Anisotropy Of The Magnetic Susceptibility Research Articles

Magnetization related to late-Variscan extensional collapse in the Lugo Dome (NW Iberian Massif): a metamorphic petrology approach

The Eastern Galicia Magnetic Anomaly (EGMA) is one of the most distinctive and best studied magnetic anomalies in Iberia. It is located in NW Spain and overlaps the Variscan gneissic domes of Lugo and Sanabria. The Lugo Dome, in the north of the EGMA, deforms a large thrust sheet, the Mondoñedo Nappe, allowing the outcropping of its relative autochthon in the Xistral Tectonic Window, where extensional detachments resulting from late-Variscan tectonics crop out. A younger major detachment, the Viveiro Fault, developed on the western limb of the dome. Detailed ground-based magnetic mapping and geological charts show a clear spatial relationship between magnetic maxima and the extensional structures. Magnetic and paleomagnetic studies carried out on samples from this region indicate that rocks in the detachments commonly bear magnetite and hematite carrying induced but also remanent magnetizations and a very well-defined anisotropy of the magnetic susceptibility with directions matching those of the late-Variscan extensional fabrics.Three pairs of metasedimentary samples in equivalent structural positions display variously developed medium-pressure Barrovian parageneses attributed to the early compressional phases of the Variscan orogeny, and low-pressure Buchan-type parageneses associated with the late Variscan extension. Our phase diagram-based petrological study suggests that the non-magnetic samples preserve the Barrovian conditions of 560–640 °C, 5–8.7 kbar. The lithologically and structurally equivalent samples, originally non-magnetic, developed magnetite/hematite-bearing mineral assemblages during decompression and cooling to 500–620 °C, 1.5–6 kbar. This recrystallization was probably assisted by metasomatic oxidizing fluids. The induced component of magnetization is essentially carried by magnetite, while hematite seems the main carrier of remanence. These results support the existing cartographic, geophysical and paleomagnetic findings indicating that the magnetization in the Lugo Dome is related to late-Variscan extension.

Deciphering Iberian Variscan Orogen Magmatism Using the Anisotropy of Magnetic Susceptibility from Granites

In this paper, we have synthesized the information derived from more than 20 papers and PhD theses on the anisotropy of the magnetic susceptibility (AMS) of 19 Variscan granite plutons, spanning the period between 320 Ma and 296 Ma. The AMS data are obtained from 876 sampling sites with more than 7080 AMS measurements and a re-interpretation is proposed. The studied granites exhibit a magnetic susceptibility (Km) ranging from 30 to 10,436 × 10−6 SI units. Most granites typically exhibit Km values below 1000 × 10−6 SI, indicative of paramagnetic behavior. Biotite serves as the main carrier of iron (Fe), emphasizing the reduced conditions prevalent during the formation of granite melts in the Variscan orogeny. The AMS fabrics of the studied granite plutons record the magma strain, expressing the chronologic evolution of the stress field during the orogeny. This chronologic approach highlights the magmatic events between around 330 and 315 Ma, occurring in an extensional regime, in which the Borralha pluton is an example of a suite that recorded this extensional AMS fabric. Plutons with ages between 315 and 305 Ma show AMS fabrics, pointing out their emplacement in a compressional tectonic regime related to the Variscan collision. The plutons, younger than 305 Ma, record AMS fabrics indicating that the tectonic setting for emplacement changes from a wrench regime to an extensional one at the end of the collision stage. This is evident as there is a chronological overlap between the granites that exhibit AMS fabrics indicating extension and the ones that have AMS fabrics indicating a wrench regime.

