Antimony Nanoparticles Research Articles

Tailoring Sb-F doped ZnO nanoparticles for dual-functionality: Photocatalytic and supercapacitor applications

In the present work, pure zinc oxide nanoparticles (ZnO NPs), antimony doped ZnO nanoparticles (Sb-ZnO NPs), fluorine doped ZnO nanoparticles (F-ZnO NPs), and antimony and fluorine co-doped ZnO nanoparticles (Sb/F-ZnO NPs) with various dopant concentrations are synthesized by co-precipitation method. The optical, structural, morphological, photocatalytic, and electrochemical activities of ZnO nanostructures by the influence of Sb and F doping were investigated. XRD showed crystallite size decreased with increasing Sb/F content, while BET showed 64.25 m2/g surface area for ZnO-5 %Sb-10 %F. SEM and TEM images suggesting Sb/F doping changed the ZnO morphology from spherical to bricks-built and nanorod-built flower structures. XPS verified Sb (+3) and F (−1) oxidation states, while absorption spectroscopy showed increased energy bandgap with 5 % Sb and 10 % F doping in ZnO. The photocatalytic activity for mixture of congo red, rhodamine B, and methylene blue are closer to real polluted water. All the samples exhibited good photocatalytic activity for the methylene blue with degradation efficiency reaching to 99 %. At a constant current density of 1 A/g, symmetric supercapacitors utilizing Sb/F-ZnO electrodes exhibited a specific capacitance of 762 Fg−1, underscoring their superior electrochemical performance and potential for advancing energy storage technologies. Further, physiochemical and electrochemical properties of ZnO can be perfectly tuned by the optimal setting for co-doping in ZnO up to 5 % Sb and 10 % F by the co-precipitation approach.

Antimony nanoparticles encapsulated in interconnected nitrogen-doped carbon nanospheres for high performances PIBs

Antimony (Sb) has attracted significant attention as an anode material for potassium-ion batteries (PIBs) due to its high theoretical capacity and suitable working voltage. However, the severe volume variations of Sb during potassiation/depotassiation process lead to sluggish kinetics and poor cyclic stability for PIBs. In this study, Sb nanoparticles are confined within interconnected N-doped carbon nanospheres (Sb@NC) through an effective carbothermal reduction process. The potassium storage performances and mechanism are elucidated through electrochemical tests combined with ex-XRD analysis. When used as an anode for PIBs, the optimized Sb@NC-2 anode exhibits excellent cycle stability of 463.0 mAh g−1 at 200 mA g−1 over 100 cycles and superior rate capability of 113.4 mAh g−1 at a high current density of 2 A g−1. Besides, a full cell comprising an Sb@NC-2 anode and a PTCDA cathode is also tested to validate the practical feasibility of the anode. Furthermore, Density Functional Theory (DFT) calculations demonstrate that N-doped carbon can enhance the adsorption of K+ and improve the kinetics of electrochemical reactions. Therefore, the unique yolk-shell structure in this study effectively restricts volume expansion and aggregation of Sb particles while facilitating rapid electron/ion transfer. These findings provide a potential alternative anode material for advanced PIBs.

Antimony trioxide nanoparticles promote ferroptosis in developing zebrafish (Danio rerio) by disrupting iron homeostasis

The widespread use of antimony trioxide (ATO) and ATO nanoparticles (nATO) has led to increasing ecological and health risks. However, there is relatively insufficient research on the aquatic ecotoxicology of nATO. This study revealed that nATO affects the development of zebrafish embryos and mainly induces ferroptosis through the dissolution of Sb(III). The size of nATO ranged from 50 to 250 nm, and it generated free radicals in water. It can be ingested and accumulate in zebrafish larvae and affects normal development. Compared with those in the control group, the levels of reactive oxygen species (ROS), cell apoptosis, mitochondrial damage and iron content in the group exposed to high concentrations of nATO were increased. The transcriptomics results indicated that nATO significantly altered the expression levels of key genes related to glutathione metabolism and ferroptosis. Quantitative polymerase chain reaction consistently demonstrated the reliability of the transcriptome data and revealed that nATO induced ferroptosis by disrupting iron homeostasis and the key factor is the dissolution of Sb(III). Furthermore, ferrostatin-1, an inhibitor of ferroptosis, decreased the levels of ROS, apoptosis and mitochondrial damage induced by nATO, which further prove that nATO can promote ferroptosis. This work deepens the understanding of the ecological toxicological effects of nATO in aquatic environments and its mechanisms, which is highly important for the development of antimony management strategies.

