soil microbiome having different physiological characteristics (e.g., oxygen, substrate, and temperature) became predominant. Outcomes of this study suggest that soil microbiome can facilitate the establishment of stable ASR processes for river water treatment by contributing to bioattenuation.

Assessment of managed aquifer recharge in saline confined aquifers for freshwater storage and improved recovery: A 3D tank study under various operational conditions

Aquifer Storage and Recovery (ASR), a subset of Managed Aquifer Recharge (MAR) techniques, is a promising technique to address water scarcity issues by recharging depleted aquifers. The application of ASR in saline groundwater regions is challenging due to mixing of recharged freshwater with the ambient saline groundwater, decreasing the recoverable amount of freshwater. This paper aimed to investigate the feasibility of ASR techniques for freshwater storage and recovery in saline confined aquifers using a laboratory scale physical model (100 cm length x 30 cm width x 60 cm depth). The study then explored the impact of operational factors (freshwater storage duration, injected freshwater volume, number of injection/extraction cycles etc.) on freshwater recovery from an applied ASR. Firstly, the behaviour of stored freshwater in a saline-confined aquifer was investigated, and in the next step, the impact of ASR operational parameters on the recovery efficiency (RE) was evaluated. Along with the physical model, these effects were studied using a mathematical model (MODFLOW linked with SEAWAT) for the representative aquifer system. The movement and spreading of the stored freshwater were monitored over time. The experimental results presented in this study suggested that several factors significantly influence the efficiency of ASR systems. A negative correlation between ambient groundwater salinity and average recovery efficiency (ARE) was confirmed, with decreasing ARE observed as the salinity level increased. The injection volume of freshwater was found to have a positive influence on ARE, although the relationship was non-linear, a polynomial trend was observed. The longer freshwater was stored in the aquifer, the lower ARE was reported, indicating a negative impact of storage duration on ASR performance. Finally, the number of successive cycles of ASR operation was found to have a positive influence on ARE, but the effect decreased with each subsequent cycle. This research provided valuable insights into the application of ASR techniques for freshwater storage and its enhanced recovery in saline confined aquifers.

Aquifer Storage and Recovery in Layered Saline Aquifers: Importance of Layer-Arrangements

Aquifer storage and recovery (ASR) refers to injecting freshwater into an aquifer and later withdrawing it. In brackish-to-saline aquifers, density-driven convection and fresh-saline water mixing lead to a reduced recovery efficiency (RE, i.e., the volumetric ratio between recovered potable water and injected freshwater) of ASR. For a layered aquifer, previous studies assume a constant hydraulic conductivity ratio between neighboring layers. In order to reflect the realistic formation of layered aquifers, we systematically investigate 120 layered heterogeneous scenarios with different layer arrangements on multiple-cycle ASR using numerical simulations. Results show that the convection (as is reflected by the tilt of the fresh-saline interface) and mixing phenomena of the ASR system vary significantly among scenarios with different layer arrangements. In particular, the lower permeable layer underlying the higher permeable layer restricts the free convection and leads to the spreading of salinity at the bottom of the higher permeable layer and early salt breakthrough to the well. Correspondingly, the RE values are different among the heterogeneous scenarios, with a maximum absolute RE difference of 22% for the first cycle and 9% for the tenth cycle. Even though the difference in RE decreases with more ASR cycles, it is still non-negligible and needs to be considered after ten ASR cycles. The method to homogenize the layered heterogeneity by simply taking the arithmetic and geometric means of the hydraulic conductivities among different layers as the horizontal and vertical hydraulic conductivities is shown to overestimate the RE for multiple-cycle ASR. The outcomes of this research illustrate the importance of considering the geometric arrangement of layers in assessing the feasibility of multiple-cycle ASR operations in brackish-to-saline layered aquifers.

