N-aryl amide bonds for peptide conformation: In the universe of peptides,theN-aryl amide bond, with its large steric and electronic effects and ability to restrain amide bond rotation, is represented as a new star. By employing N-arylation as a backbone amide modification strategy in peptides, we could unravel the different worlds of distinct and predominantly homogeneous conformations in cyclic hexa- and cyclic pentapeptides containing one or two N-aryl amide bonds. More information can be found in the Research Article by A. Dangi and U. Kiran Marelli (DOI: 10.1002/chem.202300753).