Anisotropic Characteristics Research Articles

Simple Models of Directly Measured Energy Landscapes for Different Shaped Particles in Nonuniform AC Electric Fields.

We report direct measurements of potential energy landscapes for different shaped colloidal particles interacting with nonuniform AC electric fields. Epoxy particle shapes investigated include disks, ellipses, squares, rectangles, and rhombuses, which are all part of the superelliptical prism shape class and are chosen to systematically vary particle anisotropy and corner features. The measurement configuration consists of noninteracting single particles sedimented onto microscope slides within electric fields between parallel coplanar electrodes. Thermally sampled positions and orientations of single particles in nonuniform fields are tracked in an optical microscope, and measured potential energy landscapes are obtained via Boltzmann inversions. We develop a new analytically simple model that captures all measured energy landscapes for superelliptical prism shaped colloidal particles with electrostatic double layers. The model recovers known validated potentials for spherical and ellipsoidal particles, and therefore captures energy landscapes for a variety of different colloidal particle sizes, shapes, and materials reported in prior studies.

Temperature‐dependent heat transfer deterioration in ordered graphene/ceramic composites

AbstractBoosting heat transfer of ultrahigh temperature ceramics (UHTCs) with dimensional‐crossover graphene has become an increasing challenge for improving the thermal protective performance of new‐generation spacecraft. Yet its characteristics of anisotropic and high interfacial thermal resistance inevitably cause heat transfer deterioration at high temperatures. Here we develop a few ZrB2/graphene/ZrB2 interface‐dominated diffuse models that are driven by bonding configurations and thermal converger. It has been found that forming stronger bonding configurations by Zr‐C interfacial bonding and designing a preferred thermal converger by ordered graphene are both unarguable ways of suppressing high‐temperature heat transfer deterioration. Each Zr‐C interfacial bonding serves as an independent sluice gate to accelerate heat flow. More high‐frequency phonons are excited at high temperature, which augments the interfacial thermal conductance from 38.5 to 335.4 MW·m−2·K−1 at 700 K. Impressively, a concept of thermal converger inspires us to adopt ordered graphene for changing the diverging behavior in isotropic ZrB2 composites. Its convergent process combines with anisotropic characteristics to transform the isotropic heat flow into the highly ordered graphene. Their thermal conductance can be regulated from minimum (2.5) to maximum (80.8 W·m−1·K−1) by rotating the ordered graphene from 90° to 7.5°. This work paves an optimal way for manipulating the heat transfer of UHTCs.

Investigation of dynamic impact behavior of bighorn sheep horn

The horn of the bighorn sheep is composed of keratin-based biological material that has a tubule-lamella structure, which gives it anisotropic hardening properties under impact loading. This paper aims to investigate the energy dissipation mechanisms inherent in bighorn sheep horns by developing a numerical material model that accounts for the horn’s anisotropic features and strain-rate effects. To this end, a transversely isotropic constitutive model, which includes both anisotropic hardening and strain-rate effects, was formulated to accurately predict the mechanical behavior of bighorn sheep horns. Material characterization was conducted through uniaxial compression tests that were conducted under quasi-static and dynamic conditions. The developed constitutive model was implemented into LS-Dyna via a user-defined material subroutine and was validated against empirical data. The validated numerical model was used to investigate the horn’s mechanical responses under dynamic loading conditions. The paper focused on impact energy dissipation mechanisms, including energy absorption and transition, stress distribution, and displacement wave propagation. The insights gained from this paper are expected to significantly contribute to the development of novel artificial materials with enhanced energy absorption and impact mitigation properties.

Linear and nonlinear ultrasound parameters attributed to anisotropy in granite

The anisotropic nature of granite, a key factor affecting its mechanical properties, is inherently governed by its mineral alignment and the presence of orthogonal cleavage planes: rift, grain, and hardway. This study examines how these cleavage planes influence anisotropy, particularly in the context of microcracking formation and acoustic properties. A new measurement procedure for the acoustic nonlinearity parameter (\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\:\\beta\\:$$\\end{document}) is developed to address the well-known limitations of conventional linear ultrasound methods, including wave velocity and attenuation coefficient, in detecting microstructural changes induced by existing cleavage planes. Unlike other parameters, \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\:\\beta\\:$$\\end{document} exhibits remarkable changes depending on the plane type, highlighting its high sensitivity to the mineral distribution in each cleavage plane and to the microcracks. A correlation between the linear and nonlinear parameters provides further evidence of the superiority of \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\:\\beta\\:$$\\end{document} in detecting inherent microscale defects that develop in each plane and affect the anisotropic characteristics of granite. The findings of this study confirm that nonlinear ultrasound is capable of elucidating the mechanisms underlying the origin of anisotropy in granite due to microcracks, with broader implications for understanding unidentified chemical and mechanical phenomena in geological materials.