Reactive transport modelling of push-pull tests: A versatile approach to quantify aquifer reactivity

Push-pull tests (PPTs) were evaluated with 1-D radially axisymmetric multi-component geochemical reactive transport modelling (RTM) to assess aquifer reactivity controlling groundwater quality. Nutrient fate and redox processes were investigated in an Aquifer Storage and Recovery (ASR) system, in which oxic tile drainage water (TDW; nitrate ~14 mg/L; phosphate ~17 mg/L) was stored in an anoxic aquifer for later re-use as irrigation water. During the PPTs, the ASR system did not operate. PPTs were performed in two monitoring wells (MW2, MW3), with 1 m well screens in contrasting geochemical formations at different depths. In these wells, 300 L TDW was injected, and consecutively 720 L was abstracted within 12 days, during which water quality changes were studied. The RTM simulated cation exchange, precipitation of Hydrous Ferric Oxides, Iron (III)-phosphate and Calcium-phosphate minerals, and surface complexation as equilibrium processes. Oxidation of Pyrite, soil organic matter, and dissolved ferrous iron were simulated with kinetic rate expressions. Oxygen (within 2 days) and nitrate (within 4–7 days) were fully reduced during the PPTs. The main reductants were ferrous iron (Monitoring Well (MW) 2: 2%, MW3: 13%), soil organic matter (MW2: 93%, MW3: 6%), and Pyrite (MW2: 5%, MW3: 81%). The intra aquifer differences in dominant reduction pathways are remarkable as higher reduction rates coincided with lower contents of soil organic matter and Pyrite, respectively. Phosphate was mostly re-abstracted (MW2: 73%, MW3: 64%) and partially immobilized due to precipitation of Iron-hydroxyphosphates (MW2: 4.6%, MW3: 35%), Hydroxyapatite (MW2: 23%, MW3: 0%), and to a lesser extent by surface complexation on various minerals (MW2-3: <1%). The PPT-RTM approach enables a better understanding of reaction networks controlling water quality changes, and the reaction kinetics. PPT-RTM is a promising tool in exploratory studies or regular monitoring of water quality aspects of subsurface water technologies.

Soil microbial communities-mediated bioattenuation in simulated aquifer storage and recovery (ASR) condition: Long-term study

This study evaluated the long-term organic removal performance and microbial community shift in simulated aquifer storage and recovery (ASR) conditions. For this purpose, anoxic soil box systems were operated at 15 °C for one year. The results showed that the assimilable organic carbon (AOC) concentration in the anoxic soil box systems was successfully decreased by 79.1%. The dissolved organic carbon (DOC) concentration increased during the initial operational periods; however, it subsequently decreased during long-term operation. Readily biodegradable organic fractions (i.e., low-molecular weight (LMW) neutrals and LMW acids) decreased along with time elapsed, whereas non-biodegradable fraction (i.e., humic substances) increased. Proteobacteria and Acidobacteriota were predominant in the anoxic box systems throughout the operational periods. Firmicutes and Bacteroidota suddenly increased during the initial operational period while Gemmatimonadota slightly increased during prolonged long-term operation. Interestingly, the microbial community structures were significantly shifted with respect to the operational periods while the effects of AOC/NO3− addition were negligible. Various bacterial species preferring low temperature or anoxic conditions were detected as predominant bacteria. Some denitrifying (i.e., Noviherbaspirillum denitrificans) and iron reducing bacteria (i.e., Geobacter spp.) appeared during the long-term operation; these bacterial communities also acted as organic degraders in the simulated ASR systems. The findings of this study suggest that the application of natural bioattenuation using indigenous soil microbial communities can be a promising option as an organic carbon management strategy in ASR systems.

Optimizing Multiwell Aquifer Storage and Recovery Systems for Energy Use and Recovery Efficiency.

As more aquifer storage and recovery (ASR) systems are employed for management of water resources, the skillful operation of multiwell ASR systems has become very important to improve their performance. In this study, we developed MODFLOW and MT3DMS models to simulate a multiwell ASR system in a synthetic aquifer to assess effects of hydrogeological and operational factors on the performance of the multiwell ASR system. We evaluated a simplified (dual well) ASR system in comparison with complex system (three-, four-, five-, and seven-well systems). Recovery and energy efficiencies were calculated using the model simulations. Factors such as higher hydraulic conductivity and longitudinal dispersivity significantly reduced the recovery and energy efficiencies of the system. In contrast, increasing the volume of recharged water increased the recovery efficiency; however, the energy efficiency was reduced. Recovery and energy efficiencies also plummet when there is an increase in the underlying regional gradient and the designed storage duration. Operating the system multiple times can yield higher volume of potable water, but the energy efficiency may not vary significantly after the second operating cycle. Single-well systems and multiwell systems exhibit similar responses to changes in physical factors, although operational factors have a more pronounced effect on the multiwell systems. One of the major findings was that fewer wells in a multiwell ASR system can yield higher volume of potable water and better output with respect to the electrical power being consumed. The results provide design engineers with guidelines for optimizing performance of the multiwell ASR systems.

