Andesitic Melts Research Articles

Features of crystallization of andesite melt at moderate hydrogen pressures (experimental study)

Features of crystallization of andesite melt at moderate hydrogen pressures (experimental study)

Forearc magmatism in the Pannonian basin recorded by metasomatised skarnoid xenoliths in Pliocene basalt (Novohrad-Gemer Volcanic Field, Slovakia)

Anorthite-diopside-spinel-forsterite xenoliths occur in basaltic lava flow in northern part of the Pannonian basin in the Novohrad-Gemer Volcanic Field (NGVF). Several lines of geochemical evidence suggest that the typical skarn assemblage originated by multiple carbonatitic and alkaline silicate metasomatism of pristine basalt to picrobasalt protolith rather than by the modification of crustal carbonates around shallow magma chambers. Interaction with mantle-derived magnesite or dolomite carbonatite melt triggered the crystallization of neoformed forsterite at the expense of primary clinopyroxene. The alkaline silicate metasomatism resulted in the replacement of primary diopside and augite by neoformed aegirine and aegirine-augite accompanied by amphiboles (richterite, katophorite, arfvedsonite). Weakly metasomatised Group 1 xenoliths retained their fore-arc magmatic geochemical signatures: flat REE patterns, low concentrations of high-field strength elements (Ti, P, Zr) and Ni compared to MORB, low ratios of highly-to-less incompatible elements (Ti/V, Zr/Y) relative to MORB, low Na2O, low total REE, and supra-subduction affinity of primary clinopyroxenes, being thus analogues to fore-arc basalts (FAB). In contrast, strongly metasomatised Group 2 xenoliths exhibit LREE-enriched patterns sub-parallel with those of host trachybasalts. Some Group 1 xenoliths also exhibit large positive Eu anomalies and strongly depleted signatures diagnostic of low-pressure plagioclase-pyroxene cumulates. One xenolith with complementary negative Eu, Sr and positive Rb anomalies has been identified as high-Mg basaltic andesite melt residuum. Sr and Nd isotopes plot along the OIB-MORB array. The Group 1 converges at initial 87Sr/86Sr and 143Nd/144Nd ratios of 0.7038–0.7041 and 0.5127–0.5128, respectively, thus recording a 140–190 Ma old mantle source. Thermobarometry data on metasomatically unmodified pyroxenes have been arranged along decompression cooling trend, propagating from ∼1230 °C and ∼ 1 GPa and ending at ∼1160 °C around atmospheric pressure. The maximum pressure indicates the melt generation zone ∼35 km deep, reflecting thin lithospheric mantle. The FABs identified for the first time in the AlCaPa megaunit corroborate the affinity of the NGVF lithospheric segment to Dinarides.

Electrical conductivity of anhydrous and hydrous gabbroic melt under high temperature and high pressure: implications for the high-conductivity anomalies in the mid-ocean ridge region

Abstract. The electrical conductivity of gabbroic melt with four different water contents (i.e., 0 %, 2.59 wt %, 5.92 wt %, and 8.32 wt %) was measured at temperatures of 873–1373 K and pressures of 1.0–3.0 GPa using a YJ-3000t multi-anvil high-pressure apparatus and Solartron-1260 impedance spectroscopy analyzer. At a fixed water content of 2.59 wt %, the electrical conductivity of the sample slightly decreased with increasing pressure in the temperature range of 873–1373 K, and its corresponding activation energy and activation volume were determined as 0.87 ± 0.04 eV and −1.98 ± 0.02 cm3 molec.−1, respectively. Under the certain conditions of 873–1373 K and 1.0 GPa, the electrical conductivity of the gabbroic melts tends to gradually increase with a rise in water content from 0 wt % to 8.32 wt %, and the activation enthalpy decreases from 0.93 to 0.63 eV accordingly. Furthermore, functional relation models for the electrical conductivity of gabbroic melts with variations of temperature, pressure, and water content were constructed at high-temperature and high-pressure conditions. In addition, the dependence relation of the electrical conductivity of melts with the degree of depolymerization was explored under conditions of four different water contents at 1373 K and 1.0 GPa, and three previously available reported results on those of representative calc-alkaline igneous rock melts (i.e., dacitic melt, basaltic melt, and andesitic melt) were compared in detail. In combination with our presently acquired electrical conductivity data on gabbroic melt with four different water contents and the available data on polycrystalline olivine, the electrical conductivity of a gabbroic melt–olivine system with variation of the volume percentage of anhydrous and hydrous melts was successfully constructed by using the typical Hashin–Shtrikman upper-bound model. In light of the electrical conductivity of the gabbroic melt–olivine system with previous magnetotelluric (MT) results, we find that anhydrous and hydrous gabbroic melts can be employed to reasonably interpret the high-conductivity anomalies in the Mohns Ridge of the Arctic Ocean.