Dual-Mode Stretchable Emitter with Programmable Emissivity and Air Permeability.

Materials with anisotropic emission characteristics have attracted considerable attention for thermal management. Although many dual-mode emitters have been developed for this purpose in the form of textiles, multilayer films, and photonic structures, multiple functionalities are essential for their versatile applications. Herein, a highly stretchable dual-mode emitter with programmable emissivity and air permeability is presented. The emitter comprises a planar Ge2Sb2Te5 (GST) cavity on one side of a perforated elastomer substrate and an infrared-reflecting metal layer on the other side. With a laser-induced phase transition from amorphous to crystalline GST, the emitter exhibits a large emissivity difference of 0.52 between both sides. The dual-mode emitter remains highly stable without mechanical failure after repeated stretching cycles to a strain of 50%. This air-permeable and stretchable emitter can be attached to any curved surface, including the human body. The GST-side emissivity can be programmed into an arbitrary emissivity pattern using a spatially modulated laser beam, ultimately enabling the printing of mutually independent visible and thermal images in a single emitter. This study provides a promising structure for multispectral optical security as well as thermal management.

Mechanical characterization of large diameter UHMWPE ropes under quasi-static tensile loading: An experimental study

The Large diameter UHMWPEFR (Ultra High Molecular Weight Polyethylene Fiber Rope) are ideal for heavy lifting and slinging, with their mechanical properties and behaviour characterisation are key to the application.Therefore, this study conducts uniaxial tensile tests on a 115 mm diameter rope (FR-115) to investigate its mechanical properties under quasi-static tensile conditions. considering the anisotropic structural characteristics of UHMWPEFR, a method and criteria for eliminating inter-strand gaps and uneven force through pre-tensioning were proposed. Subsequently, tensile tests were carried out to examine the mechanical properties and constitutive relationship of the rope. The experimental results indicate that pre-tensioning can effectively eliminate the influence of non-elastic deformation of the rope, meeting the formal tensioning requirements based on the stability criteria of the rope structure constructed from mechanical and physical parameters. The stress-strain curve of FR-115 shows a linear bilinear shape without a yield segment during the tensioning process, presenting a typical brittle failure mode. The mechanical behavior is closely related to the historical load effects and loading speed, with the rope transitioning from soft and tough to hard and brittle, exhibiting hysteresis. Based on the above analysis, the graded load and time-varying modulus parameter are fixed, and the internal force is more sensitive to the quasi-static tensile velocity; a two-stage principal model is established based on the analysis of curve characteristics and time-dependent correlation, with 50 % MBS(Minimum Break Strength) as the characterization point, and the UHMWPEFR principal relationship in the pre-period is linear-elastic, and the strain-rate effect is taken into account for the dense section, and the rate correlation and nonlinear characteristics of the dense section of the rope can be accurately portrayed with the introduction of Cowper-Symonds.

Anisotropy and lateral compressive strength of large-size cement-stabilized macadam for bulging deformation resistance: A numerical analysis

Large-size cement-stabilized macadam (LCSM) base effectively hinders bulging deformation in asphalt pavements. Under vibratory compaction, the embedded skeleton structure and anisotropy of large-size aggregates (LSA) impact the mechanical properties of LCSM mixes. To reveal the mesostructure and anisotropy of LSA and determine the optimal volume percentage of LSA in LCSM mixes against bulging deformation, this study first characterized the bulging deformation resistance of LCSM mixes using lateral compressive strength (LCS). Next, the evolution of coordination number (CN) and distributions of contact force and contact normal for LSAs at different volume percentages under dynamic cyclic loading were investigated using the discrete element method (DEM). In particular, the induced anisotropic behavior was explored. Then, indoor tests and numerical simulations were conducted to assess the mixes’ LCS and vertical compressive strength (VCS); additionally, the compressive damage characteristics were analyzed. The results indicate that increasing the volume percentage of LSA and dynamic cyclic loading enhanced the CN, strong contact force, and contact normal density. LSAs at varying volume percentages exhibited pronounced anisotropic characteristics before and after loading, and the anisotropy factor of the LSA dropped after loading at a volume percentage of 65 %. Furthermore, the mixes’ VCS values exceeded LCS ones at the same LSA volume percentage, and there was a consistent relationship between the LSA anisotropy and the VCS/LCS ratio, suggesting that the optimal LSA volume percentage in LCSM mixes ranged from 60 % to 65 %. Finally, as the LSA volume increased, the skeleton effect became more pronounced than the interface attenuation effect, leading to higher VCS and LCS values in the mixes, thus improving their resistance to bulging deformation.