Assimilable organic carbon removal strategy for aquifer storage and recovery applications

Aquifer storage and recovery (ASR) technology has been adopted as a strategic water management tool. However, during the injection of oxic and organic carbon-containing water to the underground aquifers, severe phenomena such as clogging and groundwater deterioration have been reported. To prevent these severe phenomena, assimilable organic carbon (AOC) concentration has been controlled in the ASR applications by supporting bacteria growth potential. In this study, the AOC removal strategy was investigated in a simulated ASR system using an indigenous bacterium, Pseudomonas jinjuensis. AOC removal was evaluated under three different experimental conditions: (i) 30 °C and aerobic, (ii) 15 °C and aerobic, and (iii) 15 °C and anoxic. The effects of contact media such as sand and granular activated carbon on AOC removal efficiency were also investigated. Results show that under the 30 °C aerobic condition, P. jinjuensis could remove 99.8% (13 μg L−1) of AOC with soil. The variations in the organic fractions determined by liquid chromatography with organic carbon detector analysis were observed and showed trends similar to those of AOC determined by the flow cytometry method. The indirect injection method in ASR application was recommended due to the AOC removal benefit by soil indigenous bacterium.

Participatory approach in Aquifer Storage and Recovery management in Arid zones, does it work?

Aquifer storage and recovery (ASR) with treated wastewater, is considered as an effective solution for a critical aquifer decline due to groundwater overexploitation. In ASR operational step and after the aquifer storage phase, the problem is the new groundwater right for stakeholders and specifically farmers. In a 2-year study, the potential of a participatory approach for solving this problem was investigated and applied in Fashafoeyeh aquifer in southern Tehran Province. This aquifer faces a critical situation of groundwater from point of view of quantitative and qualitative aspects. Firstly, five indicators were considered including agricultural efficiency, water resource efficiency, water governance, local participation, and economic factors. Then 23 farmers and agricultural landowners were selected based on age, education, and gender. A questionnaire was designed, surveyed, and filled out after interviewing them in several field trips to the site. The results of data analysis showed that 96% of farmers and landowners were highly motivated in the implementation of the participatory approach in ASR management. Moreover, 91% showed a high desire to decrease the groundwater withdrawal from wells. A high percentage of stakeholders had a tendency to participate in some aspects of ASR system. In the meantime, many farmers had a negative viewpoint about government supports. The results illustrate a correlation between agriculture efficiency with participation in the government's projects and implementation. Moreover, a correlation exists between water management in the field and participation in government's projects as well as local participatory. This research emphasises on proper planning through face-to-face dialogue with farmers and landowners. In this regard, they collaborate in a participatory approach, as well as a technical and social team to implement the aquifer storage and recovery management.

Aquifer Storage and Recovery Using Saline Aquifers: Hydrogeological Controls and Opportunities

Aquifer storage and recovery (ASR) is a valuable tool for managing variations in the supply and demand of freshwater, but system performance is highly dependent upon system-specific hydrogeological conditions including the salinity of the storage-zone native groundwater. ASR systems using storage zones containing saline (>10,000 mg/L of total dissolved solids) groundwater tend to have relatively low recovery efficiencies (REs). However, the drawbacks of low REs may be offset by lesser treatment requirements and may be of secondary importance where the stored water (e.g., excess reclaimed, surface, and storm waters) would otherwise go to waste and pose disposal costs. Density-dependent, solute-transport modeling results demonstrate that the RE of ASR systems using a saline storage zone is most strongly controlled by parameters controlling free convection (e.g., horizontal hydraulic conductivity) and mixing of recharged and native groundwater (e.g., dispersivity and aquifer heterogeneity). Preferred storage zone conditions are moderate hydraulic conductivities (5 to 20 m/d), low degrees of aquifer heterogeneity, and primary porosity-dominated siliclastic and limestones lithologies with effective porosities greater than 5%. Where hydrogeological conditions are less favorable, operational options are available to improve RE, such as preferential recovery from the top of the storage zone. Injection of large volumes of excess water currently not needed into saline aquifers could create valuable water resources that could be tapped in the future during times of greater need.