Magnesian Andesites from Kibblewhite Volcano in the Kermadec Arc, New Zealand

Abstract Primary andesitic magmas could be an important component of arc magma genesis and might have played a key role in the advent of continents. Recent studies hypothesized that primary andesitic magmas occur in the oceanic arc, where the crust is thin. The Kermadec arc has the thinnest crust among all the studied oceanic arcs (<15 km in thickness); however, there are no studies that corroborate the formation of primary andesitic magmas in the arc. The aim of this study is to develop a better understanding of primary andesites in oceanic arcs through the petrology of the Kermadec arc. Here, we present the petrology of volcanic rocks dredged from the Kibblewhite Volcano in the Kermadec arc during the R/V SONNE SO-255 expedition in 2017. Magma types range from andesite to rhyolite at the Kibblewhite Volcano, but basalts dominate at the neighboring cones. This study focuses on magnesian andesites from the northeastern flank of this volcano. The magnesian andesites are nearly aphyric and plagioclase free but contain microphenocrysts of olivine (Fo84–86) and clinopyroxene (Mg# = 81–87). Using olivine addition models, the primary magmas were estimated to contain 55–56 wt % SiO2 and 10–12 wt % MgO, similar to the high-Mg andesites observed in other convergent plate margins, indicating the generation of primary andesitic magma beneath the Kibblewhite Volcano. The trace element and isotopic characteristics of the magnesian andesites are typical of volcanic rocks from the Kermadec arc. This indicates that the subduction of a young plate or melting of a pyroxenitic source is not necessary to produce magnesian andesites. Instead, we propose that the magnesian andesites were produced by the direct melting of the uppermost mantle of the Kermadec arc. The thin crust of the Kermadec arc should yield low-pressure conditions in the uppermost mantle, allowing the sub-arc mantle to generate primary andesitic melts. This study supports the hypothesis that primary andesitic magmas generate in the arc where the crust is thin and provides a new insight into the magma genesis of the Kermadec arc.

The effect of composition, temperature and pressure on the oxidation state and coordination environment of copper in silicate melts

Copper is a redox variable element that may occur as Cu0, Cu+, and Cu2+ in the Earth’s crust. The oxidation state will affect its partitioning between coexisting minerals, melts and fluids and hence its behaviour in magmatic processes. Copper bearing silicate glasses were quenched from melts with 23 synthetic compositions (19 CaO-Na2O-MgO-Al2O3-SiO2 (CNMAS), two “granites” containing K2O ± H2O, and Fe-bearing “MORB” and “andesite”) equilibrated at oxygen fugacities (fO2), expressed in log units relative to the fayalite-magnetite-quartz (FMQ) buffer, ranging from −0.7 to 14, temperatures from 900 to 1500 °C and pressures from 0 to 2.5 GPa. Cu K-edge X-ray absorption near edge structure (XANES) spectra were recorded from the glasses and a pre-edge feature in the XANES spectra was found to scale with the proportion of Cu+. Cu+/ΣCu (where ΣCu = Cu+ + Cu2+) was quantified by fitting the intensity of the pre-edge feature as a function of fO2 to the thermodynamically expected relationship. Cu+/ΣCu was found to only weakly depend on melt composition, with more basic melts (e.g., basalts rather than granites) preferentially stabilising Cu2+. Increasing temperature stabilises Cu+, while increasing pressure had little effect on Cu+/ΣCu in CNMAS melts but preferentially stabilised Cu2+ in granite melts. Cu+/ΣCu can be predicted in silicate melts by the empirical equation:log(Cu2+/Cu+) = 0.25(ΔFMQ + 8.58 − 25050/T + 940P/T – 0.02P) − 4.73 + 5400/T + 1.99Λ + (280P – 90P2)where T is temperature in K, P is pressure in GPa and Λ is the optical basicity of the composition. The effects of fO2, melt composition, temperature and pressure on Cu+/ΣCu indicate that Cu+ will be the dominant oxidation state in terrestrial silicate melts (e.g., Cu+/ΣCu = 99% in an andesitic melt at 900 °C, 1 GPa and ΔFMQ = 1). The electron exchange reaction Cu2+ + Fe2+→ Cu+ + Fe3+ occurs on cooling and, given the abundance of Fe in natural melts, the oxidation state of Cu in natural glasses is unlikely to correspond to that in the original melt.

How is carbonate crust digested by magma?