3D Confinement Stabilizes the Metastable Amorphous State of Antimony Nanoparticles - A New Material for Miniaturized Phase Change Memories?

The wet-chemical synthesis of 3D confined antimony nanoparticles (Sb-NP) at low and high temperatures is described. Using reaction conditions that are mild in temperature and strong in reducing power allows the synthesis of amorphous Sb-NP stabilized with organic ligands. Exchanging the organic ligand 1-octanethiol by iodide enabled to investigate the unusual strong stability of this metastable material through simultaneous thermal analysis combining differential scanning calorimetry and thermogravimetric analysis. Additionally, in situ high temperature powder x-ray diffraction (p-XRD) shows a significant increase in stabilization of the amorphous phase in comparison to thin layered, 1D confined Sb or bulk material. Further, it is shown with scattering-type scanning near-field optical microscopy (s-SNOM) experiments that the optical response of the different phases in Sb-NP make the distinctness of each phase possible. It is proposed that the Sb-NP introduced here can serve as a 3D-confined optically addressable nanomaterial of miniaturized phase change memory devices.

Binder-Free Anodes for Potassium-ion Batteries Comprising Antimony Nanoparticles on Carbon Nanotubes Obtained Using Electrophoretic Deposition.

Antimony has a high theoretical capacity and suitable alloying/dealloying potentials to make it a future anode for potassium-ion batteries (PIBs); however, substantial volumetric changes, severe pulverization, and active mass delamination from the Cu foil during potassiation/depotassiation need to be overcome. Herein, we present the use of electrophoretic deposition (EPD) to fabricate binder-free electrodes consisting of Sb nanoparticles (NPs) embedded in interconnected multiwalled carbon nanotubes (MWCNTs). The anode architecture allows volume changes to be accommodated and prevents Sb delamination within the binder-free electrodes. The Sb mass ratio of the Sb/CNT nanocomposites was varied, with the optimized Sb/CNT nanocomposite delivering a high reversible capacity of 341.30 mA h g-1 (∼90% of the initial charge capacity) after 300 cycles at C/5 and 185.69 mA h g-1 after 300 cycles at 1C. Postcycling investigations reveal that the stable performance is due to the unique Sb/CNT nanocomposite structure, which can be retained over extended cycling, protecting Sb NPs from volume changes and retaining the integrity of the electrode. Our findings not only suggest a facile fabrication method for high-performance alloy-based anodes in PIBs but also encourage the development of alloying-based anodes for next-generation PIBs.

Encapsulating Antimony metal nanoparticles in hierarchical porous carbon skeleton as high-performance potassium- and lithium-ion batteries anodes

Metallic antimony (Sb) as alkaline metal battery anode material, being thoroughly researched for its high theoretical specific capacity, but there is still a huge expansion problem with repeated insertion/de-insertion., We reported a unique composite material that encapsulates Sb nanoparticles in hierarchical porous carbon skeletons (Sb@HPCs) in this work, to explore the effect of the hierarchical porous carbon structure on the electrochemical performance of the Sb@HPCs as potassium-ion batteries (KIBs) and lithium-ion batteries (LIBs) anode materials. The macropores could promote the penetration of electrolyte, thus reducing the internal impedance of the battery. The mesopores provide a short ion diffusion path and a large diffusion region, which plays a crucial role in facilitating rapid ionic migration in both KIBs and LIBs. The micropores in the electrode material contribute to a larger specific surface area, which provides more surface area for charge storage, thus enhancing the energy density of the material. Importantly, when the Sb@HPCs composite material is applied as anode material of KIBs, it exhibits an outstanding specific capacity of 360 mAh g−1 after 100 cycles at 100 mA g−1. In the LIBs, the specific capacity of the composite material is 595.2mAh g−1 after 100 cycles at a current density of 0.1 A g−1; even at a high current density of 1.0 A g−1, the specific capacity still maintains at 320.4 mAh g−1 after 800 cycles, indicating an excellent cycling stability. The development of hierarchical porous three-dimensional structure offers a practical solution to the capacity degradation issues of metal anode in KIBs/LIBs.

