Apparent Peak Research Articles

Effects of nitrogen fertilizer application on the physicochemical properties of foxtail millet (Setaria italica L.) starch

The use of nitrogen fertilizer is a crucial agronomic practice to increase crop output and quality. This study investigated the impact of five nitrogen application levels (0, 60, 135, 210, and 285 kg N/hm2) on the physicochemical properties of foxtail millet (FM) starch. Optimal nitrogen application (210 kg N/hm2) significantly increased L*, a*, and b* values, water and oil absorption capacity, water solubility, and swelling power of starch. The number of small starch granules increased as the nitrogen application rate increased, but the granule morphology and typical A-type pattern did not change among the treatments. Nitrogen application increased the relative crystallinity and ordered structure, resulting in a higher gelatinization enthalpy. Compared to the control group (7.02 J/g), the enthalpy increased by 21.94 %, 66.38 %, 73.50 %, and 103.28 % under the nitrogen application rates, respectively. Moreover, nitrogen application greatly increased the percentage of A and B3 chains while it lowered the apparent amylose content, peak viscosity, and final viscosity. The effects of 210 and 285 kg N/hm2 treatments on the water solubility and swelling power, water and oil absorption, and light transmission of starch were greater compared to the 60 and 135 kg N/hm2 treatments. These results indicate that nitrogen fertilization significantly affects the physicochemical properties of FM starch.

Challenges in the analysis of pharmaceutical lentiviral vector products by orthogonal and complementary physical (nano)particle characterization techniques

Lentiviral vectors (LVVs) are used as a starting material to generate chimeric antigen receptor (CAR) T cells. Therefore, LVVs need to be carefully analyzed to ensure safety, quality, and potency of the final product. We evaluated orthogonal and complementary analytical techniques for their suitability to characterize particulate matter (impurities and LVVs) in pharmaceutical LVV materials at development stage derived from suspension and adherent manufacturing processes. Microfluidic resistive pulse sensing (MRPS) with additional manual data fitting enabled the assessment of mode diameters for particles in the expected LVV size range in material from adherent production. LVV material from a suspension process, however, contained substantial amounts of particulate impurities which blocked MRPS cartridges. Sedimentation-velocity analytical ultracentrifugation (SV-AUC) resolved the LVV peak in material from adherent production well, whereas in more polydisperse samples from suspension production, presence of particulate impurities masked a potential signal assignable to LVVs. In interferometric light microscopy (ILM) and nanoparticle tracking analysis (NTA), lower size detection limits close to ∼ 70 nm resulted in an apparent peak in particle size distributions at the expected size for LVVs emphasizing the need to interpret these data with care. Interpretation of data from dynamic light scattering (DLS) was limited by insufficient size resolution and sample polydispersity. In conclusion, the analysis of LVV products manufactured at pharmaceutical scale with current state-of-the-art physical (nano)particle characterization techniques was challenging due to the presence of particulate impurities of heterogeneous size. Among the evaluated techniques, MRPS and SV-AUC were most promising yielding acceptable results at least for material from adherent production.

Radiation damage effects on electronic and optical properties of β-Ga2O3 from first-principles

β-Ga2O3 with an ultra-wide bandgap demonstrates great promise in applications of space missions as power electronics and solar-blind photodetector. Unraveling the radiation damage effects on its material properties is of crucial importance, especially for improving the radiation tolerance of Ga2O3-based devices. Herein, we evaluate the formation energy of gallium and oxygen vacancy defects and comprehensively investigate their influence on the electronic and optical properties of β-Ga2O3 using first-principles calculations. Ga vacancies act as deep acceptors and produce p-type defects in β-Ga2O3, while the defective Ga2O3 with O vacancies exhibits the n-type characteristics. A semimetal characteristic is observed in the defective Ga2O3 with Ga vacancies, and an apparent optical absorption peak in the infrared spectral range emerges. Moreover, the self-compensation effect emerges when β-Ga2O3 contains both Ga vacancies and O vacancies, leading to the reduced absorption peak. The doping effect on the defect formation energy of β-Ga2O3 is also investigated, and Ga vacancies are found to be easily formed in the case of In doped β-Ga2O3 (InGa2O3) compared to the undoped β-Ga2O3, while O vacancies are much harder to form. This work provides insights into how gallium and oxygen vacancy defects alter electronic and optical properties of β-Ga2O3, seeking to strengthen its radiation tolerance.