Magma’s volatile budget depends on deep magmatic sources, the degree of differentiation and degassing conditions, and volatile input from the assimilated crust. It is, therefore, important to know the exact mechanism by which the crust is assimilated into magma to understand volatile budgets and eruption behavior. To explore reactions between carbonate, calc–silicate, or skarn xenoliths and basaltic andesite magma, we studied ten calc–silicate xenoliths from the 1994, 1998, 2006, and 2010 Merapi eruptions and four sediment samples of local Javanese carbonate crust. An in situ electron probe microanalysis of the 1994–2010 calc–silicate xenolith minerals and glasses suggests that calcite is a minor and metastable mineral phase in association with wollastonite. In addition, carbonate melts quenched to calcic glasses (32 ± 7 wt% SiO2; 38 ± 3 wt% CaO), similar to experimental glasses produced by crust–melt interaction experiments. Thermodynamic modeling using rhyolite MELTS (version 1.2.0) predicts the production of highly silicic (up to ∼84 wt% of SiO2) and CaO-rich (up to ∼25 wt%) melts during partial melting of calc–silicate material. The observed mechanism of calc–silicate xenolith assimilation is the generation of highly silicic (77 ± 4 wt% of SiO2) melts in association with idiomorphic diopside [Wo49En29; 57 ± 3 Mg# = Mg/(Mg+Fe2+)] and other calcic pyroxenes (Wo54-82 En2-21; 16–43 Mg#) due to partial melting of xenolith and incongruent dissolution reactions. We hypothesize that the rate-limiting process is the subsequent mixing of the produced crustal melts with representative resident andesitic melt (average 65 wt% SiO2) through chemical diffusion, which explains major and volatile (Cl) element contents in the Merapi glass products. In addition to high Sr contents and radiogenic 87Sr/86Sr and elevated CO2, Ba, Co, Cr, Cu, V, Zn, and Zr contents in the magmatic minerals and associated glasses, the recrystallized and residual metamorphic sphene, quartz, garnet, and apatite predicted by rhyolite-MELTS or Magma Chamber Simulator modeling during wallrock melting and residual metastable calcite and wollastonite are important tracers of calc–silicate crust assimilation. The disequilibrium process of calc–silicate crustal assimilation can, thus, be well predicted by dissolution experiments and thermodynamic modeling using rhyolite-MELTS or Magma Chamber Simulator. The rate of calc–silicate crustal assimilation is still unconstrained without adequate high-temperature kinetic time-series experiments. We predict that the crustal assimilation rate is controlled by the Si–Al diffusion and associated convection in the hydrous silicate magma.

Petrology of the 2020–21 effusive to explosive eruption of La Soufrière Volcano, St Vincent: insights into plumbing system architecture and magma assembly mechanism

Abstract The 2020–21 eruption of La Soufrière, St Vincent began with extrusion of a viscous lava dome, which was destroyed upon transition to a major explosive phase. Here we present petrological data to reconstruct the processes leading up to these events. Bulk-rock SiO 2 contents range from 52.8 to 55.4 wt%, classifying the lava and the subsequent scoria as basaltic andesite, the latter being slightly more mafic. Macrocrystal chemistry and modes (plag–cpx–opx–tmt–ol) and crystallinity (45–50 vol%) are largely identical for both phases of the eruption. Pyroxenes are homogenous and precipitated mostly from andesitic melts. Conversely, plagioclase shows strong normal zonation resulting from magma ascent and stalling at multiple crustal levels. Clinopyroxene thermobarometry reveals that crystallization predominantly took place between 8 and 13 km depth at temperatures of 997 − 35 + 18 ∘ C . A lack of evidence for mafic recharge and changes in volatile content and the omnipresence of xenoliths, suggests pre-eruptive destabilization of an andesitic–dacitic melt pocket that disrupted and entrained antecedent mush. Olivine diffusion profiles show that this interaction preceded the onset of eruption. Low dissolved sulfur contents (≤270 ppm S) place constraints on the total SO 2 gas release. Melt–mush disruption appears to be a dominant driver of eruptions at La Soufrière.

High-K andesites as witnesses of a continental arc system in the Western Alps, Italy: constraints from HFSE and Hf–Nd–Sr–Pb–O isotope systematics

Geochemical and isotopic data are presented for ~ 32 Ma-old high-K andesites and dacites from the Alpine Chain. The samples consist of plagioclase, amphibole, titanomagnetite and rare biotite and quartz. Geochemical and isotope data indicate that slab-derived fluids, sediment melts and presumably AFC processes involving continental crust played a key role in the petrogenesis of the high-K rocks. A contribution of fluids is suggested based on the overall enrichment of large-ion lithophile elements and related high Ba/La, Ba/Zr, Ba/Th, Ba/Nb and Pb/Nd, sometimes distinctively higher than average continental crust. Positively correlated Ba/Nb–Th/Nb relationships, low Ce/Pb, low Nb/U and a negative correlation of Pb isotopes with Ce/Pb and Nb/U and positive ∆ 7/4 and ∆ 8/4 values similar to GLOSS imply the additional involvement of a sediment-derived melt. Negatively correlated Nb/Ta–Zr/Hf ratios at overall low Nb/Ta (13–7.5) are best explained by parental magma differentiation involving amphibole and biotite in a continental arc system. The samples have moderately unradiogenic Nd (εNd: – 2.0 to – 6.7) and radiogenic 87Sr/86Sr isotope compositions (0.7085–0.7113), moderately radiogenic Pb isotope compositions (206Pb/204Pb: 18.50–18.72; 207Pb/204Pb: 15.59–15.65; 208Pb/204Pb: 38.30–38.67), and elevated δ18O values (+ 6.5 to + 9.1 ‰). Epsilon Hf isotope values range from + 2.5 to – 4.0. Negative εHf(t) and εNd(t) values and 206Pb/204Pb ratios are correlated with elevated K2O abundances that indicate enrichment in K2O is related to AFC processes. The offset of εHf at a given εNd points to involvement of aged garnet-bearing crustal lithologies. The latter feature is qualitatively consistent with modification of unexposed primary basaltic andesites by AFC processes involving deep crustal material. In conclusion, in an Alpine context, inferred unexposed primitive high-K basaltic to andesitic melts are generated in the mantle wedge through fluid infiltration from the descending slab where fluids may have caused also partial melting of sedimentary rocks that mixed with evolving andesite–dacite compositions towards shallow-level intrusive and extrusive rocks. High-K and related trace element and isotope features thus result from a combination of already elevated values with participation of fluids and melts and probably AFC processes.