Coin cell constructed symmetric supercapacitor based on binder-free antimony trioxide (Sb2O3) in heteroatom doped carbon nanofibers

Antimony trioxide nanoparticles are synthesized in binder-free, self-standing, and nitrogen and sulfur as heteroatoms doped carbon nanofibers (Sb2O3-NSCFs). Two-step method including electrospinning and heat treatment is utilized to convert antimony species to nano-sized antimony nanoparticles. Structural, morphological, chemical composition, and surface area/pore size analysis of the materials are investigated using a series of analysis. The electrochemical performance of the materials is evaluated using both three- and two-electrode systems in basic electrolyte. The Sb2O3-NSCFs electrode shows a specific capacitance of 354.4 F/g at 1 A/g and the charge storage mechanism is investigated. The constructed coin-cell symmetric supercapacitor (Sb2O3-NSCF//Sb2O3-NSCF) exhibits a specific energy of 9.2 Wh/kg at 300 W/kg and also retains its capacitance of 94.4 % over 10 000 cycles.

Engineering Sb/Zn4(OH)6SO4·5H2O interfacial layer by in situ chemically reacting for stable Zn anode

Rechargeable aqueous zinc ion batteries with abundant resources and high safety have gained extensive attention in energy storage technology. However, the cycle stability is largely limited by notorious Zn dendrite growth and water-induced interfacial side reactions. Here, a uniform and robust protection layer consisting of metal antimony (Sb) nanoparticles and micrometer-size sheets Zn4(OH)6SO4·5H2O (ZHS) is purposely designed to stabilize Zn anode via an in situ chemical reaction strategy. The two-phase protection layers (Sb/ZHS) induce a reinforcement effect on the Zn anode (Zn@Sb/ZHS). Specifically, Sb nanoparticles play the part of nucleation sites to facilitate uniform Zn plating and homogenize the electric field around the Zn surface. ZHS micrometer-size sheets possess sufficient electrolyte wettability, fast ion transfer kinetics, and anti-corrosion, thus guaranteeing uniform ion flux and inhibiting H2O decomposition. As expected, the symmetric Zn@Sb/ZHS//Zn@Sb/ZHS cells achieve a minimal voltage hysteresis and a reversible cycle of over 2000 h at 1 mA cm−2. By pairing with the MnO2 cathode, the full cell exhibits a significantly improved stability (∼94.17 % initial capacity after 1500 cycles). This study provides a new strategy to design artificial protection layers.

Nitrogen-doped carbon with antimony nanoparticles as a stable anode for potassium-ion batteries

Potassium-ion batteries are considered promising alternatives to lithium-ion batteries (LIBs) because they have a lower redox K+/K potential, a lower Stokes radius, abundant raw materials, and economic benefits. However, K has a larger ionic radius than Li, which may limit the diffusion of K ions into electrodes and cause poor electrode rate capability and cycling stability. In this study, N-doped C and Sb (NC@Sb) composites were synthesised using a facile and cost-effective method of carbonisation and ball milling. The NC@Sb composites had an interconnected and highly porous structure, which was formed by the release of gases such as CO, H2O, CO2, and NH3 during carbonisation. Additionally, NC@Sb is a promising anode owing to the synergistic effects of the high specific capacity of Sb and the good cycling stability of NC. In particular, the NC@Sb composite that contained 10 wt% Sb (NC@Sb10) exhibited a high reversible capacity of 264 mAh g−1 after 100 cycles at a specific current of 200 mA g−1. Furthermore, the NC@Sb10 electrode maintained 85% of its initial capacity at a high specific current of 1 A g−1 even after 500 discharge–charge cycles. The excellent electrochemical performance of the NC@Sb composite is mainly attributed to the stable embedding of the Sb nanoparticles in the porous and electrically conductive NC matrix, which can buffer Sb stress and provide a pathway for the penetration of the electrolyte and K ions.

Solvothermal‐induced synthesis of in‐situ carbon‐coated antimony nanoparticles as an anode material for sodium‐ion batteries

AbstractSodium‐ion batteries (SIBs) are attracting increasing attention due to their low cost of raw materials and high potential as an alternative to lithium‐ion batteries in energy storage systems. Owing to its favorable reaction potential (0.6 V vs Na/Na+) and high reversible capacity (660 mAh g−1), antimony (Sb) has been extensively studied as an anode material for SIBs. However, the poor cyclability of a pure Sb anode, induced by the mechanical stress mechanism, hinders its application. Herein, carbon microspheres catalyzing the in‐situ polymerization and coating of Sb are developed through a “solvothermal‐induced” synthesis method. During the solvothermal process in the presence of carbon microspheres, SbCl3 can react with ethylene glycol to generate an organic‐inorganic hybrid precursor. This precursor can be further reduced into carbon‐coated Sb with controllable carbon content. Benefiting from an in‐situ coating process that buffers the volume change of Sb, the as‐prepared carbon‐coated Sb anode shows improved Na‐storage performance. It achieves a capacity of 330 mAh g−1 (based on the total mass of Sb and carbon) at 0.1 A g−1 and exhibits good cycling stability at 1 A g−1. This work contributes to a facile approach for preparing a carbon‐coated metallic anode for SIBs.