Biogenic zinc selenide nanoparticles fabricated using Rosmarinus officinalis leaf extract with potential biological activity

Zinc selenide nanoparticles (ZnSe) are semiconductor metals of zinc and selenium. ZnSe NPs are advantageous for biomedical and bio-imaging applications due to their low toxicity. ZnSe NPs can be used as a therapeutic agent by synthesizing those using biologically safe methods. As a novel facet of these NPs, plant-based ZnSe NPs were fabricated from an aqueous extract of Rosmarinus officinalis L. (RO extract). Physiochemical analyses such as UV-visible and FTIR spectroscopy, SEM-EDX and TEM Imaging, XRD and DLS-Zeta potential analyses confirmed the biological fabrication of RO-ZnSe NPs. Additionally, Ro-ZnSe NPs were investigated for their bioactivity. There was an apparent peak in the UV-visible spectrum at 398 nm to confirm the presence of ZnSe NPs. FTIR analysis confirmed RO-extract participation in ZnSe NPs synthesis by identifying putative functional groups associated with biomolecules. TEM and SEM analyses revealed that RO-ZnSe NPs have spherical shapes in the range of 90–100 nm. According to XRD and EDX analysis, RO-ZnSe NPs had a crystallite size of 42.13 nm and contain Se and Zn (1:2 ratio). These NPs demonstrated approximately 90.6% antioxidant and antibacterial activity against a range of bacterial strains at 100 µg/ml. Antibiofilm activity was greatest against Candida glabrata and Pseudomonas aeruginosa at 100 g/ml. Accordingly, the IC50 values for anticancer activity against HTB-9, SW742, and HF cell lines were 14.16, 8.03, and 35.35 g/ml, respectively. In light of the multiple applications for ZnSe NPs, our research indicates they may be an excellent option for biological and therapeutic purposes in treating cancers and infections. Therefore, additional research is required to determine their efficacy.

Mineral oil emulsion species and concentration prediction using multi-output neural network based on fluorescence spectra in the solar-blind UV band.

The accurate monitoring of oil spills is crucial for effective oil spill recovery, volume determination, and cleanup. Oil slicks become emulsified under the effects of wind and waves, which increases the consistency of the oil spills. This phenomenon makes oil spills more challenging to handle and exacerbates environmental pollution. In this study, the variation of the solar-blind ultraviolet (UV) fluorescence spectra obtained from simulated oil spills with different oil types and oil-water ratios was investigated. By designing and constructing a multi-angle excitation and detection system, an apparent fluorescence peak of the oil emulsions was observed at around 290 nm under 220 nm excitation. By utilizing competitive adaptive reweighted sampling (CARS) and multi-output neural network algorithms, both the types and concentrations of the emulsified oils were obtained simultaneously. The classification accuracy for identifying the oil type exceeds 98%, and the mean absolute percentage error (MAPE) for concentration regression is around 2%. The results indicate that active solar-blind UV fluorescence could become a supplementary method for on-site oil spill detection to achieve comprehensive monitoring of oil spills. This study provides potential applications for UV-induced fluorescence spectrometry in oil spill on-site monitoring during the daytime.

Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area

Understanding the size distribution, variation patterns, and potential formation mechanisms of particulate organic nitrates (PONs) is crucial for assessing their influences on atmospheric chemistry, air quality, and the regional climate. This study investigates PONs in the coastal atmosphere of Qingdao, China by collecting size-resolved particulate matter samples and analyzing six types of organic nitrates, namely pinene keto nitrate (PKN229), monoterpene hydroxyl nitrate (MHN215), monoterpene dicarbonyl nitrate (MDCN247), oleic acid hydroxyl nitrate (OAHN361), oleic acid keto nitrate (OAKN359), and pinene sulfate organic nitrate (PSON295), using ultrahigh-performance liquid chromatography(mass spectrometry). The mean total concentration of organic nitrates in fine particles reaches 677 ng m−3. The predominant compound is MHN215, followed by PKN229 and MDCN247. All six organic nitrates exhibited distinct concentration peaks in the droplet mode, with MDCN247 and OAHN361 showing a minor peak in the condensation mode. In addition, an apparent concentration peak is observed in the coarse mode for OAKN359. Comparative analyses under various conditions highlight the significant influences of primary emissions and secondary formation processes on the abundance and size distribution of organic nitrates. For instance, both firework displays during festivals and high NOx emissions from fuel combustion significantly increase the concentrations of condensation-mode organic nitrates, whereas dust particles enhanced the heterogeneous formation of coarse-mode particles. Furthermore, the high humidity of the coastal area promotes aqueous formation in droplet-mode particles.