Managed Aquifer Recharge as a Strategic Storage and Urban Water Management Tool in Darwin, Northern Territory, Australia

Population growth and increased irrigation demand have caused a decline in groundwater levels that limit water supply in the Darwin rural area. Managed Aquifer Recharge (MAR) is a practical solution that can be adopted to augment stressed groundwater systems and subsequently increase the security of water supply. Aquifer storage capacity is considered to be the primary constraint to MAR where unconfined dolostone aquifers rapidly recharge during the tropical, wet season and drain again in the dry season. As a result, there is a general understanding that aquifers of this nature recharge to full capacity each wet season. However, the aquifer storage capacity and the potential for niche opportunities for MAR to alleviate declining groundwater levels has not previously been examined. This paper uses the Darwin rural area’s Proterozoic Koolpinyah Dolostone aquifer and the existing Koolpinyah Groundwater System to evaluate the prospects of MAR using both infiltration and injection techniques. Direct injection wells in an aquifer storage transfer and recovery (ASTR) scheme were favoured in this area, as injection wells occupy a smaller surface footprint than infiltration basins. This assessment suggested MAR during the early to mid-dry season could alleviate the impact of the dry season decline in groundwater levels in the Darwin rural area. The use of a larger aquifer storage and recovery (ASR) system (5,000,000 m3/year) was also assessed as a potentially viable technical solution in the northern part of the aquifer where it is understood to be confined. The ASR scheme could potentially be scaleable to augment the urban water system and provide strategic long-term storage. Consideration must also be given not only to the strategic positioning of the ASR water bank, but also to the hydrogeology of the aquifers in which the systems would be developed. Not all locations or aquifer systems can successfully support a strategic storage ASR system. Scheme-scale feasibility assessment of an ASR water bank is required. The study reported here is an early phase of a series of investigations that would typically be required to demonstrate the viability of any proposal to apply MAR to increase the reliability of conjunctive groundwater and surface water supplies in stressed water resources systems. It focusses on assessing suitable storage areas in a lateritic aquifer.

Use of Numerical Groundwater Modeling to Assess the Feasibility of Aquifer Storage and Recovery (ASR) in the Wadi Watir Delta, Sinai, Egypt

The lack of water resources in Egypt’s Sinai Peninsula is a major constraint for further socioeconomic development, and flash floods in this region can damage roads and infrastructure. The Wadi Watir basin is the main water source for the groundwater aquifer, which supplies fresh water to Nuweiba city, where demands for groundwater are increasing. The objective of this research was to assess the hydrogeological suitability of installing Aquifer Storage and Recovery (ASR) systems in the Wadi Watir delta by using numerical groundwater models. The developed models were used to evaluate the effects of hydrogeological and operational parameters on the recovery efficiency of ASR systems at five potential locations in the study area. As the estimation of recovery efficiency depends on the salinity of recovered water, the recovered water salinity limit was assumed as 150% of the injected water salinity, where 150% refers to the point at which recovery has ended because the concentration of recovered water reached 150% of that of injected water. The most important output from the model runs was that the recovery efficiency of these ASR systems ranged from 25% to 54% with a longitudinal dispersivity of 10 m, volume of injected water of 12,000 m3, and storage period of 180 days. The main conclusions are as follows. 1) Using coupled numerical groundwater flow and solute transport models is an effective tool for predicting the effects of mixing between injected water and ambient groundwater in ASR systems. 2) The groundwater aquifer in the study area is not suitable as strategic area for ASR systems because the thickness of the water storage layer is relatively small and the distance to the sea is very close; consequently, it is recommended that artificial recharge systems be developed with existing technology to replenish the groundwater aquifer in the Wadi Watir delta.

