Anthropogenic Air Pollution Research Articles

Climate Change and Cardiovascular Disease: Who Is Vulnerable?

Climate change involves a shift in earth's climate indicators over extended periods of time due to human activity. Anthropogenic air pollution has resulted in trapping heat, contributing to global warming, which contributes to worsening air pollution through facilitating oxidizing of air constituents. It is becoming more evident that the effects of climate change, such as air pollution and ambient temperatures, are interconnected with each other and other environmental factors. While the relationship between climate change components and cardiovascular disease is well documented in the literature, their interaction with one another along with individuals' biological and social risk factors is yet to be elucidated. In this review, we summarize that pathophysiological mechanisms by ambient temperatures directly affect cardiovascular health and describe the most vulnerable subgroups, defined by age, sex, race, and socioeconomic factors. Finally, we provide guidance on the importance of integrating climate, environmental, social, and health data into common platforms to inform researchers and policies.

Coupling MATSim and the PALM Model System—Large Scale Traffic and Emission Modeling with High-Resolution Computational Fluid Dynamics Dispersion Modeling

To effectively mitigate anthropogenic air pollution, it is imperative to implement strategies aimed at reducing emissions from traffic-related sources. Achieving this objective can be facilitated by employing modeling techniques to elucidate the interplay between environmental impacts and traffic activities. This paper highlights the importance of combining traffic emission models with high-resolution turbulence and dispersion models in urban areas at street canyon level and presents the development and implementation of an interface between the mesoscopic traffic and emission model MATSim and PALM-4U, which is a set of urban climate application modules within the PALM model system. The proposed coupling mechanism converts MATSim output emissions into input emission flows for the PALM-4U chemistry module, which requires translating between the differing data models of both modeling systems. In an idealized case study, focusing on Berlin, the model successfully identified “hot spots” of pollutant concentrations near high-traffic roads and during rush hours. Results show good agreement between modeled and measured NOx concentrations, demonstrating the model’s capacity to accurately capture urban pollutant dispersion. Additionally, the presented coupling enables detailed assessments of traffic emissions but also offers potential for evaluating the effectiveness of traffic management policies and their impact on air quality in urban areas.

Relationships between water quality of a long-distance inter-basin water diversion project and air pollution emissions along the canal: Distributions, lag effects, and nonlinear responses

Understanding and quantifying the influences and contributions of air pollution emissions on water quality variations is critically important for surface water quality protection and management. To address this, we created a five-year daily data matrix of six water quality indicators—permanganate index (CODMn), NH3-N, pH, turbidity, conductivity, and dissolved organic matter (DOM)—and six air pollution indicators—O3, CO, NO2, SO2, 2.5 μm particulate matter (PM2.5), and inhalable particles (PM10)—using data from seven national monitoring stations along the world's longest water-diversion project, the Middle Route of the South-to-North Water Diversion Project in China (MR-SNWD). Multivariate techniques (Mann–Kendall, Spearman's correlation, lag correlation, and Generalized Additive Models [GAMs]) were applied to examine the nonlinear relationships and lag effects of air pollution on water quality. Air pollution and water quality exhibited marked spatial heterogeneity along the MR-SNWD, with all water quality parameters meeting Class I or II national standards and the air pollution indicators exceeding those thresholds. Except for CODMn and DOM, the other water quality and air pollution indicators exhibited significant seasonal differences. Air pollution exhibited significant lag effects on water quality at the northern stations, with NO2, SO2, PM2.5, and PM10 being highly correlated with changes in pH, with an average lag of 17 d. Based on the GAMs, lag effects enhanced the significant nonlinear relationships between air pollution and water quality, increasing the average deviance explained for CODMn, NH3-N, and pH by 93%, 24%, and 41%, respectively. These findings provide a scientific basis for protecting water quality along the long-distance inter-basin water-diversion project under anthropogenic air pollution.