The polarization-modulated electronic structure and giant tunneling-electroresistance effect of a one-dimensional ferroelectric Ta4OTe9I4 nanowire

Low-dimensional ferroelectrics have a great deal of potential for use in electronic memory devices. However, intrinsic one-dimensional (1D) ferroelectricity is very rare. Using first-principles calculations, we present the discovery of an inborn 1D Ta4OTe9I4 ferroelectric (FE) nanowire. Its distinctive geometry can cause spontaneous electric polarization along the z-axis and allow it to maintain a certain temperature and strain. In addition to its sizable spontaneous polarization and appropriate Curie temperature, the 1D Ta4OTe9I4 nanowire exhibits an energy barrier comparable to those of other ferroelectrics. With polarization reversal, the energy gap can be modulated in the range of 0.38–1.33 eV, corresponding to an apparent peak shift phenomenon in the optical response. We use this nanowire as an exemplary material for building a FE tunnel junction composed of Hf0.5Ta3.5OTe9I4/Ta4OTe9I4/W0.5Ta3.5OTe9I4 with a giant tunneling electroresistance ratio at zero and low bias. Our calculations suggest that this 1D intrinsically FE material obtained from van der Waals crystals can be used in miniaturized and advanced high-density information storage.

Responses of runoff processes to vegetation dynamics during 1981–2010 in the Yarlung Zangbo River basin

Study regionThe Yarlung Zangbo River basin (YRB), southwest China. Study focusThe vegetation conditions play a significant role in regulating river runoff under climate change. However, the effect of vegetation growth induced by climate change to runoff variation remains controversial as relevant studies are mainly focused on the influences of climate change to runoff variation and vegetation growth, respectively. In this study, the response of runoff generation to change of Leaf Area Index (LAI) inputs during 1981–2010 in YRB were explored by using the Variable Infiltration Capacity (VIC) model. New hydrological insightsThe VIC model with dynamic LAI inputs performs better in the YRB, especially in the sub-basins with apparent peak clipping effect by LAI overestimation. The impact mechanism of how runoff variation is driven by LAI change in the meadow, tundra and cultivated vegetation cover is evapotranspiration-controlled by energy redistribution. However, the LAI changes in coniferous and broad-leaved forest cover affect the runoff generation mainly by redistributing energy-water to alter both evapotranspiration and surface soil moisture, so do the shrub and grassland during the growing season (Apr.∼Sep.). The results highlight implanting grassland would be efficient to reduce the flash flood runoff in a short term and balance groundwater runoff in a long run. The broad-leaved forest and coniferous forest with a longer growth cycle also play a main role in adjusting soil moisture.

Investigating the relationship between butanol molecular structure and combustion performance in an optical SIDI engine

Butanol has a high potential as a renewable substitution for gasoline in spark-ignition direct-injection (SIDI) engines. Different butanol isomers showed various flame characteristics that are strongly related to their molecular structure. However, there has been limited research on the implications of the butanol isomer's molecular structure on SIDI engine combustion, performance, and emissions. This study investigated butanol isomers as gasoline substitutes in SIDI range extender engines, with a focus on the effects of isomer molecular structures. This work employed a single-cylinder optical SIDI research engine and a high-speed camera to examine engine performance, flame kernel stability, flame propagation, and particle number (PN) emissions. The investigated blends comprised 70% toluene reference fuel (TRF) and 30% butanol isomers (1-butanol (n), 2-butanol (s), isobutanol (i), and tertbutanol (t)). Experimental tests are carried out at a 1000 rpm engine speed and a load of 5.7 bar IMEP, while the fuel condition is kept stoichiometric.The results elucidate that adding 1-butanol makes the flame kernel more stable and reduces COVimep compared to pure TRF. On the other hand, TRF-i, TRF-s, and TRF-t decrease flame initiation stability and increase COVimep. 1-butanol exhibited the highest apparent flame speed, IMEP, and peak in-cylinder pressure, followed by TRF, TRF-i, TRF-s, and TRF-t. Over half of the TRF-t cycles exhibited either no or a delayed flame kernel. Flame circularity improved with 1-butanol and diminished with the other blends. Diffusion flame intensity and PN emissions were higher for TRF, TRF-n, and TRF-t compared to TRF-s and TRF-i. In conclusion, linear chain butanol isomers with more internal C-H bonds and terminal C-OH bonds provide a more stable flame kernel and superior engine performance than branched isomers featuring internal C-OH bonds. The results from this study can be useful for expanding the practical applications of butanol isomers as a renewable fuel replacement in SIDI engines.