Unveiling Influence of Dielectric Losses on the Localized Surface Plasmon Resonance in (Al,Ga)As:Sb Metamaterials.

We perform numerical modeling of the optical absorption spectra of metamaterials composed of systems of semimetal antimony nanoparticles embedded into AlxGa1-xAs semiconductor matrices. We reveal a localized surface plasmon resonance (LSPR) in these metamaterials, which results in a strong optical extinction band below, near, or above the direct band gap of the semiconductor matrices, depending on the chemical composition of the solid solutions. We elucidate the role of dielectric losses in AlxGa1-xAs, which impact the LSPR and cause non-plasmonic optical absorption. It appears that even a dilute system of plasmonic Sb nanoinclusions can substantially change the optical absorption spectra of the medium.

Sensitive Electrochemical Determination of Bisphenol a Using a Disposable, Electrodeposited Antimony-Graphene Nanocomposite Pencil Graphite Electrode (PGE) and Differential Pulse Voltammetry (DPV)

Herein the synergistic properties of electrochemically reduced graphene oxide–antimony nanoparticles (ERGO-SbNPs) were leveraged for the ultrasensitive determination of bisphenol A (BPA) in water samples using disposable pencil graphite rods. A novel pencil-graphite multi-electrode array was utilized as the coating tool resulting in the production of highly reproducible and disposable single-use ERGO-SbNP-coated pencil graphite rods. This coating method effectively mitigated the fouling caused by BPA by-products during oxidation. The analytical determination of BPA oxidation on the single-use ERGO-SbNP-coated pencil graphite rods demonstrated an impressive 0.0,125 µM detection limit, surpassing the USEPA drinking water standard of 0.087 µM. Furthermore, the developed electrochemical sensor exhibited exceptional reproducibility for BPA in tap water samples from Western Cape, South Africa with few interferences. The study’s findings not only highlight the sensor’s superior performance but also present a promising alternative to existing anti-fouling measures.

Fabrication and Characterization of Antimony doped Iron oxide Nanoparticles

Antimony oxide (Sb2O3) and Antimony-doped iron oxide (Sb-Fe2O3) nanomaterials of different (2 &3 %) concentrations were fabricated by wet synthesis technique and characterized by FTIR, XRD and XRF techniques, respectively. X-RD results showed uniform Iron oxide nanocrystals of almost 15 nm, whereas FTIR and XRF were employed to detect elemental composition of Antimony in doped (Sb-Fe2O3) samples.

Pure and Antimony-doped Tin Oxide Nanoparticles for Fluorescence Sensing and Dye Degradation Applications.

Luminescent antimony doped tin oxide nanoparticles have drawn tremendous attention from researchers due to its low cost, chemical inertness and stability. Herein, a quick, facile and economic hydrothermal/solvothermal method was utilized for the preparation of antimony doped (1%, 3%, 5%, 7% and 10%) tin oxide nanoparticles. The antimony doping in a reasonable range can change the properties of SnO2. As such, a lattice distortion increases with increase in doping, which is evidenced through crystallographic studies. It was found that the highest photocatalytic degradation efficiency of malachite green (MG) dye of about 80.86% was achieved with 10% Sb-doped SnO2 in aqueous media due to small particle size. Moreover, 10% Sb-doped SnO2 also showed the highest fluorescence quenching efficiency of about 27% for Cd2+ of concentration 0.11µg/ml in the drinking water. The limit of detection (LOD) comes out as 0.0152µg/ml. This sample selectively detected the cadmium ion even in the presence of other heavy metal ions. Notably, 10% Sb-doped SnO2 could appeared as a promising sensor for fast analysis of Cd2+ ions in real samples.