Enhanced Photodetection Performance of InBiSe3/ReS2 Polarization-Sensitive Heterostructure Photodetectors.

Individual anisotropic two-dimensional (2D) materials have been widely applied for developing polarization-sensitive photodetectors, but they often suffer from limitations in photoresponsivity, detection range, etc. To overcome these challenges, van der Waals (vdW) heterostructures created by stacking different 2D materials provide a promising solution to enhance the performance of the photoelectronic device. In this work, a novel polarization-sensitive photodetector is developed by leveraging a heterojunction formed by InBiSe3 and anisotropic ReS2 nanoflakes. The InBiSe3/ReS2 vdW heterostructure devices exhibit excellent photodetection performance with a high photoresponsivity (R)of 7.68 AW-1 and a specific detectivity (D*)up to 1.26×1011 Jones as well as an external quantum efficiency (EQE) of 1790% under 532 nm laser irradiation. Additionally, benefiting from the broadband light absorption of InBiSe3 crystals together with the pronounced anisotropic electronic and optical characteristics of ReS2 flakes, the devices demonstrate a broad spectral response range from 402 to 1006 nm with a distinct polarization sensitivity of 1.24. Moreover, the devices exhibit extraordinary optical communication and high contrast polarimetric imaging capacity. This work demonstrates the enhanced photodetection performance with the InBiSe3/ReS2 vdW heterostructures operating in a photoconductive mode and illustrates promising application of these heterostructures in integrated optoelectronic systems.

Analysis of the features of the operating conditions of modern gas turbine blades and review of methods for determining their high-temperature strength parameters

The subject of the study is modern methods and materials for the manufacture of gas turbine blades, as well as approaches and methods for assessing their dynamic and static strength under high-temperature loading. The first purpose of the article is to describe the main methods of manufacturing turbine blades, provide examples of the materials used and the features of their crystal structure. The second purpose of the article is to review approaches to ensuring the dynamic and static strength parameters of single-crystal turbine blades, in particular, to avoid dangerous resonance modes, to study the parameters of anisotropic creep, high-temperature fatigue life, and long-term strength. The goal of the article is to highlight the main advantages and disadvantages of existing methods, approaches and techniques for assessing and ensuring high-temperature strength parameters of turbine blades under static and dynamic loading, in order to select the objectives of further research. Methods used to create the publication: methods of analysis and comparison, which were used to search and compare open literature sources of information in accordance with the purpose of the article, as well as the method of deduction, which was used to identify the main shortcomings of existing methods for assessing the high-temperature strength of gas turbine blades under static and dynamic loading to outline the goals of further research. The following results have been obtained. Literature sources related to the methods of manufacturing turbine blades, namely, directional crystallization and single-crystal casting, were analyzed. The advantages of single-crystal alloys for the manufacture of turbine blades, namely increased heat strength, heat resistance, fatigue strength, durability and crack resistance, are emphasized. The main modern methods for assessing the high-temperature strength of gas turbine blades with regard to the anisotropic characteristics of single-crystal alloys are analyzed and described. Conclusions. This publication presents information about gas turbine blades, in particular, provides meaningful information about the methods of their manufacture, as well as the materials used to produce them. The study analyses and identifies the main damaging effects on gas turbine blades during their operation. The material describes the achievements of scientists who have developed numerical and experimental methods for assessing the impact of the anisotropic characteristics of single-crystal nickel heat-resistant alloys on the fatigue strength, durability and creep of turbine blades.

Manipulating formation of different InGaAs/GaAs nanostructures via tailoring As4 flux

This research provides a flexible approach to manipulate formation of InGaAs nanostructures on the GaAs (100) surface by varying arsenic (As4) beam equivalent pressure (BEP). By selecting the As4/(In+Ga) BEP ratio to be 4, 8, 20, 50 and 100, we were able to obtain different quantum structures from quantum well (QW) to quantum dots (QDs), then to spatially ordered quantum dot chains (QD-chains), and finally to quantum wires (QWRs), respectively. This transformation of nanostructures was explained by anisotropic surface diffusion coupled with the strain relieving Stranski–Krastanov growth mode, while the anisotropy was modulated by increasing As4 flux and subsequently enhanced by multilayer-stacking growth with a suitable spacer thickness. Photoluminescence characteristics show correlation to the nanostructure morphology for each sample. In particular, the formation of QD-chains and QWRs results in anisotropic features that offer potential device applications.

