Appearance Of Cracks Research Articles

Boric acid-free electrodeposition process and solar–thermal energy conversion of and Ni-carbon black nanocomposite coatings

AbstractThis work focuses on the development of a multi-layered system, of bright nickel electrodeposited on a steel substrate, and a second layer composed of black nickel either with or without carbon black nanoparticles (CB NPs), aiming for an efficient conversion of incident solar radiation into heat, for the fabrication of solar collectors. The structural characterization, revealed that the bright nickel film was composed of metallic nickel, while the black coatings contained amorphous nickel compounds. SEM analysis unveiled the presence of pinholes on the surface of the bright nickel film, suggesting that the black nickel coating was ineffective in sealing them. The appearance of cracks with the increase in the deposition time was observed. With the nanocomposite of black nickel and CB NPs, these cracks can be avoided and the pinholes sealed. The CB NPs were found to reduce reflectance, enhancing the conversion of solar energy into heat. Graphical abstract

Experimental Studies of Corrosion Resistance of Welded Seams of Steel Structures with a High Sulfur Content in Surface Layers Using Modern Methods of Modeling

Analysis of literature sources and empirical data indicate a variety and a large volume of experimental material, which often characterizes the uncertainty and contradiction of information regarding the effect of sulphur and manganese on the corrosion behaviour of steels obtained using traditional methods. This leads to the need to search for new, alternative methods for its effective analysis. The task of assessing and predicting the corrosion properties of structural steels is a key one in the general problem of managing the operational reliability of welded metal structures and equipment for the chemical, metallurgical, oil and gas, mining and other industries. The possibilities of its solution consist of using new information technologies, a component of which is intelligent means of information processing, such as artificial neural networks (ANN). The use of ANN makes it possible to create qualitatively new hardware and software that significantly expand the classes of emerging problems and increase the efficiency of analysis and forecasting. In the process of long-term operation of metal structures in many industrial industries, the metal is in direct contact with sulfur-containing agents at high temperatures. This leads to the saturation of the surface layer of the metal with sulfur with a concentration of up to 0.6%, which further makes it impossible to carry out repair and welding operations due to the formation of hot cracks. It was found that adding metallic manganese into the electrode coating in an amount of 20-25% significantly increases (4-5 times) the resistance against the formation of hot cracks. Sulfur content in the deposited metal has the opposite effect on the appearance of hot cracks. So, with a sulfur content of 0.042% and more, the resistance of the metal against the formation of hot cracks decreases sharply. It is shown that an increase in the content of metallic manganese in the electrode coating significantly reduces the content of dissolved sulfur in the deposited metal. Moreover, this tendency is typical for steels with different sulfur content in the surface layers and with different service life. For example, for steel with a service life of 20 years, the initial sulfur content in the surface layer of the metal (up to 1 mm) was about 0.52%. Adding metallic manganese in the coating of electrodes in an amount of 20-25% made it possible to reduce the sulfur content in the deposited metal to 0.03-0.045%, i.e. 12.6-17.3 times. In addition, the corrosion rate decreases with an increase in the content of metallic manganese in the electrode coating. The lowest corrosion rate for all steels involved in the research was established at 20-25% manganese content in the coating.

Effects of Acetylation on the Morphological, Physicochemical, and Thermal Properties of Enterolobium cyclocarpum Starch

AbstractThis study investigates the impact of acetylation treatment on Enterolobium cyclocarpum (Parota) starch, focusing Morphological, Physico‐chemical and thermal impact induced by varying acetylation levels. The research employed scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) to examine the structural and thermal alterations resulting from acetylation. These analyses also evaluated the starch's thermal stability. Through titration, the degree of substitution and acetyl group content were quantified, demonstrating significant morphological transformations in the starch, such as increased particle size and the appearance of surface cracks on the granules. The study revealed that the degree of substitution, which changes with the duration of acetylation, markedly influences the starch's physicochemical properties, including hydrophobicity and thermal stability. Initially, acetylation reduced the gelatinization temperature, suggesting a decrease in the energy required for gelatinization. Over longer acetylation periods, however, the gelatinization temperature increased, likely due to enhanced crystallinity or molecular reorganization. These findings indicate that acetylated Parota starch has potential applications in the food industry as an encapsulating agent and in the thermoplastics industry as a plasticizer, dependent on the level of acetylation. This research underscores the utility of specific chemical modifications to adapt starch properties for various industrial applications.

