Amiata Area Research Articles

Chemical and olfactometric inventory of gaseous spot vents in Mt. Amiata volcanic-geothermal area (Italy)

Geothermal areas are typically characterised by the presence of gases and odours in the background atmosphere, stemming from natural emissions and possible mining exploitation of the area. This study presents the first olfactometric investigation of endogenous gas emissions from natural and archaeo-industrial vents in a geothermal area. Mt. Amiata is known for its complex geology and historical cinnabar mining. This study offers an inventory of spot gas emissions, not only in terms of odour and chemical concentration but also including flux data, a ground-breaking achievement in this field. The primary challenge of this investigation was estimating the emitted flow from ground holes or mine entrances, posing the risk of hazardous anoxic conditions. To address this challenge, an innovative and adaptive approach was adopted. The main breakthrough method involved the adaptation of a balometer, typically employed for indoor ventilation systems, to measure the flow of endogenous gases. Field surveys revealed odour concentrations that can exceed 106 of ouE/m3, surpassing industrial emission level considerably. Chemical concentrations, primarily consisted of CO2 (80/90 %v/v) and CH4 (∼10%v/v), providing critical insights into the global warming potential (GWP) associated with natural emissions. Moreover, these spots, often located at ground level and lacking a substantial atmospheric dilution, pose potential risks to nearby individuals, with concentrations of gases such as H2S surpassing safety thresholds. Total emissive flux of the investigated spot vents in the Mt. Amiata area, showed that the emission rate of H2S is notably substantial (55 kg/h), roughly equivalent to emissions from approximately four 20 MW geothermal plants, as along with odour emission rates in the order of 107 ouE/s. Considering the GWP derived from emitted gases, the total inventory assessment of the spot vents resulted in 36 t/h or 23 t/h CO2eq, depending on the time horizon considered (GWP20 or GWP100 respectively).

Exposure to low levels of hydrogen sulphide and its impact on chronic obstructive pulmonary disease and lung function in the geothermal area of Mt. Amiata in Italy: The cross-sectional InVETTA study.

The geothermal power plants for electricity production currently active in Italy are all located in Mt. Amiata area in the Tuscany region. A cross-sectional survey was conducted in the framework of the regional project "InVETTA-Biomonitoring Survey and Epidemiological Evaluations for the Protection of Health in the Amiata Territories", using objective measures of lung function to investigate the role of hydrogen sulphide (H2S) in affecting the respiratory health of the population living in this area. 2018 adults aged 18-70 were enrolled during 2017-2019. Home and workplace addresses of participants were geocoded. Dispersion modelling was used to evaluate the spatial variability of exposure to H2S from the geothermal power plants' emissions. We estimated average long-term historical exposure to H2S and more recent exposure indicators. Chronic Obstructive Pulmonary Disease (COPD) was defined according to the Global Initiative for Chronic Obstructive Lung Disease (GOLD). Multivariable logistic regressions were performed to investigate associations between outcome and exposure. Our findings did not showed any evidence of an association between increasing H2S exposure and lung function impairments. Some risk reductions were observed: a -32.8% (p = 0.003) for FEV1<80% and a -51.7% (p = 0.001) risk decrease for FVC<80% were associated with interquartile increase (13.8 μg/m3) of H2S levels. Our study provides no evidence that chronic exposure to low levels of H2S is associated with decrements in pulmonary function, suggesting that ambient H2S exposure may benefit lung function.

Tree-rings analysis to reconstruct atmospheric mercury contamination at a historical mining site.

Mercury (Hg) is a global environmental concern due to its toxicity (especially high in methylated form) and the long-range distribution of its gaseous elemental form (GEM). Hg-contaminated areas, such as abandoned mining sites, pose intrinsic difficulties for their management and heavy monitoring costs. In these environments, plant-based solutions may play a key role in the ecosystem quality assessment and support remediation strategies, combining reliability and cost-effectiveness. In this study, we adopted a biomonitoring approach by using tree rings of four different species collected in the proximity of the mining-metallurgical area of Abbadia San Salvatore, central Italy, a major former Hg mining district whose reclamation is currently in progress. Our dendrochemical analysis was aimed at identifying the historical changes of local atmospheric Hg contamination and at singling out, for the first time in the study area, other potentially toxic elements (PTEs) associated with the past mining activity. Collected cores dated back to early as 1940 and provided the temporal patterns of atmospheric Hg emission vs the produced liquid quantities, so reconstructing the historical impact of the mining site on nearby terrestrial ecosystems and resident human population. Current GEM contamination was found about twenty times lower than that of the fully operational mine periods. From a first survey on other PTEs, thallium (Tl) and lead (Pb) appeared to be potentially associated with the mining activity, thus suggesting new working assumptions for further dendrochemical analyses and for the inclusion of Pb in human biomonitoring surveys of the Mt. Amiata area, actually not present in the control list. The results prompt a more thorough assessment by tracking for a longer time span a critical site that is an ideal open-field lab to study the ecophysiology of different tree species in relation to environmental behavior of PTEs for better-assessing wildlife and human exposures.

