Application Of Isotope Tracers Research Articles

Delineation of water flow paths in a tropical Andean headwater catchment with deep soils and permeable bedrock

AbstractTraditional hydrometric data combined with environmental tracers such as water stable isotopes contributes to improve the understanding of catchment hydrology. Nevertheless, the application of isotopic tracers in headwater catchments of the tropical Andes with deep soils and permeable parent material influenced by recent volcanism remains limited. In this study, the stable isotopic composition of precipitation, soil water, wetlands, and streamflow was studied to provide insights into the hydrology of a small tropical Andean catchment with deep and permeable volcanic soils, ash layers, and fractured bedrock resulting from Holocene volcanic activity. Although local precipitation forms under isotopic equilibrium conditions, the stable isotopic composition of precipitation is influenced by atmospheric moisture recycling processes. The spatial and temporal variability of isotopic signals and the analysis of inverse transit time proxies (ITTPs) of surface (streamflow) and subsurface (soil and wetlands) waters indicate that vertical flow paths through the deep volcanic ash soils are dominant across the catchment. The strongly damped isotopic composition of these waters points to high soil and wetlands water storage, increasing the transit time or age of stream water in the hydrological system. These findings indicate that water mobilizing through subsurface flow paths–that is, volcanic soils, ash layers, and cracks in the fractured bedrock resulting from Holocene volcanism–is the main contributor to streamflow generation. Comparison with previously published work from Andean catchments and other volcanic areas shows the diversity of hydrological conditions that can be found as a result of pedological and lithological differences shaped by volcanic activity. Therefore, site‐specific strategies may be needed to improve water resources management.

Application of isotopic tracers as a tool for understanding hydrodynamic behavior of the highly exploited Diass aquifer system (Senegal)

Summary The Diass horst aquifer system located 50 km east of Dakar (Senegal) is exploited in two main aquifers covered by a sandy superficial aquifer: the confined/unconfined Palaeocene karstic limestone and the confined Maastrichtian sandstone aquifer underneath. This system has experienced intensive groundwater abstraction during the last 50 years to supply increasing water demand, agricultural and industrial needs. The high abstraction rate from 1989 to 2009 (about 109,000 m 3 /d) has caused a continuous groundwater level decline (up to 30 m), a modification of the groundwater flow and salinization in parts of the aquifers. The objective of the study is to improve our understanding of the system functioning with regards to high pumping, identify the geochemical reactions that take place in the system, infer origin and timing of recharge by using mainly stable (δ 18 O, δ 2 H, 13 C) and radioactive ( 3 H and 14 C) isotopes. Water types defined in the Piper diagram vary in order of abundance from Ca–HCO 3 (65%), Ca/Na–Cl (20%), Na–HCO 3 (3%) and Na–Cl (12%). Values of δ 18 O and δ 2 H for the superficial aquifer range between −5.8 and −4.2‰ and between −42 and −31‰, respectively. For the Palaeocene aquifer they range from −5.8 to −5.0‰ and from −38 to −31‰, respectively; values in the Maastrichtian aquifer are between −5.9 and −4.3‰ for δ 18 O and −38 to −26‰ for δ 2 H. Plotted against the conventional δ 18 O vs δ 2 H diagram, data from the upper aquifer exhibit a dispersed distribution with respect to isotopic fractionation while those of the Palaeocene and Maastrichtian aquifers are aligned parallel and slightly below/or on the Global Meteoric Water Line (GMWL) evidencing ancient waters which had evaporated during infiltration. The low tritium (generally 14 C (0.7–57.2 pmc) contents indicate predominance of older water being recharged during the Pleistocene and Holocene periods. However, few boreholes which exhibit high tritium (1.2–4.3 TU) and 14 C (65.7–70.8 pmc) values indicate some mixture with recent water likely through faulting and vertical drainage from the upper to deeper aquifers as well as lateral flow along flow paths to the piezometric depressions created by pumping.

Application of isotope tracers in continental scale hydrological modeling

Isotope tracers are widely used to study hydrological processes in small catchments, but their use in continental-scale hydrological modeling has been limited. This paper describes the development of an isotope-enabled global water balance and transport model (iWBM/WTM) capable of simulating key hydrological processes and associated isotopic responses at the large scale. Simulations and comparisons of isotopic signals in precipitation and river discharge from available datasets, particularly the IAEA GNIP global precipitation climatology and the USGS river isotope dataset spanning the contiguous United States, as well as selected predictions of isotopic response in yet unmonitored areas illustrate the potential for isotopes to be applied as a diagnostic tool in water cycle model development. Various realistic and synthetic forcings of the global hydrologic and isotopic signals are discussed. The test runs demonstrate that the primary control on isotope composition of river discharge is the isotope composition of precipitation, with land surface characteristics and precipitation-amount having less impact. Despite limited availability of river isotope data at present, the application of realistic climatic and isotopic inputs in the model also provides a better understanding of the global distribution of isotopic variations in evapotranspiration and runoff, and reveals a plausible approach for constraining the partitioning of surface and subsurface runoff and the size and variability of the effective groundwater pool at the macro-scale.

Ammonium transport and reaction in contaminated groundwater: Application of isotope tracers and isotope fractionation studies

Ammonium (NH4+) is a major constituent of many contaminated groundwaters, but its movement through aquifers is complex and poorly documented. In this study, processes affecting NH4+ movement in a treated wastewater plume were studied by a combination of techniques including large‐scale monitoring of NH4+ distribution; isotopic analyses of coexisting aqueous NH4+, NO3−, N2, and sorbed NH4+; and in situ natural gradient 15NH4+ tracer tests with numerical simulations of 15NH4+, 15NO3−, and 15N2 breakthrough data. Combined results indicate that the main mass of NH4+ was moving downgradient at a rate about 0.25 times the groundwater velocity. Retardation factors and groundwater ages indicate that much of the NH4+ in the plume was recharged early in the history of the wastewater disposal. NO3− and excess N2 gas, which were related to each other by denitrification near the plume source, were moving downgradient more rapidly and were largely unrelated to coexisting NH4+. The δ15N data indicate areas of the plume affected by nitrification (substantial isotope fractionation) and sorption (no isotope fractionation). There was no conclusive evidence for NH4+‐consuming reactions (nitrification or anammox) in the anoxic core of the plume. Nitrification occurred along the upper boundary of the plume but was limited by a low rate of transverse dispersive mixing of wastewater NH4+ and O2 from overlying uncontaminated groundwater. Without induced vertical mixing or displacement of plume water with oxic groundwater from upgradient sources, the main mass of NH4+ could reach a discharge area without substantial reaction long after the more mobile wastewater constituents are gone. Multiple approaches including in situ isotopic tracers and fractionation studies provided critical information about processes affecting NH4+ movement and N speciation.

Mechanisms of Isomerization of Sym-Monothiopyrophosphates

Abstract The detailed mechanistic studies of the thiolo-thiono isomerization of monothiopyrophosphate 1 is presented. The application of isotopic tracers and isotopic effects kinetic methods provide evidence for two distinct mechanisms: SN2(P) reaction induced by external anionic species and the dissociative isomerization proceeding via ion pairs and ions.