Paleoseismological Constraints on the Anghiari Normal Fault (Northern Apennines, Italy) and Potential Implications for the Activity of the Altotiberina Low‐Angle Normal Fault

AbstractThe NE‐dipping Anghiari normal fault, bounding to the west the Sansepolcro basin in the Upper Tiber Valley (northern Apennines), is thought to be a synthetic splay of the Altotiberina low‐angle normal fault (LANF), an active ENE‐dipping extensional detachment whose seismogenic behavior is debated. In order to assess the Anghiari fault capability to break the surface during strong earthquakes and be the source of historical earthquakes, we acquired high resolution topographic data, performed field survey and geophysical investigations (Seismic reflection, Ground Penetrating Radar, Electrical Resistivity Tomography) and dug three paleoseismological trenches across different fault sections of the Anghiari fault. The acquired data reveal for the first time the Late Pleistocene to historical activity of the Anghiari fault, constraining the age of seven paleo‐earthquakes over the last 25 ka, the youngest of which is comparable with one of the poorly constrained historical earthquakes of the Sansepolcro basin. The yielded slip rate is >0.2 mm/yr averaged over the last 25 ka and the recurrence interval is about 2,500–3,200 years. An analysis of the anisotropy of the magnetic susceptibility performed in one of the paleoseismological trenches revealed an extensional stress field, continuously acting during the sedimentation of the entire trenched stratigraphy. Our results confirm the ability of the Anghiari fault to generate surface faulting earthquakes. In addition, if the Anghiari fault does sole at depth into the Altotiberina low‐angle normal fault, this LANF could also be seismogenic and generateM > 6.

Anisotropy of the Paramagnetic Susceptibility in the 3D Dirac Semimetal Cd-=SUB=-3-=/SUB=-As-=SUB=-2-=/SUB=- Caused by Chromium Impurity: the EPR on Cr-=SUP=-3+-=/SUP=- Ions

In the literature devoted to magnetic impurities in Dirac semimetals, the appearance of anisotropic and long-range non-oscillating contributions to the Ruderman--Kittel--Kasuya--Yosida interaction is predicted. These contributions are due to the hybridization of the wave functions of magnetic impurities with the wave functions of Dirac electrons, which have a linear dispersion law. We have studied electron paramagnetic resonance (EPR) in powder samples of topological 3D Dirac semimetal Cd3As2 with an admixture of chromium ions. Anisotropy of the magnetic susceptibility in the paramagnetic state was found from the behavior of the resonance field. The appearance of magnetic anisotropy in the paramagnetic state is associated with an increase in the contribution of the orbital moments of chromium ions Cr2+ and Cr3+ due to their interaction with the orbital moments of donor Dirac electrons, which have anomalously large values of g factors. Keywords: magnetic resonance, topological materials, magnetic impurities.

Анизотропия парамагнитной восприимчивости дираковского полуметалла Cd-=SUB=-3-=/SUB=-As-=SUB=-2-=/SUB=-, обусловленная примесью хрома: ЭПР на ионах Cr-=SUP=-3+-=/SUP=-

In the literature devoted to magnetic impurities in Dirac semimetals, the appearance of anisotropic and long-range non-oscillating contributions to the Ruderman–Kittel–Kasuya–Yosida interaction is predicted. These contributions are due to the hybridization of the wave functions of magnetic impurities with the wave functions of Dirac electrons, which have a linear dispersion law. We have studied electron paramagnetic resonance (EPR) in powder samples of topological 3D Dirac semimetal Cd3As2 with an admixture of chromium ions. Anisotropy of the magnetic susceptibility in the paramagnetic state was found from the behavior of the resonance field. The appearance of magnetic anisotropy in the paramagnetic state is associated with an increase in the contribution of the orbital moments of chromium ions Cr2+ and Cr3+ due to their interaction with the orbital moments of donor Dirac electrons, which have anomalously large values of g factors.

Bending a graphene cantilever by a diamagnetic force

The application of a magnetic field perpendicular to the surface of a graphene cantilever generates a bending force owing to the strong anisotropy of the magnetic susceptibility. We calculate the mechanically stable equilibrium shape of a graphene cantilever in the presence of a magnetic field by minimizing the magnetic and bending energies, which are calculated using the tight-binding model and the Tersoff–Brenner potential, respectively. Furthermore, the introduction of a continuous model enables the size-dependence of the displacement by bending to be considered.