Dependence of Pinus sylvestris (Pinaceae) Radial Growth on Meteorological Conditions and Anthropogenic Air Pollution: Data from Northwestern Part of Murmansk Oblast.

The influence of meteorological factors and anthropogenic air pollution on the radial growth of the Scots pine Pinus sylvestris L. was studied as dependent on the distance from the Pechenganickel mining and metallurgical plant (Nikel, Murmansk region). Three (control, buffer, and impact) zones of the pollution gradient were identified based on the contents of main polluting elements (S, Ni, and Cu) in the forest litter. Asignificant weakening of pine stands was observed in the impact zone and attributed to the combined effect of long-term anthropogenic pollution of the 1970s and unfavorable weather events of the mid-1980s. As the emission decreased from 1988 to 2018, the radial increment of P. sylvestris was observed to increase significantly (by up to 44%) in the impact zone and to remain much the same in the control and buffer zones. More recently, the radial increment of trees in the impact zone reached and even exceeded the values observed in the control zone, although the trees examined were relatively old. The finding demonstrated again the high adaptive capacity of P. sylvestris.

The Effects of Oxidative Stress on RNA Editing with Insight into the Relationship Between Air Pollution and Alzheimer's Disease

Human interactions with the environment today add pressure on the world’s resources and ecosystems, which in turn harm human health. Many anthropogenic environmental changes, including climate change, biodiversity loss, and pollution, have accelerated morbidity and mortality. Research across multiple countries have found correlations between anthropogenic air pollution exposure and neurological degeneration, particularly with Alzheimer’s disease (AD). RNA editing induced by oxidative stress is one possible mechanism in which air pollution increases the risk of AD. To study this further, RNA adenosine-to-inosine (A-to-I) alterations were analyzed to identify a mechanism linking air pollution to neurological degeneration. These alterations occur in RNA, most prevalently in the central nervous system (CNS). Adenosine deaminase acting on RNA (ADAR) enzymes mediate A-to-I alterations and are essential for mammalian development and survival. ADAR mediated alterations have been associated with AD and the A-to-I occurrence frequency may increase in polluted environments that trigger increased oxidative stress. To test this possibility, wildtype (WT) and ADAR knockout (adr-2(-) Caenorhabditis elegans in their first larval (L1) developmental stage were exposed to juglone solution for 0, 15, and 60 minute experimental settings. For the two worm strains, WT and adr-2(-), the 0 minute treatment was the control, the 15 minute treatment represented acute oxidative stress exposure, and the 60 minute treatment represented chronic exposure. RNA was extracted from both groups and quantitative Real Time PCR (qRT-PCR) was used to measure the expression of gst-4, an Alzheimer’s associated gene (sel-12), and adr-2 normalized to the expression of gpd-3, the housekeeping gene that corrected for systemic errors. The gst-4 gene expression confirmed that oxidative stress occurred. Lack of adr-2 gene significantly decreased sel-12 expression at acute exposure, but adr-2 gene expression in WT worms did not significantly change across treatments. It remains to be determined whether oxidative stress impacts RNA editing of target mRNAs. Future studies are needed to explore the role of adr-2 in promoting sel-12 expression.

Is Pollution the Primary Driver of Infectious Syndemics?

Syndemics, the adverse interaction of two or more coterminous diseases or other negative health conditions, have probably existed since human settlement, plant and animal domestication, urbanization, and the growth of social inequality beginning about 10-12,000 years ago. These dramatic changes in human social evolution significantly increased opportunities for the spread of zoonotic infectious diseases in denser human communities with increased sanitation challenges. In light of a growing body of research that indicates that anthropogenic air pollution causes numerous threats to health and is taking a far greater toll on human life and wellbeing than had been reported, this paper proposes the possibility that air pollution is now the primary driver of infectious disease syndemics. In support of this assertion, this paper reviews the growth and health impacts of air pollution, the relationship of air pollution to the development and spread of infectious diseases, and reported cases of air pollution-driven infectious disease syndemics, and presents public health recommendations for leveraging the biosocial insight of syndemic theory in responding to infectious disease.