Long-term exposure to low-level arsenic in drinking water is associated with cause-specific mortality and hospitalization in the Mt. Amiata area (Tuscany, Italy)

BackgroundArsenic in drinking water is a global public health concern. This study aims to investigate the association between chronic low-level exposure to arsenic in drinking water and health outcomes in the volcanic area of Mt. Amiata in Italy, using a residential cohort study design.MethodsChronic exposure to arsenic in drinking water was evaluated using monitoring data collected by the water supplier. A time-weighted average arsenic exposure was estimated for the period 2005–2010. The population-based cohort included people living in five municipalities in the Mt. Amiata area between 01/01/1998 and 31/12/2019. Residence addresses were georeferenced and each subject was matched with arsenic exposure and socio-economic status. Mortality and hospital discharge data were selected from administrative health databases. Cox proportional hazard models were used to test the associations between arsenic exposure and outcomes, with age as the temporal axis and adjusting for gender, socio-economic status and calendar period.ResultsThe residential cohort was composed of 30,910 subjects for a total of 407,213 person-years. Analyses reported risk increases associated with exposure to arsenic concentrations in drinking water > 10 µg/l for non-accidental mortality (HR = 1.07 95%CI:1.01–1.13) and malignant neoplasms in women (HR = 1.14 95%CI:0.97–1.35). Long-term exposure to arsenic concentrations > 10 µg/l resulted positively associated with several hospitalization outcomes: non-accidental causes (HR = 1.06 95%CI:1.03–1.09), malignant neoplasms (HR = 1.10 95%CI:1.02–1.19), lung cancer (HR = 1.85 95%CI:1.14–3.02) and breast cancer (HR = 1.23 95%CI:0.99–1.51), endocrine disorders (HR = 1.13 95%CI:1.02–1.26), cardiovascular (HR = 1.12 95%CI:1.06–1.18) and respiratory diseases (HR = 1.10 95%CI:1.03–1.18). Some risk excesses were also observed for an exposure to arsenic levels below the regulatory standard, with evidence of exposure-related trends.ConclusionsOur population-based cohort study in the volcanic area of Mt. Amiata showed that chronic exposure to arsenic concentrations in drinking water above the current regulatory limit was associated with a plurality of outcomes, in terms of both mortality and hospitalization. Moreover, some signs of associations emerge even at very low levels of exposure, ​​below the current regulatory limit, highlighting the need to monitor arsenic concentrations continuously and implement policies to reduce concentrations in the environment as far as possible.

Community Concern about the Health Effects of Pollutants: Risk Perception in an Italian Geothermal Area.

Geothermal fluids for electricity and heat production have long been exploited in the Mt. Amiata area (Tuscany, Italy). Public concern about the health impact of geothermal plants has been present from the outset. Several factors influence the way people perceive risk; therefore, the objective of the present research is to develop indicators of risk perception and assess indices differences in relation to some questionnaire variables. A cross-sectional survey was conducted in the Amiata area on 2029 subjects aged 18-77. From the questionnaire section about risk perception from environmental hazards, four indicators were developed and analysed. A total of 64% of the subjects considered the environmental situation to be acceptable or excellent, 32% serious but reversible, and 4% serious and irreversible; as the values of the various perception indicators increased, an upward trend was observed in the averages. Risk perception was higher among women and young people, and was associated with higher education. Those who smelled bad odours in their surroundings reported higher risk perception. Furthermore, risk perception was higher in four municipalities. The results represent the basis for further investigations to analyse the link among risk perception indicators, exposure parameters, and health status.