Grain boundary dynamics and selective grain growth in non-ferromagnetic metals in high magnetic fields

Abstract Grain boundary motion can be affected by a magnetic field if the anisotropy of the magnetic susceptibility generates a gradient of the magnetic free-energy density across the boundary. Due to this magnetic driving force, annealing of locally deformed single crystals in high magnetic fields results in growth selection. The character distribution of the boundaries connected to growth selection is found to be far from random. If a magnetic energy density gradient as a driving force is superimposed to a curvature driving force during grain growth, this biases the microstructure evolution with regard to grain size and crystallographic texture, as it is demonstrated on polycrystalline zinc and titanium. Analysis of individual orientation data reveals that the observed asymmetrical texture stems to a large extent from a difference in grain numbers of the individual texture components.

The anisotropic properties of granites – effects of tectonic emplacement mode on potential crystalline host rocks for nuclear waste deposits in Germany

Abstract. For permanent nuclear waste disposal sites, crystalline rocks, especially granitic/granodioritic batholiths, are considered an appropriate host rock. Principally, three types of granitic plutons occur in the extra-alpine crystalline basement of Germany that were consolidated during the late Paleozoic Variscan orogeny of Central Europe: (i) Pre-Variscan voluminous granodiorites that are hardly affected by the subsequent continent–continent collision; (ii) voluminous granites in various tectonic settings intruded during the late orogenic stage of the Variscides; (iii) post-orogenic granites related to vast Permian intracontinental extension. Thus, in terms of the syn-intrusive tectonic setting and post-intrusive processes there are significant differences. Although it can be expected that different tectonic environments caused significant differences in the material properties, for Germany, however, there is no systematic study regarding the fabric of such plutonites. In order to find the most suitable “granite” we investigate the primary anisotropy of granites evolved during the emplacement and crystallization of the melt. For this we sample rocks of all three principal types and various syn-intrusive tectonic settings, i.e., compression, extension, strike-slip, transtension, and transpression. By means of combined measurements of the “Anisotropy of the Magnetic Susceptibility” and the “Shape Preferred Orientation” we characterize the syn-intrusive flow pattern, i.e., the magmatic foliation and lineation. The Crystallographic Preferred Orientation is analyzed by a combination of neutron time-of-flight experiments and electron backscatter diffraction measurements at the Frank Laboratory of Neutron Physics at JINR, Dubna, Russia, and the TU Bergakademie Freiberg respectively. Furthermore, special attention is given to the systematic mapping of annealed microcracks evolved during late magmatic fluid escape and/or post-crystallization hydrothermal activity. In a second step we compare the primary anisotropy with the post-magmatic fracture pattern of the particular granites. Those fractures constitute probable fluid pathways and, thus, the first-order risk for a potential permanent nuclear waste disposal. All datasets are organized in a Geological Information System allowing for a complete traceability of the different investigation steps. The results of this study will serve as a basis for a future detailed exploration.

Characterizing the Source of the Eastern Galicia Magnetic Anomaly (NW Spain): The Role of Extension in the Origin of Magnetization at the Central Iberian Arc

AbstractThe Eastern Galicia Magnetic Anomaly is the best studied anomaly of the Central Iberian Arc. This is due to its location, on the Lugo‐Sanabria gneiss dome, and to the fact that its source rocks crop out in the Xistral Tectonic Window. Multiple studies of this anomaly have been carried out, but still, new results keep on shedding light on its understanding. This paper presents the first results on rock magnetic analyses, natural remanent magnetization, anisotropy of the magnetic susceptibility, X‐ray diffraction, and stable isotopes geochemistry carried out on the source rocks of this anomaly. Results suggest that magnetization responds to the increase in oxygen fugacity underwent by rocks affected by late Variscan (330‐300 Ma) extensional tectonics. Extensional detachments were the pathways that allowed the entrance of fluids that led to syntectonic crystallization of magnetite and hematite in metasediments and inhomogeneous S‐Type granitoids derived from their partial melting. Accordingly, magnetization is not linked to lithologies, but to extensional structures developed in the late Carboniferous/earliest Permian, during the Kiaman reverse superchron. Systematic reverse magnetic remanence exhibited by hematite‐bearing samples confirms the age of the magnetization and adds complexity to the interpretation of the anomaly. Understanding the EGMA contributes to the interpretation of other anomalies existing in the CIA, also located on thermal domes. The observed extension‐related magnetization probably affected most of the NW Iberian Massif, thus hindering the study of previous tectonics by paleomagnetic techniques. This work aims to provide new hints to interpret magnetic anomalies located in extensional tectonic contexts worldwide.