Biogenic emission as a potential source of atmospheric aromatic hydrocarbons: Insights from a cyanobacterial bloom-occurring eutrophic lake

As important precursors of ozone (O3) and secondary organic aerosol (SOA), reactive aromatic hydrocarbons (AHs) have typically been classified as anthropogenic air pollutants. However, biogenic emission can also be a potential source of atmospheric AHs. Herein, field observations in a eutrophic lake were combined with laboratory incubation experiments to investigate the biogenic AH emission. Field work showed that the water-air fluxes of AHs measured at sites with high cyanobacteria abundance could reach an order of magnitude greater than those at sites with low cyanobacteria abundance, suggesting that cyanobacteria could be the important contributor to measured AHs. Laboratory incubation experiments further confirmed the AH emission of cyanobacteria and revealed that the emission could change significantly over the lifespan of cyanobacteria and varied to their growing conditions. By combining field observations and laboratory incubation experiments, it has been suggested that the emission of different AH species from cyanobacteria could be modulated by variable biogeochemical mechanisms and that the biochemical process of toluene could be different from that of other AHs. This study investigates AH emissions from inland aquatic ecosystem and suggests that biogenic emission could be a potential source of atmospheric AHs.

The synergistic effect of NOx and SO2 on the formation and light absorption of secondary organic aerosols from ο-xylene photooxidation

Both NOx and SO2 are important anthropogenic air pollutants that significantly affect secondary organic aerosols (SOA) formation. However, our understanding of the combined effects of NOx and SO2 on SOA formation is still insufficient. The concentrations, optical properties, and chemical compositions of SOA formed through ο-xylene photooxidation under various NOx concentrations were investigated with or without SO2 in the chamber. It was found that SOA mass concentration increased from 60 to 129 μg m−3 when the initial NOx concentration was increased from 0 to 900 ppb. The presence of 50 ppb SO2 not only enhanced ο-xylene SOA formation by 1.6–2.9 times, but also changed the evolution of SOA with NOx. The enhancement of ο-xylene SOA formation was primarily attributed to acid-catalyzed heterogeneous reactions initiated by nitric acid and sulfuric acid. However, SOA concentration decreased under 900 ppb NOx when SO2 was present, likely due to the decrease in sulfate production because of the competition between NOx and SO2 for ·OH. In addition, nitrogen-containing organic compounds (NOCs) concentrations and mass absorption coefficients (MACλ=365 nm) were promoted by both NOx and SO2. Our research indicates that the promotion of both NOCs formation by NOx, and oligomer formation by SO2 were the main reasons for the enhanced SOA light absorption. The present research provides a scientific basis for understanding the combined effects of both NOx and SO2 on ο-xylene SOA formation, and illustrates that the imbalanced reduction of anthropogenic air pollutants would lead to new characteristics in SOA pollution.

Variability in molecular composition and optical absorption of atmospheric brown carbon aerosols in two contrasting urban areas of China

Atmospheric brown carbon (BrC) aerosols were investigated at two urban sites in southern (Hefei) and northern (Shijiazhuang) China during summer and winter of 2019–2020 to explore regional variability in their compositional and optical properties. Organic matter in ambient PM2.5 samples were characterized at molecular level using ultrahigh performance liquid chromatography coupled with a diode array detector and an Orbitrap mass spectrometer. Although the molecular composition of organic aerosols varied substantially over different ambient environments, they were mainly composed by CHO and CHON species in positive ionization mode while CHO and CHOS species in negative mode. The mass absorption coefficients of BrC aerosols at wavelength range 250–450 nm were relatively higher for winter samples in both cities and for Shijiazhuang samples in both seasons, partly attributed to the higher concentration levels of anthropogenic air pollutants in these environments. The absorption Ångström exponents further revealed that BrC aerosols in winter seasons and in Shijiazhuang had a greater capacity of absorption at shorter wavelengths. A total of 26 BrC species with strong absorption were unambiguously identified from different environments, which mainly consisted of CHO, CHON, and CHN species and had higher degrees of unsaturation and lower degrees of oxidation. The presence and abundance of these BrC species varied dynamically across the seasons and cities, with a greater number of species presented in the winter of Shijiazhuang. The BrC species together contributed 12–26 % in the total absorbance of light-absorbing organic components at 250–450 nm. This study highlights the regional differences in BrC properties influenced by the sources and atmospheric processes, which should be taken into account to assess their climate impacts.