Research on Deterioration Behavior of Magnesium Oxychloride Cement Under High Humidity and High Temperature.

To clarify the deterioration behavior of magnesium oxychloride cement (MOC) under conditions of high humidity and high temperature, we first placed MOC slurry samples in a simulated environment with a relative humidity of 97 ± 1% and a temperature of 38 ± 2 °C; then, we observed the changes in the macroscopic and microscopic morphology, water erosion depth, bulk density, phase composition, and mechanical properties of the samples. The results show that, over time, under the promotion of high temperature, water molecules infiltrate the MOC samples. This results in the appearance of cracks on the macroscopic surface of the MOC samples due to the volume expansion caused by the hydrolysis of P5 (5Mg(OH)2·MgCl2·8H2O) and the hydration of unreacted active MgO in the samples. The microscopic morphology of the samples changes from needle/gel-like, to flake-like, and finally leaf-like. Simultaneously, the major phase composition turns into Mg(OH)2. Since the structure of the samples becomes looser and the content of the main strength phase decreases, the overall compressive strength and flexural strength are both reduced. The compressive strength of the MOC slurry samples (0 day) is 93.2 Mpa, and the flexural strength is 16.4 MPa. However, after 18 days of treatment, water molecules reach the center of the MOC samples, and the MOC samples completely lose their integrity. As a result, their compressive and flexural strengths cannot be obtained.

Model test study on the dynamic failure process of tunnel surrounding rocks in jointed rock mass under explosive load

The presence of joints can significantly reduce the integrity and stability of an engineering rock mass. Under dynamic loads, such as from blasting excavation, the key blocks divided by joints may be destabilized and prone to sliding, potentially leading to engineering geological disasters like rockbursts. To study the dynamic instability process, similar materials for the rock mass and joints were developed based on the similarity theory, and a tunnel model in the jointed rock mass was constructed. Subsequently, a detonating fuse was used to generate a dynamic load, and the dynamic instability process of the tunnel surrounding rock in the jointed rock mass under explosive load was studied using the geotechnical multifunctional testing device. The deformation characteristics and dynamic instability process of the tunnel surrounding rock were analyzed using acceleration sensors, resistance strain gages, linear variable displacement transducers and motion camera. The study shows that the acceleration at the tunnel vault is significantly greater than at the straight wall and floor under blast loads, with differences reaching an order of magnitude. Acceleration waveforms were classified into three categories based on peak characteristics, explained through the propagation of explosive stress waves. Additionally, strain and displacement at the tunnel arch were also significantly greater than in other areas, indicating more severe stress concentration and dynamic damage at the arch, necessitating reinforced support in tunnel excavation. The entire dynamic instability process of the tunnel surrounding rock was successfully recorded using a motion camera. The dynamic failure process was divided into several phases, the appearance of cracks on the joint surface, particle ejection accompanied by the dropping of jointed blocks, a significant drop of the jointed blocks, and return to calm. The dynamic failure modes include the dropping and rotation of jointed blocks, local particle ejection, and shear cracks on jointed block.

Modelling of cracking during beam oscillation laser welding of a creep-resistant nickel alloy

During high power laser welding of Inconel 740H, horizontal solidification cracks form at locations between approximately 70–80% of the weld depth. With the integration of circular beam oscillation, the laser energy density distribution and underlying thermo-mechanical conditions were altered. By coupling three-dimensional heat transfer, fluid flow, and stress modelling tools, the role that circular beam oscillation plays in the formation of the strain rates and stresses driving this cracking phenomenon was identified. While the addition of a circular oscillation pattern appeared to lower the stress levels along the solidification front, it did not eliminate the appearance of horizontal cracking. Only when the beam amplitudes reached 1.6 mm did solidification cracking disappear, but the weld depths were also significantly reduced.