Modifying nano-silicon with nano-antimony through molten salt electrolysis for superior lithium storage materials

The application of silicon to lithium-ion batteries (LIBs) remains a challenge due to the severe volume expansion effect of silicon. In this work, a nano Si-Sb bimetal is obtained by the molten salt electrolysis of mixture of silicon and antimony sulfide (Sb2S3). The uniform hybrid of antimony nanoparticles not only prevents the agglomeration of silicon but also selectively decomposes the electrolyte additives and alleviates the rupture of SEI effectively, which can mitigate the volume expansion of silicon. When used as a negative electrode for LIBs, the Si-Sb bimetallic electrode delivers a reversible capacity of 1524 mAh/g after 100 cycles at a current density of 1 A/g. Even at 3 A/g, the reversible capacity is as high as 1062 mAh/g after 200 cycles. This work offers a new way for the fabrication of Si-based alloy anodes through using molten salt electrolysis.

A benign strategy toward mesoporous carbon coated Sb nanoparticles: A high-performance Li-ion/Na-ion batteries anode

Antimony (Sb)-based anodes can offer excellent gravimetric capacity (∼660 mAhg−1) in lithium-ion/sodium-ion batteries (LIBs/SIBs) fabricated using carbonate-based electrolytes complexed with lithium/sodium salt. However, high first-cycle irreversible loss (35–40%) and gradual capacity fade (25–30%/cycle) originate from solid electrolyte interphase (SEI), and severe volumetric stress (∼300%) associated with alloyed phase(s) impede real-life applications. Herein, we devise a benign strategy to develop mesoporous carbon coating onto antimony nanoparticles (Sb@C) based core-shell architecture for LIBs/SIBs anode. In particular, ∼30–50 nm thick mesoporous carbon spheres (∼1 ± 0.5 μm) were obtained from resorcinol-formaldehyde (RF)-based polycondensation reaction by sol-gel chemistry engulfing Sb nanoparticles by suitably controlling Cetyltrimethylammonium bromide (CTAB)-induced steric stabilization and pH modulation during synthesis. The core-shell Sb@C helps faster Li+/Na+-ion migration preventing the structural collapse of Sb during electrochemical cycling and thereby improving the capacity fade. Electrochemical results demonstrate Sb@C can deliver a specific capacity of ∼536 mAhg−1 and ∼ 291 mAhg−1 at 0.1C current rate in LIBs and SIBs, respectively, up to 200 cycles. Electrochemical impedance spectroscopy (EIS) indicates lower charge transfer (Rct) and SEI resistance (RSEI) of Sb@C cycled electrode than the bare Sb-NPs was the probable reason for improved Li/Na-ion storage in Sb@C anode. A detailed galvanostatic intermittent titration technique (GITT) and internal resistance measurements during 1st and 2nd cycles shed light on distinguishably different Li-ion/Na-ion storage behavior. The bulk Li+/Na+-ion diffusion coefficients found diminishes at reaction voltages (0.9 V/0.6 V for lithiation and 0.6 V/0.4 V for sodiation) corresponding with alloyed phase(s) concurrent with a drop in internal resistance at the quasi-open-circuit voltage (QOCV) during 1st and 2nd discharge cycle. On the contrary, de-alloying phenomena from the fully lithiated/sodiated phase(s) display an entirely opposite trend. The Li+ diffusion coefficient reaches minima at ∼1.1 V with a sudden jump in the internal resistance at QOCV during 1st and 2nd charge cycle. However, Na+ diffusion coefficient gradually drops along with a steep increase in the internal resistance, indicating partial Na-ion trapping and irreversible capacity loss.

Effect of Amorphous-Crystalline Phase Transition on Superlubric Sliding

Structural superlubricity describes the state of greatly reduced friction between incommensurate atomically flat surfaces. Theory predicts that, in the superlubric state, the remaining friction sensitively depends on the exact structural configuration. In particular the friction of amorphous and crystalline structures for, otherwise, identical interfaces should be markedly different. Here, we measure friction of antimony nanoparticles on graphite as a function of temperature between 300 and 750K. We observe a characteristic change of friction when passing the amorphous-crystalline phase transition above 420K, which shows irreversibility upon cooling. The friction data is modeled with a combination of an area scaling law and a Prandtl-Tomlinson type temperature activation. We find that the characteristic scaling factor γ, which is a fingerprint of the structural state of the interface, is reduced by 20% when passing the phase transition. This validates the concept that structural superlubricity is determined by the effectiveness of atomic force canceling processes.