Improved hourly estimate of aerosol optical thickness over Asian land by fusing geostationary satellites Fengyun-4B and Himawari-9

Asian over-land aerosols are complexities due to a mixture of anthropogenic air pollutants and natural dust. The accuracy of the aerosol optical thickness (AOT) retrieved from the satellite is crucial to their application in the aerosol data assimilation system. Fusion of AOTs with high spatiotemporal resolution from next-generation geostationary satellites such as Fengyun-4B (FY-4B) and Himawari-9, provides a new high-quality dataset capturing the aerosol spatiotemporal variability for data assimilation. This study develops a complete fusion algorithm to estimate the optimal AOT over-land in Asia from September 2022 to August 2023 at 10 km × 10 km resolution with high efficiency. The data fusion involves four steps: (1) investigating the spatiotemporal variability of FY-4B AOT within the past 1 h and 12 km radius calculation domain; (2) utilizing the aerosol spatiotemporal variability characteristics to estimate FY-4B pure and hourly merged AOTs; (3) performing bias corrections for FY-4B and Himwari-9 hourly merged AOT for different observation times and seasons considering pixel-level errors for each satellite; (4) fusing the bias-corrected FY-4B and Himawari-9 hourly merged AOT based on maximum-likelihood estimation (MLE) method. Compared to the original FY-4B AOT, validation with AERONET observation confirms that the root mean square error (RMSE) of hourly merged FY-4B AOT decreases by around 40.6 % and the correlation coefficient (CORR) increases by about 27.8 %. Compared to FY-4B and Himawari-9 merged AOT, the fused AOT significantly decreases (increases) RMSE (CORR) by around 24.7 % (7.3 %) and 20.2 % (5.6 %). In addition, fused AOT is double the number of single-sensor merged AOT. Fusion aerosol map accurately describes the spatial and temporal variations in Asian regions controlled by air pollution and dust storms. Further studies are required for other landscapes with different satellite combinations to promote the application in the data assimilation system.

Moss as a Biomonitor to Identify Atmospheric Deposition of Minor and Trace Elements in Macedonia

The present work was carried out to obtain and highlight the fifth comprehensive baseline dataset on atmospheric deposition of trace elements and to assess air quality in Macedonia. In the period from August to September 2020, a total of 72 moss samples were collected in accessible areas in the country. The content of 28 elements (Ag, Al, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, Ga, Hg, K, La, Mg, Mn, Mo, Na, Ni, P, Pb, S, Sb, Sc, Sr, Ti, U, and Zn) was determined using inductively coupled plasma–mass spectrometry. Based on the data obtained on the content of the elements, a factor analysis was carried out to identify and characterise different sources of pollution. In addition, distribution maps were created for all elements to show the regions most affected by anthropogenic activities. The survey conducted in 2020 has shown that air pollution with potentially toxic elements (PTEs) has slightly decreased compared to the results of the previous survey from 2015. This is due to the fact that, despite the operation of all mining and smelting facilities with the same capacity, government regulations for the installation of cleaning systems and additional regulations to reduce pollution have been introduced in the last five years. Nevertheless, the fact remains that the highest anthropogenic air pollution with PTEs is still caused by the operation of the ferronickel smelter in Kavadarci (Ni and Cr) in the southern part and by the lead and zinc mines in Probištip, Makedonska Kamenica, and Kriva Palanka in the eastern part of the country (Cd, Pb, and Zn).