Exploring Fatigue Crack Initiation in Helical Gears: Impact of Carburization and Frictional Influences

A computational model is presented to analyze the fatigue crack initiation period in helical gears, incorporating considerations for heat treatment via carburization and friction effects. The aim is to determine the number of stress cycles necessary for the initiation and growth of initial cracks, while investigating the impact of dynamic behavior. This study employs a dynamic gear model with two degrees of freedom in torsion, developed using MATLAB, and incorporates the Papadopoulos criterion for fatigue analysis. The computational results are benchmarked against the strain-life method. The findings underscore the significant influence of the friction coefficient between surfaces, heat treatment, and dynamic loads on the growth of initial fatigue cracks. For instance, with a friction coefficient (μ) of 0.5, the initial crack forms on the tooth surface (y=0) in both methods, with the (ε-N) method suggesting 28-65 cycles and the Papadopoulos criterion indicating 101-156 cycles. The latter accounts for the greater influence of residual stresses. Additionally, untreated gears exhibit a minimum number of loading cycles for initial crack appearance at 1.07 × 104 cycles. In contrast, carburized gears demonstrate an extended lifespan, requiring 1.45 × 105 loading cycles for crack initiation in our example. This emphasizes the efficacy of carburization in enhancing gear durability.

Prediction of mass adhesive damage based on the Rousselier model: Experimental and numerical analysis

The study of the mechanical strength of adhesives remains an important area of research for researchers. These adhesives must be prepared in the form of mass test pieces to characterize them under different mechanical stresses. However, during the preparation of the test pieces several defects are likely to be present, namely air bubbles, cavities, or impurities. The behavior of the adhesive differs depending on the presence of one of these defects and, in most cases, the real behavior of the adhesive is not precisely known. For this purpose, several tests are necessary to have a close estimate of the adhesive's behavior. To numerically model the behavior of the adhesive it is necessary to consider the presence of these types of defects. This paper proposes a damage criterion based on the Rousselier model, which describes the damage due to crack growth from the presence of cavities in an adhesive, assumed as a ductile material. The proposed damage model was developed and implemented in a user-defined subroutine in the ABAQUS finite element code. Other damage models integrated into ABAQUS were used. In addition, the extended finite element method (XFEM) was used in the numerical simulations to study automatic damage modelling by the appearance and propagation of cracks in highly stressed areas. The main objective of this work is an analysis by the finite element method to determine the elastoplastic behavior coupled with the damage in the mass adhesive, considering the size, position, and shape of the defect (porosities) by the proposed models. Initially, experimental tests were carried out on mass specimens of adhesive to characterize the tensile response and to determine their mechanical properties depending on the position and size of the defect, which may exist in the specimen following its fabrication. The numerical results were validated by uniaxial tensile tests on the mass adhesive. Comparisons with the damage models integrated into ABAQUS have proven their effectiveness in predicting the behavior of the adhesive in the presence of a cavity.

Influence of relative distance between fault and tunnel on dynamic response of tunnel: An experimental and numerical investigation

The effect of earthquakes on deep tunnels near faults has always been a significant issue in underground engineering research. The presence of fault fracture zones tends to intensify the seismic response of tunnels. On the basis of the Xianglushan tunnel project, the influence of relative distance between fault and tunnel on the dynamic response of tunnel was investigated utilizing laboratory test, shaking table test, and numerical simulation. The results indicated that as the relative distance between the fault and the tunnel increased, the peak acceleration and peak strain of the tunnel first increased and then decreased. The results of numerical simulations and experimental tests demonstrated that changes in relative distance had a significant influence on the dynamic response of the tunnel. Since the Xianglushan tunnel is located near the fault, the superposition of seismic load and the residual tensile and compressive stress led to the appearance of through-type cracks, which eventually resulted in large deformation or even failure. The left arch springing and left spandrel of the tunnel closer to the fault were prone to failure first. This study provides a reference for the seismic dynamic response and failure mechanism of near-fault tunnels.