Intelligent performance evaluation of aquifer storage and recovery systems in freshwater aquifers

We present artificial neural network (ANN) based software for rapidly predicting the recovery effectiveness (REN) of aquifer storage and recovery (ASR) wells in fresh water aquifers. The REN performance criterion equals the amount of the water injected in an ASR well that is recoverable via the same well during a specified extraction period. The software circumvents the need to prepare and run computationally intensive simulations, by invoking ANN models as surrogate simulators. The paper presents the development of the ANN models and a graphical user interface (GUI) to facilitate using the ANN models and to perform sensitivity analysis. ANN inputs include all factors significantly affecting REN in freshwater aquifers. The software can evaluate REN in any ASR system in confined aquifers whose parameters are within the range of parameters used for training the ANNs in this study.

Estimating Aquifer Storage and Recovery (ASR) Regional and Local Suitability: A Case Study in Washington State, USA

Developing aquifers as underground water supply reservoirs is an advantageous approach applicable to meeting water management objectives. Aquifer storage and recovery (ASR) is a direct injection and subsequent withdrawal technology that is used to increase water supply storage through injection wells. Due to site-specific hydrogeological quantification and evaluation to assess ASR suitability, limited methods have been developed to identify suitability on regional scales that are also applicable at local scales. This paper presents an ASR site scoring system developed to qualitatively assess regional and local suitability of ASR using 9 scored metrics to determine total percent of ASR suitability, partitioned into hydrogeologic properties, operational considerations, and regulatory influences. The development and application of a qualitative water well suitability method was used to assess the potential groundwater response to injection, estimate suitability based on predesignated injection rates, and provide cumulative approximation of statewide and local storage prospects. The two methods allowed for rapid assessment of ASR suitability and its applicability to regional and local water management objectives at over 280 locations within 62 watersheds in Washington, USA. It was determined that over 50% of locations evaluated are suitable for ASR and statewide injection potential equaled 6400 million liters per day. The results also indicate current limitations and/or potential benefits of developing ASR systems at the local level with the intent of assisting local water managers in strategic water supply planning.

Assessing aquifer storage and recovery feasibility in the Gulf Coastal Plains of Texas

Study regionThe Gulf Coast and Carrizo-Wilcox aquifer systems in the Gulf Coastal Plains of Texas. Study focusAquifer storage and recovery is a water storage alternative that is underutilized in Texas, a state with both long periods of drought and high intensity storms. Future water storage plans in Texas almost exclusively rely on surface reservoirs, subject to high evaporative losses. This study seeks to identify sites where aquifer storage and recovery (ASR) may be successful, especially in recovery of injected waters, by analyzing publicly-available hydrogeologic data. Transmissivity, hydraulic gradient, well density, depth to aquifer, and depth to groundwater are used in a GIS-based index to determine feasibility of implementing an ASR system in the Gulf Coast and Carrizo-Wilcox aquifer systems. New hydrological insights for the regionLarge regions of the central and northern Gulf Coast and the central and southern Carrizo-Wilcox aquifer systems are expected to be hydrologically feasible regions for ASR. Corpus Christi, Victoria, San Antonio, Bryan, and College Station are identified as possible cities where ASR would be a useful water storage strategy.

Development of a new model tool for evaluating groundwater resources within the Floridan Aquifer System in Southern Florida, USA

The US Army Corps of Engineers (USACE) and the South Florida Water Management District (SFWMD) are partners in an ambitious plan to restore water flows throughout the Everglades ecosystem. An important component of the restoration plan involves storing excess stormwater deep underground in the Floridan Aquifer System using aquifer, storage and recovery (ASR) wells. In order to determine the optimal ASR system and to assess environmental impacts, USACE spent over 11 years and significant resources to develop a three-dimensional groundwater model of the Floridan Aquifer System covering a large portion of the Florida peninsula. This SEAWAT model is capable of evaluating changes in aquifer pressures and density-dependent flows in the entire study area. The model has been used to evaluate the Everglades ASR system already but could also be used by water managers for other important water resources studies in Florida including water supply estimates and adaptation to climate change. As part of an effort to make the model more readily available for other important studies, this study documents and summarizes the overall development of the SEAWAT model including a discussion regarding the intensive calibration and validation efforts undertaken during model development. The paper then demonstrates the use of the model using Everglades ASR project alternatives. Lastly, the paper outlines potential future uses of the model along with its overall limitations. Supplementary online resources are also included that provide researchers with further detail regarding the model development effort beyond the scope of this summary article as well as model development databases.