Back-Analysis of the Abbadia San Salvatore (Mt. Amiata, Italy) Debris Flow of 27–28 July 2019: An Integrated Multidisciplinary Approach to a Challenging Case Study

On 27–28 July 2019, in a catchment of the Mt. Amiata area (Italy), an extreme rainfall induced a debris flow, which caused a channeled erosive process just upstream of the Abbadia San Salvatore village, the obstruction of a culvert at the entrance to the urban area, and the subsequent flooding of the village. In this paper, we present the back analysis of this event. The complexity of this case study is due to several peculiar characteristics, but above all, to the clogging of the culvert, a phenomenon difficult to simulate numerically. The methodology used for the reconstruction of the event is based on a multidisciplinary approach. A geological field investigation was carried out to characterize the catchment and assess the availability of debris. Then, a cascade of numerical models was employed to reconstruct the debris flow: the FLO-2D software was used to model the runoff along the hydrographic network while the mobile-bed debris flow TRENT2D model, available through the WEEZARD system, was used to quantify both the erosion and deposition processes that occurred during the event. To simulate the culvert clogging, a novel modelling procedure was developed and applied. Despite the challenging framework, the results, in terms of debris volume, erosion rates, deposition area, and timing of the culvert obstruction, agree reasonably well with the observed data. It is worth noticing that these results were obtained mainly using parameters set a priori, namely calibrated on a physical basis. This proves that the proposed methodology is robust and effective, with good predictive capability. Therefore, it may be considered, according to the European Union (EU) Flood Directive, an “appropriate practice and the best available technology that does not imply excessive costs” to support predictive hazard mapping of situations as the one here considered.

Geothermal power plants with improved environmental performance: assessment of the potential for an Italian site

Geothermal energy is a clean resource, which could significantly contribute to the reduction of greenhouse and other gas emissions by replacing fossil fuels for power generation. In many geothermal sites, the resource contains substantial Non-Condensable Gases (NCGs: CO2 and contaminants), whose emissions can be limited to developing power plant schemes suitable for complete resource reinjection. Organic Rankine or other closed-loop cycles are definitely favored in this light. This work investigates a solution for complete NCG reinjection in the liquid-dominated reservoir conditions typical of the Monte Amiata area (Italy), referring to the specific site of Torre Alfina (IT) which presents a specific attractiveness because of its high pressurization. The solution considered avoids flashing the resource and thus presents an appealing environmental performance. The power plant models include energy and exergy balances, as well as exergo-environmental analysis. The overall environmental performance is evaluated by a simplified (preliminary) Life Cycle Analysis (LCA). Different solutions are compared, considering the possibility of sub- or super-critical power cycles.

Mercury Dispersion through Streams Draining The Mt. Amiata District, Southern Tuscany, Italy

The Mt. Amiata area hosts the 3rd largest Hg district in the world, overlapping with a present-day geothermal system that is exploited for energy production. Mining activity ceased in 1980; remediation of mining areas was only partial, and is still under way. A significant transport of mercury is documented in the streams draining the district. By far the largest output occurs to the southeast in the Paglia River catchment; this river is tributary of Tiber River, the largest river of central Italy. A much smaller transport occurs to the north, in the Orcia-Ombrone catchment. Most transport is in particulate form; mercury is temporarily stored in stream and overbank sediments, and can be significantly mobilized and redistributed by extreme events such as flash floods. Transfer to the biosphere and food chain is not negligible, as some fish in Paglia and Tiber Rivers show Hg contents that may be harmful for human consumption. The overall output from the Monte Amiata district represents a significant contribution to the Mediterranean Sea budget of this metal.

Withdrawal notice to "Mt Amiata hydrothermal system (Italy): 3D geological and geothermal modeling"

In this paper, we build a subsurface model that helps us to visualize and understand the structural framework and geology, along with their interactions, in the Mt. Amiata geothermal system. Three-dimensional (3D) modeling provides the possibility of interpolating the geometry of structures, and is an effective method for understanding geological features. The 3D modeling approach is crucial for further progress in the reconstruction of the assessment of the geothermal model of Mt. Amiata. Furthermore, this model can be used as the basis for a 3D numerical thermo-fluid dynamic model of the existing reservoir(s). The integration of borehole data and the numerical modeling results allows us to reconstruct the temperature distribution in the subsoil of the Mt. Amiata area.