СТІЙКІСТЬ ЗАЛІЗОБЕТОННИХ СТІЙОК ПРИ КОРОТКОЧАСНІЙ ТА ТРИВАЛІЙ ДІЇ НАВАНТАЖЕННЯ

The behavior of hinged support at the ends of the rack with initial bending under the action of load is considered. Spring rods are arranged symmetrically. The rack has an initial bend, compressed by forces constant in time. All real elements have one or another imperfections in the form of technological bends, therefore, they begin to bend from the very beginning of the load. The load, when it is exceeded even by an infinitesimally small amount, there is a loss of stability of this type of deformation, is called critical. In the calculation of stability under the long-term action of external forces, it is necessary to determine the load, at which the rate of movement in time monotonically decays. Solving the problem in such a setting is acceptable for systems, the development of movements of which in time leads to a change in the stress state. This condition for a compressed rack is fulfilled only in the presence of initial imperfections (initial bending, off-center application of compressive force, etc.). When solving the problems of the theory of stability, taking into account the creep of the material plays an important role. Creep can be limited in time or unlimited. When solving the problem of the stability of racks with initial imperfections, made of a material that has creep and reinforced with elastic rods, the following assumptions are made: 1) the hypothesis of flat sections is considered valid; 2) the deformations of the creeping material and the elastic rods at the points of contact are the same; 3) the modulus of deformations during stretching and compression are equal; 4) the creep material works in the stretched zone without the appearance of cracks. The relationship between deformations and elasticities in the material of the rack is established by a formula based on the linear relationship between deformations and elasticities. The creep rate of concrete is based on the hereditary theory of aging. In the work, an integro-differential equation was obtained - the equation of slow motion of the rod, expressions were obtained for the study of bends in any at what point in time, the formula for determining the critical force with long-term load action is derived.

Experimental investigation of the compressive and shear resistance of laminated steel-reinforced glass beams

This paper presents an experimental investigation into the compressive and shear resistance of triple-layered laminated steel-reinforced glass beams. Two types of tests are performed: (a) local compressive tests (force over a support) and (b) bending tests (force close to a support). In total, six local compressive tests and eight bending tests are performed. Overall, beams with a shear span-to-effective depth ratio (a/d) approximately equal to 0, 0.63, and 1.0 are tested. Two different types of flexural reinforcement are used separately: solid (S) and hollow (H) reinforcement. The behaviour of the outer glass panes, and top and bottom reinforcement is monitored using strain gauges and Digital Image Correlation (DIC). The test results are elaborated in terms of load-displacement curves, the evolution of strains and crack patterns. Three failure modes are observed: yielding of the reinforcement (PF), crushing of glass (CF), and rupture of the reinforcement (RR). Shear failure occurred due to the crushing of glass in the compressed diagonal strut in the shear span. It was found that the shear resistance increases with a smaller shear span-to-effective depth ratio and stronger reinforcement. The dominant shear transfer mechanism was the direct strut action. It was found that the post-fracture capacity had a relatively constant value for all the tests with a slight increase for smaller a/d. The actual tensile strains in the bottom reinforcement measured by DIC are compared with the calculated strains based on the curvature of uncracked and cracked cross-sections, assuming plane section behaviour. It was observed that the actual strains are systematically larger than the calculated ones because, in reality, the section does not remain plane. After the appearance of the first crack, the beams essentially behave like strut-and-tie systems, where the strut is the diagonally compressed laminated glass and the tie is the bottom reinforcement.

CERTAIN ASPECTS OF RESEARCH WORK IN THE RESTORATION OF THE KYIV VELODROME

Kyiv Velodrome is the oldest sports facility in Ukraine and one of the oldest in Europe. In 2016-2017, the restoration of its track, administrative building, construction of an underground parking lot and reorganization of the adjacent territory were carried out. As part of the scientific and technical support, an examination of the velodrome track was carried out to determine all existing defects and damages and as a result, recommendations for their elimination were provided. In particular, solutions have been developed to repair cracks and recommended measures are aimed at preventing their appearance in the future. Also, within the scope of research work, some experimental studies were carried out with the designed constructions of the bicycle track for their compliance with the technical documentation and to establish durability (in laboratory conditions). The article analyzes and researches the structural and technological solutions proposed in the project documentation for the restoration and arrangement of the bicycle track, providing solutions and recommendations that will ensure the necessary quality and the project's design life. Thus, recommendations are being considered to reduce the likelihood of the appearance of new cracks and the development of existing ones on the track.