Improved childhood asthma control after exposure reduction interventions for desert dust and anthropogenic air pollution: the MEDEA randomised controlled trial

IntroductionElevated particulate matter (PM) concentrations of anthropogenic and/or desert dust origin are associated with increased morbidity among children with asthma.ObjectiveThe Mitigating the Health Effects of Desert Dust Storms Using Exposure-Reduction...

Responses of Ecosystem Productivity to Anthropogenic Ozone and Aerosols at the 2060

AbstractTerrestrial ecosystems help mitigate global warming by sequestering atmospheric carbon dioxide (CO2) through plant photosynthesis, the rate of which is affected by surface ozone (O3) and aerosols under simultaneous impacts of climate change and rising CO2. While the changes in anthropogenic emissions perturb atmospheric components, their consequent impacts on ecosystem productivity in the future climate remain unclear. Here, we apply a fully coupled climate‐chemistry‐vegetation model, ModelE2‐YIBs, to explore the effects of O3 and aerosols from anthropogenic emissions on global gross primary productivity (GPP) under different emission scenarios at 2060. At the present day, anthropogenic air pollutants induce a GPP loss of −1.67 Pg[C] (−4%) in boreal summer with the contributions of −2.18 Pg[C] by O3 and +0.52 Pg[C] by aerosols. At 2060, the detrimental effect of air pollutants on GPP is exacerbated to −1.85 Pg[C] under a high emissions scenario but alleviated to −0.59 Pg[C] under a low emission scenario. The mitigated GPP loss in the latter scenario is owing to the effective control of anthropogenic emissions that on average reduces surface O3 concentrations by 8.14 ppbv globally relative to 2010. Although the CO2 fertilization effect is weaker in the low emission scenario, the strong decline in air pollutants brings additional GPP gains compared to the high scenario. Regionally, such GPP amelioration is close to or even overweighs the CO2 fertilization effect in eastern China and United States, suggesting that the deep cut of anthropogenic emissions can effectively promote future ecosystem productivity over the nowadays polluted regions.

Enhanced sensing performance of carboxymethyl cellulose sodium to hydrogen sulphide gas and methylene blue dye by constructing CuO@ZnO core/shell heterostructure: A DFT/TD-DFT study

Anthropogenic air and water pollution are two of the world's most serious public health threats, causing around 9 million fatalities each year. Accordingly, CuO, ZnO, and CuO@ZnO core/shell structures were optimized utilizing the time-dependent density functional theory (TD-DFT) method to study the effect of CuO@ZnO core/shell on the sensitivity of carboxymethyl cellulose sodium (CMC). Absorption spectra and optical band gap (Eg) have been investigated utilizing the TD-DFT method. The calculated Eg values for CuO and ZnO equal 1.23 and 3.29 eV, respectively, which agree well with those reported in the literature. The effects of H2S gas and methylene blue dye (MB) adsorption on the electronic characteristics of dimer CMC /CuO@ZnO structures were investigated in terms of TDM, HOMO/LUMO energy, and molecular electrostatic potential (MESP). The TDM in dimer CMC/CuO@ZnO structure was increased to 72.152 and 67.606 Debye, while ΔE was reduced by 6.42% and 82.57% due to the adsorption of H2S and MB dye, respectively. This means that it has a faster response to MB than to H2S. Additionally, MESP confirms the increased reactivity of dimer CMC/CuO@ZnO due to the adsorption process. As a result, dimer CMC/CuO@ZnO structures appear to be attractive candidates for H2S and MB dye sensing applications.