Updated picture of the Ligurian and Sub-Ligurian units in the Mt. Amiata area (Tuscany, Italy): elements for their correlation in the framework of the Northern Apennines

The Mt. Amiata region (Southern Tuscany, Italy) represents the southernmost area of the Northern Apennines in which different lithologies belonging to the Ligurian and Sub-Ligurian units crop out widely. This paper provides an update on the stratigraphic, paleontological and structural features of the Ligurian and Sub-Ligurian units in the Mt. Amiata area by integrating new data from the Regional Geological Mapping project with those available from the existing literature. In the study area, the Sub-Ligurian units are represented by the Canetolo unit, which comprises the middle Eocene (Zone NP15) Argille e Calcari and Vico Fms showing heteropic relationships. The Ligurian units are represented by the Ophiolitic and Santa Fiora units. The Ophiolitic unit consists mainly of Early Cretaceous Palombini Shale associated with scattered Middle-Late Jurassic ophiolites. The age of the Palombini Shale spans from late Hauterivian-Barremian Zone CC5 to Aptian Zone CC7 of SISSINGH (1977). The Ophiolitic unit overlies the Santa Fiora unit consisting of the Pietraforte Fm and Varicoloured Shales topped by the Santa Fiora Fm. The Pietraforte Fm shows heteropic relationships with the Varicoloured Shale, and both formations can be referred to the ?Aptian to middle Coniacian. The age of the Santa Fiora Fm seems to span from the late Coniacian-early Santonian (Zone CC14) to middle-late Campanian (Zones CC21-CC22). Structural analyses indicate that all the Ligurian and Sub-Ligurian units experienced complex polyphase deformation through several folding phases during the closure of the Ligurian-Piemontese oceanic basin and the subsequent continental collision, which began in the middle Eocene. The Ligurian and Sub-Ligurian units now come into contact through low-angle shear zones developed during the last deformation phase identified in these units, i.e. middle Miocene extensional tectonics. This tectonic phase produced strong delamination through low-angle faults with staircase geometry, so that not only several stratigraphic levels but also entire tectonic units were omitted. Despite the extensional tectonics, the collected stratigraphic and structural data suggest a correlation between the Ligurian and Sub-Ligurian units of the Mt. Amiata area and the units cropping out in Southern Tuscany and the Ligurian-Emilian Apennines.

The Tuscan Nappe structures in the Monte Amiata geothermal area (central Italy): a review

The present knowledge on the structures affecting the Tuscan Nappe in the Monte Amiata area is here presented, highlighting that the tectonic evolution of the area is incorporated in the inner Northern Apennines framework. In fact, field and subsurface data indicate that the Tuscan Nappe is internally characterized by tectonic doublings, occurred during the collisional stage. Subsequently, as well as in the whole southern Tuscany, Miocene extension determined the lateral segmentation of the Tuscan Nappe; in the Mt. Amiata area, it resulted in three isolated geological bodies, partly cropping out. During Pliocene, the Tuscan Nappe was cross-cut by normal to oblique faults which contributed to channel the hydrothermal fluids that gave rise to the Pleistocene Hg-Sb ore deposits and Present geothermal resources. As it regards the deformation ages, since the late Oligocene-Aquitanian Macigno Fm is involved in the thrusts, the internal stacking of the Tuscan Nappe is related to the post-Aquitanian and pre-Langhian time period, on the basis of the Langhian sediments deposited in an extensional setting and presently recognised underneath the sediments of the nearby Pliocene Radicofani extensional Basin. It is therefore concluded that the switch from compression to extension occurred in a time span encompassed between early Burdigalian and early Langhian.

Investigating fossil hydrothermal systems by means of fluid inclusions and stable isotopes in banded travertine: an example from Castelnuovo dell’Abate (southern Tuscany, Italy)