Effects of folded fissure properties on tunnel model failure: Experiments and numerical simulations

Natural folded fissures commonly exist rather than simple straight fissures in rock masses surrounding tunnels. The presence of folded fissures significantly affects the fracture processes and failure modes of tunnel structures, thereby affecting their safety and stability. However, the research in this area is limited. Given this, this study fabricates city-gate section tunnel specimens containing folded fissures of various dip angles (α) and orientation angles (β), utilising 3D sand printing with sand and furan resin as matrix materials. Uniaxial compression fracture tests were conducted at a loading rate of 0.3 mm/min on these specimens using a digital image correlation technique to assess the impact of folded fissures on the mechanical properties and failure modes of the tunnel structures. Additionally, the improved smoothed particle hydrodynamics (SPH) method was used for damage evolution simulations during interactions between folded fissures and tunnels, and the simulation results were compared with the experimental results to verify the correctness of the method. The results show that for folded fissures, wing cracks and anti-wing cracks initiate not only from the ends but also from the bends of the fissures, whereas for straight fissures, they appear only at the fissure ends. Except for β = 0°, the interaction between folded fissures and tunnels generally results in the formation of a crack connecting the folded fissure upper end with tunnel, and the connection position varies with β. Different β values of folded fissures also influence the appearance and morphologies of top major cracks, underside major cracks, side cracks, and corner cracks around tunnels. As α increases, the overlap point of the crack and the tunnel moves from the tunnel corner to the tunnel crown. Moreover, folded fissures significantly affected the peak strength of the tunnel structures. As β increases, the peak strength first decreases, then increases, and finally decreases, reaching a minimum of 3.58 MPa at β = 90°. However, the peak strength differences are not evident under different α values. Finally, the influence of folded fissures on the cracking mechanism of the tunnel models is discussed in detail. This study provides insights into the impact of folded fissures on tunnel fracture modes and offers a reference for the application of SPH to reveal the underlying failure mechanisms of tunnel structures.

Characteristics of soil moisture transport in the aeration zone of subsidence areas under the disturbance of coal seam mining

High-intensity coal mining has induced a series of ecological and environmental problems issues, including surface subsidence, the development of ground cracks, and the deterioration of vegetation. The disruption of water circulation systems induced by mining, such as perched groundwater, groundwater of aeration zone, and phreatic water, is the root cause of vegetation withering. The aeration zone serves as a crucial nexus in the process of water cycling and exerts a significant influence on soil fertility. To explore the characteristics of soil moisture transport in subsidence areas under the mining disturbance, on-site monitoring of the size and morphology characteristics of subsidence areas and ground cracks was conducted in typical mining areas in Inner Mongolia, China. Subsequently, a typical soil moisture transport model was constructed in subsidence areas, the soil moisture transport patterns under the influence of different types of subsidence and cracks were analyzed, and the influence law of soil damage on soil moisture transport in the aerated zone was clarified. The results indicate that (1) Based on the occurrence and distribution characteristics of subsidence cracks, the subsidence area can be divided into tension zone, compression zone, and neutral zone; the ground cracks are divided into permanent tension cracks and dynamic cracks. (2) The drought stress effect of soil in the subsidence area is significant. Under the influence of soil structure variation, the water-holding capacity of the soil in the subsidence area decreases, and the soil moisture dissipation is strong. The soil moisture transport rate in the aeration zone of the subsidence area is ranked as follows: tension zone > neutral zone > compression zone. (3) Ground cracks can exacerbate the soil moisture transport rate in the aeration zone. After 15 d of crack appearance, the soil moisture transport reaches a relatively stable state, and the soil moisture transport rate in the surface layer of the crack is the fastest, and the loss of soil moisture is the most significant. The crack effect is not significant beyond 100 cm from the crack. This study provides a theoretical and data support for soil and vegetation remediation in mining subsidence areas.