Simulation and experimental verification of the orthogonal friction continuous wear of PTFE-Kevlar fabric liner

Woven fabric liners, which are customizable and maintenance-free, have extensive applications in self-lubricating spherical bearings. However, owing to the orthogonal anisotropy and non-homogeneous characteristics, their frictional and wear behaviors are complex. Currently, average performance testing is primarily based on long-term macroscopic wear experiments. However, unobservable parameters such as mesoscopic stress and pressure distribution in liners are bottlenecks in the experimental exploration of wear sources and mechanisms. Therefore, an innovative strategy for modeling orthogonal friction and continuous wear in non-homogeneous liners is presented. This approach has the potential to overcome experimental limitations and significantly expedite liner design and cost-effective validation. The initial step involves establishing a mesoscopic voxel-based planar model of the liner that maintains the topological relationship during wear processes. This is achieved by introducing a circular voxel mesh and spatial transformation methods. Based on orthogonal friction and wear assumptions, separate constitutive models for orthogonal friction and wear are developed. Using the CETR UMT-3 friction and wear testing machine, GCr15 is selected as the counterface material, the pin disc wear method is adopted to conduct sliding test on PTFE and Kevlar fibers, and the required wear constitutive parameters are fitted. Furthermore, incremental equations for the total wear are derived. An element wear fusion strategy is introduced. This approach leads to the development of a continuous wear algorithm for liners and subsequently to the establishment of a voxel-based finite element model with continuous wear capability in the form of a circular voxel grid. This method transcends experimental methods and allows for the determination of the mesoscopic contact pressure, stress distribution, and variations in the contact material composition patterns of liner. The accuracy of the average macroscopic wear prediction is validated experimentally. This method has the potential for practical applications in bearing design.

Influence of Temperature and Bedding Planes on the Mode I Fracture Toughness and Fracture Energy of Oil Shale Under Real-Time High-Temperature Conditions

The anisotropic fracture characteristics of oil shale are crucial in determining reservoir modification parameters and pyrolysis efficiency during in situ oil shale pyrolysis. Therefore, understanding the mechanisms through which temperature and bedding planes influence the fracture behavior of oil shale is vital for advancing the industrialization of in situ pyrolysis technology. In this study, scanning electron microscopy (SEM), CT scanning, and a real-time high-temperature rock fracture toughness testing system were utilized to investigate the spatiotemporal evolution of pores and fractures in oil shale across a temperature range of 20–600 °C, as well as the corresponding evolution of fracture behavior. The results revealed the following: (1) At ambient temperature, oil shale primarily contains inorganic pores and fractures, with sizes ranging from 50 to 140 nm. In the low-temperature range (20–200 °C), heating primarily causes the inward closure of inorganic pores and the expansion of inorganic fractures along bedding planes. In the medium-temperature range (200–400 °C), organic pores and fractures begin to form at around 300 °C, and after 400 °C, the number of organic fractures increases significantly, predominantly along bedding planes. In the high-temperature range (400–600 °C), the number, size, and connectivity of matrix pores and fractures increase markedly with rising temperature, and clay minerals exhibit adhesion, forming vesicle-like structures. (2) At room temperature, fracture toughness is highest in the Arrester direction (KIC-Arr), followed by the Divider direction (KIC-Div), and lowest in the Short-Transverse direction (KIC-Shor). As the temperature increases from 20 °C to 600 °C, both KIC-Arr and KIC-Div initially decrease before increasing, reaching their minimum values at 400 °C and 500 °C, respectively, while KIC-Shor decreases continuously as the temperature increases. (3) The energy required for prefabricated cracks to propagate to failure in all three directions reaches a minimum at 100 °C. Beyond 100 °C, the absorbed energy for crack propagation along the Divider and Short-Transverse directions continues to increase, whereas for cracks propagating in the Arrester direction, the absorbed energy exhibits a ‘W-shaped’ pattern, with troughs at 100 °C and 400 °C. These findings provide essential data for reservoir modification during in situ oil shale pyrolysis.