Southern Tuscany (Italy) hosts geothermal anomalies with associated widespread CO2 gas-rich manifestations and active travertine-deposing thermal springs. Geothermal anomalies have been active since the Late Miocene and have led to the formation of widespread Late Miocene–Pleistocene travertine deposits and meso- and epithermal mineralizations. This study investigates the travertine deposit exposed in the Castelnuovo dell’Abate area of southern Tuscany. Here, a fissure-ridge type travertine deposit and its feeding conduits, currently filled with banded calcite veins (i.e. banded travertine), represent a spectacular example of fossil hydrothermal circulation in the peripheral area of the exploited Monte Amiata geothermal field. The Castelnuovo dell’Abate travertine deposit and associated calcite veins were analysed to establish the characteristics of the parent hydrothermal fluids, and the age of this circulation. The focus of the study was on fluid inclusions, rarely considered in travertine studies, but able to provide direct information on the physico-chemical characteristics of the original fluid. Uranium–thorium geochronological data provided further constraints on the: (1) age of tectonic activity; (2) age of the hydrothermal circulation; and (3) evolution of the Monte Amiata geothermal anomaly. Results indicate that brittle deformation (NW- and SE-trending normal to oblique-slip faults) was active during at least the Middle Pleistocene and controlled a hydrothermal circulation mainly characterized by fluids of meteoric origin, and as old as 300–350 ka. This is the oldest circulation documented to date in the Monte Amiata area. The fluid chemical composition is comparable to that of fluids currently exploited in the shallow reservoir of the Monte Amiata geothermal field, therefore suggesting that fluid composition has not changed substantially over time. These fluids, however, have cooled by about 70 °C in the last 300–350 ka, corresponding to a cooling rate of the Monte Amiata geothermal area of about 20 °C 100 ka−1.

3D Geothermal Modelling of the Mount Amiata Hydrothermal System in Italy

In this paper we build a subsurface model that helps in visualizing and understanding the structural framework, geology and their interactions with the Mt. Amiata geothermal system. Modelling in 3D provides the possibility to interpolate the geometry of structures and is an effective way of understanding geological features. The 3D modelling approach appears to be crucial for further progress in the reconstruction of the assessment of the geothermal model of Mt. Amiata. Furthermore, this model is used as the basis of a 3D numerical thermo-fluid-dynamic model of the existing reservoir(s). The integration between borehole data and numerical modelling results allows reconstructing the temperature distribution in the subsoil of the Mt. Amiata area.

Environmental impact of electricity from selected geothermal power plants in Italy

Abstract Geothermal plants supply a significant contribution to the electricity balance from renewable sources in Tuscany. However, this electricity conversion is not exempt from environmental drawbacks. In our study, the electricity production phases of four geothermal electricity plants are analyzed by means of a careful airborne emissions assessment carried out over the entire LCA of the plants. The impact categories considered are global warming (GWP), acidification (ACP) and human toxicology (HTP). The functional unit used is 1 MWh of electric energy produced from geothermal power plants in Mount Amiata area. For the environmental impact categories considered, the impact potentials are evaluated for each of the four geothermal power plants as follows: 380–1045 kg CO2 eq/MWh for GWP, 0.1–44.8 kg SO2 eq/MWh for ACP and 1.1–31.6 kg, 1.4-DB eq/MWh for HTP. The main contributions to the impact are associated with the high content of NH3, H2S, CH4 and CO2 gases present in the effluents of each plant. The impact change in relation to the geothermal site has a strong correlation to the basin of fluid withdrawal and is related to the technologies used for pollutants depletion. In some cases the impact is higher than that found for production of electricity from fossil fuels (for example, a coal plant of comparable power).

Reflectance spectral analyses for the assessment of environmental pollution in the geothermal site of Mt. Amiata (Italy)

We studied the environmental impact of geothermal activities in the Mt. Amiata area, using on-site spectral analyses of various ecological components. Analytical techniques were based on the study of the “red-edge”, which represents the spectral feature of the reflectance spectra defined between red and infrared wavelengths (λ) within the range 670–780 nm. Since in the study area the geothermal exploitation causes the drifting of contaminants such as Hg, Sb, S, B, As and H2S (hydrogen sulfide) from power plants, the spectral response of vegetation and lichens depends on their distance from the power stations, and also on the exposed surface, material type and other physical parameters. In the present research, the spectral radiance of targets was measured in the field using an Analytical Spectral Device (ASD) Field-Spec™FR portable radiometer. Spectral measurements were made on vegetation and lichen samples located near to and far from geothermal areas and potential pollution sources (e.g., power plants), with the aim of spatially defining their environmental impact. Observations for vegetation and lichens showed correlation with laboratory chemical analyses when these organisms were under stress conditions. The evaluation of relationships was carried out using several statistical approaches, which allowed to identify methods for identifying contamination indicators for plants and lichens in polluted areas. Results show that the adopted spectral indices are sensitive to environmental pollution and their responses spatialstatically correlated to chemical and ecophysiological analyses within a notable distance.

