To increase the hit efficiency and lethality of a flight vehicle, it is necessary to consider the vehicle’s guidance law concerning both impact time and angle constraints. In this study, a novel and straightforward impact time and angle control guidance law that is independent of time-to-go and small angle approximations is proposed with two stages using a data-driven method and proportional navigation guidance. First, a proportional navigation guidance-based impact angle control guidance law is designed for the second stage. Second, from various initial conditions on the impact angle control guidance simulation with various initial conditions, the input and output datasets are obtained to build a mapping network. Using the neural network technique, a mapping network model that can output the ideal flight path angle in flight is constructed for impact time control in the first stage. The proposed impact time and angle control guidance law reduces to the proportional navigation guidance law when the flight path angle error converges to zero. The simulation results show that the proposed guidance law delivers excellent performance under various conditions (including cooperative attack) and features better acceleration performance and less control energy than does the comparative impact time and angle control guidance law. The results of this research are expected to supplement those exploring various paradigms to solve the impact time and angle control guidance problem, as concluded in the current literature.