We report a novel BPS jumping phenomenon of 5d N\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$ \\mathcal{N} $$\\end{document} = 1 supersymmetric gauge theories whose brane configuration is equipped with an O7-plane. The study of the relation between O7+-plane and O7−-plane reveals that such BPS jumps take place when the Higgsing is triggered near the O7-plane upon a particular parameter tuning of the theories. We propose two types of gauge theories whose BPS spectra jump. One is the SU(2N + 8) gauge theory with a symmetric hypermultiplet converted to the SU(2N) gauge theory with an antisymmetric hypermultiplet. The other is pure SO(2N + 8) gauge theory jumping to pure Sp(N) gauge theory. We explicitly confirm our proposal through the (un)refined instanton partition functions. Furthermore, we discuss feasible generalizations involving an Op-plane for supersymmetric gauge theories of eight supercharges in four and three dimensions (p = 6, 5 respectively).