Research on orthotropic anisotropy characteristics of thick bedded limestone based on in situ deformation tests

The orthotropic anisotropy of sedimentary rocks has a significant impact on the force and deformation behavior of the project. In this paper, radial pressurization tests were carried out in the borehole in a typical northern karst area to obtain the deformation properties and orthotropic anisotropy of the rock masses. The test results showed that the deformation modulus and elastic modulus of the limestone rocks in the dam site area obeyed normal distribution. The deformation modulus was basically larger than the proposed deformation modulus of Class II rocks (10 GPa). The deformation behavior and anisotropy degree of the limestone showed a weak correlation with the elevation, but a strong correlation with the development density of the rock joints. The larger development density of the rock in the right bank test section leads to a larger degree of orthotropic anisotropy and frequency of occurrence.

A triangular acoustic emission source location method considering its anisotropic propagation behavior on the surface of finger-joint-laminated board

ABSTRACT To understand the anisotropic propagation characteristics of acoustic emission (AE) signals in finger-joint-laminated boards, an improved planar localization method for AE sources is proposed. Initially, the AE source was generated by the pencil-lead break (PLB) at a fixed position on the surface of the glued wood specimen, and two AE sensors were arranged in different directions at a fixed distance of 60 mm, and the AE propagation velocity was calculated according to the time difference of arrival (TDOA). For clarity, the grain parallel direction was defined as 0 degrees, with velocities measured every 10 degrees through a counterclockwise rotation. Using these measurements, two angular anisotropic wave velocity models were developed. Subsequently, three AE sensors arranged linearly on the specimen surface pinpointed the AE source’s location. This source location problem was formulated as a multi-parameter optimization model, constrained by the geometric relationships between the AE source and the sensors. A particle swarm optimization (PSO) algorithm was utilized to estimate the AE source’s angles relative to each sensor. The findings indicate that the located AE sources deviated by 6.0–19.0 mm from the predetermined PLB positions, with inaccuracies largely attributed to the anisotropic AE wave velocity models’ precision.

Study on the uniaxial tensile mechanical behavior of two-dimensional single-crystal aluminum nitride

Abstract To investigate the tensile behavior and mechanical properties of single-crystal aluminum nitride (AlN) at the microscopic level, molecular dynamics simulations were used to study the effects of crystal orientation, strain rate, environmental temperature, and hole defect size on fracture strength, fracture mechanism, and potential energy during uniaxial tensile. The results show that the tensile strength of AlN in the [100] crystal direction is stronger. The anisotropic behavior characteristics of Al-N bonds fracture mechanism, crack growth rate, and cracking degree are significant when stretched along the [100], [010], and [110] crystal directions. Under high temperature condition, the lattice structure undergoes changes, causing grain boundaries to move and slip. This facilitates the breaking of bonds, leading to a decrease in tensile strength and a reduction in stored potential energy. Hole defects cause more lattice damage, reducing the energy required for Al-N bonds breakage and facilitating the propagation of microcracks. Additionally, it was found that the strain rate affects the stress-strain behavior of the model. An increase in strain rate leads to an increase in breaking stress, and the rapid deformation of AlN results in more energy being stored in the lattice in the form of potential energy. Therefore, the tensile strength and potential energy are improved.

Insights into anisotropic compression characteristics of unsaturated compacted GMZ bentonite

Insights into anisotropic compression characteristics of unsaturated compacted GMZ bentonite

Interfacical polarization dominant rGO aerogel decorated with molybdenum sulfide towards lightweight and high-performance electromagnetic wave absorber

Lightweight reduced graphene oxide aerogel (rGO) has obtained enormous attention as microwave absorber due to anisotropic characteristics in their structure and electromagnetic parameters. However, the controllable preparation of reduced graphene oxide (rGO) aerogels with tailored multidimensional structure with broadened effective absorption bandwidth is a thorny difficulty. In this paper, rGO aerogel decorated with molybdenum sulfide (rGO/MoS2) with three-dimensional (3D) layered porous structure were synthesized by a two-step hydrothermal method. The unique three-dimensional layered porous structure of graphene aerogel not only effectively avoids the stacking of graphene flake layers, but also provides space for the loading of MoS2 nanosheets. The introduction of MoS2 nanosheets compensates for the imbalance of impedance matching caused by graphene due to the excessive conductivity, and the folded MoS2 nanosheets are uniformly loaded on the graphene lamellae, which is conducive to generate multiple reflections and scattering of electromagnetic waves. Besides, the construction of heterogeneous interfaces strengthens the interfacial polarizability of the composites. As a result, excellent electromagnetic wave attenuation properties were obtained for rGO/MoS2, and the effective absorption bandwidth (EAB) reached 6.56 GHz at 2.1 mm. In addition, the radar cross section (RCS) simulation results further demonstrate the dissipation capability of the composite in practical application scenarios. This paper provides a new idea for the design of lightweight EM wave absorbing materials with broad absorption bandwidth.