Study of the bending properties of variable stiffness chain mail fabrics

This study aims to explore a chain mail fabric with fast, reversible, and controllable stiffness adjustment. The structured fabric consists of three-dimensional single-cell particles. The chain mail fabric was first printed by 3D printing technology using polyamide 12 material. A three-point bending test was then carried out to investigate the mechanical tunability of the fabric under different external pressures and to establish a finite element model. Finally, the effects of pressure and particle structure on the apparent bending modulus, energy absorption, and peak load of chain mail fabrics are investigated to reveal the mechanical strengthening mechanism of chain mail fabrics. The results show that the apparent bending modulus of the chain mail fabric increases up to more than 20 times its original value as the pressure increases from 0 to 60 kPa, and the energy absorption and strength increase up to 22 and 19 times, respectively, providing a new approach to developing structural fabrics with adjustable bending modulus and new ideas for the development of lightweight, robust and adaptable structures.

Straightforward monitoring of honey with foreign diastase by leveraging the differentiation in LC-UV proteome profiles of authentic and fraudulent samples

Honey adulteration using sugar syrups is ubiquitous and adulterated honey may also be prepared by direct addition of α-amylases from different sources to match the legislation for honey trade. Colorimetric diastase assays may report false negatives in terms of foreign diastase (FD) detection owing to using substrates being prone to be cleaved by any α-amylases. The main objective of this study was to develop a reliable analytical method to determine FD contained honey. For this purpose, intrinsic honey proteins were first isolated, enriched, and cleaned up via experimentally designed serial ultrafiltration methodology. Next, diastase and invertase as abundant honey enzymes were purified simultaneously from obtained crude protein isolate by means of FPLC and novel purification protocol. Total protein and enzyme activity assays along with SDS-PAGE analysis were conducted for purity check. Subsequently, two purity-confirmed enzymes were used as analytical references in method development. With the hyphenation of UV detection, optimized chromatographic resolution, and practical dilute & shoot sample pretreatment, Foreign Amylase Monitoring (FAM) method has been introduced for routine analysis. Purified authentic enzymes were labeled in LC-UV chromatogram of honey proteome profile to distinguish any unnatural enzyme/protein signal. According to the validation of the FAM method, precise (RSDR; 1.27%), and linear (mean R2 >0.995) results were able to obtain. Commercial honey samples (n = 202) collected over 3 consecutive years were probed using the FAM method and industrial α-amylases were also analyzed for verification. The diastase activities were also measured prior to FAM application to elucidate if any positive correlation. The developed method rapidly and reliably detected the presence of FD qualitatively. A total of 74 samples were found to contain FD. It was observed that the presence of FD was correlated in samples with abnormally high diastase activities and an apparent FD peak was identified readily in all enzyme adulterated samples. The developed FAM method and performed trend analysis allowed us to decipher a dramatic increase in FD existence and this revealed the recently emerging problem of honey authenticity.

Dimension dependence of current injection path in GaInN/GaN multi-quantum-shell (MQS) nanowire-based light-emitting diode arrays

Abstract To light emitting diodes (LEDs), solving the common non-uniform current injection and efficiency degradation issues in (0001) plane micro-LED is essential. Herein, we investigated the light emission characteristics of various mesa sizes and different p-electrode areas toward the realization of coaxial GaInN/GaN multi-quantum-shell (MQS) nanowires (NWs)-based micro-LEDs. As the mesa area was reduced, the current leakage decreases, and further reduction of the area showed a possibility of realizing micro-LED with less current leakage. The large leakage path is mainly associated with the defective MQS structure on the (0001) plane area of each NW. Therefore, more NWs involved in an LED chip will induce higher reverse leakage. The current density-light output density characteristics showed considerably increased electroluminescence (EL) intensity as the mesa area decreased, owing to the promoted current injection into the efficient NW sidewalls under high current density. The samples with a mesa area of 50 × 50 µm2 showed 1.68 times higher light output density than an area of 100 × 100 µm2 under a current density of 1000 A/cm2. In particular, the emission from (1-101) and (10-10) planes did not exhibit an apparent peak shift caused by the quantum-confined Stark effect. Furthermore, by enlarging the p-electrode area, current can be uniformly injected into the entire chip with a trade-off of effective injection to the sidewall of each NW. High performance of the MQS NW-based micro-LED can be expected because of the mitigated efficiency degradation with a reducing mesa area and an optimal dimension of p-electrode.