Experimental investigation of trace element partitioning between amphibole and alkali basaltic melt: Toward a more general partitioning model with implications for amphibole fractionation at deep crustal levels

Abstract Time-series experiments were carried out in a piston-cylinder apparatus at 0.8 GPa and 1030–1080 °C using a hydrous K-basalt melt as the starting material to determine the element partition coefficients between amphibole and silicate glass. Major, minor, and trace element compositions of amphibole and glass were determined with a combination of electron microprobe and laser ablation inductively coupled plasma mass spectrometry. Results show that the main mineral phase is calcic amphibole, and the coexisting glass compositions range from basaltic trachyandesite to andesite. We estimated the ideal radius, the maximum partition coefficient and the apparent Young’s modulus of the A, M1-M2-M3, and M4-M4′ sites of amphibole. The influence of melt and amphibole composition, temperature, and pressure on the partition coefficients between amphiboles and glasses has also been investigated by comparing our data with a literature data set spanning a wide range of pressures (0.6–2.5 GPa), temperatures (780–1100 °C), and compositions (from basanite to rhyolite). Finally, we modeled a deep fractional crystallization process using the amphibole-melt partition coefficients determined in this study, observing that significant amounts of amphibole crystallization (>30 wt%) well reproduce the composition of an andesitic melt similar to that of the calc-alkaline volcanic products found in Parete and Castelvolturno boreholes (NW of Campi Flegrei, Italy).

Genesis of the Kiruna-type Nixintage iron deposit, Chinese Western Tianshan, NW China: Constrains of ore geology, geochemistry and geochronology

The Nixintage iron deposit is located in the central segment of the Awulale metallogenic belt, Chinese Western Tianshan. Iron ores are mainly hosted by andesitic tuff and andesite of the Carboniferous Dahalajunshan Formation. The paragenetic sequence includes a magmatic magnetite-apatite stage (I); a magmatic–hydrothermal stage (II), and three substages can be divided, including magnetite-albite substage (II-1), magnetite-chlorite-pyrite substage (II-2), magnetite-quartz-calcite substage (II-3); and a late hydrothermal quartz-calcite-sulfides stage (III). Anhedral, fine-grained magnetite associated with apatite in brecciated and matrix ores formed in stage I with relatively variable compositions, most probably indicate the fast crystallization under a disequilibrium condition. The high-grade magnetite orebodies mainly formed in the stage II, are featured by widespread hydrothermal mineral assemblages associated with the ores. Magnetite formed in this stage has medium-to-high concentrations of V, low-to-medium concentrations of Ti, Cr, relative depletion of Mg, Ni, K, and these data mainly plot in the Kiruna and porphyry fields of discriminant diagrams that comparable to magnetite from typical Kiruna-type iron deposits. Both stages I and II magnetites show similar wide δ18O ranges and with peak values at 6.0–10.0 ‰, heavier than typical Kiruna-type deposits, while could be attributed to the relatively low crystallization temperature inferred by microthermometric data of a previous study. The δ34S values of pyrite formed in different stages range between 0.1 and 2.4 ‰, comparable to the sulfur isotopic composition of the mantle-derived magma. These features indicate that stage I iron mineralization was generated by the extrusion of iron phosphorous oxide melts separated from the parental silicate magma. Subsequent deuteric fluids exsolved from basaltic to andesitic melts during the late stage of volcanism, generated magmatic–hydrothermal iron mineralization in stage II, and the continuous evolution of the deuteric fluids formed stage III hydrothermal veins. In summary, integrated evidence suggests the Nixintage is a Kiruna-type iron deposit.Zircon U-Pb ages of ore-hosting andesite and andesitic tuff are 317.6–314.4 Ma, and timing for iron mineralization was inferred at the same time, i.e., ca. 315 Ma. Previously published petro-geochemical data combined with our geochronological data of these rocks, suggest the ore-related volcanism in Nixintage probably originated from the partial melting of the mantle wedge modified by subducted fluids under a Late Carboniferous continental arc setting. Consequently, a genetic model for the studied deposit could be created. Furthermore, the southeast of the Nixintage nearer to the vent might have potential for prospecting large Kiruna-type iron deposits.