Assessing anthropogenic contribution to PM2.5 from an urban residential area of Lagos, Nigeria using aliphatic hydrocarbon compounds as indicators

Aliphatic hydrocarbons in PM2.5 samples from a residential area of Lagos, Nigeria, were quantified using a Curie-point pyrolysis–gas chromatography–mass spectroscopy (CPPGC/MS). The total concentrations of ∑n-alkanes (C20-C34), hopanes (∑4Hopanes), and steranes (∑3Steranes) ranged from 1.8 to 146.6 ng m-3 (avg. 43.6 ± 35.1 ng m-3), 0.0 to 89.9 ng m-3 (avg. 18.7 ± 25.9 ng m-3), and 0.0 to 26.0 ng m-3 (avg. 3.3 ± 6.7 ng m-3), accounting for 0.2%, 0.1%, and 0.01% of the total PM2.5 mass concentrations, respectively. They also accounted for, 1%, 0.4% and 0.1% of the organic matter content, respectively, making them non-negligible component of the organic matter in this region. An evaluation of the n-alkanes source diagnostic indices revealed that engines powered by gasoline and diesel were the main sources of particulate matter aliphatic hydrocarbons in this area of Lagos, consistent with the results obtained from steranes and hopanes profiles. Based on the air mass trajectories, both local and regional air mass transports showed a significant influence on the amounts of carbonaceous materials and aliphatic hydrocarbon compounds arriving at the study site. The results from this study established the occurrence of anthropogenic air pollution in Lagos residential area with a major contribution from petrogenic sources.

Paul J. Crutzen – a pioneer in Earth system science and a founding member of the journal Atmospheric Chemistry and Physics

Abstract. Paul Jozef Crutzen was a pioneer in the atmospheric sciences, a kind-hearted and humorous person with empathy for the private lives of his colleagues and students, and a man who upheld the highest scientific standards for himself and for others. He made fundamental scientific contributions to a wide range of scientific topics in all parts of the atmosphere, from the mesosphere to the stratosphere and from the stratosphere to the troposphere. In particular, he was the first to describe the NOx-driven ozone depletion cycle in the stratosphere, he was among the first to develop the idea of chemical formation of ozone in the troposphere, he provided key concepts to explain the “ozone hole”, and he made fundamental discoveries about the effects of biomass burning on the troposphere. Understanding and addressing the causes of anthropogenic air pollution and climate change were the driving motivations for his scientific work. In his work, he did not shy away from challenge and provocation. His work on smoke from fires after a potential nuclear war inspired new research on a concept now known as “nuclear winter”. He also initiated the reopening of the debate on “geoengineering” – a concept now referred to as “climate intervention”. He also brought the term “Anthropocene” to the popular debate. Moreover, he had a strong influence on atmospheric science through his educational role; there is a very large number of outstanding scientists who started their career with scientific work with Paul. In 2000, Paul was among the founders of the journal Atmospheric Chemistry and Physics, which was unique at the time in providing public discussion of published preprints as well as what we now call “open access” to published articles. Paul's work on human impacts on atmosphere and climate has had a profound impact on the environmental policies of many countries for decades. In the future, his work will continue to be a guide for generations of scientists and environmental policymakers to come.

Contribution of Road Transport to Pakistan’s Air Pollution in the Urban Environment

The urban areas of Pakistan exhibit some of the world’s highest levels of air pollution, primarily due to sub-2.5 μm particulate emissions. This issue significantly impairs both the country’s economy and the quality of life of its residents. Road transport is a significant contributor to anthropogenic air pollution but there are discrepancies about the extent of its share. Source apportionment and sectoral inventory studies attribute anywhere between 5 and >80% of the total air pollution to vehicular sources. This uncertainty propagates into the transport policy interventions that are informed by such studies and can thus hinder the achievement of desired pollution mitigation targets. In an effort to reconcile such discrepancies and guide future studies and policy-making efforts, this paper critically reviews source apportionment studies conducted in the urban centres of Pakistan over the past two decades. The strengths and weaknesses of different approaches are compared, and results from the studies are discussed based on the emissions profile of Pakistan’s automotive fleet that emerges. Inconsistencies in the reporting of pollutant concentrations and interpreting their impacts without accounting for the relative disease burden of different pollutant species are found to be the major reasons for the large variations in the reported sectoral shares. At the end, a framework for regular air pollution monitoring and source tracking is proposed in which high-fidelity receptor-based studies inform lower-fidelity but economical sectoral inventory assessments.