New record of the green algal fossil Proterocladus and coexisting microfossils from the Meso-Neoproterozoic Diaoyutai Formation in southern Liaoning, North China

The Mesoproterozoic-Neoproterozoic transition represents a crucial interval of evolutionary innovation and phylogenetic diversification. A spotty fossil record indicates that several clades of multicellular eukaryotes, including red and green algae, as well as fungi, may have diverged and diversified at this transition. However, the Meso-Neoproterozoic fossil record remains poorly documented, particularly at the assemblage level, greatly limiting our understanding of the marine ecosystem in this critical time interval. Here we report a well-preserved assemblage of organic-walled microfossils from the Meso-Neoproterozoic Diaoyutai Formation (ca. 1050–950 Ma) in Southern Liaoning Province of the North China Block. Raman geothermometric analysis of these organic-walled microfossils suggests that the Diaoyutai Formation experienced relatively low-grade metamorphism, with apparent peak metamorphic temperatures of ∼ 215 ℃. The Diaoyutai assemblage consists of 14 species belonging to 9 genera, as well as several unnamed or unidentified forms. In addition to simple forms such as aggregated coccoidal and unbranched filamentous fossils that are often interpreted as cyanobacteria, a moderate diversity of eukaryotes is also observed. Probable eukaryotic fossils in this assemblage include the branched multicellular alga Proterocladus antiquus that has been previously interpreted as a green alga, several morphologically complex spheroidal taxa (e.g., Germinosphaera bispinosa, Pterospermopsimorpha insolita, P. pileiformis and Squamosphaera colonialica), and relatively large leiospheres (50–700 μm in diameter). We note that the occurrence of Proterocladus antiquus in the Diaoyutai assemblage predates its previously reported occurrence from the overlying Nanfen Formation. Overall, the Diaoyutai assemblage presents a glimpse of the coastal marine ecosystem at the Meso-Neoproterozoic transition, which consisted of benthic microbial mats dominated by filamentous cyanobacteria, millimeter-sized benthic green algae with thallus elevating above the sediment–water interface, and micrometer-sized planktonic prokaryotic and eukaryotic organisms. From the perspective of primary producers, the rise of photosynthetic eukaryotes in the Meso-Neoproterozoic represents a transformative innovation to modernize the coastal marine ecosystem in terms of ecological functions.

Study on Thermal Decomposition and Thermal Safety of Mixtures of Highly Active Aluminum Powder and Nitramine Explosive

The newly prepared and stored highly active aluminum powder were mixed with common nitramine explosives HMX and CL-20 at a mass ratio of 1:1, respectively. The effects of the two kinds of high active aluminum powder on the thermal decomposition properties of HMX and CL-20 were investigated by differential scanning calorimetry (DSC). The thermal explosion critical temperature of the mixture of high active aluminum powder and nitramine explosive was calculated. The result shows that after joining highly active aluminium powder, highly active aluminium/nitramine explosive mixture, moderate and apparent activation energy decrease thermal decomposition peak suggests that highly active aluminium can contribute to the thermal decomposition of HMX and CL-20, compared with highly active aluminium stored after a certain period of time, the new system is highly active aluminum powder with a mixture of nitramine explosives with lower apparent activation energy, At the same time, the critical temperature of thermal explosion also decreased significantly, which indicated that the newly prepared high-activity aluminum powder had higher chemical reactivity, but its thermal safety was reduced.