Petrology of the magmatic system beneath Osorno volcano (Central Southern Volcanic Zone, Chile)

Petrological studies of volcanic systems and magmatic processes provide small-scale information that are inaccessible to the current resolution of geophysical tools. In the Southern Volcanic Zone of the Chilean arc, Osorno ranks sixth in the official risk classification in a region of increasing vulnerability due to soaring human activities coupled with lahar hazard and the threat of a tsunami induced by a flank collapse. However, its magmatic system remained poorly investigated. Here, we present and integrate to existing geophysical models a comprehensive set of petrographic and geochemical data including whole-rock and mineral major and trace element analyses, associated with detailed numerical modelling to constrain the storage conditions below Osorno. To capture the full complexity of the system, over 154 samples of all known major units of the volcano have been collected. They cover a large range from tholeiitic primary basalt (Mg# = 0.72 and ≥ 50 wt% SiO 2 ) to rhyodacite (Mg# = 0.18 and ≥ 70 wt% SiO2), displaying a compositional gap within andesite (59–63 wt% SiO 2 ). This gap results either from andesitic melt thermal instability or from the interstitial melt extraction of the crystal mush. Basalt and basaltic andesite lava with plagioclase and olivine (± clinopyroxene) are dominant. Their crystallinity largely varies from 1 to 53 area % with the lowest values in the most evolved basaltic andesites. Dacites are limited to three small domes with low crystallinities between 7 and 13 area %. The presence of diktytaxitic enclaves within the dacites indicate minor mingling with a less differentiated melt. Water-bearing phases are generally absent, except for one dacite sample where few small amphibole crystals occur. Petrology, chemical data and thermobarometric results imply shallow fractional crystallization of troctolitic, gabbroic and gabbronoritic cumulates. Differentiation dominantly takes place between 2 and 3 kbar (6–10 km) and results from a water-poor (≈1 wt% H 2 O), tholeiitic parental melt. No evidence of high-pressure fractionation was observed. We interpret this differentiation depth as Osorno's main storage zone. It correlates with the depth of the intracrustal discontinuity and seismic reports below the volcano. Only the upper half of the storage zone, imaged with geophysical methods, was erupting. We suggest a comparable behavior for a potential future event. • Basalt evolves to dacite at ≈2 kbar near the depth of the intracrustal discontinuity. • Fractional crystallization dominates under water undersaturated conditions. • Petrographic observations and numerical models were integrated with geophysical data.

TWO STAGES OF THE CENOZOIC ALKALINE-BASALT VOLCANISM IN THE DARKHAD DEPRESSION (NORTHERN MONGOLIA) – GEOCHRONOLOGY, GEOCHEMISTRY, AND GEODYNAMIC CONSEQUENCES

The isotopic data showed that there are two stages distinguished in the Cenozoic history of the Darkhad depression volcanic activity, the Late Oligocene initial stage (~28.0–26.6 Ma) and the final Late Miocene – Early Pliocene stage (~5.8–4.2 Ma). It has been stated that the rocks of the initial stage are only represented by trachybasalts; however, among the final-stage basaltoids there are series of shield-volcano hawaite-basanite-phonotephrite rocks and compex trachybasaltic "valley" lava flows, the formation of which is the last stage in the territorial volcanic evolution. It has been shown that the initial-stage trachybasaltic andesites are characterized by their enrichment of TiO2, P2O5, Sr, Zn, Ga and low concentrations of Al2O3, MnO, CaO, Sc and HREE (La/Yb=27.2–30.2). Basaltoids of the final stage have a similar rare-element distribution and show an increase in the contents of TiO2, Al2O3, P2O5, LILE, HFSE, Th, U and in the degree of fractionation of REE (La/Yb from 12.2 to 20.9) towards the rocks alkalinity enhancement. Modeling of eclogite, pyroxenite and peridotite melting processes in the La/Yb – Sm/Yb system shows that trachybasaltic andesite melts could be formed at ~7–8 % melting of eclogitic matter or at ~10–11 % melting of Grt-containing pyroxenites, with trachybasalt formed at ~3 % melting of Grt-containing peridotites. The composition distribution of rocks in coordinates (Mg# – Fe/Mn) indicates that the parental magmas are the initial-stage trachybasaltic andesite magmas as well as the Early Pliocene trachybasaltic "valley" lava flows. Sr, Nd, Pb isotope characteristics of the Darkhad depression basaltoids show significant shift of isotopic ratios in time towards the relatively enriched mantle as compared with the depleted MORB mantle. The initial formation of trachybasaltic andesite melts occurred in the Late Oligicene at the pre-rift stage of the territory development involving metasomatized mantle matter, with the pyroxenite or eclogite component contained in the magma formation source. The origin of trachybasalt magmas of the final stage is associated with the processes of decompression melting of peridotites in a weakly metasomatized lithospheric mantle at the rift stage of the Darkhad structure development.