The Impact of Hydrostatic Pressure on the Structural, Mechanical, Thermal, and Optoelectronic Characteristics of the RbV3Sb5 Kagome Compound: Ab initio Approach.

We studied the RbV3Sb5 kagome compound's structural, mechanical, thermal, and optoelectronic properties. Mulliken and Hirshfeld population analysis found ionic and covalent connections in RbV3Sb5. The Born stability criterion shows that pure RbV3Sb5 is mechanically stable. The precise measurement of 3.96 indicates that our sample has higher machinability at 20 GPa. Low anticipated hardness of RbV3Sb5 suggests it can be used as a soft solid lubricant. Hardness ratings rise with pressure, however there are exceptions. Pressure causes large nonmonotonic changes in RbV3Sb5's anisotropic characteristics. A comparable 20 GPa Zener anisotropic value, RbV3Sb5 has the highest. The structure's projected Debye temperature at 0 GPa is 284.39 K, indicating softness. Dispersion curves with negative frequencies suggest ground state structural dynamical instability. The structure has no negative-energy phonon branches under 10 GPa stress. From band structure and density of state analysis, the structure behaves metallically under hydrostatic pressure. Also, the structure has maximal ultra-violet conductivity and absorption. The absorption coefficient, conductivity, and loss function plots show uniform patterns at all pressures. As pressure rises, these graphs' peaks blue shift.

Highly Polarization‐Sensitive Solar‐Blind Ultraviolet Photodetection Based on 1D Rb2CuCl3 Microwires

AbstractPolarization‐sensitive solar‐blind ultraviolet (UV) photodetectors are essential in both civilian and military applications. 1D perovskites derivative Rb2CuCl3 holds promise for polarization‐sensitive solar‐blind UV photodetectors due to its wide direct bandgap, anisotropic crystal structure, and long carrier lifetime. However, no studies on the polarization properties of Rb2CuCl3 are reported. Here, the electronic structural anisotropy of Rb2CuCl3 is confirmed by calculating the partial charge density distribution in the ac‐plane and bc‐plane. Then, the Raman‐active modes and corresponding atomic vibration modes are explored within the bc‐plane through joint experimental and theoretical Raman spectroscopy. Besides, angle‐resolved Raman, photoluminescence, and absorption spectroscopy reveal the intriguing anisotropic photoelectric characteristics of Rb2CuCl3 microwires (MWs). By using single Rb2CuCl3 MW as the photoactive layer, a polarization‐sensitive solar‐blind UV photodetector is fabricated, showing high photoresponsivity of 78 mA W−1 and photocurrent anisotropy ratio of ≈1.7 at 265 nm. Importantly, the proposed photodetectors without encapsulation exhibit excellent stability in ambient air, retaining the original photocurrent after two months, showcasing practical applicability. This study underscores the promise of Rb2CuCl3 for high‐performance polarization‐sensitive solar‐blind UV photodetectors, contributing valuable insights into its electronic structure, photoelectric properties, and practical applicability.

Molybdenum-Modified Niobium Oxide: A Pathway to Superior Electrochromic Materials for Smart Windows and Displays

Electrochromic materials enable the precise control of their optical properties, making them essential for energy-saving applications such as smart windows. This study focuses on the synthesis of molybdenum-doped niobium oxide (Mo-Nb2O5) thin films using a one-step hydrothermal method to investigate the effect of Mo doping on the material’s electrochromic performance. Mo incorporation led to distinct morphological changes and a transition from a compact granular structure to an anisotropic rod-like feature. Notably, the MN-3 (0.3% Mo) sample displayed an optimal electrochromic performance, achieving 77% optical modulation at 600 nm, a near-perfect reversibility of 99%, and a high coloration efficiency of 89 cm2/C. Additionally, MN-3 exhibited excellent cycling stability, with only 0.8% degradation over 5000 s. The MN-3 device also displayed impressive control over color switching, underscoring its potential for practical applications. These results highlight the significant impact of Mo doping on improving the structural and electrochromic properties of Nb2O5 thin films, offering improved ion intercalation and charge transport. This study underscores the potential of Mo-Nb2O5 for practical applications in energy-efficient technologies.