Lattice misorientation at domain boundaries in β‐Ga2O3 single‐crystal substrates observed via synchrotron radiation X‐ray diffraction imaging and X‐ray reticulography

AbstractTo evaluate the lattice misorientation at domain boundaries (DBs) in β‐Ga2O3, we performed X‐ray diffraction imaging (XRDI), X‐ray reticulography (XRR), and X‐ray topography (XRT) using a synchrotron radiation light source. Four reciprocal lattice vectors (g‐vectors) were applied, and the DBs showed different visibilities in the XRDI maps depending on the g‐vector. By analyzing possible characteristics of the misorientation, the XRDI results suggested that the DB being investigated was associated with a misorientation on the () plane and contained twist and tilt components. The apparent peak change in XRDI caused by the two components was calculated. We further succeeded in separating the tilt and twist components using XRR images in conjunction with simulation. Dislocation arrays at the DBs were observed using XRT, and the average distance between the dislocations in the array was consistent with the misorientation obtained using XRDI and XRR. The distribution of DBs across a wide area was acquired by a combination of XRR images recorded on a charge‐coupled device camera and X‐ray films. The fringe‐patterned XRR on X‐ray films provided a powerful and nondestructive tool to characterize DBs distributed across a large‐diameter wafer with an angular resolution on the order of several arc sec (low 10−5 rad).

Pharmacokinetics comparison of vardenafil as administered by an intranasal spray formulation vs a 10-mg oral tablet.

Oral vardenafil (VDF) tablet is an effective treatment for erectile dysfunction (ED), but intranasal administration with a suitable formulation can lead to a faster onset of action and offer more convenient planning for ED treatment. The primary purpose of the present pilot clinical study was to determine whether intranasal VDF with an alcohol-based formulation can result in more "user-friendly pharmacokinetics" as compared with oral tablet administration. This single-dose randomized crossover study was conducted in 12 healthy young volunteers receiving VDF as a 10-mg oral tablet or 3.38-mg intranasal spray. Multiple blood concentrations were obtained, and VDF concentrations were determined with a liquid chromatography-tandem mass spectrometry assay. Pharmacokinetic parameters following each treatment were compared and adverse events assessed. Pharmacokinetic parameters were obtained: apparent elimination rate constant, elimination half-life, peak concentration, peak time, total area under the curve, and relative bioavailability. Although mean apparent elimination rate constant, elimination half-life, peak concentration, and total area under the curve were similar between intranasal and oral administration, the median peak time from intranasal was much shorter (10vs 58minutes, P < .001, Mann-Whitney U test). The variability of the pharmacokinetic parameters was also less with intranasal than oral administration. The relative bioavailability of intranasal to oral was 1.67. Intranasal VDF caused transient but tolerable local nasal reactions in 50% of subjects. Other adverse events (eg, headache) were similar between the treatments. The incidence of adverse events was, however, significantly less in the second treatment after initial exposure to VDF. No serious adverse events were noted. Intranasal VDF potentially offers a more timely and lower dose for the treatment of ED in patients who can tolerate the transient local adverse reactions. The strength of this study is its randomized crossover design. Because the study was conducted in 12 healthy young subjects, the results may not reflect those observed in elderly patients who may be likely taking VDF for ED. Nevertheless, the changes of pharmacokinetic parameters in the present study are likely a reflection of the differences between intranasal and oral administration of the formulations. Our study indicated that the present VDF formulation, when administered intranasally, can achieve a more rapid but similar plasma concentration with only about one-third dose when compared with the oral administration.

Dynamics of Interlayer Na-Ions in Ga-Substituted Na2Zn2TeO6 (NZTO) Studied by Variable-Temperature Solid-State 23Na NMR Spectroscopy and DFT Modeling.

Local Na-coordination and dynamics of Na2-xZn2-xGaxTeO6; x = 0.00 (NZTO), 0.05, 0.10, 0.15, 0.20, were studied by variable-temperature, 23Na NMR methods and DFT AIMD simulations. Structure and dynamics were probed by NMR in the temperature ranges of 100-293 K in a magnetic field of 18.8 T and from 293 up to 500 K in a magnetic field of 11.7 T. Line shapes and T1 relaxation constants were analyzed. At 100 K, the otherwise dynamic Na-ions are frozen out on the NMR time scale, and a local structure characterization was performed for Na-ions at three interlayer sites. On increasing the temperature, complex peak shape coalescences occurred, and at 293 K, the Na NMR spectra showed some averaging due to Na-ion dynamics. A further increase to 500 K did not reveal any new peak shape variations until the highest temperatures, where an apparent peak splitting was observed, similar to what was observed in the 18.8 T experiments at lower temperatures. A three-site exchange model coupled with reduced quadrupolar couplings due to dynamics appear to explain these peak shape observations. The Ga substitution increases the Na-jumping rate, as proved by relaxation measurements and by a decrease in temperature for peak coalescence. The estimated activation energy for Na dynamics in the NZTO sample, from relaxation measurements, corresponds well to results from DFT AIMD simulations. Upon Ga substitution, measured activation energies are reduced, which is supported, in part, by DFT calculations. Addressing the correlated motion of Na-ions appears important for solid-state ion conductors since benefits can be gained from the decrease in activation energy upon Ga substitution, for example.