Petrogenesis of Havre Volcano in the Kermadec Arc: 2012 Eruption of a Chemically Homogeneous Rhyolite

The 2012 Havre submarine eruption produced a 1.5 km3 bulk rock volume or 0.52 km3 dense rock equivalent volume of rhyolite emplaced as minor lava flows, a field of sunken seafloor pumice, and a volumetrically dominant pumice raft. This moderately large volume of medium-K (1.4–1.6 wt% K2O) rhyolite pumice is relatively chemically homogeneous (71.5–73.0 wt% SiO2), and no trace element variation or cryptic zoning has been detected despite the textural diversity of pumice material. Radiogenic isotope ratios (87Sr/86Sr 0.703693–0.703744; 206Pb/204Pb 18.7648–18.7781; 208Pb/204Pb 38.587–38.605; 143Nd/144Nd 0.513001–0.513020) demonstrate the Havre rhyolite is sourced from mantle similar to regional eruptive products of the Kermadec arc volcanic front. Providing some further insight into the Havre magmatic system is an abundance of diverse volcanic rock fragments primarily embedded in the banded raft pumice. Embedded rock fragments represent a variety of fresh to hydrothermally altered lavas ranging in composition from basaltic to rhyolitic (50.6–72.3 wt% SiO2) and are likely sourced from varying depths within the volcanic conduit during explosive fragmentation. The diverse embedded volcanic rock fragments, therefore, represent earlier erupted lavas that constructed Havre volcano and are snapshots of the petrogenetic history of Havre. Magnesian augite in basaltic to basaltic andesite embedded rock fragments has a similar compositional range (En55Fs12Wo33 to En39Fs26Wo35) to the previously documented antecrystic clinopyroxene observed in the 2012 rhyolite pumice raft. Herein, we explain how this large volume of chemically homogeneous crystal-poor rhyolite can be generated in an oceanic arc setting based on major and trace element petrogenetic models. Rhyolite-MELTS crystal fractionation models indicate the antecrystic mineral compositions within the Havre pumice of plagioclase (An55–78), and magnesian augites (En53Fs10Wo37 to En40Fs26Wo34) are the primary phases that would crystallize in basaltic to andesitic melt compositions. Modeling indicates that the forerunner basaltic magma must be a relatively dry (∼1 wt% H20) low-K tholeiitic basalt in composition and would require ∼78% crystallization at different pressures to ultimately generate the Havre 2012 rhyolite.

Experimental Constraints on the H2O-Saturated Plagioclase Liquidus and the Storage Depth of the Izu-Oshima 1986B Basaltic Andesite Melt

High-temperature melting and crystallization experiments were carried out at pressures from 1 atm to 196 MPa and under H2O-saturated conditions on the basaltic andesite melt of the Izu-Oshima 1986B eruption (i.e., the BM melt), using a 1-atmosphere fO2-controlled furnace and an internally heated pressure vessel. These data were used to constrain the H2O-saturated plagioclase liquidus (HSPL) of the melt. The fO2 conditions were controlled by a mixed H2-CO2 gas at the Ni-NiO (NNO) buffer for the 1 atm experiments, but were not controlled for the high-pressure experiments. Plagioclase is the liquidus phase at 1 atm, whereas early saturation of Fe-Ti oxide above the plagioclase liquidus occurred in the high-pressure experiments due to the elevated fO2 conditions. The HSPL temperature decreases from 1172 ± 8°C to 1030 ± 20°C as the pressure increases from 1 atm to 196 MPa. A combination of previously proposed models for the plagioclase liquidus and melt H2O-solubility can predict the experimentally determined HSPL temperatures, even if oxidation-induced magnetite crystallization occurs. Using these models and the previously reported pre-eruptive temperature of ∼1100 ± 30°C, we estimate the pre-eruptive pressure conditions of the BM melt to be 42-32+48 MPa, which corresponds to depths of 1.9-1.4+1.9 km. The estimated depth is consistent with that of the shallow active dikes previously identified from geophysical studies, suggesting that the BM melt was derived from a small, shallow magma chamber formed in the shallow dike region.

Reconstruction of ancient volcanic complexes using magnetic signature: A case study from Cambrian andesite lava flow, Bohemian Massif

Reconstruction of the Upper Cambrian Křivoklát-Rokycany Volcanic Complex was made using anisotropy of magnetic susceptibility (AMS). The correlation of AMS with visible structures at a few sites showed that the most important and reliable information was the direction of magnetic lineation K1 that determines the direction of a lava flow. The analysis of K1 directions together with radially propagating dikes helped to determine the feeding area along the NW rim of the volcanic complex. One andesite feeder and one rhyodacite feeder were recognized with certainty. In addition, K1 directions pointed to a suspicious area with the presence of another andesite feeder in a caldera-like structure. The evaluation of data strongly suggests that magnetic susceptibility in andesite lavas increases with the distance from the feeder and also with the distance towards the upper part of the andesitic lava flow. We suggest that this might be related to the degree of oxidation of the lava flow before solidification as a reaction with oxygen in the atmosphere. Oxygen can react with FeO in the andesite melt, which consequently results in the formation of magnetite.

