Lunar regolith simulants from the NU-LHT series were characterized using different configurations for performing Raman spectroscopy measurements, including with different excitation wavelengths and spot sizes. This testing was performed to explore various Raman measurement configurations for analyzing lunar regolith, especially in terms of capturing distinctive fluorescence features that can provide more information about the composition of the regolith. Results obtained utilizing configurations having a 785 nm laser for excitation showed relatively narrow, intense fluorescence signals between 870-890 nm, which, to the best of our knowledge, has not been observed before in lunar regolith or lunar simulant samples. These distinctive fluorescence features, attributed to a specific rare earth element (REE) impurity, adds further support that these types of features can be utilized for identification and potentially quantification of the amount of REE or transition metal impurities in lunar regolith. Further, other aspects of these Raman instrument configurations and their advantages were explored, especially those applicable for use in a lunar environment in support of in-situ resource utilization (ISRU).