Magnetic Susceptibility Properties of Loess From the Willendorf Archaeological Site: Implications for the Syn/Post-Depositional Interpretation of Magnetic Fabric

At the Willendorf site Upper Paleolithic archeological layers associated to early Aurignacian cultures were found. The environmental conditions of the associated society, potentially co-existing with Neanderthal groups, is still not fully understood. Here, we report on environmental magnetic analyses including anisotropy of the magnetic susceptibility (AMS) carried out on loessic aeolian sediments at the Willendorf site. Data on lineation, foliation and the degree of anisotropy were used to assess depositional and post-depositional magnetic fabric properties and to deduce site-specific environmental processes. Overall, the loess is of aeolian origin and shows magnetic enhancement and magnetic fabric properties similar to those of other European loess geoarchives, but the magnetic mineralogy differs from many ‘dry’ loess sites, insofar as it shows a higher susceptibility during heating. We infer an enhanced neoformation of magnetite during heating due to the presence of organic matter. While at face value the AMS properties are indicative of pure aeolian loess consistent with previous studies, imbrication suggests post-depositional slope movement toward the Danube, which obscures inferences on palaeo-wind direction. It is well possible that these post-depositional magnetic fabric alterations occur at other localities with similar geomorphological settings.

High-Spin Cobalt(II) Complex with Record-Breaking Anisotropy of the Magnetic Susceptibility According to Paramagnetic NMR Spectroscopy Data

The tetrahedral cobalt(II) complex [CoL2](HNEt3)2 (I), where L is 1,2-bis(methanesulfonamido)benzene, exhibiting the properties of a single-molecule magnet is synthesized and characterized. The electronic structure parameters of complex I are determined by paramagnetic NMR spectroscopy. They completely reproduce the results of less available methods of studying single-molecule magnets. The value of axial anisotropy of the magnetic susceptibility estimated for complex I (Δχax = 34.5 × 10–32 m3 at 20°C) is record-breaking among all transition metal complexes studied by the NMR method, which provides wide possibilities for the use of complex I as a paramagnetic label for structural biology or as a contrast agent and even a temperature sensor for medical diagnostics. The data obtained indicate the advantages of paramagnetic NMR spectroscopy as a method of investigation of the magnetic properties and electronic structures of highly anisotropic transition metal complexes, which are precursors of many functional materials.

Ferromagnetic Kitaev interaction and the origin of large magnetic anisotropy in α-RuCl3

$\alpha$-RuCl$_3$ is drawing much attention as a promising candidate Kitaev quantum spin liquid. However, despite intensive research efforts, controversy remains about the form of the basic interactions governing the physics of this material. Even the sign of the Kitaev interaction (the bond-dependent anisotropic interaction responsible for Kitaev physics) is still under debate, with conflicting results from theoretical and experimental studies. The significance of the symmetric off-diagonal exchange interaction (referred to as the $\Gamma$ term) is another contentious question. Here, we present resonant elastic x-ray scattering data that provides unambiguous experimental constraints to the two leading terms in the magnetic interaction Hamiltonian. We show that the Kitaev interaction ($K$) is ferromagnetic, and that the $\Gamma$ term is antiferromagnetic and comparable in size to the Kitaev interaction. Our findings also provide a natural explanation for the large anisotropy of the magnetic susceptibility in $\alpha$-RuCl$_3$ as arising from the large $\Gamma$ term. We therefore provide a crucial foundation for understanding the interactions underpinning the exotic magnetic behaviours observed in $\alpha$-RuCl$_3$.