A three-dimensional zincophilic nano-copper host enables dendrite-free and anode-free Zn batteries

Aqueous zinc (Zn) batteries have attracted significant attention for large-scale energy storage applications due to their advantages of high theoretical capacity, high-safety, and low-cost. However, the commercialization of Zn batteries is hindered by the low utilization and parasitic reactions of Zn anode. Herein, we design a three-dimensional nano-copper host modified by zincophilic antimony (Sb) nanoparticles (referred to as ZA@3D-nanoCu) for dendrite-free and anode-free Zn batteries. The ZA@3D-nanoCu offers adequate zincophilic sites with homogeneous Zn nucleation and uniform current density distribution for Zn plating/stripping. It is further revealed that the synergistic effect of 3D structures and zincophilic particles can induce uniform Zn deposition for highly reversible plating/stripping. The dendrite-free Zn plating/stripping on the ZA@3D-nanoCu substrate can stably cycle for over 1100 h at an areal capacity of 2 mAh cm−2 with nearly 100% Zn utilization, much superior to a planar Cu foil without any structural design. By coupling the ZA@3D-nanoCu anode with a bromine cathode, an anode-free Zn–Br2 battery can be cycled stably over 1000 cycles at a high areal capacity of 10 mAh cm−2. The anode-free ZA@3D-nanoCu host with remarkable advantages for stable Zn plating/stripping offers a new arena for large-scale energy storage applications of Zn batteries.

High stability asymmetric supercapacitor cell developed with novel microwave-synthesized graphene-stabilized ruthenium antimonide nanomaterial

Ruthenium antimony oxide (RuSbO), and ruthenium antimony oxide graphene (RuSbO-G) nanomaterial was synthesized via the microwave-assisted method for the first time and tested as a possible electrode material for an asymmetric supercapacitor device. The formation of the nanocomposites was confirmed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images where the RuSbO material showed randomly distributed spherically shaped nanoparticles, and the RuSbO-G showed ruthenium and antimony nanoparticles scattered randomly on the graphene sheets. The SEM-electron dispersion X-ray spectroscopy (SEM-EDS) showed significant proof for nanoparticle formation with the elemental composition, while the X-ray photoelectron spectroscopy confirmed the oxidation states of the elements present. Both materials were further characterized in a three-electrode cell setup using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) and their electrochemical properties were compared to establish their suitability for energy storage purposes. From the result, different double layer properties were shown by the RuSbO and RuSbO-G in the 1 M Li2SO4 electrolyte. When compared to the RuSbO electrode, the composite had greater energy storage capabilities with a maximum capacitance of 289.47 F g−1 at 0.1 A g−1 current load. An efficiency of ~100 % was reached at a current density of 0.5 A g−1. Subsequently, both materials were used to fabricate a portable asymmetric supercapacitor. The RuSbO-G device yielded a maximum specific capacitance of 167.96 F g−1, resulting in an energy density of 75.58.0 W h kg−1 at a power density of 360 W kg−1 at 0.1 A g−1 current load, with ~100 % charge retention after 4900 cycles. This study turns a new research light on RuSbO based materials as an energy storage material for supercapacitors.

Superflexible hybrid aerogel-based fabrics enable broadband electromagnetic wave management

As problematic interference from electromagnetic waves (EMWs) in modern human life continues to increase, broadband EMW management aerogels have received extensive attention in the safety and thermal management fields, but the mismatch in terms of their mechanical flexibility and functionality has limited their application. This work reports an ultra-lightweight (8.7 mg cm−3), superflexible, hyperelastic (≥95% strain), and superhydrophobic (contact angle: 157°) wearable hybrid aerogel-based fabric that offers both electromagnetic interference (EMI) shielding and infrared (IR) shielding functions. A nanotape-enabled multi-crosslinked hybridization strategy, in which freeze-drying-initiated hydrophobic -Si-O-Si- nanotape welds weak bacterial nanocellulose-silver nanowire interfaces perfectly, gives the fabric outstanding mechanical properties. Optimized synergy gain engineering between the metal and the semiconductor (antimony tin oxide nanoparticles) produces significant enhancements in the electrical conductivity (502.46 S m−1), the EMI shielding effectiveness (SE, 100 dB), and the IR shielding performance (ultralow thermal conductivity of 0.025 W m−1 K−1) of the fabric. The hybrid aerogel-based fabric is fabricated into broadband EMW management clothing, which has excellent prospects for safety and thermal management applications.