Diagenesis versus hydrothermalism and fluid–rock interaction within the Tuscan Nappe of the Monte Amiata CO2‐rich geothermal area (Italy)

AbstractIn southern Tuscany (central Italy), deep to shallow geothermal systems were active since the Pleistocene and comprise fluids carrying variable amounts of CO2. The Monte Amiata geothermal fields include two main reservoirs: a deep one located in the Palaeozoic metamorphic succession (1300–3000 m deep) belonging to the Tuscan metamorphic ‘basement’ and a shallow one hosted in the Mesozoic sedimentary succession (500–1000 m deep) belonging to the Tuscan Nappe. Multiple sets of calcite veins were investigated in some outcrops of the Tuscan Nappe succession exposed in the Monte Amiata area and surroundings. Two main fluid systems were characterized: the former related to combined diagenetic syn‐tectonic processes from highly saline fluids after interaction with the Late Triassic evaporites (Burano Fm) and the latter related to a fossil geothermal system, Pleistocene in age, fed by low‐salinity meteoric fluids, carrying CO2, radiogenic Sr and heavy O isotopes after interaction with the subsurface rocks. Comparison with the present‐day hydrothermal fluids allowed to sketch the thermal evolution of the system from past to present. Geochemical data proved that portions of the vein–host rocks were reset after interaction with CO2‐rich fluids circulating in the past. Consequently, textural and mineralogical changes are expected to have occurred with respect to the undisturbed rock masses. Understanding these modifications, their location and extension, is a prerequisite to construct (i) geochemical models addressed to the comprehension of the diagenesis induced in sediments after long‐term CO2 storage; and (ii) geological models applied to the prediction of rock heterogeneity distribution within the upper reservoirs, characterizing the shallow (500–1500 m) geothermal systems of southern Tuscany.

Distribution of gaseous Hg in the Mercury mining district of Mt. Amiata (Central Italy): A geochemical survey prior the reclamation project

The Mt. Amiata volcano is the youngest and largest volcanic edifice in Tuscany (central-northern Italy) and is characterized by a geothermal field, exploited for the production of electrical energy. In the past Mt. Amiata was also known as a world-class Hg district whose mining activity was mainly distributed in the central-eastern part of this silicic volcanic complex, and particularly in the municipality of Abbadia San Salvatore. In the present work we report a geochemical survey on Hg0 measurements related to the former mercury mine facilities prior the reclamation project. The Hg0 measurements were carried out by car for long distance regional surveys, and on foot for local scale surveys by using two LUMEX (915+ and M) devices. This study presents the very first Hg0 data obtained with this analytical technique in the Mt. Amiata area. The facilities related to the mining areas and structures where cinnabar was converted to metallic Hg are characterized by high Hg values (>50,000ngm−3), although the urban center of Abbadia San Salvatore, few hundred meters away, does not appear to be receiving significant pollution from the calcine area and former industrial edifices, all the recorded values being below the values recommended by the issuing Tuscany Region authorities (300ngm−3) and in some cases approaching the Hg background levels (3–5ngm−3) for the Mt. Amiata area.

Modeling the dynamics of a geothermal reservoir fed by gravity driven flow through overstanding saturated rocks

We formulate a mathematical model for a geothermal basin with an idealized geometry characterized by: (1) radial symmetry around an extracting well (or a cluster of wells), (2) a relatively thin horizontal fractured layer lying underneath a low permeability, low porosity rock layer, saturated with water. Vaporization is allowed only at the boundary of the extracting well (or well cluster). The model is based on the assumption that the flow from the reservoir to the well is fed by a gravity driven flow through the overstanding rocks. Despite the various simplifying assumptions, the resulting mathematical problem is considerably difficult also because we consider the effect of thermal expansion and thermal variation of viscosity. Though there is no evidence that the assumed configuration of the basin approaches the structure of a known geothermal field, the results obtained match with surprising accuracy the data of a specific field in the Mt. Amiata area (data kindly provided by ENEL Green Power through Tuscany Region).