Transport modeling and multivariate adaptive regression splines for evaluating performance of ASR systems in freshwater aquifers

The study presents a procedure using solute transport and statistical models to evaluate the performance of aquifer storage and recovery (ASR) systems designed to earn additional water rights in freshwater aquifers. The recovery effectiveness (REN) index quantifies the performance of these ASR systems. REN is the proportion of the injected water that the same ASR well can recapture during subsequent extraction periods. To estimate REN for individual ASR wells, the presented procedure uses finely discretized groundwater flow and contaminant transport modeling. Then, the procedure uses multivariate adaptive regression splines (MARS) analysis to identify the significant variables affecting REN, and to identify the most recovery-effective wells. Achieving REN values close to 100% is the desire of the studied 14-well ASR system operator. This recovery is feasible for most of the ASR wells by extracting three times the injectate volume during the same year as injection. Most of the wells would achieve RENs below 75% if extracting merely the same volume as they injected. In other words, recovering almost all the same water molecules that are injected requires having a pre-existing water right to extract groundwater annually. MARS shows that REN most significantly correlates with groundwater flow velocity, or hydraulic conductivity and hydraulic gradient. MARS results also demonstrate that maximizing REN requires utilizing the wells located in areas with background Darcian groundwater velocities less than 0.03m/d. The study also highlights the superiority of MARS over regular multiple linear regressions to identify the wells that can provide the maximum REN. This is the first reported application of MARS for evaluating performance of an ASR system in fresh water aquifers.

Consequences and mitigation of saltwater intrusion induced by short-circuiting during aquifer storage and recovery in a coastal subsurface

Abstract. Coastal aquifers and the deeper subsurface are increasingly exploited. The accompanying perforation of the subsurface for those purposes has increased the risk of short-circuiting of originally separated aquifers. This study shows how this short-circuiting negatively impacts the freshwater recovery efficiency (RE) during aquifer storage and recovery (ASR) in coastal aquifers. ASR was applied in a shallow saltwater aquifer overlying a deeper, confined saltwater aquifer, which was targeted for seasonal aquifer thermal energy storage (ATES). Although both aquifers were considered properly separated (i.e., a continuous clay layer prevented rapid groundwater flow between both aquifers), intrusion of deeper saltwater into the shallower aquifer quickly terminated the freshwater recovery. The presumable pathway was a nearby ATES borehole. This finding was supported by field measurements, hydrochemical analyses, and variable-density solute transport modeling (SEAWAT version 4; Langevin et al., 2007). The potentially rapid short-circuiting during storage and recovery can reduce the RE of ASR to null. When limited mixing with ambient groundwater is allowed, a linear RE decrease by short-circuiting with increasing distance from the ASR well within the radius of the injected ASR bubble was observed. Interception of deep short-circuiting water can mitigate the observed RE decrease, although complete compensation of the RE decrease will generally be unattainable. Brackish water upconing from the underlying aquitard towards the shallow recovery wells of the ASR system with multiple partially penetrating wells (MPPW-ASR) was observed. This leakage may lead to a lower recovery efficiency than based on current ASR performance estimations.

Laboratory Study of Low-Flow Rates on Clogging Processes for Application to Small-Diameter Injection Wells

A new concept in aquifer storage and recovery (ASR) aims to lower costs by using gravity-induced infiltration and small diameter wells installed with direct-push technology. Such systems will have significantly lower injection rates than traditional ASR. Clogging is a major concern for ASR systems; however, previous investigations of injection well clogging assumed a high injection rate. To address this bias, this study investigates the potential for clogging in low-flow (<0.38 m3/min) ASR injection wells. The effects of low-flow rate injection on hydraulic conductivity and geochemistry were examined using laboratory columns packed with sand and gravel taken from an experimental low-flow ASR site. Changes in hydraulic conductivity and geochemistry were monitored over 17 days using two types of source water (treated surface water and native groundwater) at three different flow rates (Darcy velocities 1 m/d, 3 m/d, 5 m/d). The hydraulic conductivity of the lowest flow rate columns decreased below initial levels by at least one order of magnitude during the experiment. Observations of biofilm in effluent tubing suggest bacterial clogging reduced the hydraulic conductivity in medium and low flow treated surface water columns, but bacterial abundance was not quantified in this study. Clay dispersion was estimated to be an important process, partially reversing the bacterial clogging. Further understanding of clogging factors at low flow rates will aid in the selection of the most beneficial clogging prediction tests and pretreatment and redevelopment methods for low-flow ASR systems.