Making Andesites and the Continental Crust: Mind the Step When Wet

ABSTRACT Andesites are iconic of subduction zone magmatism. Yet intermediate magmas (57–66 wt % SiO2) are less abundant than generally thought in arc settings. A comparison of experimental hydrous liquid lines of descent, melt inclusions and bulk-rock compositions demonstrates the importance of polybaric crystallization–differentiation in producing the compositional range and dictating the relative abundance of arc melts, but also highlights the preponderant role of mixing (sensu lato) in producing andesitic magmas. Based on their P2O5 contents, at least 74% of the arc magmas with around 64 wt % SiO2 are inferred to be mixing products. In addition to their surprisingly low abundance, andesitic melt inclusions are characterized by relatively low H2O, Al2O3, ± Na2O contents compared to the ranges measured in mafic and silicic melt inclusions. These compositional characteristics suggest that there is a sweet spot for the production of andesitic melts delimited by the low-pressure stability limit of amphibole (<150 MPa) and the adiabatic ascent path of mafic melts, but that this low-pressure differentiation pathway plays a minor role in the production of silicic arc magmas that principally form along high-pressure hydrous liquid line of descents (>700 MPa) before decompression. The compositional bimodality recorded by the melt inclusions and in well-preserved intra-oceanic arc crustal sections is a fundamental characteristic of differentiation in transcrustal arc magmatic systems, with important consequences for the chemical evolution of the continental crust. We propose that the overall bimodality shown by arc melts does not relate to a compositional gap in the differentiation mechanisms but results from a combination of (1) the disparity in volume of differentiated magmas produced by low and high-pressure crystallization–differentiation and (2) the strong nonlinearity of the high-pressure liquid lines of descent in composition–temperature–crystallinity space related to crystallization of amphibole-rich assemblages. In this context, the compositional characteristics shared by andesitic magmas and the continental crust principally depict the central role of mixing and mass balance processes in producing andesitic compositions. The step in differentiation efficiency encountered by hydrous magmas entering the amphibole stability field at high pressure plays an important role in defining the silicic component involved in these scenarios.

A thermodynamic model for sulfur content at sulfide saturation (SCSS) in hydrous silicate melts: With implications for arc magma genesis and sulfur recycling

Modeling the effect of H2O on the “sulfur content at sulfide saturation” (SCSS) in silicate melt is essential for the estimation of SCSS in both arc magmas and slab melts. Here we present a thermodynamic approach, in which, SCSS in hydrous silicate melt has been modeled as a combination of S dissolving as S2− and HS−/H2S, based on the sulfide capacity (CS2−) and the hydro-sulfide capacity (CHS), respectively. By adopting the thermodynamic framework of O’Neill and Mavrogenes (2002), S dissolution as HS−/H2S can be modeled in an analogous fashion to that for modeling S2− in anhydrous melt with the relation: lnHSSCSS=-ΔG°Fes-FeO/RT+lnCHS-lnaFeOmelt+lnaFeSsulfide. To obtain an expression for CHS, we compiled published experimental data on SCSS in hydrous silicate melts covering a PT range of 0.15–3 GPa and 785–1600 °C, and melt H2O contents of ∼1–13 wt%. While the contribution of S dissolving as S2− in basaltic and andesitic melts can be calculated based on the updated SCSS model for anhydrous basic melt from O’Neill (2021), S2− is considered negligible in rhyolitic and dacitic melts, i.e., when melt FeO content <∼5 wt%. We propose an expression for CHS as a function of temperature, mole fractions of cations for the normalized anhydrous melt composition, ln(XOH + XH2O), and a Na + K-Al term for alkaline-enriched rhyolitic melts. The coefficients for cation mole fractions are adopted from the expression for CS2− from O’Neill (2021); the coefficients for the 1/T and Na + K-Al terms are obtained from regression. The reproducibility of compiled SCSS values is ±50% for hydrous rhyolitic and dacitic melts, and ±10–30% for hydrous basaltic and andesitic melts, representing a significant improvement in comparison to previous models.Our model produces SCSS values for the primitive arc magmas compiled by Ruscitto et al. (2012), that are in most cases higher than the measured S contents, implying sulfide under-saturated conditions during mantle wedge melting. The contribution of H2S dissolution to the calculated SCSS values varies in a range of 70–1234 ppm, which increases with the increase of H2O content (0.3–6.2 wt%). H2S dissolution therefore contributes to the higher S content in arc basalt compared to MORB, an observation which is further corroborated by the positive correlation between H2O and S contents in primitive arc magmas. Applying our current model to experimentally produced sediment melts spanning a PT range of 690–1050 °C and 2.5–4.5 GPa, demonstrates that sediment melts, especially those of intermediate supercritical character with >25 wt% H2O and peralkaline in composition, can have high SCSS values as a result of H2S dissolution, and act as the transfer medium for S recycling between the slab and mantle wedge under reduced conditions.