Instantaneous Heat Transfer Coefficient of Droplets Impinged on Heated Surfaces

Droplet impingement is one of the phase change techniques used for equipment cooling because of the proper utilization of sensible and latent heat. This study analyzes droplet evaporation on aluminum and copper substrate. The instantaneous heat transfer coefficient (HTC) during evaporation of 100 µl de-ionized water is studied. The infrared camera is used to visualize and analyze the evaporation mechanism. The effect of substrate and fluid temperature on droplet evaporation is analyzed. The surface temperatures of both substrates are varied from 105 °C to 165 °C. The test fluid is maintained at temperatures of 30 °C, 50 °C, 75 °C, and 99.4 °C. The droplets exhibited Leidenfrost behavior for temperatures beyond 145 °C with copper and 150 °C with aluminum surface. It is observed that the evaporation rate is higher for copper than aluminum. A user-friendly interface is developed for determining the instantaneous surface area of an evaporating droplet. The apparent peak in the area in copper is higher than aluminum for all cases due to surface tension gradient and Marangoni flow. HTC increases with the temperature of droplet evaporating on a given substrate and is higher for copper. When substrate temperature increases for a given droplet temperature, the instantaneous HTC increases.

Spatial and temporal trends of polyhalogenated carbazoles in sediments of the Yangtze river: insights into the origin

Abstract Fifteen surface sediments and three sediment cores were sampled in the Yangtze River (YR) of China to study the composition and temporal distribution trends of 10 selected polyhalogenated carbazoles (PHCZs) and gained insight into their origin. The total concentrations of PHCZs in the surface sediments ranged from 1.58 to 5.45 ng g−1 dry weight (dw), with an average of 3.11 ng g−1 dw. The composition profiles of PHCZs in the surface sediments were dominated by 1,3,6,8-tetrabromocarbazole, 1,3,6-dibromocarbazole, and 3,6-dichlorocarbazole. The variation trends of PHCZs in the sediment cores showed an apparent peak concentration and subsequently a significant decreasing trend in recent years. A strong correlation existed between PHCZs and sediment physicochemical properties. Furthermore, human activities directly or indirectly affected PHCZ concentrations. The evaluation of the potential toxic effect suggested that the toxic equivalent of PHCZs was less than the safe sediment value.

The history of global strain and geodynamics on Mars

The tectonic record of Mars is dominated by compressional wrinkle ridges on volcanic surfaces, and these structures have been widely used as a record of tectonic and geodynamic evolution. This study analyzes the density of compressional tectonic structures and inferred strain as functions of time, using the lengths and heights of compressional ridges together with geologic estimates of surface age. Our analyses confirm an apparent peak in compressional strain in the late Noachian and early Hesperian, and comparatively lower values before and after. The lower tectonic strain in the early and middle Noachian relative to the early Hesperian reflects the incompleteness of the ancient compressional tectonic record of strain, as older surfaces should accumulate more strain than younger surfaces. This strain deficit necessitates other means of accommodating contractional strain in the ancient crust, including distributed strain and small-scale faulting. The abrupt decrease in the accumulated tectonic strain and strain rate after the early Hesperian reflects a rapid episode of global contraction followed by much lower rates, in conflict with models of steady-state mantle evolution. The decreasing strain rate may be explained by a changing mantle rheology due to volcanic outgassing. Alternatively, the strain history may be explained by the dominance of mantle plumes in the late Noachian and early Hesperian associated with the formation of Tharsis and the early Hesperian volcanic provinces, which could have led to a pulse of rapid contraction caused by disequilibrium cooling and volcanic outpourings. The tectonic record of strain on Mars – including the incomplete ancient record and evidence for strong departures from steady-state models – may have implications for the interpretation of the tectonic record and thermal evolution of other bodies as well.