Aquifer pre-oxidation using permanganate to mitigate water quality deterioration during aquifer storage and recovery

Water quality deterioration is a common occurrence that may limit the recovery of injected water during aquifer storage and recovery (ASR) operations. This limitation is often induced by the oxidation of the reduced aquifer components by the oxygenated injection water. This study explores the potential of aquifer pre-oxidation using permanganate to improve the quality and volume of the recovered water during ASR. An experimental ASR column setup was developed to simulate the oxygenated water injection and recovery cycles. Undisturbed sediments from an anoxic brackish aquifer at a pilot ASR site were used. A series of 4 conventional ASR cycles injecting oxygenated tap (drinking) water was initially performed. These experimental trials showed a persistent Mn(II) production due to the dissolution of a Mn-containing carbonate that was triggered by pyrite oxidation reactions, as shown by the observed sulfate production. The rise in the Mn(II) concentrations above the drinking water standards would limit the recovery to 15–30% of the injected water without treatment of the recovered water. To a lesser extent, arsenic production resulting from the oxidative dissolution of pyrite posed a water quality threat to the ASR operation. Consequently, a second series of experiments was performed with an oxidation cycle using a dilute (5%) potassium permanganate (KMnO4) solution, aimed at deactivating the reactive phases responsible for the acidity-triggered Mn(II) production. This pre-treatment cycle improved the net recovery ratio to 84% during a conventional ASR cycle using oxygenated tap water. The extent of pyrite oxidation was decreased by 63% after the permanganate treatment. The increased competition for oxygen by the adsorbed Fe(II) and Mn(II) on the newly precipitated Mn-oxides combined with the pyrite “deactivation” by removal of the most reactive iron-sulfide crystals during the permanganate flush were primarily responsible for the observed decrease in the pyrite oxidation. The stability of the Mn-oxide precipitates was tested by flushing the columns with native groundwater before performing a final ASR cycle, simulating an increase in the reducing conditions during static periods in the ASR system. The Mn-oxide reduction by ferrous iron in the native groundwater released substantial amounts of Mn(II), which adversely affected the ASR operation in the subsequent cycle. In these cases, repeating the permanganate treatment should be considered.

A multi-period optimization model for conjunctive surface water–ground water use via aquifer storage and recovery in Corpus Christi, Texas

The present study develops and evaluates a decision support system for the conjunctive management of the current surface and proposed aquifer storage and recovery (ASR) facility of the city of Corpus Christi, TX using a simulation–optimization approach. The objective of the model is to maximize water storage in the surface and subsurface storage units while meeting (1) the freshwater inflow requirements to the Corpus Christi estuary and (2) the water demands of the city and its service area. The model is parameterized using streamflow data from the U. S. Geological Survey gauging stations on the Nueces River and its tributaries as well as long-term climatic data and regional hydrogeologic information. Results indicate that a single-well field ASR facility is capable of storing approximately 925 ha-m (7,500 ac-ft) of water over a 5-year period in the Evangeline Aquifer with a total potential storage of about 2,715 ha-m (22,000 ac-ft) of water over the jurisdictional area of the Corpus Christi Aquifer Storage and Recovery Conservation District. Surplus surface water sources are seen to contribute approximately 49–96 % of the water stored in the ASR during the simulation period. The remaining storage came from either Choke Canyon Reservoir or Lake Corpus Christi, which also resulted in a slight reduction in evapotranspiration in both reservoirs. The analysis indicates that the proposed ASR system is not limited on the supply side but multiple well fields may be required to increase the storage capacity within the aquifer.