Petrogenesis and tectonic implications of Tonian island arc volcanic rocks from the Gabgaba Terrane in the Arabian-Nubian Shield (NE Sudan)

• The volcanic rocks in the Gabgaba Terrane were erupted during Tonian. • The volcanic rocks have positive εHf(t) values, indicative of derivation from a juvenile arc magmatism . • The depleted mantle source was metasomatized by slab-dehydration fluids. • The primitive magma was subjected to crustal assimilation prior to eruption. • The volcanic rocks were erupted during different stage of arc maturity. An integrated study of zircon U-Pb geochronology and geochemistry together with Lu-Hf isotopes, has been carried out on basaltic andesite and andesite from the Haweit area (Gabgaba Terrane, NE Sudan) to indicate their magmatic evolution. In-situ U-Pb zircon dating yielded a weighted mean age of 752 ± 11 Ma for andesite and 773 ± 17 Ma for basaltic andesite, suggesting they were generated during Tonian. The Haweit volcanic rocks are generally sub-alkaline and tholeiitic lavas. They are characterized by low Mg# (29–44), low TiO 2 (0.70–1.41 wt%), and relatively high Al 2 O 3 (14.60–18.30 wt%) indicating that they are not a primitive melt. The nearly flat REEs pattern of the basaltic andesites indicate that they were formed in an immature island arc setting. While andesites are slightly enriched in LREE and LILEs, suggesting more mature island arc setting. The calculated Hf-T DM C (0.87–1.6 Ga) ages of zircons preclude the possibility of interaction of the parental magma with a pre-Neoproterozoic crustal source. The low (La/Yb) N (0.73–9.56) and high Zr/Nb (33–62) ratios, along with positive εHf(t) values (+1.33 to +12.5) indicate that the Haweit volcanic rocks were originated from depleted mantle with little crustal contamination. The geochemical data suggest that the parent magma of the Haweit volcanic rocks could be formed by low degree partial melting of spinel‐bearing Iherzolite depleted mantle metasomatized by slab‐derived fluids. The Haweit andesitic melts were later subjected to crustal assimilation before the final eruption of lavas during two stages of arc evolution.

Silicic magmas in the Michoacán-Guanajuato Volcanic Field: an overview about plumbing systems, crustal storage and genesis processes

The origin of silicic rocks in the Michoacán-Guanajuato volcanic field (MGVF) has been understudied since the volcanic field attracted the attention of researchers. Using geochemical, petrological and structural data from the literature, here we propose a model for the origin of silicic magmas. We found that all volcanic rocks known to date in the MGVF can be divided in 40 % andesite, 33 % basaltic andesite, 15 % basalt, 2 % trachybasalt to trachyandesite, and 10 % dacite-rhyolite. The structural systems that deformed the crust in the MGVF are NNW-SSE-oriented normal faults of the Taxco-San Miguel de Allende fault system, developed during the Oligocene, and the Morelia-Acambay fault system consisting of ENE-SSW to E-W sinistral strike-slip faults developed during the Oligocene-Miocene. In addition to bibliographic data, we present a gravimetric-magnetometric model to investigate the characteristics of the local basement where magmas acquire their final silicic composition, and a seismic tomography model to investigate the deep plumbing system that contribute to form the silicic rocks emplaced on the surface. The only report of assimilation experiments we found in the MGVF literature suggest that plagioclase and pyroxene are more easily digested than quartz by hotter magmas. The digestion of these mineral phases has a direct consequence on the generation of dacites and rhyolites. We propose that regardless of the genesis of andesitic melts, such intermediate magmas arrive to the upper-crust and are forced to evolve within local compression zones where they melt the local granitic basement and form crystal mushes. The compositional variability of silicic rocks in the MGVF is a consequence of the variable mixing between the intermediate magmas and the granitic partial melts.

A mélange contribution to arc magmas recorded by Nd–Hf isotopic decoupling: An example from the southern Qiangtang Block, central Tibet

• The Nd and Hf isotopes are decoupled in the Early Cretaceous rocks of SQB. • Partial melting of subduction mélange induced the Nd-Hf isotopic decoupling. • Mélange is an important medium for chemical exchange between crust and mantle. Subduction zones are the main sites of material exchange between the crust and mantle. Sediments subducted at these zones are widely considered to play a key role in generating arc magmas. Here we report whole-rock Nd–Hf isotopic compositions of late Mesozoic intermediate–felsic igneous rocks from the southern Qiangtang Block, central Tibet. The late Jurassic Rena Co ( ca. 150 Ma) and Jiacuo ( ca. 152 Ma) granodiorites , which were derived from ancient lower crust, show Nd–Hf isotopic coupling (Δε Hf ( t ) = 0.7–2.4). Conversely, the early Cretaceous Rena Co granodiorite porphyries ( ca. 112 Ma), which were derived from juvenile lower crust, display marked Nd–Hf isotopic decoupling (Δε Hf ( t ) = 7.5). We suggest that the juvenile crust was compositionally andesitic and similar to the Duolong andesitic rocks (118–106 Ma) of the southern Qiangtang Block, which were derived by partial melting of the mélange (a physical mixture of mid-ocean ridge basalts, subducted sediments, and mantle-wedge peridotites). A simple mixing modeling indicates that the source of the early Cretaceous Duolong andesitic rocks includes 1–2% bulk subducted sediments. The Duolong andesitic rocks also show Nd–Hf isotopic decoupling (Δε Hf ( t ) = 3.0–11.3). Furthermore, the early Cretaceous Duolong dioritic and granitic rocks, which were generated by mixing between andesitic melts and ancient-lower-crust-derived magmas, display Nd–Hf isotopic decoupling. Thus, we infer a significant contribution of mélange melting in the Nd–Hf isotopic decoupling of early Cretaceous igneous rocks of the southern Qiangtang Block.