Sb–Hg ore deposit distribution controlled by brittle structures: The case of the Selvena mining district (Monte Amiata, Tuscany, Italy)

This paper deals with the tectonic control on the hydrothermal system that gave rise to Sb–Hg ore deposits in the Monte Amiata area that was one of the most relevant mining district for the exploitation of mercury in Italy. The study area (Selvena mining district) is located in southern Tuscany (inner Northern Apennines) one of the most important mineralized area in the western Mediterranean region. Southern Tuscany was severely affected by Middle–Late Miocene low-angle normal faults, later dissected by Pliocene–Pleistocene faults, coeval magmatism (Late Miocene–Pleistocene) and hydrothermal activity (Pliocene–Present). The Selvena mining district is located south of Middle Pleistocene Monte Amiata volcanic complex. Our structural and kinematic study is based on the integration among fieldwork, borehole and mine data. The results highlight two Pleistocene–Holocene left-lateral transtensional shear zones linked by normal faults, defining a coeval pull-apart structure. Here, the Sb–Hg mineralization, transported by meteoric hydrothermal fluids mainly, is particularly diffuse and concentrated in the cataclasites and in damage zones of the normal faults. Furthermore, a widespread mineralization also occurs in the cataclasites of Miocene low-angle normal faults. Mine evidence suggests that ore-bearing fluids percolated through structural conduits located along the fault planes and resulting parallel to the intermediate stress axis. Geological structures and ore deposit distribution are related to a single hydrothermal circuit, with meteoric water channelled to depth through conduits parallel to the intermediate stress axis of the transcurrent shear zones; then, hydrothermal fluids mainly ascended through the almost vertical deformation zones located at the intersection between normal and strike-slip faults. Thus, hydrothermal fluids permeated also the Middle–Late Miocene cataclasites. This study shed light on the relationships between geological structures and mineralization in southern Tuscany and underlines the importance to investigate mine areas to understand hydrothermal fluids path.

The structure of the Monte Amiata volcano-geothermal area (Northern Apennines, Italy): Neogene-Quaternary compression versus extension

The tectonic evolution of the Mt Amiata volcano-geothermal area is under discussion. Some authors state that this region, as well as the hinterland of the Northern Apennines, were affected by compression from the Cretaceous to the Quaternary. In contrast, most authors believe that extension drove the tectonic evolution of the Northern Apennines from the Early Miocene to the Quaternary. Field data, seismic analyses and borehole logs have been integrated in order to better define the structural features of the continental crust in the Mt Amiata geothermal area. In this paper I propose the hypothesis that the structure of the crust in the Mt Amiata volcano-geothermal area derives from two main geological processes: (1) contractional tectonics related to the stacking of the Northern Apennines (Cretaceous–Early Miocene), (2) subsequent extensional collapse of the hinterland of the mountain chain, and related opening of the Northern Tyrrhenian Sea (Early Miocene–Quaternary). Compressional and extensional structures characterise the Mt Amiata region, although extensional structures dominate its geological framework. In particular the extension produced: (a) Middle-Late Miocene boudinage of the previously stacked tectonic units; (b) Pliocene–Quaternary normal faulting which favoured the emplacement of a magmatic body in the middle-upper crust; and (c) the eruption of the Mt Amiata volcano, which gave rise to an acid and intermediate volcanic complex (0.3–0.19 Ma). The extension produced the space necessary to accommodate the Middle-Late Miocene marine and continental sediments. Pliocene and Quaternary normal and transtensional faults dissected the previous structures and influenced the Early Middle Pliocene marine sedimentation within the structural depressions neighbouring the Mt Amiata volcano. The magmatic body was emplaced at depth (about 6–7 km) during the Pliocene extension, and produced the eruption of the Mt Amiata volcano during the Late Pleistocene. This gave rise to local uplift, presently reaching about 3,000 m, as well as a negative Bouguer anomaly (−16 mgal), both centred on the Mt Amiata area. The crustal dome shows a good correspondence with the convex shape of the regional seismic marker known as the K-horizon, which corresponds to the 450°C isotherm, and the areas with greatest heat flow. This is probably a consequence of the above-cited magmatic body presently in the process of solidification. A Late Pleistocene eruption occurred along a crustal fissure striking N50° (Mt Amiata Fault), which crosscuts the crustal dome. Hydrothermal circulation, proven by the occurrence of thermal springs and gas vents (mainly CO2 and H2S), mainly occurs along the Mt Amiata Fault both in the northeastern ans southwestern sides of the volcano.