Determining the local low-energy excitations in the Kondo semimetalCeRu4Sn6using resonant inelastic x-ray scattering

We have investigated the local low-energy excitations in CeRu$_4$Sn$_6$, a material discussed recently in the framework of strongly correlated Weyl semimetals, by means of Ce $M_5$ resonant inelastic x-ray scattering (RIXS). The availability of both $^2$F$_\frac{5}{2}$ and $^2$F$_\frac{7}{2}$ excitations of the Ce $4f^1$ configuration in the spectra allows for the determination of the crystal-electric field parameters that explain quantitatively the temperature dependence and anisotropy of the magnetic susceptibility. The absence of an azimuthal dependence in the spectra indicates that all crystal-electric field states are close to being rotational symmetric. We show further that the non-negligible impact of the $\check A_6^0$ parameter on the ground state of CeRu$_4$Sn$_6$ leads to a reduction of the magnetic moment due to multiplet intermixing. The RIXS results are consistent with inelastic neutron scattering (INS) data and are compared to the predictions from \textsl{ab-initio} based electronic structure calculations.

The carriers of AMS in remagnetized carbonates. Insights for remagnetization mechanism and basin evolution

Magnetic fabrics are usually studied to unravel the evolution of sedimentary basins, mainly focusing the attention in paramagnetic minerals. However, since basins are sometimes affected by burial-related chemical remagnetizations, magnetic fabrics can also be carried by authigenic ferromagnetic minerals related to remagnetization processes. Consequently, the study of the different types of fabrics can give complementary and valuable information about the evolution of sedimentary basins. Here, we explore, in the Jurassic carbonates of the Central High Atlas (Morocco), the role in magnetic fabrics of authigenic magnetite that grew during the Cretaceous (ca. 100 Ma) widespread remagnetization event.Magnetic fabrics are studied in 53 sites using the anisotropy of the magnetic susceptibility measured at room temperature (RT-AMS) and comparing results with sub-fabrics that alternatively enhance the paramagnetic and the ferromagnetic signal. Furthermore, an innovative analysis is proposed, comparing the magnetic fabrics before and after bedding correction (the common procedure) with fabric orientation after partial bedding correction. We use the paleomagnetic information to reconstruct the attitude of bedding at the remagnetization time and to restore the magnetic fabrics at this time.The performed analysis allows interpreting RT-AMS in terms of the contribution of different subfabrics, and the relationship between these, tectonic processes and the magnetic mineralogy. Four RT-AMS types are defined: T1 is carried by superparamagnetic magnetite that grew during the remagnetization stage and shows a horizontal lineation parallel to the extension direction at this time; T3 and T4 are carried by paramagnetic minerals and show compressive fabrics with the magnetic lineation parallel to intersection (bedding-cleavage) lineation; finally, T2 shows a mix between ferrimagnetic and paramagnetic fabrics.

Analysis of the magnetic properties of Ce3Pt23Si11: orthorhombic crystal field and mean-field approximation

We present here a quantitative analysis of the ground state and magnetic properties of Ce3Pt23Si11, based on a crystalline electric field description within the mean-field approximation. In this face-centered cubic compound, the point group symmetry at the Ce site is orthorhombic. One main difficulty in this low symmetry case is that the CEF potential for Ce3+ ions is determined by five independent parameters, while only two magnetic excitations are observed by inelastic neutron scattering. Moreover the anisotropy of the magnetic susceptibility of the Ce ion, that permits an independent determination of the second-order CEF parameters is hidden by the cubic symmetry of the compound. A specific procedure is developed for this purpose that combines genetic algorithms and more conventional optimization methods. A set of CEF parameters is found that best reproduces the different experimental observations in both the paramagnetic and ferromagnetic phases of Ce3Pt23Si11. The analysis accounts for two seemingly contradictory properties: a strong local anisotropy that aligns the moment along a fourfold axis and a rather weak anisotropy of the bulk magnetization with an easy threefold magnetization axis. Ce3Pt23Si11 is shown to be a model system where single site anisotropies compete within a crystal structure of overall high symmetry.

Colossal Anisotropy of the Dynamic Magnetic Susceptibility in Low-Dimensional Nanocube Assemblies.