Creep fatigue interaction at high temperature in C630R ferritic/martensitic heat-resistant steel

The study investigated the creep-fatigue interaction behavior, fracture mechanism, and microstructure evolution of C630R ferritic/martensitic heat-resistant steel at 630 °C and 1% strain amplitude. The results indicate that C630R ferritic/martensitic heat-resistant steel exhibits noticeable cyclic softening behavior, with a decrease in the softening ratio from 0.46 to 0.40 as loading time increases. Microstructure evolution was examined using optical and scanning electron microscopes, revealing the appearance of secondary cracks on the longitudinal section of the sample. These cracks exhibited a curved expansion trend with multiple deformations and highly bifurcated micro-cracks at a low loading time of 30s. However, when the load holding time was increased to 300s, the fatigue cracks tended to expand in a straight line with fewer branches. Furthermore, the observed crack growth path under different loading times showed enrichment in Fe and Cr, with the crack tip containing Cr oxide, which helped prevent fatigue crack propagation. As the loading time increases, the rise in crack closure resulting from oxidation leads to a decrease in crack propagation. Electron backscatter diffraction observation revealed the formation of numerous substructures and recrystallized grains after varying holding times, enhancing the material's resistance to crack propagation. Moreover, the study found that with increasing load dwell time, the deformed grains decreased, and substructural grains became dominant (57.68% and 62.77% under 30s and 300s, respectively). This increased crack resistance resulted in shorter secondary cracks under prolonged load retention, with the secondary crack length decreasing from 146.36 μm at 30s loading time to 109.09 μm at 300s loading time. Additionally, the kernel misorientation angle value decreased significantly after different loading times, leading to a higher likelihood of cracks or holes forming in regions with high KAM values, where low-angle grain boundaries were formed.

Thermal properties and microstructure of Al–Sn alloys

The Al–Sn alloys feature excellent wear and corrosion resistance, along with good mechanical properties. They are mostly used as bearing materials. However, the application of these alloys as phase change materials (PCMs) for thermal energy storage (TES) has recently been suggested. To assess the adequacy of these alloys in a given area, a detailed evaluation of their thermal properties is required. In the present study, Al–Sn alloys with 11.7, 22.4, 32.8, 41.1, and 53.4 at.% Sn were produced by melting of pure metals. The melt was continuously stirred to avoid segregation, after which casting was carried out in a stainless steel mold. The obtained ingots had a homogeneous microstructure without the appearance of cracks and pores. The thermal diffusivities of the solid Al–Sn alloys in the temperature interval 25–150 °C were measured using the light flash method. The densities at room temperature were measured by the Archimedes method, and the specific heat capacities at different temperatures were calculated using the calculation of phase diagrams (CALPHAD) method. Then the thermal conductivities for studied Al–Sn alloys were obtained by the specific conversion equation. The phase transition temperatures and related heat effects were studied using differential scanning calorimetry (DSC). Variations of thermal conductivity with composition and temperature were determined as well as variation of latent heat of fusion with alloy composition. Moreover, the microstructures and phase compositions of the alloys were examined using scanning electron microscopy (SEM) combined with energy dispersive spectrometry (EDS). The present research results provide important information on the thermal properties and microstructure of the Al–Sn alloys for designing new PCM for thermal energy storage.

Experimental and theoretical study on the shear behaviors of an innovative precast UHPC composite beams reinforced with inverted T-shaped steel

The innovative precast composite beam consisted of reinforced UHPC beam and inner inverted T-steel shape (forming ITSRU composite beam) is proposed for the marine structures serviced in harsh environment and subjected to complicated loading conditions. The novel composite beam possesses the advantages of lightweight, high strength and ductility, enhanced durability. To study the shear behaviors of ITSRU beams, a shear test program consisted of seven composite beams were conducted to study the effects of shear span-to-depth ratio, steel fiber volume fraction, stirrup ratio and inverted T-steel web thickness. UHPC used in this paper possess compressive strength more than 125 MPa, ultimate tensile strength more than 8.9 MPa and ultimate tensile strain more than 2256με. The inverted T-steel and steel rebar used in this paper have grades of Q355 and HRB400, respectively. A segmented loading control method was used in the shear test, in which a forced-controlled with a rate of 20 kN/min was used before the beam yield and the displacement control was implemented at a rate of 0.5 mm/min after reaching the yield load. The test results revealed that the ITSRU beams exhibited admirable deformation capacity and considerable residual shear capacity even for the composite beam with shear span-to-depth ratio of 1.0. The increasing of stirrup ratio, steel fiber volume fraction and inverted T-steel web thickness could improve the shear resistance and the ductility as well as suppress the appearance of the diagonal shear critical cracks. Based on the test results, an analytical shear model considering the contributions of UHPC in shear compression region, stirrups, steel fibers and inverted steel web was developed to predicted the shear resistance of ITSRU beams. The interaction mechanism of the different components in the ITSRU beams was considered in the analytical shear model. The accuracy of the developed calculation method was verified by the test results.