Airborne Pesticides from Agricultural Practices: A Critical Review of Pathways, Influencing Factors, and Human Health Implications.

This critical review examines the release of pesticides from agricultural practices into the air, with a focus on volatilization, and the factors influencing their dispersion. The review delves into the effects of airborne pesticides on human health and their contribution to anthropogenic air pollution. It highlights the necessity of interdisciplinary research encompassing science, technology, public policy, and agricultural practices to effectively mitigate the risks associated with pesticide volatilization and spray dispersion. The text acknowledges the need for more research to understand the fate and transport of airborne pesticides, develop innovative application technologies, improve predictive modeling and risk assessment, and adopt sustainable pest management strategies. Robust policies and regulations, supported by education, training, research, and development, are crucial to ensuring the safe and sustainable use of pesticides for human health and the environment. By providing valuable insights, this review aids researchers and practitioners in devising effective and sustainable solutions for safeguarding human health and the environment from the hazards of airborne pesticides.

Consistent histories of anthropogenic western European air pollution preserved in different Alpine ice cores

Abstract. Individual high-Alpine ice cores have been proven to contain a well-preserved history of past anthropogenic air pollution in western Europe. The question of how representative one ice core is with respect to the reconstruction of atmospheric composition in the source region has not been addressed so far. Here, we present the first study systematically comparing longer-term ice-core records (1750–2015 CE) of various anthropogenic compounds, such as major inorganic aerosol constituents (NH4+, NO3-, SO42-), black carbon (BC), and trace species (Cd, F−, Pb). Depending on the data availability for the different air pollutants, up to five ice cores from four high-Alpine sites located in the European Alps analysed by different laboratories were considered. Whereas absolute concentration levels can partly differ depending on the prevailing seasonal distribution of accumulated precipitation, all seven investigated anthropogenic compounds are in excellent agreement between the various sites for their respective, species-dependent longer-term concentration trends. This is related to common source regions of air pollution impacting the four sites less than 100 km away including western European countries surrounding the Alps. For individual compounds, the Alpine ice-core composites developed in this study allowed us to precisely time the onset of pollution caused by industrialization in western Europe. Extensive emissions from coal combustion and agriculture lead to an exceeding of pre-industrial (1750–1850) concentration levels already at the end of the 19th century for BC, Pb, exSO42- (non-dust, non-sea salt SO42-), and NH4+, respectively. However, Cd, F−, and NO3- concentrations started surpassing pre-industrial values only in the 20th century, predominantly due to pollution from zinc and aluminium smelters and traffic. The observed maxima of BC, Cd, F−, Pb, and exSO42- concentrations in the 20th century and a significant decline afterwards clearly reveal the efficiency of air pollution control measures such as the desulfurization of coal, the introduction of filters and scrubbers in power plants and metal smelters, and the ban of leaded gasoline improving the air quality in western Europe. In contrast, NO3- and NH4+ concentration records show levels in the beginning of the 21th century which are unprecedented in the context of the past 250 years, indicating that the introduced abatement measures to reduce these pollutants were insufficient to have a major effect at high altitudes in western Europe. Only four ice-core composite records (BC, F−, Pb, exSO42-) of the seven investigated pollutants correspond well with modelled trends, suggesting inaccuracies of the emission estimates or an incomplete representation of chemical reaction mechanisms in the models for the other pollutants. Our results demonstrate that individual ice-core records from different sites in the European Alps generally provide a spatially representative signal of anthropogenic air pollution trends in western European countries.

Simulation of ecosystem responses to anthropogenic air pollution (OBS data for evaluation is included)

Simulation of ecosystem responses to anthropogenic air pollution (OBS data for evaluation is included)