One of the ultimate goals of nanocrystal self-assembly is to transform nanoscale building blocks into a material that displays enhanced properties relative to the sum of its parts. Herein, we demonstrate that 1D needle-shaped assemblies composed of Fe3-δO4 nanocubes display a significant augmentation of the magnetic susceptibility and dissipation as compared to 0D and 2D systems. The performance of the nanocube needles is highlighted by a colossal anisotropy factor defined as the ratio of the parallel to the perpendicular magnetization components. We show that the origin of this effect cannot be ascribed to shape anisotropy in its classical sense; as such, it has no analogy in bulk magnetic materials. The temperature-dependent anisotropy factors of the in- and out-of-phase components of the magnetization have an extremely strong particle size dependence and reach values of 80 and 2500, respectively, for the largest nanocubes in this study. Aided by simulations, we ascribe the anisotropy of the magnetic susceptibility, and its strong particle-size dependence to a synergistic coupling between the dipolar interaction field and a net anisotropy field resulting from a partial texture in the 1D nanocube needles.

Controls of structural inheritance on orogenic curvature and foreland basin sedimentation: Insights from the Przemyśl area, Western Carpathians

Orogenic curvatures can have various origins and are widely debated worldwide. In the Poland-Ukraine border area, the Outer Western Carpathians are characterized by a marked curvature. The origin of this curvature was analysed by integrating stratigraphic information with structural constraints and anisotropy of the magnetic susceptibility (AMS) data. Hangingwall frontal ramp domains are characterized by a relatively simple deformation dominated by layer-parallel shortening and folding around a regional NW-SE trending axis, recorded by an AMS lineation with a similar trend. On the other hand, the N-S trending hangingwall oblique ramp domain is characterized by maximum AMS axes recording transpressional strain either dominated by simple shear (sub-horizontal AMS lineation) or pure shear (steeply plunging AMS lineation) components. Early Miocene basin inversion with two distinct depocentres created a number of different detachment surfaces and thickness variations for the sedimentary successions involved in thrusting. The main depocentre of the Lower-Middle Miocene foredeep was originally located in the recess area of the curved Carpathian front. On the other hand, the occurrence of a salient to the west resulted in the axial zone of the foreland flexure being filled with allochthonous units, thereby dramatically reducing the accommodation space for foredeep sediments in this area. Our results suggest that thrust-belt geometry was controlled by the inherited Mesozoic extensional basin architecture.

The Taratash indenter and its role in the geological structure of the Urals

This work presents the results of studying zones bounded by the Archean and Early Proterozoic Taratash block, which breaks the meridional structure of the Urals, pinching its structural zones at the latitude of the town of Miass. The mesostructures of rupture zones, microtextures of tectonites, anisotropy of the magnetic susceptibility, and seismic-wave propagation rate in blastomylonites were studied. The kinematic history of the Taratash block consists of two phases: (1) exhumation in the Middle Riphean under conditions of crustal extension; and (2) the formation of an indenter in the Late Paleozoic under conditions of compression.

The relationships of thrust and shear deformations in the southern part of the Polar Urals as indicated by petromagnetic data

Based on the petromagnetic characteristics of rocks that crop out within the Main Ural Fault zone (MUF) and Voykar–Synya ophiolites the multistage pattern of deformation processes in the study areas has been established. An analysis of the anisotropy of magnetic susceptibility of rock minerals detected the orientation, which allows us to reveal magnetic orientations in minerals recorded as a results of thrust (overthrust) and strike-slip deformations at an early stage of the evolution of the Ural orogenic belt. The main axes of the ellipsoid of anisotropy of the magnetic susceptibility (AMS) associated with regional thrusting, namely, the main stage of formation of the structure of the Urals, have rarely been revealed. This is evidence that thrust petrofabrics are almost completely veiled by superimposed shear deformations.

Thrust and strike-slip deformations on the southern part of polar Urals based on the rock magnetic data

Petromagnetic characteristics rocks croup out in the Main Uralian Fault zone and Voikar- Synya ophiolites confirmed that multistage deformation led to formation of modern structure of Ural. Analysis of the anisotropy of the magnetic susceptibility of rock minerals detects orienta- tion formed by the thrust (reverse faults) and strike-shear strain at an early stage of the Uralian orogeny. The main axes of the ellipsoid of the anisotropy of magnetic susceptibility associated with regional thrusting - the main stage of formation of structure of the Urals have been revealed rarely. It indicates almost complete resetting thrust petrofabric by later shear deformations.