Hierarchical Significance of Environment Impact Factor on the Sand Erosion Performance of Lightweight Alloys.

This paper addresses the challenge of ranking the factors that affect the erosion resistance of lightweight alloys, with a specific focus on aluminum alloys. A three-factor, four-level orthogonal experimental design was employed to examine the influence of various sand particle sizes, erosion speeds, and sand concentrations on the abrasion qualities of these alloys. Parameters such as mass loss, depth, residual stresses, and failure mechanisms were assessed to determine erosion performance. Analysis of variance (ANOVA) and regression analysis of the three key factors were performed. Our findings resulted in an erosion rate formula: erosion rate = 0.679 sand particle size +0.067 sand concentration -0.002 erosion velocity +0.285. Our findings indicate that particle size is the most significant factor affecting erosion rate, with sand concentration and erosion velocity being secondary factors. The failure mechanism reveals that larger sand particles tend to produce deeper slides, and higher sand concentrations result in an increased number of slides. A lower concentration leads to the appearance of erosion pits. And the test conditions of high concentration and low velocity lead to more serious brittle fractures of the substrate, often accompanied by the appearance of cracks.

Effect of aromatization degree of mesophase pitch on cracks and mechanical properties of mesophase pitch-based carbon fibers

The aromatization degree of MP is closely related to the orientation of carbon fibers, which determines their properties. To investigate the effect of the aromatization degree of MP on the properties of carbon fibers, this study prepared MP with varying aromatization degrees using the self-pressurization/N2-blowing two-stage thermal condensation method with refined coal tar pitch as raw material. Mesophase pitch-based carbon fibers (MPCFs) were obtained through melt spinning, pre-oxidation, and carbonization processes. Results show that the C/H atomic ratio rises from 2.067 to 2.318 as the aromatization degree of MP increases. After carbonization at 1300 ℃, the microcrystalline structure of MPCFs becomes ordered, with obvious axial radiation in the cross-section. The carbon layers in MPCFs are tightly stacked in parallel, significantly improving tensile strength and modulus. When the C/H atomic ratio of MP exceeds 2.262, the resulting MPCFs exhibit a maximum tensile strength of 1389 MPa and a maximum tensile modulus of 167 GPa. However, when the C/H atomic ratio of MP exceeds 2.318, the excessive aromatization degree makes the MPCFs structure prone to cracking due to circumferential volume shrinkage, and the appearance of cracks reduces the tensile strength of MPCFs.

Effect of gamma radiation on the crack pattern of a styrene-acrylic emulsion dry droplet

We present findings on the influence of gamma radiation on the crack pattern of dried drops of an aqueous styrene-acrylic emulsion. An increase in the dose of gamma radiation reduces the number of cracks and expands the edge of the dried droplet. Furthermore, gamma radiation induces a reduction in the branching of the crack pattern and an increase in the frequency of cracks, with a magnitude comparable to the width of the edge of the dried droplet. The results of the infrared analysis indicated that the micelles surrounding the styrene-acrylic copolymer in the emulsion exerted a protective effect, preventing indirect damage caused by radicals formed due to water radiolysis. The results of the zeta potential and particle size measurements demonstrated that gamma radiation caused an increase in the average size of the micelles, a widening of the size distribution, and a redistribution of surface charges. Doses above 100 kGy induce a loss of emulsion stability. The effects of gamma radiation on the crack patterns were interpreted by considering the dynamics of micelle deposition at the edge of the drop during drying and the appearance of mechanical instabilities in the deposit that lead to cracks. The larger micelles produced due to gamma radiation on the emulsion modify the microstructure formation at the edge of the dried drop, thereby alleviating the formation of mechanical stresses that result in the appearance of cracks.